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GeoPower Turkey, Istanbul 2011




                            Geothermal Power Plants

                                 Linde - Cryostar




                                                      1
GeoPower Turkey, Istanbul 2011



Linde and Cryostar
                                 World Presence - Figures



The Linde Group

  •Global presence in > 100 countries
  •48’000 employees
  • € 11.2 Mrd sales (year 2009)


Cryostar   (Linde Engineering subsidiary)

  •Global presence
  •500 employees
  •€ 150 M sales (year 2009)
                                                            Linde Group Presence
                                                                                   2
GeoPower Turkey, Istanbul 2011



Linde and Cryostar
                                     Markets & Technologies Focus

                                                              Energy Value Chain
                                                                                                 Energy Transport
                                         Energy Extraction          Energy Conversion
                                                                                                 Storage & Usage
Linde                                Baseload      Floating   GTL          NG Process.     Merchant      LPG
Existing Business   Fossil           LNG           LNG                                     LNG
                    (Gaseous)
                                     Unconv. Gas              Cogene-
Linde                                                         ration
Business Focus
                                     N2 EOR        NRU        Clean Coal   Refinery        CO2 Network
Linde               Fossil                                                 Hydrogen
Technology Focus    (Solid Liquid)   CO2 EOR                  Oxyfuel      PCC


Linde & Cryostar                     Geothermal    Heat       Biomass      Photo Voltaïc   Hydrogen
Joint Focus         Renewable                      Recovery   Conv.                        as Fuel
                                     Solar                    Green                        Energy
                                     Thermal                  Hydrogen                     Storage
                                                                                                                    3
GeoPower Turkey, Istanbul 2011



Linde & Cryostar
                           Vision and objectives for geothermal business


•   Geothermal business is a key target for Linde & cryostar

•   Technology is characterized by
     • Higher power output
     • Better efficiency / Energy output on « off design » points
     • Expertise of both Linde & Cryostar

•   Offer characterized by
     • Flexible ORC and Power Plant design
     • From turbo generator up to turnkey power plant supply

•   We want to become the reference for geothermal power plant in Europe

                                                                           4
GeoPower Turkey, Istanbul 2011



Linde & Cryostar
                          Linde and Cryostar Offer

•   Cryostar
     • Turbogenerator
     • ORCs
     • Engineering, Manufacturing, on site Construction Supervision, Local sourcing, Local Subcontracting

•   Linde and Cryostar
      • Turnkey Power plants (engineering, equipment sourcing, and construction)
         From wells heads up to grid connexion
      • EPC contract
      • Engineering, Manufacturing, on site Construction, Local sourcing, Local Subcontracting




                                                                                                            5
GeoPower Turkey, Istanbul 2011



Linde & Cryostar
                      Split of scope of supply for turnkey power plants

                        Item                                                   Linde   Cryostar
                        Project Management
                        Process Engineering for ORC
                        Process Engineering for Geothermal loop
                        Process Engineering for District Heating
                        Detailed Engineering
   Leader               Equipment Supply (turbo generator excluded)
                        Equipment Supply (Turbo generator + Aux)
    Assistant
                        Civil Work / Steel Structure / Piping / Elect. Works
                        Construction
                        Precommissioning
                        Start-up & Performances
                        Commissioning & Final Acceptance

                                                                                                  6
GeoPower Turkey, Istanbul 2011



Linde & Cryostar
                          Sub and Supercritical cycle

                                                                  Temp.
                                                                                                   Supercritical
•   Supercritical ORC = Medium Pressure over critical pressure                                     Available
     • Built and tested in the US in the 80s                                                       Work Lost
     • Our solution is application for ORC at medium pressure
        of current high performance supercritical steam rankine cycle
                                                                                   Dual Pressure
        (used in more than 500 modern coal fired power plants)

•   Subcritical cycle dual pressure ORC
                                                                          Single Pressure
•   Subcritical cycle single pressure ORC

                                                                                    Air
                                                                                                   Entropy
                                                                                                          7
GeoPower Turkey, Istanbul 2011



Linde & Cryostar
                             Sub and Supercritical cycle
Advantages of medium pressure supercritical ORC

     •   Recovering the largest amount of heat with minimized energy losses

     •   Smoother and easier evaporation process compared to the conventional
          design which would need preheater, vaporiser and superheater

     •   Easy control: no risk of ingress of liquid inside the turbine

     •   Standard execution of radial turbine

     •   High pressure operation reduces the frame size of the turbine



                                                                                8
GeoPower Turkey, Istanbul 2011



 Linde
                                             References
                                                                     Biogas refuelling stations with   LNG plant, StatoilHydro,                           LNG import terminal, StatoilHydro,   PCC flue gas wash, RWE,
                                                                                                       Hammerfest, Norway                                 Nynäshamn, Sweden                    Niederaußem, Germany
Linde is already involved                                            LNG backup, Sweden


in many clean energy projects


                                   Landfill gas LNG plant,
                                                                                                                                                                                               Oxyfuel pilot plant, Vattenfall,
                                   Waste Management, Altamont,
                                                                                                                                                                                               Schwarze Pumpe, Germany
                                   USA




                                   N2 EOR plant, Pemex, Cantarell,    CO2 network, OCAP,
                                                                                                                                                                                               LNG plant network for fleet
                                   Mexico                             Rotterdam/Amsterdam,
                                                                                                                                                                                               fueling, South East Australia
                                                                      Netherlands




Hydrogen Fuel Stations, Germany,                                      CO2 injection for EGR, Gas de                      CO2 injection and storage, GFZ    N2 EOR plant, ADNOC,
USA, Japan, China                                                     France, Maxdorf, Germany                           Potsdam, Ketzin, Germany          Mirfa, Abu Dhabi




                                                                                                                                                                                                                               9
GeoPower Turkey, Istanbul 2011



Linde
                          LNG References

•   Linde covers the entire LNG value chain
•   Commercial plants in operation and under construction

•   Altamont California
     • Landfill Gas from the natural decomposition of
        organic waste
     • World’s largest landfill gas to liquefied natural gas
     • Use of Cryostar LNG pumps and dispensers

•   Stockholm, Sweden
      • LNG terminal to supply greater Stockholm area with
        NG


                                                               10
GeoPower Turkey, Istanbul 2011



Linde
                            CCS References, e.g., Post Combustion Capture

•   Projects description:
     • Cooperation with RWE
     • Capturing carbon from flue gas of coal-fired power plants
     • Pilot plant status, 1 552 Nm3/h flue gas from lignite power plant ,
         7.2 t/d CO2
     • Since Q1/2010, tests with new solvent
     • Lower steam consumption (-20%)

•   Next Steps
     • Demonstration of scaled technology in DoE financed project
     • Extended operational testing for long term stability
     • CO2 utilization for tests and R&D programs


                                                                             11
GeoPower Turkey, Istanbul 2011



Linde
                            Algea References
Algea to Biofuel: Sapphire Energy & Algenol Biofuels

     •   Method utilizes algae, CO2, salt water and sunlight to directly
         produce 3G bioethanol and other 3G biofuels.

     •   Optimal and cost-efficient supply of CO2 key success factor.

     •   CO2 from fossil fuel sources.

     •   Fuels or chemicals from algae are a promising way of reducing
         green-house gas emissions.

     •   Sapphire Energy: open-pond, algae-to-fuel cultivation systems.

     •   Algenol: photobioreactor technology

                                                                           12
GeoPower Turkey, Istanbul 2011



Linde
                           2011 Highlights & outlook: Hydrogen as fuel
                                                                                    Fuelling station projects currently implemented in G.A.S.
Highlights
                                                                                                      Shell, Berlin                             Vattenfall, Hamburg
      • 13 Mio € order intake                                                                         -Commissioning: Q2/ 2011                  -Commissioning: Q4/ 2011
                                                                                                                                                -

      • 10 stations projects won
      • H2 supplier & partner of Mercedes-Benz World Drive                                           Linde, Munich
                                                                                                     -Commissioning: Q2/ 2011
                                                                                                                                                H2 Mobility, Germany
                                                                                                                                                - 2 Stations for TOTAL:
                                                                                                     - Linde HRS-Test Center                    - 2 Stations for EnBW:

      • Daimler and Linde announced integrated initiative to set-up 20 additional                                                               -C
                                                                                                                                                -
                                                                                                                                                  ommissioning: Q3 + Q4/ 2011



          H2 stations until 2014                                                                      ATZ, Vienna                               BMW, Munich
                                                                                                      -Commissioning: Q4/ 2011                  - 2 Prototype Stations:


      • New H2 dustribution concept for efficient bulk H2 delivery                                    - ATZComponent-Test Center                -Commissioning: Q3/ 2011
                                                                                                                                                    + Q4/ 2012



      • Certified green H2 @ biomass to hydrogen plant, Leuna site
      • Handover of first public station with newly developed
          cryo pump and underground LH2 storage (Shell Berlin)

Mid-term strategic perspective
     • Aim to be leading H2 as fuel supplier in full value chain
     • Improve H2 sourcing to lever current strength in refueling
     • Build capabilities to scale up to be ready for vehicle ramp-up in 2015
                                                                                                                                                                                13
GeoPower Turkey, Istanbul 2011



Cryostar
                           References
Turbines and turbogenerators
      • 1800 turbines in operation worldwide
      • 200 turbogenerators in operation


Geothermal projects in operation

     •   Soultz-sous-Forêts (France)
           • EGS project
           • ORC – Isobutane
           • Radial inflow turbine - TG400 - 2,5MWel

     •   Unterhaching (Germany)
           • Kalina: Ammonia/water
           • Radial inflow turbine - TG500 - 3,7MWel

                                                       14
GeoPower Turkey, Istanbul 2011



Linde & Cryostar
                           2011 Highlights - Geothermal

Turnkey geothermal power plants

     •   under construction
           • 1 project won in Germany

     •   Final bid
            • Several projects in Europe




                                                          15
GeoPower Turkey, Istanbul 2011



Linde & Cryostar



                          Thank you for your attention

                                                         Cryostar Headquarters Hésingue France
Cryostar SAS
ZI - BP 48
68220 Hésingue France


Damien THIOLET
Business Development
Tel: 03.89.70.27.97
Damien.thiolet@cryostar.com
www.cryostar.com
                                                                                                 16

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Geothermal Power Plants

  • 1. GeoPower Turkey, Istanbul 2011 Geothermal Power Plants Linde - Cryostar 1
  • 2. GeoPower Turkey, Istanbul 2011 Linde and Cryostar World Presence - Figures The Linde Group •Global presence in > 100 countries •48’000 employees • € 11.2 Mrd sales (year 2009) Cryostar (Linde Engineering subsidiary) •Global presence •500 employees •€ 150 M sales (year 2009) Linde Group Presence 2
  • 3. GeoPower Turkey, Istanbul 2011 Linde and Cryostar Markets & Technologies Focus Energy Value Chain Energy Transport Energy Extraction Energy Conversion Storage & Usage Linde Baseload Floating GTL NG Process. Merchant LPG Existing Business Fossil LNG LNG LNG (Gaseous) Unconv. Gas Cogene- Linde ration Business Focus N2 EOR NRU Clean Coal Refinery CO2 Network Linde Fossil Hydrogen Technology Focus (Solid Liquid) CO2 EOR Oxyfuel PCC Linde & Cryostar Geothermal Heat Biomass Photo Voltaïc Hydrogen Joint Focus Renewable Recovery Conv. as Fuel Solar Green Energy Thermal Hydrogen Storage 3
  • 4. GeoPower Turkey, Istanbul 2011 Linde & Cryostar Vision and objectives for geothermal business • Geothermal business is a key target for Linde & cryostar • Technology is characterized by • Higher power output • Better efficiency / Energy output on « off design » points • Expertise of both Linde & Cryostar • Offer characterized by • Flexible ORC and Power Plant design • From turbo generator up to turnkey power plant supply • We want to become the reference for geothermal power plant in Europe 4
  • 5. GeoPower Turkey, Istanbul 2011 Linde & Cryostar Linde and Cryostar Offer • Cryostar • Turbogenerator • ORCs • Engineering, Manufacturing, on site Construction Supervision, Local sourcing, Local Subcontracting • Linde and Cryostar • Turnkey Power plants (engineering, equipment sourcing, and construction) From wells heads up to grid connexion • EPC contract • Engineering, Manufacturing, on site Construction, Local sourcing, Local Subcontracting 5
  • 6. GeoPower Turkey, Istanbul 2011 Linde & Cryostar Split of scope of supply for turnkey power plants Item Linde Cryostar Project Management Process Engineering for ORC Process Engineering for Geothermal loop Process Engineering for District Heating Detailed Engineering Leader Equipment Supply (turbo generator excluded) Equipment Supply (Turbo generator + Aux) Assistant Civil Work / Steel Structure / Piping / Elect. Works Construction Precommissioning Start-up & Performances Commissioning & Final Acceptance 6
  • 7. GeoPower Turkey, Istanbul 2011 Linde & Cryostar Sub and Supercritical cycle Temp. Supercritical • Supercritical ORC = Medium Pressure over critical pressure Available • Built and tested in the US in the 80s Work Lost • Our solution is application for ORC at medium pressure of current high performance supercritical steam rankine cycle Dual Pressure (used in more than 500 modern coal fired power plants) • Subcritical cycle dual pressure ORC Single Pressure • Subcritical cycle single pressure ORC Air Entropy 7
  • 8. GeoPower Turkey, Istanbul 2011 Linde & Cryostar Sub and Supercritical cycle Advantages of medium pressure supercritical ORC • Recovering the largest amount of heat with minimized energy losses • Smoother and easier evaporation process compared to the conventional design which would need preheater, vaporiser and superheater • Easy control: no risk of ingress of liquid inside the turbine • Standard execution of radial turbine • High pressure operation reduces the frame size of the turbine 8
  • 9. GeoPower Turkey, Istanbul 2011 Linde References Biogas refuelling stations with LNG plant, StatoilHydro, LNG import terminal, StatoilHydro, PCC flue gas wash, RWE, Hammerfest, Norway Nynäshamn, Sweden Niederaußem, Germany Linde is already involved LNG backup, Sweden in many clean energy projects Landfill gas LNG plant, Oxyfuel pilot plant, Vattenfall, Waste Management, Altamont, Schwarze Pumpe, Germany USA N2 EOR plant, Pemex, Cantarell, CO2 network, OCAP, LNG plant network for fleet Mexico Rotterdam/Amsterdam, fueling, South East Australia Netherlands Hydrogen Fuel Stations, Germany, CO2 injection for EGR, Gas de CO2 injection and storage, GFZ N2 EOR plant, ADNOC, USA, Japan, China France, Maxdorf, Germany Potsdam, Ketzin, Germany Mirfa, Abu Dhabi 9
  • 10. GeoPower Turkey, Istanbul 2011 Linde LNG References • Linde covers the entire LNG value chain • Commercial plants in operation and under construction • Altamont California • Landfill Gas from the natural decomposition of organic waste • World’s largest landfill gas to liquefied natural gas • Use of Cryostar LNG pumps and dispensers • Stockholm, Sweden • LNG terminal to supply greater Stockholm area with NG 10
  • 11. GeoPower Turkey, Istanbul 2011 Linde CCS References, e.g., Post Combustion Capture • Projects description: • Cooperation with RWE • Capturing carbon from flue gas of coal-fired power plants • Pilot plant status, 1 552 Nm3/h flue gas from lignite power plant , 7.2 t/d CO2 • Since Q1/2010, tests with new solvent • Lower steam consumption (-20%) • Next Steps • Demonstration of scaled technology in DoE financed project • Extended operational testing for long term stability • CO2 utilization for tests and R&D programs 11
  • 12. GeoPower Turkey, Istanbul 2011 Linde Algea References Algea to Biofuel: Sapphire Energy & Algenol Biofuels • Method utilizes algae, CO2, salt water and sunlight to directly produce 3G bioethanol and other 3G biofuels. • Optimal and cost-efficient supply of CO2 key success factor. • CO2 from fossil fuel sources. • Fuels or chemicals from algae are a promising way of reducing green-house gas emissions. • Sapphire Energy: open-pond, algae-to-fuel cultivation systems. • Algenol: photobioreactor technology 12
  • 13. GeoPower Turkey, Istanbul 2011 Linde 2011 Highlights & outlook: Hydrogen as fuel Fuelling station projects currently implemented in G.A.S. Highlights Shell, Berlin Vattenfall, Hamburg • 13 Mio € order intake -Commissioning: Q2/ 2011 -Commissioning: Q4/ 2011 - • 10 stations projects won • H2 supplier & partner of Mercedes-Benz World Drive Linde, Munich -Commissioning: Q2/ 2011 H2 Mobility, Germany - 2 Stations for TOTAL: - Linde HRS-Test Center - 2 Stations for EnBW: • Daimler and Linde announced integrated initiative to set-up 20 additional -C - ommissioning: Q3 + Q4/ 2011 H2 stations until 2014 ATZ, Vienna BMW, Munich -Commissioning: Q4/ 2011 - 2 Prototype Stations: • New H2 dustribution concept for efficient bulk H2 delivery - ATZComponent-Test Center -Commissioning: Q3/ 2011 + Q4/ 2012 • Certified green H2 @ biomass to hydrogen plant, Leuna site • Handover of first public station with newly developed cryo pump and underground LH2 storage (Shell Berlin) Mid-term strategic perspective • Aim to be leading H2 as fuel supplier in full value chain • Improve H2 sourcing to lever current strength in refueling • Build capabilities to scale up to be ready for vehicle ramp-up in 2015 13
  • 14. GeoPower Turkey, Istanbul 2011 Cryostar References Turbines and turbogenerators • 1800 turbines in operation worldwide • 200 turbogenerators in operation Geothermal projects in operation • Soultz-sous-Forêts (France) • EGS project • ORC – Isobutane • Radial inflow turbine - TG400 - 2,5MWel • Unterhaching (Germany) • Kalina: Ammonia/water • Radial inflow turbine - TG500 - 3,7MWel 14
  • 15. GeoPower Turkey, Istanbul 2011 Linde & Cryostar 2011 Highlights - Geothermal Turnkey geothermal power plants • under construction • 1 project won in Germany • Final bid • Several projects in Europe 15
  • 16. GeoPower Turkey, Istanbul 2011 Linde & Cryostar Thank you for your attention Cryostar Headquarters Hésingue France Cryostar SAS ZI - BP 48 68220 Hésingue France Damien THIOLET Business Development Tel: 03.89.70.27.97 Damien.thiolet@cryostar.com www.cryostar.com 16