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SOIL BIOTECHNOLOGY OF IIT, BOMBAY


    Prof H.S.Shankar - hss@iitb.ac.in




     Department of Chemical Engineering
                IIT-Bombay
          Tel No 91-22-25767239,25768239
CONTENTS

• PRINCIPLES

• WATER PURIFICATION

• PROCESSING OF SOLID RESIDUES

• AGRICULTURE

• SUMMING UP
A natural water body
A natural water body
A river system once a life line now in distress due
A river system once a life line now in distress due
       to nutrient overload from agriculture
        to nutrient overload from agriculture
A natural water body in the process of decay
A natural water body in the process of decay
A natural water body converted to land due to
A natural water body converted to land due to
              nutrient overload
              nutrient overload
CO2 in the
                                         Atmosphere                              90
               6                            750
                         110               (1 1 y)
                                            - 0


                   Photosynthesis                              Respiration
                                                     50


                                                                                 CO2 Dissolved
                         Plants                           Animals
                                                                                     4,000
                          500                             100-150
                                                                                   Live 1-5
                             (50 y)                            (2 y)                   (0.2 y)


                                      Dead Organics in
                                            Soil     (1 y)
                                                                             50 - 65
                              50                          18


                    Fossil               Dead Organics
                    Fuels               Reserve in Soil                                 Quantities in 1015g
                    4,000                   1,576
                                           (300 y)


               Global Carbon Cycle (Meilli, 1995)
               Global Carbon Cycle (Meilli, 1995)
Source: Encyclopedia of Environmental Biology, Vol.1, Academy press, 1995, pp.235-248
 Source: Encyclopedia of Environmental Biology, Vol.1, Academy press, 1995, pp.235-248
ENERGY CONSUMPTION IN DIFFERENT HABITATS




   1. Water      500 kJ/g live C. yr

   2. Land       3   kJ/g live C. yr
SCHEMATIC OF WATER RENOVATION

                                     1.Raw water
Recycle (vr )        Feed (vf )      2.Raw Water slurry
                                     3. Air scrubbing
                                     4. Leachates of solids
                                     5. Waste water
                     Reactor


                C1
                          Discharge (vf )



                     C2
SCHEMATIC OF MULTISTAGE PURIFICATION


T1         R1     T2     R2        T3   R3       T4




                 R1           R2        R3




     T1          T2           T3        T4
LARGE SCALE FACILITY FOR SEWAGE RENOVATION
MAJOR CHEMICAL REACTIONS AT WORK


Respiration
(CH2ONxPySzKyQ)n + nO2 + nH2O + Micro-organisms =
                          nCO2 + 2nH2O + Mineral (N, P, S, K,Q) + Energy


Photosynthesis
nCO2 + 2nH2O + Minerals (N,P, S,K,Q) + Sunlight =
                                       [CH2ONxPySzKyQ]n + nO2 + nH2O


Chemical Mineral weathering
CO2 + H2O = HCO3 - + H+
Primary mineral + CO2 + H2O = M+n + n HCO3 - + soil/sand/clay
BIOMASS YIELD, MINERAL CONTENT, NITROGEN
CONTENT, WATER CONSUMPTION FOR SOME CROPS


       Crop          Mineral            N          Water         Yield
                      % DM            % DM       ton / ton DM ton DM / ha
     Subabul         0.5 – 0.8        Small          50           20
    Sugarcane        1.5 – 2.0        Small          400          18
       Corn          5.0 – 6.0       0.3 – 0.5       200          14
      Wheat            9 – 11        0.3 – 0.5       600          12
       paddy          18 - 20        0.3 – 0.5      1000          9
                         *               *
   DM – Dry Matter
   Yield is total biomass-grain, straw etc.
CHEMISTRY OF SBT
Respiration
(CH2ONxPySzKy)n + nO2 + nH2O = nCO2 + 2nH2O + Mineral (N, P, S, K) + Energy     (1)
Photosynthesis
nCO2 + 2nH2O + Minerals (N,P, S,K) + Sunlight =
                              [CH2ONxPySzKy]n + nO2 + nH2O (Photosynthesis)     (2)
Nitrogen Fixation
N2 + 2H2O + Energy = NH3 + O2                                   ( in soil)      (3)
N2 + 2H2O + Light = NH3 + O2                                    (in water)      (4)

Acidogenesis
4C3H7O2NS + 8H20 = 4CH3COOH + 4CO2 + 4NH3 + 4H2S + 8H+ + 8e-                    (5)

Methanogenesis
8H+ + 8e- + 3CH3COOH + CO2 = 4CH4 + 3CO2 + 2H2O                                 (6)
   Adding 5 and 6 give overall biomethanation chemistry
4C3H7O2NS + 6H20 = CH3COOH + 6CO2 + 4CH4 + 4NH3 + 4H2S                          (7)

Mineral weathering
CO2 + H2O = HCO3 - + H+                                                         (8)
Primary mineral + CO2 + H2O = M+n + n HCO3 - + soil/clay/sand                   (9)

Nitrification
NH3 + CO2 + 1.5O2 = Nitrosomonas + NO2- + H2O + H+                             (10)
NO2-+ CO2 + 0.5O2 = Nitrobacter + NO3-                                         (11)
Denitrification
4NO3- + 2H2O + energy = 2N2 + 5O2 + 4OH -                                     (12a)
NO2- + NH4+ = N2 + H2O + energy                                               (12b)
The trinity – showing importance of combining
  The trinity – showing importance of combining
organics, inorganics & suitable life forms to derive
organics, inorganics & suitable life forms to derive
                 value from wastes
                 value from wastes
ENERGY CONSUMPTION FOR FOOD CROPS


    Crop              Energy Input                        Yield          Output    Efficiency
                       M k cal / ha                      kg / ha        M cal / ha      (-)
                 Fossil Labour      Total
  Wheat
                  3.77        0.002        3.772          2284               7.5             2.2
   (USA)
  Wheat
                 0.256       0.1845       0.4405           821               2.7            6.25
  (India)
   Rice
                15.536        0.009       15.545          5796              21.0            1.35
   (USA)
   Rice
                 0.582       0.1728        0.754          1655               6.0            7.69
   (Phil)
  Potato
                  8.90        0.018         8.92         26208              20.2            2.27
   (USA)
 Cassava
                 0.016        0.385        0.401       5824 (Dry)           19.2            50.0
 (Tanga)
Source: Energy in agriculture, Lockeritz (ed.) International Congress energy in agriculture Missouri,
        1975-76
10                                                                              60

                    9
                                             Direction of
                                                                                                    50
                    8                    Increasing biological potential

                    7
                                                                                                    40
Energy efficiency




                                                                           Wheat,USA
                    6                                                      Rice,USA
                                                                           Potato,USA
                    5                                                                               30
                                                                           Wheat,India
                    4                                                      Rice,Phillipines
                                                                           Cassava,Tanga            20
                    3

                    2
                                                                                                    10
                    1

                    0                                                                               0
                         0   1.0   2.0       3.0        4.0         5.0           6.0         7.0
                                              Yield , Ton/ha



                    Yield -Efficiency correlation for some crops
                    Yield -Efficiency correlation for some crops
Organics and rock
     Organics
                                       particles




              Gut residence              Gut residence
              time: about 5 h            time: about 1 h

                                                           Refeeding


              Anaerobic                  Aerobic
              processing                 processing




   Residual                                                 Pump is
                                  Biosoil                   organism
   organics
                                incubation                  as mobile
                                                            bioreactor
  Single-pass                     Loop
  Bioreactor                    Bioreactor
(Say Red worm)             (Say Earthworm)
 Bioprocessing by the two types of organisms
 Bioprocessing by the two types of organisms
          Source: Bhawalkar (1996)
           Source: Bhawalkar (1996)
ECO-ENERGETICS OF AN EARTHWORM (Lavell, 1974)

 Fresh Weight mg/individual                    1025
 Ingestion (J/g.d)                             1570
 Assimilation (J/g.d)                          140
 Production (J/g.d)                            10
 Respiration (J/g.d)                           130
 Egestion (J/g.d)                              1430


EXPONENTIAL GROWTH OF BACTERIA IN EARTHWORM GUT
(no. in million) (Parle, 1959)
                             Forgut   Midgut          Hindgut

All Bacteria                 475      32900           440900
Actinomycetes                26       358             15000
11

                 Optimum       Fly Larvae
      9


             Optimum       Earthworm
      7                                                     Mosquito
                 Termite      Cockroach                     Fly
pH




                                                            Redworm
      5                Rats, ants



      3
                                            Potworm


      1


            20        40        60          80        100
                               Moisture (%)

          Niches of Earthworms and Pests (Bhawalkar, 1996)
A picture of red worms – r selected organisms in
A picture of red worms – r selected organisms in
               waste environment
                waste environment
EXPERIMENT
                 SET -UP


                       E(theta) vs theta

           0.008
           0.007
           0.006
           0.005
E(theta)




           0.004
           0.003
           0.002
           0.001
              0
                   0         1             2   3
                                 theta



           Concentration vs Time Plot
TWO CHANNEL MODEL




α = fraction of holdup in the macrochannel
β = fraction of tracer that enters the macrochannel
TWO CHANNEL MODEL

                       ⎛ ⎛ βθ 1 ⎞ 2 ⎞                     ⎛ ⎛ (1 − β )θ ⎞ 2 ⎞
                       ⎜ ⎜1 −     ⎟ ⎟                     ⎜ ⎜1 −         2
                                                                           ⎟ ⎟
         β2   1        ⎜ ⎝    α ⎠ ⎟ (1 − β )
                                             2
                                                 1        ⎜ ⎜ ⎝  (1 − α ) ⎟ ⎟
                                                                           ⎠
E (θ ) =           exp ⎜ −            +
                                    ⎟ (1 − α )        exp ⎜ −                ⎟
         α    πθ 1           4θ 1                πθ 2             4θ 2
            2          ⎜            ⎟          2          ⎜                  ⎟
                       ⎜     Pe1    ⎟                     ⎜       Pe2        ⎟
              Pe1      ⎝            ⎠            Pe2      ⎝                  ⎠



  τ1   =
         α
           τ         τ2 =
                          (1 − α ) τ                 θ1 =
                                                            t
                                                                 θ2 =
                                                                        t
         β                (1 − β )                          τ1          τ2


                          β         (1 − β ) Pe
                     Pe1 = Pe Pe2 =
                          α         (1 − α )
THEORETICALLY CALCULATED PARAMETERS

                    RT λio
Diffusivity       D= 2          = 1.9 * 10-5 cm/s2
                    F zi

                         3μ Q
 Film Thickness   δ =3          = 0.1 mm
                         ρgW

                        uL
 Peclet Number     Pe =         = 6 - 14
                        D
C (th e ta ) ve rsu s th e ta
                 1 .4
                                                                                  Exp
                                                                                  Mo d e l

                 1 .2




                   1




                 0 .8
      C(theta)




                 0 .6




                 0 .4




                 0 .2




                   0
                        0   0 .5   1              1 .5                 2   2 .5              3
                                                 th e ta




RTD Plot of normalized concentration (C/Co) vs. Time for 2m soil filter
RTD Plot of normalized concentration (C/Co) vs. Time for 2m soil filter
 showing fit to Dispersion model equation (8) for Run 2a (22.3 cm/h)
  showing fit to Dispersion model equation (8) for Run 2a (22.3 cm/h)
              with fitted parameters α=0.67, β=0.9, Pe=9
               with fitted parameters α=0.67, β=0.9, Pe=9
EXPERIMENT AND THEORETICAL PARAMETERS

      Run No         Q                τ                   α               Pe
                  (ml/min)          (min)
        I           95              155                  0.73             12.1
        II          100             153                  0.69             18.3
        V           125             133                  0.63             9.7
       III          155             102                  0.75             10.1
       VI           182              91                  0.68             12.3
       IV           200              90                  0.68             11.5

Run       Q           τ        δ           H       A                u            Pe
No     (ml/min)     (min)    (mm)         (lit)   (m2)            (m/s)
 I           95     155      0.06         14.72   245           6.46 ×10-9       6.1
II          100     153      0.06         15.3    255           6.53 ×10-9       6.2
V           125     133      0.07         16.62   237           8.79 ×10-9       8.4
III         155     102      0.07         15.81   226           11.4 ×10-9       10
VI          182      91      0.08         16.56   207           14.6 ×10-9       13.9
IV          200      90      0.08           18    225           14.8 ×10-9       14.1
RTD Plot of normalized concentration (C/Co) vs. Time for soil filter
 RTD Plot of normalized concentration (C/Co) vs. Time for soil filter
showing fit to Dispersion model equation (8) for Run 2a (22.3 cm/h)
 showing fit to Dispersion model equation (8) for Run 2a (22.3 cm/h)
          with fitted parameters α=0.25, β=0.68, Pe=0.83
           with fitted parameters α=0.25, β=0.68, Pe=0.83
Plot of normalized concentration (C/Co) and RTD function E (t) vs.
 Plot of normalized concentration (C/Co) and RTD function E (t) vs.
Time for soil filter showing fit to Dispersion model equation (8) for
 Time for soil filter showing fit to Dispersion model equation (8) for
Run 1a (7.2 cm/h) with fitted parameters α=0.09, β=0.40, Pe=0.89
 Run 1a (7.2 cm/h) with fitted parameters α=0.09, β=0.40, Pe=0.89
1000

                          Equipment : Pheretima Biofilter
                          Intial loading on bed =24.4gmCOD/L
                          Restoration rate constant I stage =0.2 /h
                           Restoration rate constant II stage =0.11/h



                500
ORP, milivolt




                                                                        ORP data (Probe 9, Depth:-2.5cm)

                                                                        Fit to model Eqn 3.6.13 & 3.6.14

                  0




            -500
                      0
                                       50                100              150                 200
                                                         Time,h




        ORP (Reference calomel electrode+244 mV) restoration
         profile showing fit to model Pattanaik, B.R. (2000)
PHYSICAL MASS TRANSFER
                      7



                      6



                      5
Dissolved O2, mg/L.




                                                                Pheretima biofilter
                      4
                                                                T = 30.2 C
                                                                vs = 7.2 cm/h
                                                                CI = 1.8mg/L
                      3
                                                                Ce = 6.8 mg/L
                                                                Run : OTR 14
                                                                     Experimental data
                      2
                                                                     Fit to model



                      1



                      0
                          0       20          40          60             80              100     120
                                                       Time, min
                      Variation of outlet O2 concentration with time as per single cell model
                       Variation of outlet O2 concentration with time as per single cell model
                                                  Pattanaik.,(2000)
                                                   Pattanaik.,(2000)
PHYSICAL MASS TRANSFER




            8
            6
DO (mg/L)




                                                                120 ml/min
            4
                                                                250 ml/min
            2
            0
                0          20        40       60        80
                                Time (Mins)



                    Variation of outlet O2 concentration with time,
                                 Sathyamoorthy(2006)
COD REMOVAL


              600
              500
COD (m g/l)




              400
              300                                  150 ml/min
              200
              100
                0
                    0   2    4        6   8   10
                              Time (hr)


         COD concentration with Time Kadam.(2005)
COMPARISON OF AIR TO WATER OXYGEN
          TRANSFER COEFFICIENTS



Agitated & sparged vessels 10-3 to 10-2 /sec
  This work                   5 x 10-3/sec

  Quiescent fluids           10-5/sec
GOVERNING EQUATIONS
                         ∂ρ
1. Continuity Equation      + ∇ ⋅ (ρ v ) = 0
                         ∂t
2. Momentum balance
        ( )
     ∂ ρv
            + ∇ ⋅ ( ρ v v ) = −∇ p + ρ g + F
       ∂t
From Darcy’s Law
                       μ
                    F=− v
                       α                    Rate equations for substrates
                                           Substrate   Description     Rate Equation
3. Species Transport Equation
                                           COD         Mass Transfer   Kac(C1-C1*)
 ∂Ci
  ∂t
           ( )
     + ∇ ⋅ vCi + ∇.(Di ,m∇Ci ) − R i = 0   COD         Oxidation       KcCs
                                           NH4+-N      Mass Transfer   Kan(C2-C2*)

4. conc. balance in holding tank           NH4+-N      Nitrification   KNN s
                  dS2
               τh     = S1 (t) − S2 (t)
                  dt
1.2

                                                                   C2/C20 fit to Eq.3.4.7, Run 2b
                                                                   Exptl data, C2/C20, Run 2b
          1                                                        C2/C20 fit to Eq. 3.4.7, Run 3b
                                                                   Exptl. Data, C2/C20, Run 3b


         0.8
C2/C20




         0.6




          0.4

                            Run        Hyd.
                                      Loading rate ka
                                      (m3/m2.hr ) (hr-1)
         0.2                2b          0.6      0.22
                            3b          0.8      0.53




               0
                   0              1                2       3   4             5           6           7   8
                                                   Time,hr
                       Effect of hydraulic loading on distribution of liquid on biofilter
                       Effect of hydraulic loading on distribution of liquid on biofilter
CFD MODEL VALIDATION:
                      COMPARISON WITH EXPERIMENTAL DATA
               200                                                          6
                                                                                6
               180
                                                                            5
                                                                                5
               160




                                                       NH −N conc. (mg/L)
                                                      NH −N conc. (mg/L)
               140                                                          4
                                                                                4
COD ( mg/L )




               120
                                                                            3
                                                                                3
               100
                                                                            2




                                                      +
                                                          4
                80                                                              2




                                                        +
                                                                     4
                60
                                                                            1
                                                                                1
                40
                                                                            0
                20                                                           00     1       2           3       4       5       6
                  0    1   2          3   4   5   6                            0        1       2           3       4       5       6
                                                                                                    Time (h)
                               Time (h)                                                              Time (h)




                      Vb =13 L, Vl = 30 L, vr = 5x 10-5 m3/m2h
                 kac = 2.7 h-1, kC = 0.05 h-1, kan = 11 h-1, kN =1.5 h-1,
Comparison between Dispersion model prediction
       and reactor performance data for sewage
                                                                                             8
                  90
                   90                                                                            8

                  80
                   80
                                                                                             7
                                                                                                 7                                         Model Eq. 9 & 10
                                                Model Eq. 9 & 10                                                                            Model Eq. 9 & 10
                                                 Model Eq. 9 & 10
                  70
                   70                           Experimental                                 6
                                                                                                 6
                                                                                                                                           Experimental
                                                                                                                                            Experimental




                                                                          NH4+ N (mg/ L)
                                                 Experimental




                                                                         NH4+ - -N (mg/ L)
                  60
                   60                                                                        5
                                                                                                 5
 CO D ( g / L )




                  50
CO D ( g / L )




                   50                                                                        4
                                                                                                 4
                  40
                   40                                                                        3
                                                                                                 3
                  30
                   30                                                                        2
                                                                                                 2
                  20
                   20
                                                                                             1
                  10
                   10
                                                                                                 1

                                                                                             0
                   00                                                                            0
                                                                                                  0       1       2        3         4          5         6       7
                                                                                                      0       1       2      3         4            5         6       7
                        00    22           44            66         88                                                    Time ( h)
                                 Time (h)                                                                                  Time ( h)
                                  Time (h)


                             Model Parameters: Vb =13 L, Vl = 30 L, vr = 5.1 m3/m2 h
                                         α = 0.32, β = 0.81, εd = 0.25,
                                            Pe = 0.18, kac = 1.5 h-1, kan = 11 h-1,
DISTILLERY SPENT WASH




Before SBT Processing   After SBT Processing

  COD: 12,160mg/L          COD: 64 mg/L
COLI FORM REMOVAL

                                                        Coliform rem oval                        Total coliform
                                                                                                 fecal coliform

                        1.0E+09

                        1.0E+08
Coliform (CFU/100 ml)




                        1.0E+07

                        1.0E+06

                        1.0E+05

                        1.0E+04

                        1.0E+03

                        1.0E+02

                        1.0E+01
                                  Inf luent   E0   E1        E2              E3        E4   E5    E6      E7

                                                            R e c y c l i n g ( hr )




                           Effect of recycling on micro-organism removal;
                        E0: Effluent 0 hr, E1: Effluent 1 hr etc Kadam., (2005)
ARSENIC REMOVAL BY SOIL FILTER


• As(III) oxidation and removal As(V) via
  precipitation as ion complex with Fe(III).
• These results show that <10 ppb As are
  attained via natural oxidation and
  chemical precipitation revealing typically
  0.3 mg As (III)/lit.hr.
• These natural rates of removal sustain via
  the natural aeration of the
PROCESS DIAGRAM FOR ARSENIC REMOVAL FROM
WATER



As (III)
water               As (V)   Precipitation   Fe3++ As
           Soil                                           Filter
           Filter            Fe3+ + As




                                                        As Sludge
                                                        30 %
                                                        %Complex
ARSENIC REMOVAL IN SOIL FILTER SYSTEM
Initial As(III)=500 μg/l; Filter bed volume=17 lit;
Flow rate = 60ml/min,
Total volume of water passed per day = 30 lit, which constitute one run.

       Expt. Run No     Initial Arsenic Conc.      Residual Arsenic
                                 μg/l                    μg/l
             1                   500                       8
             2                   500                       8
             3                   500                       8
             4                   500                       8
             5                   500                       8
             6                   500                       8
             7                   500                       3
             8                   500                       6
             9                   500                       5
            10                   500                       4
            11                   500                       4
            12                   500                       4
            13                   500                       4
COMPARISON OF ARSENIC REMOVAL RATES


• Zero Valent iron 0.85 mg As/lit.hr( Leupin
  et al., 2005)
• Iron coated sand 0.75 mg As/lit.hr (Joshi
  and Chaudhari, 2004)
• Activated Alumina 0.15 mg As/lit.hr (Pant
  and Singh, 2005)
  Soil filter process 0.30 mg As/lit.hr
LAY OUT OF SBT MEDIA
Effect of Feed Distribution arrangement
           on Fluid distribution
 Contours of Velocity Magnitude (m/s)




            Fig 4a: Feed From Top surface only
 Fig 4b: Feed From Top & Slopes          vr = 0.15 m3/m2h
SBT PLANT
 TOP VIEW
PLANT ELEVATION




500 m3/day BPGC Plant for wastewater treatment
SBT PLANT




3MLD Sewage purification in Corporation Of Bombay
WATER QUALITY ANALYSIS OF SBT PLANT
           PARAMETERS       INFLUENT   EFFLUENT
Temp. (0C)                    31.4       31.3
pH                            6.91       8.26
Conductivity (micro S/cm)     2160       987
DO (mg/l)                     0.85       7.01
Turbidity (NTU)               145        5.32
COD (mg/L)                    352         64
BOD                           211        7.04
Ammonia (mg/L)                33.4       0.010
Phosphate-P (mg/L)            0.474     0.0016
SS(mg/l)                      293.3       16
Alkalinity(mg/L)              212        148
Fecal coliform(cfu/100ml)    145*105      55
Total coliform(cfu/100ml)    150*108     110
PROCESS FEATURES

•   Very low energy use intensity due to high
    Natural oxygen transfer in process. (0.06
    kWh/kL sewage).
•   Very low space intensity of 0.8-1.0 sqm/kL
    per day sewage.
•   An engineered evergreen natural process
    with no moving parts except for pumps.
•   No sludge due to ecology at work.
•   Very high bacteria, BOD, COD, suspended
    solids, colour, odour, ammonia removal.
•   Practically maintenance free.
SBT PLANT




3MLD Sewage purification in Corporation Of Bombay
SBT PLANT




3MLD Sewage purification in Corporation Of Bombay
SBT PLANT




3MLD Sewage purification in Corporation Of Bombay
SBT PLANT




Renovation of colony sewage for irrigation in sports
Renovation of colony sewage for irrigation in sports
                     complex
                     complex
REUSABLE WATER FROM WASTEWATER




  Wastewater      Treated Wastewater
SBT PLANT




Colony sewage treatment
Colony sewage treatment
  showing untreated &
   showing untreated &
      treated water
       treated water
SBT PLANT




Renovation of septic tank waste water for irrigation in a
Renovation of septic tank waste water for irrigation in a
                   Research Center
                    Research Center
SBT PLANT




Retrofitting of idle activated sludge plant
Retrofitting of idle activated sludge plant
SUMMARY OF SBT PROCESS FEATURES
     FOR SEWAGE TREATMENT

       Item                Features
   Organic loading      150-200 g / sqm.d

   Oxygen transfer      150-200 g / sqm.d

   Heat generation    600-800 k.cal / sqm.d

     Conversion            As required

  Hydraulic loading   0.05 - 0.25 cum/sqm.h

     Shear rate        0.01 – 0.1 per sec.
OPERATING FACILITIES

•   Bombay Presidency Golf Club
•   Naval Housing Colony, Bombay
•   Vazir Sultan Tobacco, Hyderabad
•   Jindal Steel, Delhi
•   Taj Kiran, Gwalior
•   IIT Bombay
•   Beru Ashram Badlapur
•   Delhi Travel Tourism Dev Corporation
•   Bombay Municipal Corporation (in progress)
•   University of Hyderabad (in progress).
SBT PLANT




Close up of solid waste processing
Close up of solid waste processing
100 m
 ORGANIC                                             ROAD
                                             2
 RESIDUE    10 m                                  Loading Rows
                                             4
 PROCESSING
                                             6




                                      ROAD




                                                                 ROAD
     Raw organics
                              5m
                                                                         300 m

1m



      Underdrain


                    Semi-processed
                       organics

         A
                                             38
                                             39
                                                     ROAD

                                     10 m                           5m
               Schematic of organic residue processing.
               Schematic of organic residue processing.
Restoration of municipal dumping grounds
Restoration of municipal dumping grounds
Processing chicken offals
Processing chicken offals
SUMMARY OF PROCESS FEATURES FOR
    ORGANIC SOLID CONVERSION

       Item               Features
   Organic loading    150-200 g / sq.m.d

   Oxygen transfer    150-200 g / sq.m.d

   Heat generation   600-800 k.cal / sq.m.d

     Conversion             20-30%

    Product Yield    0.375 – 0.500 kg / kg

      Products       fertilizer/culture/soil
Chickoo plant affected by fungal disease
Chickoo plant affected by fungal disease
Chickoo plant after restoration of soil
Chickoo plant after restoration of soil
ECONOMICS FOR SEWAGE TREATMENT

Item                   Unit                       Capacity (m3 / d)
                                    5    50 100 200 500 3,000                    10,000
1. Space              m2           40 250 400 600 1500 3500                      10000
2.Civil, mech., Elec. Rs. Mil 0.10 0.5 0.9 1.0                   1.5        12     25
3.Bioreactor          Rs. Mil 015 0.6 1.0 1.5                    2.5        17     50
Total (2 + 3)         Rs. Mil 0.25 1.1 1.9 2.5                   4.0        29     75
4. Power              Rs./d        10 100 200 400 800 1200                        4000
5. Additives          Rs./d        20 100 250 500 1250 5000                      15000
6. Staff              Rs./d       250 250 500 500 1000 2500                       5000
7. Miscellaneous      Rs./d        10    50 50 150 200                     300     500
Total (5 to 7)        Rs./d       340 600 1000 1550 3250 9000                    24500
US $ = Rs. 47.00; Power Rs. 4 per kWh ; Mil – Million; additives – Rs. 5 / kg
ECONOMICS FOR MUNICIPAL ORGANIC SOLIDS
  Item                   Unit                    Features
  Capacity               Ton/day     1      10              20      100
  Space                  Sq.m       2000   15000        20000      50000
  Civil, mech., elec.    Rs. mil    0.5     2.5             4.5     15
  bioreactor             Rs. mil    0.2     1.0             1.5     5.0
  Total (3+4)            Rs. mil    0.7     3.5             6.0     20
  production             Ton/year   150    1500             3000   15000
  Labour                 Rs./day    450    3500             5000   10000
  Power fuel             Rs./day     -       -              1000   5000
  Additives              Rs./day    400    4000             8000   20000
  Misc.                  Rs./day    50     200              500    1000
  Total (6-8)            Rs./day    850    7500         15500      36000


   mil. – million
   mech. – mechanical
   elec. – electrical
   Rs. – Rupees (1US$ = Rs.47)
APPLICATIONS
•   Rain water harvesting via storm water conservation
•   Primary purification of drinking water
•   Primary purification of swimming pool water

•   Sewage treatment for reuse in construction, cleaning &
    gardening, ground water recharge, make up water for
    swimming pools & industries etc
•   Industrial wastewater treatment,
•   Industrial air purification

•   Organic solid waste conversion
•   Municipal solid waste processing
•   Commercial production of Soil
•   Animal House waste processing
•   Hospital waste disposal
SUMMING UP


Engineered natural oxygen supply

Evergreen Environment

No moving parts

No biosludge
THANK YOU !
XRD ANALYSIS

            1400
            1200
            1000
Intensity




             800
                                                              Murram
             600
             400
             200
               0
                   0     20      40           60   80   100
                                      Angle




                   Partially weathered Rock (Murram)
XRD ANALYSIS
            1000

            800
Intensity




            600
                                                            Black soil
            400

            200

              0
                   0    20     40           60   80   100
                                    Angle




                   Artificially weathered Rock (Black soil)
XRD ANALYSIS
               1400

               1200

               1000
   Intensity




                800
                                                               Blacksoil
                600                                            Murram

                400

                200

                  0
                      0   20      40           60   80   100
                                       Angle




    Comparison of Artificially weathered Rock
(Black soil) with Murram (partially weathered Rock)
XRD ANALYSIS

            900
            800
            700
            600
Intensity




            500
                                                             Rock Powder
            400
            300
            200
            100
              0
                  0       20    40           60   80   100
                                     Angle




                      Primary mineral (Rock powder)
XRD ANALYSIS

            1200

            1000

            800
Intensity




            600                                             Redsoil
            400

            200

              0
                   0   20      40           60   80   100
                                    Angle




             Naturally weathered Rock (Red soil)
XRD ANALYSIS

              1400

              1200

              1000
  Intensity




              800                                           Rock-Powder
              600                                           Murram

              400

              200

                0
                     0   20    40           60   80   100
                                    Angle



Comparison of Primary Mineral (Rock powder) with
       Murram (Partially weathered Rock)
XRD ANALYSIS

             1400

             1200

             1000
 Intensity




              800                                           REDSOIL
              600                                           Murram

              400

              200

                0
                    0   20     40           60   80   100
                                    Angle


Comparison of Naturally weathered Rock (Red soil)
    with Murram (partially weathered Rock)
XRD ANALYSIS
                                    AW-1


            1350
            1250
            1150
            1050
Intensity




             950
             850
             750
             650
             550
             450
                   25   30    35   40      45   50   55   60   65

                                        Angle




                   Artificially weathered Rock - 1
XRD ANALYSIS

                                   AW-2


           1300

           1200

           1100

           1000
In n ity




            900
  te s




            800

            700

            600

            500
                  25   30    35   40     45   50   55   60   65
                                   Angle




                  Artificially Weathered Rock - 1
XRD ANALYSIS

                                  AW-3


           1300

           1200

           1100

           1000
In n ity
  te s




            900

            800

            700

            600

            500
                  25   30    35   40      45     50   55   60   65

                                         Angle




              Artificially Weathered Rock - 2
XRD ANALYSIS

                               AW-4


           1200

           1100

           1000
In n ity




            900
  te s




            800

            700

            600

            500
                  25     35           45   55   65
                              Angle




              Artificially Weathered Rock - 2
XRD ANALYSIS

                                  Worli pad-5

           1600


           1400


           1200
In n ity
  te s




           1000


            800


            600


            400
                  25   30    35     40    45     50   55   60   65

                                         Angle




              Artificially Weathered Rock
XRD ANALYSIS

                                  Garde n Soil


           1500

           1400

           1300

           1200
In n ity




           1100
  te s




           1000

            900

            800

            700

            600
                  25   30    35     40        45   50   55   60   65
                                         Angle




                   Artificially Weathered Rock
PATENTS AND PUBLICATIONS

1.   US Patent No: 6890438 " Process for treatment of organic wastes"
     H.S.Shankar, B.R.Patnaik, U.S.Bhawalkar, issued 10 May 2005

2.   "Process for treatment of Organic residues" India Patent Application
     MUM/384/26 April 2002, H.S.Shankar, B.R.Patnaik,U.S.Bhawalkar

3.   " Process for treatment of waste water" India Patent Application
     MUM/383/26 April 2002, H.S.Shankar,B.R.Patnaik,U.S.Bhawalkar

4.   Patnaik, B.R., Bhawalkar, U.S., Gupta, A., Shankar, H.S., “Residence
     Time Distribution model for Soil Filters, Water Environment Research,
     76(2), 168-174,2004

5.   Patnaik, B.R., Bhawalkar, V.S., Shankar, H.S., “Waste Processing in
     Engineered Ecosystems”, 4th World Congress on Chemical
     Engineering, 23-27, September 2001, Melbourne, Australia

6.   Patnaik, B.R., Bhawalkar, U.S., Kadam, A, Shankar, H.S., “Soil
     Biotechnology for Waste Water Treatment and utilization”, 13th ASPAC
     2003, International Water Works Association Conference 13-18, October,
     2003, Quezon City, Philippines
PATENTS AND PUBLICATIONS

7.    Kadam,AM,Ojha,Goldie., Shankar,H.S Soil Biotechnology for
      Processing of waste waters, 9 th International conference,
      Indian Water Works Association, Bombay 26-27 Nov2005
8.    Yeole,U.R., Patnaik,B.R.,Shankar,H.S.," Soil Biotechnology
      process simulation using computational fluid dynamics"
      Session Advanced Computations for Environmental
      Applications II" AIChE Annual Meeting, 7-12 Nov 2005,Austin
      Texas, USA
9.    Pattanaik., B.R.(2000),” Processing of Wastewater in Soil
      Filters”, Ph.D. Dissertation, Dept of Chemical Engg., IIT
      Bombay
10.   Yeole,Umesh      Prabhakar"Soil   Biotechnology    Process
      Simulation using Computational Fluid dynamics" 2004
11.   Bhuddhiraju,Sudheendra., "Soil Biotechnology Process
      simulation using Computational Fluid dynamics" 2005
MEDIA AND CULTURE
US Patent: Process for treatment of organic wastes; US
                Patent no: 6890438,
     www.uspto.gov; Issue date: 10 May 2005 ;
   Underdrain:- Stone rubble of various sizes ranging upto Gravel (200.0-2.0
   mm), Very coarse sand (1.0-2.0 mm), Coarse sand (0.5-1.0 mm), Medium
   sand (0.25-0.5 mm), Fine sand (0.1-0.25 mm)

   Media:- Formulated from soil as required and primary minerals of suitable
   particle size and composition

   Culture:- Geophagus (Soil living) worm Pheretima elongata and bacterial
   culture from natural sources containing bacteria capable of processing
   cellulose, lignin, starch, protein, also nitrifying and denitrifying organisms.
   Anaerobic organisms for methanogenesis. For industrial wastes,
   development of appropriate culture required

   Additives:- Formulated from natural materials of suitable particle size and
   composition to provide sites for respiration, CO2 capture

   Bioindicators:- Green plants particularly with tap root system
EXTRACT FROM VISION 21 DOCUMENT OF WHO
 EXTRACT FROM VISION 21 DOCUMENT OF WHO

 Current sanitation solutions contribute, either directly or indirectly, to many of the
 problems faced by society today: water pollution, scarcity of fresh water, food insecurity,
 destruction and loss of soil fertility, global warming, and poor man health as well as loss of
 life.

 In summary, we divert excreta away from land, consuming a limited resource – fresh water,
 into receiving water bodies causing water pollution. We then try to treat the water we drink.
 Both processes create health hazards. By diverting nutrients away from land, artificial
 fertilizers are added to land, creating even more water pollution, which is difficult and
 expensive to treat.

 We must find another way. We have to design and build new systems, which promote
 waste as a resource and envisage local solutions and cultural attitudes and contribute to the
 solving society’s most pressing problems.


Source: Esrey, S. & Anderson, I., Vision 21- Environmental Sanitation Ecosystems Approach, report published by Water Supply
        and Sanitation Collaborative Council ( WSSCC) World Health Organization, United Nations, 1993
AS (III) TO AS (V) CONVERSION IN SOIL FILTER SYSTEM

As(III) =1000 µg/l As(III); Flow rate= 130 ml/minute; Filter bed volume = 17 lit;
Precipitation with Fe(III); (FeCl3 ) dose as Fe added 55 mg/l.


       Time         Total As      As(III) conversion to As(V) in   Precipitation
       minute         µg/l                    Soil Filter              of FeCl3
                                      As(V)       Residual           Residual
                                       µg/l       As(III)            Total As
                                                  µg/l                 µg/l
 0                   995.50      150.00           640.00              18.5
 30                  986.67      636.67           350.00              15.65
 60                 1020.00      783.33           236.67              13.34
 90                 1003.33      826.67           176.67              11.25
 120                1000.00      926.67           73.33                7.75
 150                1026.67      973.33           53.33                5.85
 180                1016.67      983.33           33.33                7.00
 210                1013.33      950.00           63.33                7.42
 240                1016.67      933.33           83.33                7.40

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Soil BioTechnology

  • 1. SOIL BIOTECHNOLOGY OF IIT, BOMBAY Prof H.S.Shankar - hss@iitb.ac.in Department of Chemical Engineering IIT-Bombay Tel No 91-22-25767239,25768239
  • 2. CONTENTS • PRINCIPLES • WATER PURIFICATION • PROCESSING OF SOLID RESIDUES • AGRICULTURE • SUMMING UP
  • 3. A natural water body A natural water body
  • 4. A river system once a life line now in distress due A river system once a life line now in distress due to nutrient overload from agriculture to nutrient overload from agriculture
  • 5. A natural water body in the process of decay A natural water body in the process of decay
  • 6. A natural water body converted to land due to A natural water body converted to land due to nutrient overload nutrient overload
  • 7. CO2 in the Atmosphere 90 6 750 110 (1 1 y) - 0 Photosynthesis Respiration 50 CO2 Dissolved Plants Animals 4,000 500 100-150 Live 1-5 (50 y) (2 y) (0.2 y) Dead Organics in Soil (1 y) 50 - 65 50 18 Fossil Dead Organics Fuels Reserve in Soil Quantities in 1015g 4,000 1,576 (300 y) Global Carbon Cycle (Meilli, 1995) Global Carbon Cycle (Meilli, 1995) Source: Encyclopedia of Environmental Biology, Vol.1, Academy press, 1995, pp.235-248 Source: Encyclopedia of Environmental Biology, Vol.1, Academy press, 1995, pp.235-248
  • 8. ENERGY CONSUMPTION IN DIFFERENT HABITATS 1. Water 500 kJ/g live C. yr 2. Land 3 kJ/g live C. yr
  • 9. SCHEMATIC OF WATER RENOVATION 1.Raw water Recycle (vr ) Feed (vf ) 2.Raw Water slurry 3. Air scrubbing 4. Leachates of solids 5. Waste water Reactor C1 Discharge (vf ) C2
  • 10. SCHEMATIC OF MULTISTAGE PURIFICATION T1 R1 T2 R2 T3 R3 T4 R1 R2 R3 T1 T2 T3 T4
  • 11. LARGE SCALE FACILITY FOR SEWAGE RENOVATION
  • 12. MAJOR CHEMICAL REACTIONS AT WORK Respiration (CH2ONxPySzKyQ)n + nO2 + nH2O + Micro-organisms = nCO2 + 2nH2O + Mineral (N, P, S, K,Q) + Energy Photosynthesis nCO2 + 2nH2O + Minerals (N,P, S,K,Q) + Sunlight = [CH2ONxPySzKyQ]n + nO2 + nH2O Chemical Mineral weathering CO2 + H2O = HCO3 - + H+ Primary mineral + CO2 + H2O = M+n + n HCO3 - + soil/sand/clay
  • 13. BIOMASS YIELD, MINERAL CONTENT, NITROGEN CONTENT, WATER CONSUMPTION FOR SOME CROPS Crop Mineral N Water Yield % DM % DM ton / ton DM ton DM / ha Subabul 0.5 – 0.8 Small 50 20 Sugarcane 1.5 – 2.0 Small 400 18 Corn 5.0 – 6.0 0.3 – 0.5 200 14 Wheat 9 – 11 0.3 – 0.5 600 12 paddy 18 - 20 0.3 – 0.5 1000 9 * * DM – Dry Matter Yield is total biomass-grain, straw etc.
  • 14. CHEMISTRY OF SBT Respiration (CH2ONxPySzKy)n + nO2 + nH2O = nCO2 + 2nH2O + Mineral (N, P, S, K) + Energy (1) Photosynthesis nCO2 + 2nH2O + Minerals (N,P, S,K) + Sunlight = [CH2ONxPySzKy]n + nO2 + nH2O (Photosynthesis) (2) Nitrogen Fixation N2 + 2H2O + Energy = NH3 + O2 ( in soil) (3) N2 + 2H2O + Light = NH3 + O2 (in water) (4) Acidogenesis 4C3H7O2NS + 8H20 = 4CH3COOH + 4CO2 + 4NH3 + 4H2S + 8H+ + 8e- (5) Methanogenesis 8H+ + 8e- + 3CH3COOH + CO2 = 4CH4 + 3CO2 + 2H2O (6) Adding 5 and 6 give overall biomethanation chemistry 4C3H7O2NS + 6H20 = CH3COOH + 6CO2 + 4CH4 + 4NH3 + 4H2S (7) Mineral weathering CO2 + H2O = HCO3 - + H+ (8) Primary mineral + CO2 + H2O = M+n + n HCO3 - + soil/clay/sand (9) Nitrification NH3 + CO2 + 1.5O2 = Nitrosomonas + NO2- + H2O + H+ (10) NO2-+ CO2 + 0.5O2 = Nitrobacter + NO3- (11) Denitrification 4NO3- + 2H2O + energy = 2N2 + 5O2 + 4OH - (12a) NO2- + NH4+ = N2 + H2O + energy (12b)
  • 15. The trinity – showing importance of combining The trinity – showing importance of combining organics, inorganics & suitable life forms to derive organics, inorganics & suitable life forms to derive value from wastes value from wastes
  • 16. ENERGY CONSUMPTION FOR FOOD CROPS Crop Energy Input Yield Output Efficiency M k cal / ha kg / ha M cal / ha (-) Fossil Labour Total Wheat 3.77 0.002 3.772 2284 7.5 2.2 (USA) Wheat 0.256 0.1845 0.4405 821 2.7 6.25 (India) Rice 15.536 0.009 15.545 5796 21.0 1.35 (USA) Rice 0.582 0.1728 0.754 1655 6.0 7.69 (Phil) Potato 8.90 0.018 8.92 26208 20.2 2.27 (USA) Cassava 0.016 0.385 0.401 5824 (Dry) 19.2 50.0 (Tanga) Source: Energy in agriculture, Lockeritz (ed.) International Congress energy in agriculture Missouri, 1975-76
  • 17. 10 60 9 Direction of 50 8 Increasing biological potential 7 40 Energy efficiency Wheat,USA 6 Rice,USA Potato,USA 5 30 Wheat,India 4 Rice,Phillipines Cassava,Tanga 20 3 2 10 1 0 0 0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 Yield , Ton/ha Yield -Efficiency correlation for some crops Yield -Efficiency correlation for some crops
  • 18. Organics and rock Organics particles Gut residence Gut residence time: about 5 h time: about 1 h Refeeding Anaerobic Aerobic processing processing Residual Pump is Biosoil organism organics incubation as mobile bioreactor Single-pass Loop Bioreactor Bioreactor (Say Red worm) (Say Earthworm) Bioprocessing by the two types of organisms Bioprocessing by the two types of organisms Source: Bhawalkar (1996) Source: Bhawalkar (1996)
  • 19. ECO-ENERGETICS OF AN EARTHWORM (Lavell, 1974) Fresh Weight mg/individual 1025 Ingestion (J/g.d) 1570 Assimilation (J/g.d) 140 Production (J/g.d) 10 Respiration (J/g.d) 130 Egestion (J/g.d) 1430 EXPONENTIAL GROWTH OF BACTERIA IN EARTHWORM GUT (no. in million) (Parle, 1959) Forgut Midgut Hindgut All Bacteria 475 32900 440900 Actinomycetes 26 358 15000
  • 20. 11 Optimum Fly Larvae 9 Optimum Earthworm 7 Mosquito Termite Cockroach Fly pH Redworm 5 Rats, ants 3 Potworm 1 20 40 60 80 100 Moisture (%) Niches of Earthworms and Pests (Bhawalkar, 1996)
  • 21. A picture of red worms – r selected organisms in A picture of red worms – r selected organisms in waste environment waste environment
  • 22. EXPERIMENT SET -UP E(theta) vs theta 0.008 0.007 0.006 0.005 E(theta) 0.004 0.003 0.002 0.001 0 0 1 2 3 theta Concentration vs Time Plot
  • 23. TWO CHANNEL MODEL α = fraction of holdup in the macrochannel β = fraction of tracer that enters the macrochannel
  • 24. TWO CHANNEL MODEL ⎛ ⎛ βθ 1 ⎞ 2 ⎞ ⎛ ⎛ (1 − β )θ ⎞ 2 ⎞ ⎜ ⎜1 − ⎟ ⎟ ⎜ ⎜1 − 2 ⎟ ⎟ β2 1 ⎜ ⎝ α ⎠ ⎟ (1 − β ) 2 1 ⎜ ⎜ ⎝ (1 − α ) ⎟ ⎟ ⎠ E (θ ) = exp ⎜ − + ⎟ (1 − α ) exp ⎜ − ⎟ α πθ 1 4θ 1 πθ 2 4θ 2 2 ⎜ ⎟ 2 ⎜ ⎟ ⎜ Pe1 ⎟ ⎜ Pe2 ⎟ Pe1 ⎝ ⎠ Pe2 ⎝ ⎠ τ1 = α τ τ2 = (1 − α ) τ θ1 = t θ2 = t β (1 − β ) τ1 τ2 β (1 − β ) Pe Pe1 = Pe Pe2 = α (1 − α )
  • 25. THEORETICALLY CALCULATED PARAMETERS RT λio Diffusivity D= 2 = 1.9 * 10-5 cm/s2 F zi 3μ Q Film Thickness δ =3 = 0.1 mm ρgW uL Peclet Number Pe = = 6 - 14 D
  • 26. C (th e ta ) ve rsu s th e ta 1 .4 Exp Mo d e l 1 .2 1 0 .8 C(theta) 0 .6 0 .4 0 .2 0 0 0 .5 1 1 .5 2 2 .5 3 th e ta RTD Plot of normalized concentration (C/Co) vs. Time for 2m soil filter RTD Plot of normalized concentration (C/Co) vs. Time for 2m soil filter showing fit to Dispersion model equation (8) for Run 2a (22.3 cm/h) showing fit to Dispersion model equation (8) for Run 2a (22.3 cm/h) with fitted parameters α=0.67, β=0.9, Pe=9 with fitted parameters α=0.67, β=0.9, Pe=9
  • 27. EXPERIMENT AND THEORETICAL PARAMETERS Run No Q τ α Pe (ml/min) (min) I 95 155 0.73 12.1 II 100 153 0.69 18.3 V 125 133 0.63 9.7 III 155 102 0.75 10.1 VI 182 91 0.68 12.3 IV 200 90 0.68 11.5 Run Q τ δ H A u Pe No (ml/min) (min) (mm) (lit) (m2) (m/s) I 95 155 0.06 14.72 245 6.46 ×10-9 6.1 II 100 153 0.06 15.3 255 6.53 ×10-9 6.2 V 125 133 0.07 16.62 237 8.79 ×10-9 8.4 III 155 102 0.07 15.81 226 11.4 ×10-9 10 VI 182 91 0.08 16.56 207 14.6 ×10-9 13.9 IV 200 90 0.08 18 225 14.8 ×10-9 14.1
  • 28. RTD Plot of normalized concentration (C/Co) vs. Time for soil filter RTD Plot of normalized concentration (C/Co) vs. Time for soil filter showing fit to Dispersion model equation (8) for Run 2a (22.3 cm/h) showing fit to Dispersion model equation (8) for Run 2a (22.3 cm/h) with fitted parameters α=0.25, β=0.68, Pe=0.83 with fitted parameters α=0.25, β=0.68, Pe=0.83
  • 29. Plot of normalized concentration (C/Co) and RTD function E (t) vs. Plot of normalized concentration (C/Co) and RTD function E (t) vs. Time for soil filter showing fit to Dispersion model equation (8) for Time for soil filter showing fit to Dispersion model equation (8) for Run 1a (7.2 cm/h) with fitted parameters α=0.09, β=0.40, Pe=0.89 Run 1a (7.2 cm/h) with fitted parameters α=0.09, β=0.40, Pe=0.89
  • 30. 1000 Equipment : Pheretima Biofilter Intial loading on bed =24.4gmCOD/L Restoration rate constant I stage =0.2 /h Restoration rate constant II stage =0.11/h 500 ORP, milivolt ORP data (Probe 9, Depth:-2.5cm) Fit to model Eqn 3.6.13 & 3.6.14 0 -500 0 50 100 150 200 Time,h ORP (Reference calomel electrode+244 mV) restoration profile showing fit to model Pattanaik, B.R. (2000)
  • 31. PHYSICAL MASS TRANSFER 7 6 5 Dissolved O2, mg/L. Pheretima biofilter 4 T = 30.2 C vs = 7.2 cm/h CI = 1.8mg/L 3 Ce = 6.8 mg/L Run : OTR 14 Experimental data 2 Fit to model 1 0 0 20 40 60 80 100 120 Time, min Variation of outlet O2 concentration with time as per single cell model Variation of outlet O2 concentration with time as per single cell model Pattanaik.,(2000) Pattanaik.,(2000)
  • 32. PHYSICAL MASS TRANSFER 8 6 DO (mg/L) 120 ml/min 4 250 ml/min 2 0 0 20 40 60 80 Time (Mins) Variation of outlet O2 concentration with time, Sathyamoorthy(2006)
  • 33. COD REMOVAL 600 500 COD (m g/l) 400 300 150 ml/min 200 100 0 0 2 4 6 8 10 Time (hr) COD concentration with Time Kadam.(2005)
  • 34. COMPARISON OF AIR TO WATER OXYGEN TRANSFER COEFFICIENTS Agitated & sparged vessels 10-3 to 10-2 /sec This work 5 x 10-3/sec Quiescent fluids 10-5/sec
  • 35. GOVERNING EQUATIONS ∂ρ 1. Continuity Equation + ∇ ⋅ (ρ v ) = 0 ∂t 2. Momentum balance ( ) ∂ ρv + ∇ ⋅ ( ρ v v ) = −∇ p + ρ g + F ∂t From Darcy’s Law μ F=− v α Rate equations for substrates Substrate Description Rate Equation 3. Species Transport Equation COD Mass Transfer Kac(C1-C1*) ∂Ci ∂t ( ) + ∇ ⋅ vCi + ∇.(Di ,m∇Ci ) − R i = 0 COD Oxidation KcCs NH4+-N Mass Transfer Kan(C2-C2*) 4. conc. balance in holding tank NH4+-N Nitrification KNN s dS2 τh = S1 (t) − S2 (t) dt
  • 36. 1.2 C2/C20 fit to Eq.3.4.7, Run 2b Exptl data, C2/C20, Run 2b 1 C2/C20 fit to Eq. 3.4.7, Run 3b Exptl. Data, C2/C20, Run 3b 0.8 C2/C20 0.6 0.4 Run Hyd. Loading rate ka (m3/m2.hr ) (hr-1) 0.2 2b 0.6 0.22 3b 0.8 0.53 0 0 1 2 3 4 5 6 7 8 Time,hr Effect of hydraulic loading on distribution of liquid on biofilter Effect of hydraulic loading on distribution of liquid on biofilter
  • 37. CFD MODEL VALIDATION: COMPARISON WITH EXPERIMENTAL DATA 200 6 6 180 5 5 160 NH −N conc. (mg/L) NH −N conc. (mg/L) 140 4 4 COD ( mg/L ) 120 3 3 100 2 + 4 80 2 + 4 60 1 1 40 0 20 00 1 2 3 4 5 6 0 1 2 3 4 5 6 0 1 2 3 4 5 6 Time (h) Time (h) Time (h) Vb =13 L, Vl = 30 L, vr = 5x 10-5 m3/m2h kac = 2.7 h-1, kC = 0.05 h-1, kan = 11 h-1, kN =1.5 h-1,
  • 38. Comparison between Dispersion model prediction and reactor performance data for sewage 8 90 90 8 80 80 7 7 Model Eq. 9 & 10 Model Eq. 9 & 10 Model Eq. 9 & 10 Model Eq. 9 & 10 70 70 Experimental 6 6 Experimental Experimental NH4+ N (mg/ L) Experimental NH4+ - -N (mg/ L) 60 60 5 5 CO D ( g / L ) 50 CO D ( g / L ) 50 4 4 40 40 3 3 30 30 2 2 20 20 1 10 10 1 0 00 0 0 1 2 3 4 5 6 7 0 1 2 3 4 5 6 7 00 22 44 66 88 Time ( h) Time (h) Time ( h) Time (h) Model Parameters: Vb =13 L, Vl = 30 L, vr = 5.1 m3/m2 h α = 0.32, β = 0.81, εd = 0.25, Pe = 0.18, kac = 1.5 h-1, kan = 11 h-1,
  • 39. DISTILLERY SPENT WASH Before SBT Processing After SBT Processing COD: 12,160mg/L COD: 64 mg/L
  • 40. COLI FORM REMOVAL Coliform rem oval Total coliform fecal coliform 1.0E+09 1.0E+08 Coliform (CFU/100 ml) 1.0E+07 1.0E+06 1.0E+05 1.0E+04 1.0E+03 1.0E+02 1.0E+01 Inf luent E0 E1 E2 E3 E4 E5 E6 E7 R e c y c l i n g ( hr ) Effect of recycling on micro-organism removal; E0: Effluent 0 hr, E1: Effluent 1 hr etc Kadam., (2005)
  • 41. ARSENIC REMOVAL BY SOIL FILTER • As(III) oxidation and removal As(V) via precipitation as ion complex with Fe(III). • These results show that <10 ppb As are attained via natural oxidation and chemical precipitation revealing typically 0.3 mg As (III)/lit.hr. • These natural rates of removal sustain via the natural aeration of the
  • 42. PROCESS DIAGRAM FOR ARSENIC REMOVAL FROM WATER As (III) water As (V) Precipitation Fe3++ As Soil Filter Filter Fe3+ + As As Sludge 30 % %Complex
  • 43. ARSENIC REMOVAL IN SOIL FILTER SYSTEM Initial As(III)=500 μg/l; Filter bed volume=17 lit; Flow rate = 60ml/min, Total volume of water passed per day = 30 lit, which constitute one run. Expt. Run No Initial Arsenic Conc. Residual Arsenic μg/l μg/l 1 500 8 2 500 8 3 500 8 4 500 8 5 500 8 6 500 8 7 500 3 8 500 6 9 500 5 10 500 4 11 500 4 12 500 4 13 500 4
  • 44. COMPARISON OF ARSENIC REMOVAL RATES • Zero Valent iron 0.85 mg As/lit.hr( Leupin et al., 2005) • Iron coated sand 0.75 mg As/lit.hr (Joshi and Chaudhari, 2004) • Activated Alumina 0.15 mg As/lit.hr (Pant and Singh, 2005) Soil filter process 0.30 mg As/lit.hr
  • 45. LAY OUT OF SBT MEDIA
  • 46. Effect of Feed Distribution arrangement on Fluid distribution Contours of Velocity Magnitude (m/s) Fig 4a: Feed From Top surface only Fig 4b: Feed From Top & Slopes vr = 0.15 m3/m2h
  • 48. PLANT ELEVATION 500 m3/day BPGC Plant for wastewater treatment
  • 49. SBT PLANT 3MLD Sewage purification in Corporation Of Bombay
  • 50. WATER QUALITY ANALYSIS OF SBT PLANT PARAMETERS INFLUENT EFFLUENT Temp. (0C) 31.4 31.3 pH 6.91 8.26 Conductivity (micro S/cm) 2160 987 DO (mg/l) 0.85 7.01 Turbidity (NTU) 145 5.32 COD (mg/L) 352 64 BOD 211 7.04 Ammonia (mg/L) 33.4 0.010 Phosphate-P (mg/L) 0.474 0.0016 SS(mg/l) 293.3 16 Alkalinity(mg/L) 212 148 Fecal coliform(cfu/100ml) 145*105 55 Total coliform(cfu/100ml) 150*108 110
  • 51. PROCESS FEATURES • Very low energy use intensity due to high Natural oxygen transfer in process. (0.06 kWh/kL sewage). • Very low space intensity of 0.8-1.0 sqm/kL per day sewage. • An engineered evergreen natural process with no moving parts except for pumps. • No sludge due to ecology at work. • Very high bacteria, BOD, COD, suspended solids, colour, odour, ammonia removal. • Practically maintenance free.
  • 52. SBT PLANT 3MLD Sewage purification in Corporation Of Bombay
  • 53. SBT PLANT 3MLD Sewage purification in Corporation Of Bombay
  • 54. SBT PLANT 3MLD Sewage purification in Corporation Of Bombay
  • 55. SBT PLANT Renovation of colony sewage for irrigation in sports Renovation of colony sewage for irrigation in sports complex complex
  • 56. REUSABLE WATER FROM WASTEWATER Wastewater Treated Wastewater
  • 57. SBT PLANT Colony sewage treatment Colony sewage treatment showing untreated & showing untreated & treated water treated water
  • 58. SBT PLANT Renovation of septic tank waste water for irrigation in a Renovation of septic tank waste water for irrigation in a Research Center Research Center
  • 59. SBT PLANT Retrofitting of idle activated sludge plant Retrofitting of idle activated sludge plant
  • 60. SUMMARY OF SBT PROCESS FEATURES FOR SEWAGE TREATMENT Item Features Organic loading 150-200 g / sqm.d Oxygen transfer 150-200 g / sqm.d Heat generation 600-800 k.cal / sqm.d Conversion As required Hydraulic loading 0.05 - 0.25 cum/sqm.h Shear rate 0.01 – 0.1 per sec.
  • 61. OPERATING FACILITIES • Bombay Presidency Golf Club • Naval Housing Colony, Bombay • Vazir Sultan Tobacco, Hyderabad • Jindal Steel, Delhi • Taj Kiran, Gwalior • IIT Bombay • Beru Ashram Badlapur • Delhi Travel Tourism Dev Corporation • Bombay Municipal Corporation (in progress) • University of Hyderabad (in progress).
  • 62. SBT PLANT Close up of solid waste processing Close up of solid waste processing
  • 63. 100 m ORGANIC ROAD 2 RESIDUE 10 m Loading Rows 4 PROCESSING 6 ROAD ROAD Raw organics 5m 300 m 1m Underdrain Semi-processed organics A 38 39 ROAD 10 m 5m Schematic of organic residue processing. Schematic of organic residue processing.
  • 64. Restoration of municipal dumping grounds Restoration of municipal dumping grounds
  • 66. SUMMARY OF PROCESS FEATURES FOR ORGANIC SOLID CONVERSION Item Features Organic loading 150-200 g / sq.m.d Oxygen transfer 150-200 g / sq.m.d Heat generation 600-800 k.cal / sq.m.d Conversion 20-30% Product Yield 0.375 – 0.500 kg / kg Products fertilizer/culture/soil
  • 67. Chickoo plant affected by fungal disease Chickoo plant affected by fungal disease
  • 68. Chickoo plant after restoration of soil Chickoo plant after restoration of soil
  • 69. ECONOMICS FOR SEWAGE TREATMENT Item Unit Capacity (m3 / d) 5 50 100 200 500 3,000 10,000 1. Space m2 40 250 400 600 1500 3500 10000 2.Civil, mech., Elec. Rs. Mil 0.10 0.5 0.9 1.0 1.5 12 25 3.Bioreactor Rs. Mil 015 0.6 1.0 1.5 2.5 17 50 Total (2 + 3) Rs. Mil 0.25 1.1 1.9 2.5 4.0 29 75 4. Power Rs./d 10 100 200 400 800 1200 4000 5. Additives Rs./d 20 100 250 500 1250 5000 15000 6. Staff Rs./d 250 250 500 500 1000 2500 5000 7. Miscellaneous Rs./d 10 50 50 150 200 300 500 Total (5 to 7) Rs./d 340 600 1000 1550 3250 9000 24500 US $ = Rs. 47.00; Power Rs. 4 per kWh ; Mil – Million; additives – Rs. 5 / kg
  • 70. ECONOMICS FOR MUNICIPAL ORGANIC SOLIDS Item Unit Features Capacity Ton/day 1 10 20 100 Space Sq.m 2000 15000 20000 50000 Civil, mech., elec. Rs. mil 0.5 2.5 4.5 15 bioreactor Rs. mil 0.2 1.0 1.5 5.0 Total (3+4) Rs. mil 0.7 3.5 6.0 20 production Ton/year 150 1500 3000 15000 Labour Rs./day 450 3500 5000 10000 Power fuel Rs./day - - 1000 5000 Additives Rs./day 400 4000 8000 20000 Misc. Rs./day 50 200 500 1000 Total (6-8) Rs./day 850 7500 15500 36000 mil. – million mech. – mechanical elec. – electrical Rs. – Rupees (1US$ = Rs.47)
  • 71. APPLICATIONS • Rain water harvesting via storm water conservation • Primary purification of drinking water • Primary purification of swimming pool water • Sewage treatment for reuse in construction, cleaning & gardening, ground water recharge, make up water for swimming pools & industries etc • Industrial wastewater treatment, • Industrial air purification • Organic solid waste conversion • Municipal solid waste processing • Commercial production of Soil • Animal House waste processing • Hospital waste disposal
  • 72. SUMMING UP Engineered natural oxygen supply Evergreen Environment No moving parts No biosludge
  • 74. XRD ANALYSIS 1400 1200 1000 Intensity 800 Murram 600 400 200 0 0 20 40 60 80 100 Angle Partially weathered Rock (Murram)
  • 75. XRD ANALYSIS 1000 800 Intensity 600 Black soil 400 200 0 0 20 40 60 80 100 Angle Artificially weathered Rock (Black soil)
  • 76. XRD ANALYSIS 1400 1200 1000 Intensity 800 Blacksoil 600 Murram 400 200 0 0 20 40 60 80 100 Angle Comparison of Artificially weathered Rock (Black soil) with Murram (partially weathered Rock)
  • 77. XRD ANALYSIS 900 800 700 600 Intensity 500 Rock Powder 400 300 200 100 0 0 20 40 60 80 100 Angle Primary mineral (Rock powder)
  • 78. XRD ANALYSIS 1200 1000 800 Intensity 600 Redsoil 400 200 0 0 20 40 60 80 100 Angle Naturally weathered Rock (Red soil)
  • 79. XRD ANALYSIS 1400 1200 1000 Intensity 800 Rock-Powder 600 Murram 400 200 0 0 20 40 60 80 100 Angle Comparison of Primary Mineral (Rock powder) with Murram (Partially weathered Rock)
  • 80. XRD ANALYSIS 1400 1200 1000 Intensity 800 REDSOIL 600 Murram 400 200 0 0 20 40 60 80 100 Angle Comparison of Naturally weathered Rock (Red soil) with Murram (partially weathered Rock)
  • 81. XRD ANALYSIS AW-1 1350 1250 1150 1050 Intensity 950 850 750 650 550 450 25 30 35 40 45 50 55 60 65 Angle Artificially weathered Rock - 1
  • 82. XRD ANALYSIS AW-2 1300 1200 1100 1000 In n ity 900 te s 800 700 600 500 25 30 35 40 45 50 55 60 65 Angle Artificially Weathered Rock - 1
  • 83. XRD ANALYSIS AW-3 1300 1200 1100 1000 In n ity te s 900 800 700 600 500 25 30 35 40 45 50 55 60 65 Angle Artificially Weathered Rock - 2
  • 84. XRD ANALYSIS AW-4 1200 1100 1000 In n ity 900 te s 800 700 600 500 25 35 45 55 65 Angle Artificially Weathered Rock - 2
  • 85. XRD ANALYSIS Worli pad-5 1600 1400 1200 In n ity te s 1000 800 600 400 25 30 35 40 45 50 55 60 65 Angle Artificially Weathered Rock
  • 86. XRD ANALYSIS Garde n Soil 1500 1400 1300 1200 In n ity 1100 te s 1000 900 800 700 600 25 30 35 40 45 50 55 60 65 Angle Artificially Weathered Rock
  • 87. PATENTS AND PUBLICATIONS 1. US Patent No: 6890438 " Process for treatment of organic wastes" H.S.Shankar, B.R.Patnaik, U.S.Bhawalkar, issued 10 May 2005 2. "Process for treatment of Organic residues" India Patent Application MUM/384/26 April 2002, H.S.Shankar, B.R.Patnaik,U.S.Bhawalkar 3. " Process for treatment of waste water" India Patent Application MUM/383/26 April 2002, H.S.Shankar,B.R.Patnaik,U.S.Bhawalkar 4. Patnaik, B.R., Bhawalkar, U.S., Gupta, A., Shankar, H.S., “Residence Time Distribution model for Soil Filters, Water Environment Research, 76(2), 168-174,2004 5. Patnaik, B.R., Bhawalkar, V.S., Shankar, H.S., “Waste Processing in Engineered Ecosystems”, 4th World Congress on Chemical Engineering, 23-27, September 2001, Melbourne, Australia 6. Patnaik, B.R., Bhawalkar, U.S., Kadam, A, Shankar, H.S., “Soil Biotechnology for Waste Water Treatment and utilization”, 13th ASPAC 2003, International Water Works Association Conference 13-18, October, 2003, Quezon City, Philippines
  • 88. PATENTS AND PUBLICATIONS 7. Kadam,AM,Ojha,Goldie., Shankar,H.S Soil Biotechnology for Processing of waste waters, 9 th International conference, Indian Water Works Association, Bombay 26-27 Nov2005 8. Yeole,U.R., Patnaik,B.R.,Shankar,H.S.," Soil Biotechnology process simulation using computational fluid dynamics" Session Advanced Computations for Environmental Applications II" AIChE Annual Meeting, 7-12 Nov 2005,Austin Texas, USA 9. Pattanaik., B.R.(2000),” Processing of Wastewater in Soil Filters”, Ph.D. Dissertation, Dept of Chemical Engg., IIT Bombay 10. Yeole,Umesh Prabhakar"Soil Biotechnology Process Simulation using Computational Fluid dynamics" 2004 11. Bhuddhiraju,Sudheendra., "Soil Biotechnology Process simulation using Computational Fluid dynamics" 2005
  • 89. MEDIA AND CULTURE US Patent: Process for treatment of organic wastes; US Patent no: 6890438, www.uspto.gov; Issue date: 10 May 2005 ; Underdrain:- Stone rubble of various sizes ranging upto Gravel (200.0-2.0 mm), Very coarse sand (1.0-2.0 mm), Coarse sand (0.5-1.0 mm), Medium sand (0.25-0.5 mm), Fine sand (0.1-0.25 mm) Media:- Formulated from soil as required and primary minerals of suitable particle size and composition Culture:- Geophagus (Soil living) worm Pheretima elongata and bacterial culture from natural sources containing bacteria capable of processing cellulose, lignin, starch, protein, also nitrifying and denitrifying organisms. Anaerobic organisms for methanogenesis. For industrial wastes, development of appropriate culture required Additives:- Formulated from natural materials of suitable particle size and composition to provide sites for respiration, CO2 capture Bioindicators:- Green plants particularly with tap root system
  • 90. EXTRACT FROM VISION 21 DOCUMENT OF WHO EXTRACT FROM VISION 21 DOCUMENT OF WHO Current sanitation solutions contribute, either directly or indirectly, to many of the problems faced by society today: water pollution, scarcity of fresh water, food insecurity, destruction and loss of soil fertility, global warming, and poor man health as well as loss of life. In summary, we divert excreta away from land, consuming a limited resource – fresh water, into receiving water bodies causing water pollution. We then try to treat the water we drink. Both processes create health hazards. By diverting nutrients away from land, artificial fertilizers are added to land, creating even more water pollution, which is difficult and expensive to treat. We must find another way. We have to design and build new systems, which promote waste as a resource and envisage local solutions and cultural attitudes and contribute to the solving society’s most pressing problems. Source: Esrey, S. & Anderson, I., Vision 21- Environmental Sanitation Ecosystems Approach, report published by Water Supply and Sanitation Collaborative Council ( WSSCC) World Health Organization, United Nations, 1993
  • 91. AS (III) TO AS (V) CONVERSION IN SOIL FILTER SYSTEM As(III) =1000 µg/l As(III); Flow rate= 130 ml/minute; Filter bed volume = 17 lit; Precipitation with Fe(III); (FeCl3 ) dose as Fe added 55 mg/l. Time Total As As(III) conversion to As(V) in Precipitation minute µg/l Soil Filter of FeCl3 As(V) Residual Residual µg/l As(III) Total As µg/l µg/l 0 995.50 150.00 640.00 18.5 30 986.67 636.67 350.00 15.65 60 1020.00 783.33 236.67 13.34 90 1003.33 826.67 176.67 11.25 120 1000.00 926.67 73.33 7.75 150 1026.67 973.33 53.33 5.85 180 1016.67 983.33 33.33 7.00 210 1013.33 950.00 63.33 7.42 240 1016.67 933.33 83.33 7.40