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By : Siti Auliaddina
Do you know the definition of acids
      and bases in general ?
Produce H+ (as H3O+) ions in water
Produce a negative ion (-) too
Taste sour
Corrode metals
React with bases to form salts and water
 Produce OH- ions in water
 Are electrolytes
 Feel soapy, slippery
 React with acids to form salts and water



                 LecturePLUS Timberlake      4
•   Used for acid and bases in solution
    (neutralization)
•   Cations (positive ions) derived from the
    bases and anions (negative ions) derived
    from acid
•   Salt: compounds which can remove ion of
•   H + positive and negative ion of non OH-
 Acids produce H+ in aqueous solutions
             water
    HCl              H+(aq) + Cl- (aq)

 Bases produce OH- in aqueous solutions
             water
    NaOH             Na+(aq) + OH- (aq)
• In this idea, the ionization of an acid by water is
  just one example of an acid-base reaction.

                  H            H
                                 +
 Cl H    +    O             HO    +        Cl
                 H               H
 acid        base       conjugate acid conjugate base
             conjugate acid-base pairs
• Acids and bases are identified based on whether
  they donate or accept H+.
• “Conjugate” acids and bases are found on the
  products side of the equation. A conjugate base
  is the same as the starting acid minus H+.
Arrehenius                  Acids – produce H+
     only in water              Bases - produce OH-


                                Acids – donate H+
    Bronsted-Lowry
                                Bases – accept H+
    any solvent



          Lewis                 Acids – accept e- pair
used in organic chemistry,      Bases – donate e- pair
wider range of substances
Acid, Base   Name
        or Salt
CaCl2   ______       _________________
KOH     ______       _________________
Ba(OH)2 ______       _________________
HBr     ______       _________________
H2SO4   ______       __________________
   The pH scale
    measures
    how acidic
    or basic a
    solution is.
   The pH scale is the concentration of
    hydrogen ions in a given substance.




       pH         log H
 Acids   have a ph from 0-7
   Lower pH value indicates a
    stronger acid.


 Bases   have a pH from 7-14
   Higher pH value indicates a
    stronger base.
Strong acids/bases – 100% dissociation into ions

     HCl                    NaOH
     HNO3                   KOH
     H2SO4
Weak acids/bases – partial dissociation,
               both ions and molecules

     CH3COOH                NH3
        Weak Acid          Weak Base
pH of Rainwater
      across United States in 2001


                                          You
                                           are
                                          here!




Why is the eastern US more acidic?
     http://nadp.sws.uiuc.edu/isopleths
Dissolved carbon dioxide lowers the pH

CO2 (g) +   H2O  H2CO3  H+ + HCO3-


Atmospheric pollutants from combustion

NO, NO2 + H2O …      HNO3          both
                                    strong
                                    acids

SO2, SO3 +    H2O …  H2SO4

                  pH < 5.3
Acid & base

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Acid & base

  • 1. By : Siti Auliaddina
  • 2. Do you know the definition of acids and bases in general ?
  • 3. Produce H+ (as H3O+) ions in water Produce a negative ion (-) too Taste sour Corrode metals React with bases to form salts and water
  • 4.  Produce OH- ions in water  Are electrolytes  Feel soapy, slippery  React with acids to form salts and water LecturePLUS Timberlake 4
  • 5.
  • 6. Used for acid and bases in solution (neutralization) • Cations (positive ions) derived from the bases and anions (negative ions) derived from acid • Salt: compounds which can remove ion of • H + positive and negative ion of non OH-
  • 7.  Acids produce H+ in aqueous solutions water HCl H+(aq) + Cl- (aq)  Bases produce OH- in aqueous solutions water NaOH Na+(aq) + OH- (aq)
  • 8. • In this idea, the ionization of an acid by water is just one example of an acid-base reaction. H H + Cl H + O HO + Cl H H acid base conjugate acid conjugate base conjugate acid-base pairs • Acids and bases are identified based on whether they donate or accept H+. • “Conjugate” acids and bases are found on the products side of the equation. A conjugate base is the same as the starting acid minus H+.
  • 9. Arrehenius  Acids – produce H+ only in water  Bases - produce OH-  Acids – donate H+ Bronsted-Lowry  Bases – accept H+ any solvent Lewis  Acids – accept e- pair used in organic chemistry,  Bases – donate e- pair wider range of substances
  • 10. Acid, Base Name or Salt CaCl2 ______ _________________ KOH ______ _________________ Ba(OH)2 ______ _________________ HBr ______ _________________ H2SO4 ______ __________________
  • 11. The pH scale measures how acidic or basic a solution is.
  • 12. The pH scale is the concentration of hydrogen ions in a given substance. pH log H
  • 13.  Acids have a ph from 0-7  Lower pH value indicates a stronger acid.  Bases have a pH from 7-14  Higher pH value indicates a stronger base.
  • 14. Strong acids/bases – 100% dissociation into ions HCl NaOH HNO3 KOH H2SO4 Weak acids/bases – partial dissociation, both ions and molecules CH3COOH NH3 Weak Acid Weak Base
  • 15. pH of Rainwater across United States in 2001 You are here! Why is the eastern US more acidic? http://nadp.sws.uiuc.edu/isopleths
  • 16. Dissolved carbon dioxide lowers the pH CO2 (g) + H2O  H2CO3  H+ + HCO3- Atmospheric pollutants from combustion NO, NO2 + H2O …  HNO3 both strong acids SO2, SO3 + H2O …  H2SO4 pH < 5.3