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Canned	
  Heat	
  Energy	
  Storage	
  
J.	
  Skardon	
  	
  
2	
  June	
  2013	
  
	
  jskardon@gmail.com	
  
CONFIDENTIAL-­‐	
  John	
  N.	
  Skardon	
  
 	
  	
  	
  	
  Thermal	
  Energy	
  Storage	
  (TES)-­‐Technology	
  Status	
  
	
  
The	
   purpose	
   of	
   Thermal	
   Energy	
   Storage	
   (TES)	
   systems	
   is	
   to	
   store	
   a	
   sizeable	
   quanNty	
   of	
   thermal	
  
energy	
  (heat	
  or	
  cold)	
  for	
  long	
  periods.	
  The	
  ability	
  to	
  store	
  thermal	
  energy	
  is	
  very	
  important	
  for	
  using	
  
renewable	
  energy	
  in	
  heaNng	
  and	
  cooling	
  systems	
  effecNvely,	
  since	
  it	
  decouples	
  the	
  availability	
  of	
  
renewable	
   energy	
   from	
   the	
   Nme	
   when	
   it	
   is	
   needed,	
   thus	
   increasing	
   the	
   degree	
   which	
   it	
   can	
   be	
  
uNlized.	
  
	
  
There	
  are	
  three	
  major	
  reasons	
  for	
  using	
  thermal	
  energy	
  storage:	
  
	
  
1.  Improving	
   system	
   efficiency	
   by	
   avoiding	
   parNal	
   load	
   operaNon	
   ,or	
   operaNon	
   at	
   other	
   sub-­‐
opNmal	
  Nmes,	
  or	
  taking	
  advantage	
  of	
  waste	
  energy	
  (e.g.	
  heat	
  released	
  from	
  chillers).	
  This	
  can	
  
involve	
  storage	
  over	
  hours,	
  days	
  or	
  months.	
  
2.  ShiUing	
   demand	
   over	
   Nme	
   to	
   reduce	
   peak	
   loads.	
   This	
   can	
   improve	
   overall	
   energy	
   system	
  
efficiency,	
   reduce	
   investment	
   in	
   energy	
   infrastructure	
   and	
   reduce	
   costs.	
   Storage	
   is	
   typically	
  
required	
  for	
  hours	
  or	
  days.	
  
3.  FacilitaNng	
  the	
  greater	
  use	
  of	
  renewable	
  energy	
  by	
  storing	
  energy	
  available	
  at	
  a	
  certain	
  Nme,	
  so	
  
it	
  can	
  beVer	
  cover	
  demand	
  (storing	
  solar	
  thermal	
  energy	
  over	
  days,	
  weeks	
  or	
  months	
  to	
  match	
  
water	
  and/or	
  space	
  heaNng	
  demand).	
  
CONFIDENTIAL-­‐	
  John	
  N.	
  Skardon	
  
Canned	
  Heat	
  (CH)-­‐Energy	
  Storage	
  Technology	
  
CONFIDENTIAL-­‐	
  John	
  N.	
  Skardon	
  
•  We	
  plan	
  to	
  commercialize	
  a	
  technology	
  for	
  storing	
  energy	
  in	
  adsorbents.	
  
•  Charging	
  the	
  storage	
  unit	
  is	
  done	
  with	
  a	
  variety	
  of	
  waste	
  heat	
  sources	
  or	
  using	
  
renewable	
  driven	
  heaters.	
  
	
  	
  
•  Heat	
   can	
   be	
   extracted	
   at	
   60-­‐80ºC	
   by	
   simply	
   adding	
   humid	
   air	
   via	
   a	
   baVery	
  
powered	
  fan.	
  	
  
	
  
•  Material	
  used	
  are	
  low	
  cost,	
  well	
  studied,	
  but	
  can	
  also	
  be	
  grown	
  as	
  a	
  thin	
  film,	
  
enabling	
   us	
   to	
   use	
   micro	
   fabricaNon	
   techniques	
   to	
   achieve	
   very	
   high	
   storage	
  
densiNes.	
  
	
  
•  Markets	
   include	
   seasonal	
   storage	
   of	
   excess	
   thermal	
   energy	
   in	
   summer,	
  	
  
emergency	
  heat	
  for	
  first	
  responders	
  and	
  military	
  during	
  disasters,	
  intrinsically	
  
safe	
  process	
  heat	
  (no	
  flame	
  or	
  spark),	
  space	
  heaNng	
  of	
  all	
  types.	
  
Some	
  Basics	
  (CH)	
  
	
  
	
  
Adsorbents	
  Material:	
  
•  Can	
  be	
  purchased	
  (bulk)	
  or	
  made	
  on	
  site.	
  
•  Can	
  be	
  grown	
  as	
  very	
  thin	
  film.	
  	
  
•  Energy	
  storage	
  200kw/m3,	
  upper	
  limit	
  may	
  be	
  300+.	
  
	
  
OperaAon	
  Mode:	
  
•  Charging	
  Mode:	
  	
  Energy	
  stored	
  when	
  H20	
  is	
  desorbed. 	
  	
  
•  Discharge	
  Mode:	
  	
  Energy	
  released	
  when	
  H20	
  (humid	
  air)	
  added	
  .	
   	
  	
  
•  Reversible,	
  no	
  degradaNon.	
  
Science	
  Background	
  :	
  
•  Surface	
  science.	
  	
  
•  Langmuir	
  Isotherms.	
  
CONFIDENTIAL-­‐	
  John	
  N.	
  Skardon	
  
RH,T	
  sensors	
  	
  
60-­‐80º	
  Hot	
  
Dry	
  Air	
  
output	
  	
  	
  
Micro	
  Controller	
  Unit	
  	
  
RH,T	
  sensors	
  	
  
25-­‐35ºC	
  
90%	
  RH	
  Air	
  
input	
  	
  
Adsorbent	
  filled	
  cylinder	
  
	
  	
  	
  (Insulated)	
  
*As	
  water	
  adsorbs	
  onto	
  the	
  adsorber,	
  energy	
  is	
  released	
  and	
  the	
  weight	
  of	
  the	
  adsorber	
  
	
  	
  container	
  increases	
  due	
  to	
  the	
  adsorbed	
  water	
  (max	
  about	
  250mg/g	
  of	
  H20).	
  
*RH-­‐RelaNve	
  Humidity	
  	
  
*T-­‐	
  Temperature	
  
AdsorpAon/Discharge	
  Mode	
  (GeneraAon	
  of	
  Heat)	
  
CONFIDENTIAL-­‐	
  John	
  N.	
  Skardon	
  
	
  	
  
Canned	
  Heat	
  -­‐Concept:	
  
Adsorbent	
  filled	
  cylinder	
  
	
  	
  	
  (Insulated)	
  
100-­‐250ºC	
  
Renewable	
  powered	
  	
  
air	
  heater	
  or	
  waste	
  
heat.	
  
Hot	
  moist	
  air	
  out	
  
	
  (60-­‐80ºC)	
  
DesorpAon/Charging	
  Mode	
  (Thermal	
  Storage)	
  
*As	
  water	
  desorbs,	
  steam	
  is	
  released	
  and	
  the	
  weight	
  of	
  the	
  adsorber	
  container	
  decreases.	
  
CONFIDENTIAL-­‐	
  John	
  N.	
  Skardon	
  
Canned	
  Heat	
  -­‐	
  Concept:	
  
Output:	
  Dry	
  hot/moist	
  
air	
  depending	
  on	
  the	
  	
  
mode	
  of	
  operaAon.	
  
Water	
  circulaAon	
  to	
  
generate	
  humid	
  air.	
  
Storage	
  mode	
  :	
  
	
  Input	
  heated	
  air	
  from	
  
fan	
  100-­‐250ºC.	
  
	
  GeneraAon	
  mode	
  :	
  
Input	
  90%	
  RH	
  air	
  using	
  a	
  
fan	
  powered	
  by	
  solar	
  	
  
VenAlator	
  
powered	
  by	
  solar	
  	
  
energy	
  	
  for	
  hot	
  air	
  
generaAon.	
  
Renewable	
  solar	
  	
  
energy.	
  
CONFIDENTIAL-­‐	
  John	
  N.	
  Skardon	
  
Adsorber	
  
filled	
  
Cylinder	
  
(CH)	
  	
  	
  	
  
Commercial	
  CH	
  -­‐	
  Energy	
  Storage	
  System	
  	
  
Simple	
  Product	
  Concept	
  
•Energy	
  storage	
  appliance	
  
•Modular/expandable	
  energy	
  storage	
  “bank”.	
  
•Room	
  Heater.	
  
•Emergency	
  Heat	
  for	
  car,	
  truck,	
  first	
  responder.	
  
•Seasonal	
  heat	
  storage.	
  
	
  •Carbon	
  credits.	
  
A	
  20kg	
  unit	
  can	
  store	
  about	
  1KW	
  indefinitely	
  at	
  
room	
  temp.	
  Unit	
  must	
  be	
  kept	
  air	
  Nght	
  during	
  
storage	
  (valves	
  closed)	
  
CONFIDENTIAL-­‐	
  John	
  N.	
  Skardon	
  
Summary:	
  	
  

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Low fidelity prototype assignment

  • 1. Canned  Heat  Energy  Storage   J.  Skardon     2  June  2013    jskardon@gmail.com   CONFIDENTIAL-­‐  John  N.  Skardon  
  • 2.          Thermal  Energy  Storage  (TES)-­‐Technology  Status     The   purpose   of   Thermal   Energy   Storage   (TES)   systems   is   to   store   a   sizeable   quanNty   of   thermal   energy  (heat  or  cold)  for  long  periods.  The  ability  to  store  thermal  energy  is  very  important  for  using   renewable  energy  in  heaNng  and  cooling  systems  effecNvely,  since  it  decouples  the  availability  of   renewable   energy   from   the   Nme   when   it   is   needed,   thus   increasing   the   degree   which   it   can   be   uNlized.     There  are  three  major  reasons  for  using  thermal  energy  storage:     1.  Improving   system   efficiency   by   avoiding   parNal   load   operaNon   ,or   operaNon   at   other   sub-­‐ opNmal  Nmes,  or  taking  advantage  of  waste  energy  (e.g.  heat  released  from  chillers).  This  can   involve  storage  over  hours,  days  or  months.   2.  ShiUing   demand   over   Nme   to   reduce   peak   loads.   This   can   improve   overall   energy   system   efficiency,   reduce   investment   in   energy   infrastructure   and   reduce   costs.   Storage   is   typically   required  for  hours  or  days.   3.  FacilitaNng  the  greater  use  of  renewable  energy  by  storing  energy  available  at  a  certain  Nme,  so   it  can  beVer  cover  demand  (storing  solar  thermal  energy  over  days,  weeks  or  months  to  match   water  and/or  space  heaNng  demand).   CONFIDENTIAL-­‐  John  N.  Skardon  
  • 3. Canned  Heat  (CH)-­‐Energy  Storage  Technology   CONFIDENTIAL-­‐  John  N.  Skardon   •  We  plan  to  commercialize  a  technology  for  storing  energy  in  adsorbents.   •  Charging  the  storage  unit  is  done  with  a  variety  of  waste  heat  sources  or  using   renewable  driven  heaters.       •  Heat   can   be   extracted   at   60-­‐80ºC   by   simply   adding   humid   air   via   a   baVery   powered  fan.       •  Material  used  are  low  cost,  well  studied,  but  can  also  be  grown  as  a  thin  film,   enabling   us   to   use   micro   fabricaNon   techniques   to   achieve   very   high   storage   densiNes.     •  Markets   include   seasonal   storage   of   excess   thermal   energy   in   summer,     emergency  heat  for  first  responders  and  military  during  disasters,  intrinsically   safe  process  heat  (no  flame  or  spark),  space  heaNng  of  all  types.  
  • 4. Some  Basics  (CH)       Adsorbents  Material:   •  Can  be  purchased  (bulk)  or  made  on  site.   •  Can  be  grown  as  very  thin  film.     •  Energy  storage  200kw/m3,  upper  limit  may  be  300+.     OperaAon  Mode:   •  Charging  Mode:    Energy  stored  when  H20  is  desorbed.     •  Discharge  Mode:    Energy  released  when  H20  (humid  air)  added  .       •  Reversible,  no  degradaNon.   Science  Background  :   •  Surface  science.     •  Langmuir  Isotherms.   CONFIDENTIAL-­‐  John  N.  Skardon  
  • 5. RH,T  sensors     60-­‐80º  Hot   Dry  Air   output       Micro  Controller  Unit     RH,T  sensors     25-­‐35ºC   90%  RH  Air   input     Adsorbent  filled  cylinder        (Insulated)   *As  water  adsorbs  onto  the  adsorber,  energy  is  released  and  the  weight  of  the  adsorber      container  increases  due  to  the  adsorbed  water  (max  about  250mg/g  of  H20).   *RH-­‐RelaNve  Humidity     *T-­‐  Temperature   AdsorpAon/Discharge  Mode  (GeneraAon  of  Heat)   CONFIDENTIAL-­‐  John  N.  Skardon       Canned  Heat  -­‐Concept:  
  • 6. Adsorbent  filled  cylinder        (Insulated)   100-­‐250ºC   Renewable  powered     air  heater  or  waste   heat.   Hot  moist  air  out    (60-­‐80ºC)   DesorpAon/Charging  Mode  (Thermal  Storage)   *As  water  desorbs,  steam  is  released  and  the  weight  of  the  adsorber  container  decreases.   CONFIDENTIAL-­‐  John  N.  Skardon   Canned  Heat  -­‐  Concept:  
  • 7. Output:  Dry  hot/moist   air  depending  on  the     mode  of  operaAon.   Water  circulaAon  to   generate  humid  air.   Storage  mode  :    Input  heated  air  from   fan  100-­‐250ºC.    GeneraAon  mode  :   Input  90%  RH  air  using  a   fan  powered  by  solar     VenAlator   powered  by  solar     energy    for  hot  air   generaAon.   Renewable  solar     energy.   CONFIDENTIAL-­‐  John  N.  Skardon   Adsorber   filled   Cylinder   (CH)         Commercial  CH  -­‐  Energy  Storage  System    
  • 8. Simple  Product  Concept   •Energy  storage  appliance   •Modular/expandable  energy  storage  “bank”.   •Room  Heater.   •Emergency  Heat  for  car,  truck,  first  responder.   •Seasonal  heat  storage.    •Carbon  credits.   A  20kg  unit  can  store  about  1KW  indefinitely  at   room  temp.  Unit  must  be  kept  air  Nght  during   storage  (valves  closed)   CONFIDENTIAL-­‐  John  N.  Skardon   Summary: