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Exp Reactants Products Observation
I
2.6 g of zinc and
50 cm3
of acid P
2.0 mol dm-3
Zinc chloride
and hydrogen
gas
The
temperature
of the mixture
increases
II
2.6 g of zinc and
50 cm3
of acid Q
2.0 mol dm-3
Zinc sulphate
and hydrogen
gas
The
temperature
of the mixture
increases
data from Exp I and Exp II that were carried out to study
the rate of reaction of zinc with two acids, P and Q.
QUESTION 1- RATE OF REACTION
• (i) By choosing either
Experiment I or Experiment II, state
the name of the acid used.
•  
• (i) Write the chemical equation
for the reaction of this acid with
zinc. [2 marks]
(ii) Draw an energy profile diagram for
the reaction in 10(a)(i). On the energy
profile diagram show the:
–Heat of reaction, AH
–Activation energy without a catalyst,
–Activation energy with a catalyst, E'
Explain the energy profile diagram.
[10 marks]
∆H
E- activattion energy
without catalyst
E’- activattion
energy with catalyst
energy
Energy profile diagram of reaction
zinc and hydrochloric acid
(ii) Explain the energy profile diagram.
∆H
(ii) Explain the energy profile diagram.
∆H
(ii) Explain the energy profile diagram.
∆H
∆H
(ii) Explain the energy profile diagram.
∆H
(ii) Explain the energy profile diagram.
∆H
What is the function of these food additives?
a) Colouring agents
b) preservatives
c) Anti oxidants
d) Flavouring agents
e) Stabilisers and
thickeners
a) To restore the colour of
original food
b) To destroy or prevent growth
of micro organisms in food
c) To prevention oxidation of
food by air
d) To to give or enhance the
flavour of food
e) To prevent food such as ice
cream from separating into layers
and to thicken soup or gravy
Question no. 2) consumer
What type of food additives?
Colouring agents
preservatives
Anti oxidants
Flavouring agents
Stabilisers and thickeners
a) Benzoic acid
b) Pectin
c) Saccharin
d) aspartam
e) Ascorbic acid
Flavouring agents
f) tartrazine
f) Sodium nitrite preservatives
What type of food additives?
Colouring agents
preservatives
Anti oxidants
Stabilisers and thickeners
a) Azo compound
b) Vitamin E
c) Mono sodium glutamate
d) agar-agar
e) Gelatin
Flavouring agents
f) Sodium benzoate
Stabilisers and thickeners
g) Sulphur dioxide preservatives
What is the function of these traditional medicines?
a) lime
b) garlic
c) ginger
d) onions
e) Betel leaves-
daun sireh
a) To increase digestive juice
b) Has antibiotic property
c) To warm the body
d) To purift blood
e) Stop bleeding nose
What is the function of these modern medicines?
a) analgesics
b) antibiotics
c)
Psychotherapeutic
medicines
a) To relieve pain without affecting
consciousness
b) Kill bacteria
c) To treat
mental illness
a) stimulants
b) Anti
depressant
c) Antipsychotic
drug
a) To stimulate mental activity
b) To control worry,
fear, anxiety, panic
c) To treat
psychotic illness or
schizophrenia
c) Psychotherapeutic medicines
What type of modern medicines?
analgesics
Anti biotics
a) aspirin
b) Penicillin
c) streptomycin
d) Para cetamol
e) caffeine
f) codeine
g) barbiturate
Anti biotics
analgesics
stimulant
analgesics
antidepressant
h) tranquiliser antidepressant
What is the uses of modern medicines?
Fever, prevent heart
attack
fever
a) aspirin
b) Penicillin
c) streptomycin
d) Para cetamol
f) codeine
pneumonia Tuberculosis,
dysentry
Treat gonorrhea, syphlis,
pneumonia, meningitis
Cough medicine,
headache
Soap:
RCOO –
Na +
or R COO –
K +
Detergent:
What is general formula for
soap?
and detergent?
What does hard water contains?
•Hard water contains
calcium ion, Ca2+
or
magnesium ion, Mg2+.
Why do soaps form scum with
hard water?
• Soap reacts with calcium
ion, Ca2+
or magnesium ion,
Mg2+
in hard water to form
insoluble salt, called scum
Why is soap not effective in hard
water?
• Because formation of scum
reduce the amount of soap
for cleaning and thus wastage
of soap occur.
Why is detergent more effective than
soap in hard water?
 • Detergent form soluble salt with 
calcium ion, Ca2+
or
magnesium ion, Mg2+
in hard 
water.
• Therefore the cleaning power is 
not affected by hard water.
Below are some additives in detergents.
Fill in missing words
Additives Functions
1 Drying agents
( such as sodium
sulphate, sodium
silicate)
to keep the
powder………
……….
DRY
Additives Functions
2 Builders
( such as
Sodium
triphosphate)
……………
water.
softe
n
Additives Functions
3 Biological
enzymes
( such as
amylase,
lipase)
to digest
in dirt or to
modify fabric
feel
PROTEIN, FAT
OR
CARBOHYDRA
TE
Additives Functions
4 Such as
sodium
perborate
Convert
stains into
…………………
substances
colourles
s
Additives Functions
5  Perfumes Make clothes 
smell  
……………. And 
clean
fres
h
Additives Functions
6.
Stabilizers
( such as
silicones)
Prevent
formation of
………………foam
Change of one 
homologous series to 
another homologous 
series 
Question 3) Revision on alcohols, carboxylic
acids and ester
Alcohol
Carboxylic
acid
Ester
State the general formula for
Many reactions of ethanol
Reaction 1
• Combustion
• ethanol is burnt in excess oxygen
Observation: ethanol burns with blue
flame, no soot
Reaction 2
• Dehydration
• ethanol is passed over heated
porcelain chips to produce ethene
Observation: gas formed that will
decolorize brown bromine water
Reaction 3
• hydration or addition of steam
• When a mixture of ethene and steam is
heated over phosphoric acid as
catalyst, temp of 300o
C, pressure 60
atm.
Reaction 4
• Esterification
• When a mixture of ethanol and
ethanoic acid is warmed with conc
sulphuric acid as catalyst,
Observation: sweet smelling liquid is
formed
Reaction 5
• Esterification
• When a mixture of ethanoic acid and
ethanol is warmed with conc sulphuric
acid as catalyst
Observation: Sweet smelling liquid is formed
Reaction 6
• Oxidation
• When ethanol is warmed with acidified
potassium dichromate as oxidizing agent
Observation: Orange solution change to green
Naming of esters
5) A student obtained the data to
determine heat of precipitation of PbSO4
Solution Vol
(cm3)
Conc
(moldm-
3)
Initial temp
(0
C)
Pb(NO3)2 50 0.5 27.4
Na2SO4 50 0.5 27.6
Highest temperature : 30.5 0
C
Question 4- thermochemistry
What is meant by heat of
precipitation?
• Heat changed when 1 mole of
precipitate is formed from its
ions in an aqueous solution
b) Calculate heat of precipitation of
PbSO4
• Mole Pb 2+
: (0.5)(50)/1000 = 0.025 mol
• Mole SO4
2-
: (0.5)(50)/1000 = 0.025
mol
• Pb2+
+ SO2-
4 PbSO4
mole PbSO4 = Mole Pb2+
or mole SO2-
4
= 0.025 mol
ϴ = 30.5 - ( 27.4 + 27.6 )
2
= 3.0 ° C
Heat of precipitation = mCϴ
mol
= ( 100)(4.2)(3)
0.025
= 50400 J/mol
∆ H = - 50.4 KJ/mol
d)Write thermo chemical equation
•Pb2+
+ SO4
2-
PbSO4
∆ H = - 50.4 KJ/mol
e) Write the ionic equation
•Pb2+
+ SO4
2-
PbSO4
E) Construct energy level diagram
Pb2+
+ SO4
2-
Energy
∆ H = - 50.4 KJ/mol
PbSO4
f) The experiment is repeated using K2SO4
to replaced Na2SO4. Heat of precipitation
of PbSO4 remain the same. Explain.
• Because the same precipitate is formed,
which is PbSO4.
• Only Pb 2+
ions and SO4
2-
ions react
• Na+
ions and K+
ions do not react
• 6) A student carried out an experiment
to determine heat of displacement of
copper from CuSO4 solution. He added
excess zinc powder to 50 cm3
of 0.2
moldm-3
CuSO4. The thermo chemical
equation is shown below :
Zn + Cu2+
Zn2+
+ Cu
∆ H = -80.64 KJ/mol
a) Calculate the change in
temperature
Mol Copper= mol copper(II) sulphate
= (0.2)(50)/1000 = 0.01 mol
∆ H = mCϴ
mol
80 640 J = ( 50)(4.2)(ϴ)
0.01
ϴ = 3.8 ° C
b) Write the ionic equation
Zn + CuSO4  Cu + ZnSO4
Zn + Cu2+ 
Zn2+
+ Cu
The experiment is repeated with the
following changes. What is the effect in
the change of temperature when :
• Concentration of CuSO4 is doubled,
without changing the volume :
So, change of temp or ϴ is doubled.
Because as the concentration
doubled, the number of particle per
unit volume also doubled.
The experiment is repeated with the
following changes. What is the effect
in the change of temperature when :
• volume of CuSO4 is halved, without
changing the concentration :
So, change of temp or ϴ is remain
the same. Because, the changes in
volume do not affect the number of
particles per unit volume
7) State the diff betw heat change and the
heat of reaction
HEAT CHANGE HEAT OF REACTION
A)
OTHER
NAMES
Depends on name of
reactions :
Heat
absorb
, heat
released
-Heat of Precipitation
-Heat of displacement
-Heat of neutralisation
-Heat of combustion
7) State the differences between heat
change and heat of reaction
HEAT CHANGE HEAT OF REACTION
B) FORMULA
USED
H= mCϴ ∆ H= mCϴ
mol
C)UNIT
Joule Kilo Joule/ mol
D) SYMBOL
none ∆ H
E) SIGN
No sign Either + for
endothermic rex or
– for exothermic rex

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Revision on consumer, r te, thermo and carbon compound

  • 1. Exp Reactants Products Observation I 2.6 g of zinc and 50 cm3 of acid P 2.0 mol dm-3 Zinc chloride and hydrogen gas The temperature of the mixture increases II 2.6 g of zinc and 50 cm3 of acid Q 2.0 mol dm-3 Zinc sulphate and hydrogen gas The temperature of the mixture increases data from Exp I and Exp II that were carried out to study the rate of reaction of zinc with two acids, P and Q. QUESTION 1- RATE OF REACTION
  • 2. • (i) By choosing either Experiment I or Experiment II, state the name of the acid used. •  
  • 3. • (i) Write the chemical equation for the reaction of this acid with zinc. [2 marks]
  • 4. (ii) Draw an energy profile diagram for the reaction in 10(a)(i). On the energy profile diagram show the: –Heat of reaction, AH –Activation energy without a catalyst, –Activation energy with a catalyst, E' Explain the energy profile diagram. [10 marks]
  • 5. ∆H E- activattion energy without catalyst E’- activattion energy with catalyst energy Energy profile diagram of reaction zinc and hydrochloric acid
  • 6. (ii) Explain the energy profile diagram. ∆H
  • 7. (ii) Explain the energy profile diagram. ∆H
  • 8. (ii) Explain the energy profile diagram. ∆H ∆H
  • 9. (ii) Explain the energy profile diagram. ∆H
  • 10. (ii) Explain the energy profile diagram. ∆H
  • 11. What is the function of these food additives? a) Colouring agents b) preservatives c) Anti oxidants d) Flavouring agents e) Stabilisers and thickeners a) To restore the colour of original food b) To destroy or prevent growth of micro organisms in food c) To prevention oxidation of food by air d) To to give or enhance the flavour of food e) To prevent food such as ice cream from separating into layers and to thicken soup or gravy Question no. 2) consumer
  • 12. What type of food additives? Colouring agents preservatives Anti oxidants Flavouring agents Stabilisers and thickeners a) Benzoic acid b) Pectin c) Saccharin d) aspartam e) Ascorbic acid Flavouring agents f) tartrazine f) Sodium nitrite preservatives
  • 13. What type of food additives? Colouring agents preservatives Anti oxidants Stabilisers and thickeners a) Azo compound b) Vitamin E c) Mono sodium glutamate d) agar-agar e) Gelatin Flavouring agents f) Sodium benzoate Stabilisers and thickeners g) Sulphur dioxide preservatives
  • 14. What is the function of these traditional medicines? a) lime b) garlic c) ginger d) onions e) Betel leaves- daun sireh a) To increase digestive juice b) Has antibiotic property c) To warm the body d) To purift blood e) Stop bleeding nose
  • 15. What is the function of these modern medicines? a) analgesics b) antibiotics c) Psychotherapeutic medicines a) To relieve pain without affecting consciousness b) Kill bacteria c) To treat mental illness
  • 16. a) stimulants b) Anti depressant c) Antipsychotic drug a) To stimulate mental activity b) To control worry, fear, anxiety, panic c) To treat psychotic illness or schizophrenia c) Psychotherapeutic medicines
  • 17. What type of modern medicines? analgesics Anti biotics a) aspirin b) Penicillin c) streptomycin d) Para cetamol e) caffeine f) codeine g) barbiturate Anti biotics analgesics stimulant analgesics antidepressant h) tranquiliser antidepressant
  • 18. What is the uses of modern medicines? Fever, prevent heart attack fever a) aspirin b) Penicillin c) streptomycin d) Para cetamol f) codeine pneumonia Tuberculosis, dysentry Treat gonorrhea, syphlis, pneumonia, meningitis Cough medicine, headache
  • 19. Soap: RCOO – Na + or R COO – K + Detergent: What is general formula for soap? and detergent?
  • 20. What does hard water contains? •Hard water contains calcium ion, Ca2+ or magnesium ion, Mg2+.
  • 21. Why do soaps form scum with hard water? • Soap reacts with calcium ion, Ca2+ or magnesium ion, Mg2+ in hard water to form insoluble salt, called scum
  • 22. Why is soap not effective in hard water? • Because formation of scum reduce the amount of soap for cleaning and thus wastage of soap occur.
  • 23. Why is detergent more effective than soap in hard water?  • Detergent form soluble salt with  calcium ion, Ca2+ or magnesium ion, Mg2+ in hard  water. • Therefore the cleaning power is  not affected by hard water.
  • 24. Below are some additives in detergents. Fill in missing words Additives Functions 1 Drying agents ( such as sodium sulphate, sodium silicate) to keep the powder……… ………. DRY
  • 25. Additives Functions 2 Builders ( such as Sodium triphosphate) …………… water. softe n
  • 26. Additives Functions 3 Biological enzymes ( such as amylase, lipase) to digest in dirt or to modify fabric feel PROTEIN, FAT OR CARBOHYDRA TE
  • 27. Additives Functions 4 Such as sodium perborate Convert stains into ………………… substances colourles s
  • 28. Additives Functions 5  Perfumes Make clothes  smell   ……………. And  clean fres h
  • 29. Additives Functions 6. Stabilizers ( such as silicones) Prevent formation of ………………foam
  • 31.
  • 32.
  • 33.
  • 34.
  • 35.
  • 36.
  • 38. Many reactions of ethanol
  • 39. Reaction 1 • Combustion • ethanol is burnt in excess oxygen Observation: ethanol burns with blue flame, no soot
  • 40. Reaction 2 • Dehydration • ethanol is passed over heated porcelain chips to produce ethene Observation: gas formed that will decolorize brown bromine water
  • 41. Reaction 3 • hydration or addition of steam • When a mixture of ethene and steam is heated over phosphoric acid as catalyst, temp of 300o C, pressure 60 atm.
  • 42. Reaction 4 • Esterification • When a mixture of ethanol and ethanoic acid is warmed with conc sulphuric acid as catalyst, Observation: sweet smelling liquid is formed
  • 43. Reaction 5 • Esterification • When a mixture of ethanoic acid and ethanol is warmed with conc sulphuric acid as catalyst Observation: Sweet smelling liquid is formed
  • 44. Reaction 6 • Oxidation • When ethanol is warmed with acidified potassium dichromate as oxidizing agent Observation: Orange solution change to green
  • 46. 5) A student obtained the data to determine heat of precipitation of PbSO4 Solution Vol (cm3) Conc (moldm- 3) Initial temp (0 C) Pb(NO3)2 50 0.5 27.4 Na2SO4 50 0.5 27.6 Highest temperature : 30.5 0 C Question 4- thermochemistry
  • 47. What is meant by heat of precipitation? • Heat changed when 1 mole of precipitate is formed from its ions in an aqueous solution
  • 48. b) Calculate heat of precipitation of PbSO4 • Mole Pb 2+ : (0.5)(50)/1000 = 0.025 mol • Mole SO4 2- : (0.5)(50)/1000 = 0.025 mol • Pb2+ + SO2- 4 PbSO4 mole PbSO4 = Mole Pb2+ or mole SO2- 4 = 0.025 mol
  • 49. ϴ = 30.5 - ( 27.4 + 27.6 ) 2 = 3.0 ° C Heat of precipitation = mCϴ mol = ( 100)(4.2)(3) 0.025 = 50400 J/mol ∆ H = - 50.4 KJ/mol
  • 50. d)Write thermo chemical equation •Pb2+ + SO4 2- PbSO4 ∆ H = - 50.4 KJ/mol
  • 51. e) Write the ionic equation •Pb2+ + SO4 2- PbSO4
  • 52. E) Construct energy level diagram Pb2+ + SO4 2- Energy ∆ H = - 50.4 KJ/mol PbSO4
  • 53. f) The experiment is repeated using K2SO4 to replaced Na2SO4. Heat of precipitation of PbSO4 remain the same. Explain. • Because the same precipitate is formed, which is PbSO4. • Only Pb 2+ ions and SO4 2- ions react • Na+ ions and K+ ions do not react
  • 54. • 6) A student carried out an experiment to determine heat of displacement of copper from CuSO4 solution. He added excess zinc powder to 50 cm3 of 0.2 moldm-3 CuSO4. The thermo chemical equation is shown below : Zn + Cu2+ Zn2+ + Cu ∆ H = -80.64 KJ/mol
  • 55. a) Calculate the change in temperature Mol Copper= mol copper(II) sulphate = (0.2)(50)/1000 = 0.01 mol ∆ H = mCϴ mol 80 640 J = ( 50)(4.2)(ϴ) 0.01 ϴ = 3.8 ° C
  • 56. b) Write the ionic equation Zn + CuSO4  Cu + ZnSO4 Zn + Cu2+  Zn2+ + Cu
  • 57. The experiment is repeated with the following changes. What is the effect in the change of temperature when : • Concentration of CuSO4 is doubled, without changing the volume : So, change of temp or ϴ is doubled. Because as the concentration doubled, the number of particle per unit volume also doubled.
  • 58. The experiment is repeated with the following changes. What is the effect in the change of temperature when : • volume of CuSO4 is halved, without changing the concentration : So, change of temp or ϴ is remain the same. Because, the changes in volume do not affect the number of particles per unit volume
  • 59. 7) State the diff betw heat change and the heat of reaction HEAT CHANGE HEAT OF REACTION A) OTHER NAMES Depends on name of reactions : Heat absorb , heat released -Heat of Precipitation -Heat of displacement -Heat of neutralisation -Heat of combustion
  • 60. 7) State the differences between heat change and heat of reaction HEAT CHANGE HEAT OF REACTION B) FORMULA USED H= mCϴ ∆ H= mCϴ mol C)UNIT Joule Kilo Joule/ mol D) SYMBOL none ∆ H E) SIGN No sign Either + for endothermic rex or – for exothermic rex