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Algae
Fuel of
Biofuel
the Future
Presented by
KONERU VAMSI KRISHNA
138W1A0389
Agenda
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Introduction to Biofuels
Why Algae Biofuel?
Production Process
Production Costs
Rates of Improvement
Entrepreneurial Opportunities
Conclusion
Biofuels โ€“ the green alternative
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Derived form biological materials through biomass conversion
Renewable
Production requires more effort and resources
Can significantly reduce greenhouse gas
โ€ข Release CO2 when burning
โ€ข Biofuel production consumes it back
Types:
emissions
โ€ข
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Ethanol
Biodiesel
Bio gasoline
Bio butanol
Methane
Jet fuel
Evolution of Biofuel Production
http://www.responsiblebusiness.eu/display/rebwp7/Technology
1st 2ndGeneration vs. Generation
1st 2ndGeneration: Generation:
โ€ข โ€ขProduced mainly from agricultural
crops traditionally grown for food
and animal purposes
Wheat, sugar cane and oily seeds
Contribute to higher food prices,
carbon stores & land use
Net energy negative
Produced from non-edible crops
grown on non-arable land
Lignocellulosic biomass or woody
crops, agricultural residues or
organic waste
Harder to extract the required fuel
Potential to be net energy positive
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Agenda
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โ€ข
Introduction to Biofuels
Why Algae Biofuel?
Production Process
Production Costs
Rates of Improvement
Entrepreneurial Opportunities
Conclusion
Algal Basics
โ€ข Algae are simple plants that range from microalgae to large
seaweeds, such as giant kelp
Algae can be grown using brackish-, sea-, and wastewater
unsuitable for cultivating agricultural crops
Most microalgae grow through photosynthesis by
converting sunlight, CO2, and a few nutrients, including
nitrogen and phosphorous, into biomass
Other algae can grow in the dark using sugar or starch
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Why Algae Biofuel?
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Can be grown on marginal lands useless for ordinary crops
High yield per acre โ€“ have a harvesting cycle of 1โ€“10 days
Can be grown with minimal impact on fresh water resources
Can be grown using flue gas from power plants as
a CO2 source
Can convert a much higher fraction of biomass to oil thanโ€ข
conventional crops, e.g. 60% versus 2-3% for soybean
Comparison of Oil Yields
โ€ข Algae yield is multiple times higher than
other biofuel crops
Algae Biofuel vs. Other Biofuels
โ€ข Algae biofuel production also fares better than others in
greenhouse gas emissions and resources needed for fuel
manufacturing, except energy
Biofuel Energy Density Comparison
โ€ข Algae oil
biofuels
energy density is comparable to currently used
60
50
40
30
20
10
0
Biofuels
http://biofuel.org.uk/types-of-biofuels.html
EnergyDensity(MJ/kg)
Agenda
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Introduction to Biofuels
Why Algae Biofuel?
Production Process
Production Costs
Rates of Improvement
Entrepreneurial Opportunities
Conclusion
Algae Biofuel Production Process
Overview of Algae Production
Pyrolysis
Source: Biofuels from algae: challenges and potential, Michael Hannon et al.
Algae Oil Production Process
Source: T.J. Lundquist et al: A Realistic Technology and Engineering Assessment of Algae Biofuel Production
Algae Species
โ€ข Microalgae preferred:
โ€ข Highest-yielding algae in the wild โ€“ Aquatic unicellular
green algae (Chlorophyceae)
High growth rates & population densities
Can double its biomass in < 24 hours
Harvesting cycle: 1-10 days
Less complex structure
Higher oil content
Produces oil, protein & sugars
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โ€ข Areas of improvements
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Polycultures
Genetic engineering:
Improve traits โ€“ tolerant to harsh conditions
& enhanced growth & yield
Biosafety issue โ€“may facilitate survival and growth of
GE algae in unmanaged ecosystems, detrimental to
natural environment
โ€ข
http://www.oilgae.com/algae/oil/yield/yield.html#sthash.f2Udun8U.dpuf
http://link.springer.com/article/10.1007/s10811-010-9644-1
Microalgal species Oil
content(%)
Ankistrodesmus TR-87 28-40
Botryococcus braunii 29-75
Chlorella sp. 29
Chlorella 15-55
protothecoides(autotrophic/ he
terothrophic)
Cyclotella DI- 35 42
Dunaliella tertiolecta 36-42
Hantzschia DI-160 66
Nannochloris 31(6-63)
Nannochloropsis 46(31-68)
Nitzschia TR-114 28-50
Phaeodactylum tricornutum 31
Scenedesmus TR-84 45
Stichococcus 33(9-59)
Tetraselmis suecica 15-32
Thalassiosira pseudonana (21-31)
Crpthecodinium cohnii 20
Neochloris oleoabundans 35-54
Schiochytrium 50-77
Algae Growth Methods
Open Pond vs PBR - Cost Comparison
OP = Open pond
PBR -Photobioreactor
Source: http://www.energytrendsinsider.com/2012/05/07/current-and-projected-costs-for-biofuels-from-algae-and-pyrolysis
Dominant Growth Method
โ€ข Open pond is likely to become dominant:
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Lower capital investment
Easy to scale up
No cleaning required
Yield improvement because of genetic engineering and polycultures
Contamination risk can be reduced by genetic engineering and
polycultures
ftp://ftp.fao.org/docrep/fao/011/ak333e/ak333e00.pdf
Current Oil Extraction Process
http://sjvceonews.blogspot.sg/2010_10_01_archive.html
Future Oil Extraction Process
http://sjvceonews.blogspot.sg/2010_10_01_archive.html
Future Oil Extraction Process
http://sjvceonews.blogspot.sg/2010_10_01_archive.html
Biomass Processing โ€“ Cost Improvement
Source: http://www.energytrendsinsider.com/2012/05/07/current-and-projected-costs-for-biofuels-from-algae-and-pyrolysis/
Impact of Improvements on Future
Algae Cost
Source: http://www.energytrendsinsider.com/2012/05/07/current-and-projected-costs-for-biofuels-from-algae-and-pyrolysis/
Agenda
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Introduction to Biofuels
Why Algae Biofuel?
Production Process
Production Costs
Rates of Improvement
Entrepreneurial Opportunities
Conclusion
Biofuels vs. Fossil Fuels
http://www.afdc.energy.gov/fuels/prices.html
Biofuel Production
Source: http://antaresgroupinc.com/algae-biofuels/
Agenda
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Introduction to Biofuels
Why Algae Biofuel?
Production Process
Production Costs
Rates of Improvement
Entrepreneurial Opportunities
Conclusion
Summary of where Improvements Occur
โ€ข Improvement in production methods. For example:
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Using flue gas
Using waste water
Using genetically engineered algae to increase oil yield
โ€ข Improvement in harvesting methods. For example:
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Liquefaction
Hydrogenation
Pyrolysis
โ€ข Improvement in technology ๏ƒ  Conversion of algae
different form of fuel. For example:
to
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Bio-ethanol; Bio-methane;
Bio-hydrogen; Bio-butanol;
Bio-Diesel; bio-gasoline;
Jet fuel
Timeline for Algal Fuel
Source: Algae 2020 study, Emerging Markets Online Consulting Services
Biofuel
Region
Demand in Transport Sector by
ExaJoules (EJ) = 10^18 Joules
this demand is expected to be fulfilled by algae biofuel sinceMajor part of
it has high potential in terms of technology and yield.
Source: https://www.iea.org/publications/freepublications/publication/Biofuels_Roadmap_WEB.pdf
Global
Sector
Energy Use in the Transport
in 2050
Global energy use in the transport sector (left) and use of biofuels in
different transport modes (right) in 2050
Source: https://www.iea.org/publications/freepublications/publication/Biofuels_Roadmap_WEB.pdf
How
Use
Government Policy Affects Biofuel
Source: Battle for the Barrel, Robert F. Service
Inhibiting Factors
โ€ข Algaculture is performed mainly to produce high added value
compounds used in food and cosmetics
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โ€ข
Biggest inhibiting factors are capital, harvesting and fuel extraction costs
New methods of energy-efficient extraction of fuel is needed e.g.
hydrolysis
Source: Energy-efficient extraction of fuel and chemical feedstocks from algae, Rodrigo E. Teixeira
Algae-based Biofuels: A Review of Challenges and Opportunities for Developing Countries
Product Type Unique Product Price/Kg
Healthfood Spirulina ~S$ 12
Food for aquatic organisms Nannochloropsis ~S$ 725
Vitamin A precursor รŸ-carotene ~S$ 1,450
Anti-oxidant Astaaxanthin ~S$ 15,000
Fatty acids 13C labelled fatty acids ~S$ 51 M
Algal Biofuel ~S$ 9
Agenda
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โ€ข
Introduction to Biofuels
Why Algae Biofuel?
Production Process
Production Costs
Rates of Improvement
Entrepreneurial Opportunities
Conclusion
Commercial Uses of Algae
Biogas Bioethanol
Nutraceuticals
Pharmaceuticals
Vitamins
Cosmetics
BiobutanolBiodiesel
Biofuel
Food
Bioplastics
Feedstock Fertilizer/nutrientsAnimal feed
Algal Products
http://solazyme.com/innovation/
Building Powered by Algae
Building in Hamburg with a facade of bioreactors
Bioreactors contain algae which generate biomass and heat sustainably
System provides thermal and sound insulation
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โ€ข Algae biomass can be harvested and converted
pharmaceutical and food products
to biogas, or used in
SolarLeaf โ€“ bioreactor faรงade
http://syndebio.com/biq-algae-house-splitterwerk/
Algae Architecture
http://www.lyxia.com/algal-architecture-and-automobile-design/
What Changes might enable
Farming in buildings?
Glass Production Technology
Algae
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Ultra-strong glass with thinner walls
Increased light penetration and larger volumes
Mechanical stability allows continuous in-line cleaning
Efficient use of Lightings
โ€ข Redirect sunlight into building interior
โ€ข Use of existing LED lightings at night for continuous algae production
Genetic Modification of Algae
โ€ข Significantly higher concentration in terms of mass per litre
โ€ข Grow in the dark algae strains created through genetic modification
Policies enabling the use of empty spaces
โ€ข External walls, rooftops & walls of stairwells
Cost per kilowatt hour needs to become lower
โ€ข Current estimates: cost per kilowatt-hour produced by algae bioreactors would be 7
times as much as solar power and 14 times as much as crude oil
Offshore Membrane Enclosures
for Growing Algae (OMEGA)
http://www.nasa.gov/centers/ames/research/OMEGA/#.VQ1FSPmUc9Q
From ALPHA to OMEGA
http://blog.planetos.com/nasa-omega-project-the-ocean-as-a-platform-for-biofuel/
Agenda
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โ€ข
Introduction to Biofuels
Why Algae Biofuel?
Production Process
Production Costs
Rates of Improvement
Entrepreneurial Opportunities
Conclusion
Conclusion
Algae Biofuel is a very promising candidate to replace fossil fuels
โ€ข
โ€ข
Algaeโ€™s cultivation does not require that it compete with food crops
Ability for algae to be cultivated on non-arable land, using saltwater,
greatly reduces its impact on the environment
Produces over 20 times the oil production of any food crop - an acre of
algae can produce almost 5,000 gallons of biodiesel
Production can reach 60 billion gallons/year that could replace all diesel in
the U.S.
However, current economic climate makes development of algal programs
quite costly
For algae to be truly competitive, it should receive its own share of the
subsidies currently only allocated to feedstock
A highly feasible way to continue biofuel development while remaining
commercially competitive is to produce algal fuel as a co-product to more
lucrative products such as animal feed and nutraceuticals product
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Thank You!
Any Questions?

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Algae fuel

  • 1. Algae Fuel of Biofuel the Future Presented by KONERU VAMSI KRISHNA 138W1A0389
  • 2. Agenda โ€ข โ€ข โ€ข โ€ข โ€ข โ€ข โ€ข Introduction to Biofuels Why Algae Biofuel? Production Process Production Costs Rates of Improvement Entrepreneurial Opportunities Conclusion
  • 3. Biofuels โ€“ the green alternative โ€ข โ€ข โ€ข โ€ข Derived form biological materials through biomass conversion Renewable Production requires more effort and resources Can significantly reduce greenhouse gas โ€ข Release CO2 when burning โ€ข Biofuel production consumes it back Types: emissions โ€ข โ€ข โ€ข โ€ข โ€ข โ€ข โ€ข Ethanol Biodiesel Bio gasoline Bio butanol Methane Jet fuel
  • 4. Evolution of Biofuel Production http://www.responsiblebusiness.eu/display/rebwp7/Technology
  • 5. 1st 2ndGeneration vs. Generation 1st 2ndGeneration: Generation: โ€ข โ€ขProduced mainly from agricultural crops traditionally grown for food and animal purposes Wheat, sugar cane and oily seeds Contribute to higher food prices, carbon stores & land use Net energy negative Produced from non-edible crops grown on non-arable land Lignocellulosic biomass or woody crops, agricultural residues or organic waste Harder to extract the required fuel Potential to be net energy positive โ€ข โ€ข โ€ข โ€ข โ€ขโ€ข
  • 6. Agenda โ€ข โ€ข โ€ข โ€ข โ€ข โ€ข โ€ข Introduction to Biofuels Why Algae Biofuel? Production Process Production Costs Rates of Improvement Entrepreneurial Opportunities Conclusion
  • 7. Algal Basics โ€ข Algae are simple plants that range from microalgae to large seaweeds, such as giant kelp Algae can be grown using brackish-, sea-, and wastewater unsuitable for cultivating agricultural crops Most microalgae grow through photosynthesis by converting sunlight, CO2, and a few nutrients, including nitrogen and phosphorous, into biomass Other algae can grow in the dark using sugar or starch โ€ข โ€ข โ€ข
  • 8. Why Algae Biofuel? โ€ข โ€ข โ€ข โ€ข Can be grown on marginal lands useless for ordinary crops High yield per acre โ€“ have a harvesting cycle of 1โ€“10 days Can be grown with minimal impact on fresh water resources Can be grown using flue gas from power plants as a CO2 source Can convert a much higher fraction of biomass to oil thanโ€ข conventional crops, e.g. 60% versus 2-3% for soybean
  • 9. Comparison of Oil Yields โ€ข Algae yield is multiple times higher than other biofuel crops
  • 10. Algae Biofuel vs. Other Biofuels โ€ข Algae biofuel production also fares better than others in greenhouse gas emissions and resources needed for fuel manufacturing, except energy
  • 11. Biofuel Energy Density Comparison โ€ข Algae oil biofuels energy density is comparable to currently used 60 50 40 30 20 10 0 Biofuels http://biofuel.org.uk/types-of-biofuels.html EnergyDensity(MJ/kg)
  • 12. Agenda โ€ข โ€ข โ€ข โ€ข โ€ข โ€ข โ€ข Introduction to Biofuels Why Algae Biofuel? Production Process Production Costs Rates of Improvement Entrepreneurial Opportunities Conclusion
  • 14. Overview of Algae Production Pyrolysis Source: Biofuels from algae: challenges and potential, Michael Hannon et al.
  • 15. Algae Oil Production Process Source: T.J. Lundquist et al: A Realistic Technology and Engineering Assessment of Algae Biofuel Production
  • 16. Algae Species โ€ข Microalgae preferred: โ€ข Highest-yielding algae in the wild โ€“ Aquatic unicellular green algae (Chlorophyceae) High growth rates & population densities Can double its biomass in < 24 hours Harvesting cycle: 1-10 days Less complex structure Higher oil content Produces oil, protein & sugars โ€ข โ€ข โ€ข โ€ข โ€ข โ€ข โ€ข Areas of improvements โ€ข โ€ข โ€ข Polycultures Genetic engineering: Improve traits โ€“ tolerant to harsh conditions & enhanced growth & yield Biosafety issue โ€“may facilitate survival and growth of GE algae in unmanaged ecosystems, detrimental to natural environment โ€ข http://www.oilgae.com/algae/oil/yield/yield.html#sthash.f2Udun8U.dpuf http://link.springer.com/article/10.1007/s10811-010-9644-1 Microalgal species Oil content(%) Ankistrodesmus TR-87 28-40 Botryococcus braunii 29-75 Chlorella sp. 29 Chlorella 15-55 protothecoides(autotrophic/ he terothrophic) Cyclotella DI- 35 42 Dunaliella tertiolecta 36-42 Hantzschia DI-160 66 Nannochloris 31(6-63) Nannochloropsis 46(31-68) Nitzschia TR-114 28-50 Phaeodactylum tricornutum 31 Scenedesmus TR-84 45 Stichococcus 33(9-59) Tetraselmis suecica 15-32 Thalassiosira pseudonana (21-31) Crpthecodinium cohnii 20 Neochloris oleoabundans 35-54 Schiochytrium 50-77
  • 18. Open Pond vs PBR - Cost Comparison OP = Open pond PBR -Photobioreactor Source: http://www.energytrendsinsider.com/2012/05/07/current-and-projected-costs-for-biofuels-from-algae-and-pyrolysis
  • 19. Dominant Growth Method โ€ข Open pond is likely to become dominant: โ€ข โ€ข โ€ข โ€ข โ€ข Lower capital investment Easy to scale up No cleaning required Yield improvement because of genetic engineering and polycultures Contamination risk can be reduced by genetic engineering and polycultures ftp://ftp.fao.org/docrep/fao/011/ak333e/ak333e00.pdf
  • 20. Current Oil Extraction Process http://sjvceonews.blogspot.sg/2010_10_01_archive.html
  • 21. Future Oil Extraction Process http://sjvceonews.blogspot.sg/2010_10_01_archive.html
  • 22. Future Oil Extraction Process http://sjvceonews.blogspot.sg/2010_10_01_archive.html
  • 23. Biomass Processing โ€“ Cost Improvement Source: http://www.energytrendsinsider.com/2012/05/07/current-and-projected-costs-for-biofuels-from-algae-and-pyrolysis/
  • 24. Impact of Improvements on Future Algae Cost Source: http://www.energytrendsinsider.com/2012/05/07/current-and-projected-costs-for-biofuels-from-algae-and-pyrolysis/
  • 25. Agenda โ€ข โ€ข โ€ข โ€ข โ€ข โ€ข โ€ข Introduction to Biofuels Why Algae Biofuel? Production Process Production Costs Rates of Improvement Entrepreneurial Opportunities Conclusion
  • 26. Biofuels vs. Fossil Fuels http://www.afdc.energy.gov/fuels/prices.html
  • 28. Agenda โ€ข โ€ข โ€ข โ€ข โ€ข โ€ข โ€ข Introduction to Biofuels Why Algae Biofuel? Production Process Production Costs Rates of Improvement Entrepreneurial Opportunities Conclusion
  • 29. Summary of where Improvements Occur โ€ข Improvement in production methods. For example: โ€ข โ€ข โ€ข Using flue gas Using waste water Using genetically engineered algae to increase oil yield โ€ข Improvement in harvesting methods. For example: โ€ข โ€ข โ€ข Liquefaction Hydrogenation Pyrolysis โ€ข Improvement in technology ๏ƒ  Conversion of algae different form of fuel. For example: to โ€ข โ€ข โ€ข โ€ข Bio-ethanol; Bio-methane; Bio-hydrogen; Bio-butanol; Bio-Diesel; bio-gasoline; Jet fuel
  • 30. Timeline for Algal Fuel Source: Algae 2020 study, Emerging Markets Online Consulting Services
  • 31. Biofuel Region Demand in Transport Sector by ExaJoules (EJ) = 10^18 Joules this demand is expected to be fulfilled by algae biofuel sinceMajor part of it has high potential in terms of technology and yield. Source: https://www.iea.org/publications/freepublications/publication/Biofuels_Roadmap_WEB.pdf
  • 32. Global Sector Energy Use in the Transport in 2050 Global energy use in the transport sector (left) and use of biofuels in different transport modes (right) in 2050 Source: https://www.iea.org/publications/freepublications/publication/Biofuels_Roadmap_WEB.pdf
  • 33. How Use Government Policy Affects Biofuel Source: Battle for the Barrel, Robert F. Service
  • 34. Inhibiting Factors โ€ข Algaculture is performed mainly to produce high added value compounds used in food and cosmetics โ€ข โ€ข Biggest inhibiting factors are capital, harvesting and fuel extraction costs New methods of energy-efficient extraction of fuel is needed e.g. hydrolysis Source: Energy-efficient extraction of fuel and chemical feedstocks from algae, Rodrigo E. Teixeira Algae-based Biofuels: A Review of Challenges and Opportunities for Developing Countries Product Type Unique Product Price/Kg Healthfood Spirulina ~S$ 12 Food for aquatic organisms Nannochloropsis ~S$ 725 Vitamin A precursor รŸ-carotene ~S$ 1,450 Anti-oxidant Astaaxanthin ~S$ 15,000 Fatty acids 13C labelled fatty acids ~S$ 51 M Algal Biofuel ~S$ 9
  • 35. Agenda โ€ข โ€ข โ€ข โ€ข โ€ข โ€ข โ€ข Introduction to Biofuels Why Algae Biofuel? Production Process Production Costs Rates of Improvement Entrepreneurial Opportunities Conclusion
  • 36. Commercial Uses of Algae Biogas Bioethanol Nutraceuticals Pharmaceuticals Vitamins Cosmetics BiobutanolBiodiesel Biofuel Food Bioplastics Feedstock Fertilizer/nutrientsAnimal feed
  • 38. Building Powered by Algae Building in Hamburg with a facade of bioreactors Bioreactors contain algae which generate biomass and heat sustainably System provides thermal and sound insulation โ€ข โ€ข โ€ข โ€ข Algae biomass can be harvested and converted pharmaceutical and food products to biogas, or used in SolarLeaf โ€“ bioreactor faรงade http://syndebio.com/biq-algae-house-splitterwerk/
  • 40. What Changes might enable Farming in buildings? Glass Production Technology Algae โ€ข โ€ข โ€ข Ultra-strong glass with thinner walls Increased light penetration and larger volumes Mechanical stability allows continuous in-line cleaning Efficient use of Lightings โ€ข Redirect sunlight into building interior โ€ข Use of existing LED lightings at night for continuous algae production Genetic Modification of Algae โ€ข Significantly higher concentration in terms of mass per litre โ€ข Grow in the dark algae strains created through genetic modification Policies enabling the use of empty spaces โ€ข External walls, rooftops & walls of stairwells Cost per kilowatt hour needs to become lower โ€ข Current estimates: cost per kilowatt-hour produced by algae bioreactors would be 7 times as much as solar power and 14 times as much as crude oil
  • 41. Offshore Membrane Enclosures for Growing Algae (OMEGA) http://www.nasa.gov/centers/ames/research/OMEGA/#.VQ1FSPmUc9Q
  • 42. From ALPHA to OMEGA http://blog.planetos.com/nasa-omega-project-the-ocean-as-a-platform-for-biofuel/
  • 43. Agenda โ€ข โ€ข โ€ข โ€ข โ€ข โ€ข โ€ข Introduction to Biofuels Why Algae Biofuel? Production Process Production Costs Rates of Improvement Entrepreneurial Opportunities Conclusion
  • 44. Conclusion Algae Biofuel is a very promising candidate to replace fossil fuels โ€ข โ€ข Algaeโ€™s cultivation does not require that it compete with food crops Ability for algae to be cultivated on non-arable land, using saltwater, greatly reduces its impact on the environment Produces over 20 times the oil production of any food crop - an acre of algae can produce almost 5,000 gallons of biodiesel Production can reach 60 billion gallons/year that could replace all diesel in the U.S. However, current economic climate makes development of algal programs quite costly For algae to be truly competitive, it should receive its own share of the subsidies currently only allocated to feedstock A highly feasible way to continue biofuel development while remaining commercially competitive is to produce algal fuel as a co-product to more lucrative products such as animal feed and nutraceuticals product โ€ข โ€ข โ€ข โ€ข โ€ข