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SEMINAR ON
PASHMINAFIBER
(PRODUCTION, PROCESSINGAND IDENTIFICATION)
Name-Chaitanya Chaudhary
Roll no.-12TT016
Date- 09-10-2015
CONTENTS
1. Introduction
2. Production
3. Properties
4. Processing
5. Marketing
6. Identification and Differentiation
7. Future thrust area of research
8. Conclusion
9. References
T.I.T.&S BHIWANI
1
INTRODUCTION
Pashmina, popularly known as
‘Cashmere’, is well known for its fineness,
warmth & softness. It is luxurious, softer
and warmer than superfine merino wool.
The word pashmina is originated from a
word ‘pashm’ means ‘soft gold’ in local
language. India produces about 40-50
tones of fiber annually. The fiber is mostly
used for preparing shawls with designs by
the artisans of J&K and Himchal.
T.I.T.&S BHIWANI
2
PRODUCTION
• The world-wide total production of pashmina fiber is about 10000-
15000 tons/annum.
• The major fiber producing countries are China, Mongolia, Iran,
Afghanistan, Pakistan, Nepal and India.
• China is the major producer of pashmina with the share of 70%
followed by Mongolia with 20% share. The rest 10% of the total
production is from other countries including India, which produces
less than 1% of the total production.
In India, two pashmina producing goat breeds are found i.e.
Changthangi and Chegu. Changthangi breed is domesticated in
Ladakh region of Jammu and Kashmir and Chegu in Lahul and Spitti
and Kinnaur region of Himachal Pradesh.
T.I.T&S BHIWANI 3.
PROPERTIES
Physical Properties
fiber fineness is the most important quality parameter giving value to
pashmina fiber and differentiates it from the sheep wool. The average fiber
fineness is 12-13 µ. The average fiber length is 35-40 mm. The fiber
length depends on its source, origin and grade. The mean fiber length of
guard hair varies from 25mm to 93 mm, which needs to be combed/sorted
for better spin ability.
Chemical Properties
Pashmina fiber is a protein fiber with polyamide polymer made up of 18
amino acids with α- keratin arranged in helical structure like that in
wool. Pashmina is more sensitive towards the chemicals due to its more
hydrophilic groups and less hydrophobic groups than in wool. The
breakdown of the fiber even at relatively low temperature and low
concentration in alkali.
T.I.T.&S BHIWANI
4
Structural Properties
The morphological structure of pashmina fiber is similar to fine wool
fiber comprising outer cuticle and cortex. However, there is no
medullation in the fiber. The cortex is the main fiber compound
surrounded by outer cuticle scales. The morphological structure of the
fiber is given in Fig. 1.
The SEM of pashmina fiber is given in Fig. 2. It shows the pashmina
fiber having even diameter and relatively distant & smooth cuticle
scales. The mean scale frequency is 10-15 per 100µm.
Fig. 1—Morphological structure of
wool
Fig. 2—SEM of (a) pashmina (b)
wool fibers
T.I.T.&S BHIWANI 5
1.fiber Harvesting and Marketing
fiber harvesting
• Raw pashmina is collected during spring moulting season when animals naturally
shed their undercoat.
• Combing is the major method of harvesting pashmina using special type of
comb.
• After harvesting, pashmina is dusted manually to remove adhered impurities
like sand, dust, etc.
Marketing
• Generally, white fibers with long fiber length fetch higher price since longer
fibers are easy to spin.
• The price of the fiber mainly depends on its fineness, length, colour and
fiber content.
• The price of raw pashmina fiber is 10-15 times more than that of crossbred fine
wool in India.
PROCESSING
T.I.T.&S BHIWANI
6
2. Dehairing
• Dehairing is a process by which outer coat of guard hair is separated from
the under coat fine fibers.
• Raw pashmina fiber is having 50-60% guard hair.
• The guard hair should be removed completely before processing for
improving the spin ability and for development of best quality products.
3.Scouring
• The pashmina fiber is scoured at fiber stage itself before dehairing.
• The scouring is done by using 0.2 gpl non-ionic detergent at 50°C for 10
min.
T.I.T.&S BHIWANI 7
4.Spinning
 Hand spun yarn
• On account of small availability of this specialty fiber, most of it is
utilized locally with the help of specially designed manually
operated traditional charkha locally known as yander.
• Traditionally, combing is done by impaling dehaired raw pashmina
repeatedly on an upright comb (10 cm wide, set on a wooden
stand).
• The yarn can be spun up to 108 Nm (92.6 tex). Generally, 2/64-
2/108 Nm yarn is spun for making high quality shawls.
 Machine Spun yarn
• The advent of technology, efforts have been made by the
industries to spun 100% pashmina yarn by mixing with nylon
fiber.
• The resultant sliver is then converted into roving on last
pre-spinning machine i.e. bobbiner. The roving is taken to
ring frame for spinning.
• In this process, the dehaired and carded sliver of pashmina
fiber is passed through gill box 3-4 times to remove the short
fibers and to parallelize them.
Fig-3 hand spun yarn on
charkha
Fig-4 Machine spun yarn
T.I.T.&S BHIWANI 8
• Property Hand spun Machine spun
• yarn yarn
• Breaking strength, kg 4.964 4.975
• Extension, % 40.72 25.67
• Alkali solubility, % 38.00 46.00
• Abrasion loss, % 3.75 5.73
• Thermal insulation, tog 2.00 1.95
Difference between the Performance properties of pashmina fabrics
produced from hand spun and machine spun yarns
Spinning of Pashmina with PVA
Pashmina fiber is also spun in machine using polyvinyl alcohol fiber (PVA) instead
of nylon as carrier fiber. PVA fibers are soluble in hot water. To remove the PVA from
the fabric, the fabric is treated with hot boiling water instead of hydrochloric acid. The
advantage of this technique is that pashmina fiber does not get damaged in hot water as
in case of HCl. This method of spinning is considered as ecofriendly but costly due to
the higher price of PVA fiber. Compared to nylon and PVA fiber, the PVA based
spinning of pashmina is ecofriendly due to the use of only hot water in place of
hydrochloric acid used for removing nylon.
T.I.T.&S BHIWANI 9
5.Weaving
• The weaving of pashmina yarn into shawl is carried out in a special type of handloom.
• Before weaving, pashmina yarn is sized with of starch/resin.
• The handloom weaving of shawl is usually done by the skilled artisans.
• The weight of the hand woven shawl is approximately 200 g.
• The ends and picks per inch are generally kept between 50-60 and 46-56 respectively.
• The fabric weight (GSM) is kept at 50-70g.
• The shawl is produced with intricate and unique designs viz. chasme bulbul, ribbed weave etc.
Some quantity of hand spun yarn is also used in knitting for manufacturing of pullover and
sweaters.
Fig-5 Weaving of pashmina shawl
T.I.T.&S BHIWANI
10
• .
6.Dyeing and Finishing
a)Dyeing
• The dyeing behavior of pashmina is identical with sheep wool. However, due
to hydrophilic outer cuticle, the uptake of dye is faster.
• The acid dyes, 1:1 metal-complex dyes, 1:2 metal-complex dyes and reactive
dyes are used for dyeing pashmina fabrics.
• Generally, pashmina fabrics are dyed with dark and bright colors like red, blue,
yellow, green and black.
• Dyeing with acid dyes is carried out at pH 2-3 with the addition of sulphuric
acid.
• The other important dye used for dyeing pashmina products is 1:2 metal
complex dyes.
(This class of dye provides excellent washing and light fastness to the
pashmina fabrics. )The dyeing of shawls is carried out in a pot type vessel
heated with gas stove by exhaust method.
• The dyeing of shawl is done individually by hand dyeing technique. After
dyeing the fabrics are air dried under relaxed condition.
T.I.T.&S BHIWANI 11
b)Finishing
• Pashmina products have unique softness property along with lustre. Therefore,
normally it does not require any finishing process. The addition of any type of
finishing agent may spoil the unique softness of the product. However, now-a-days,
the pashmina fabrics are produced out of machine spun yarn in blends with other
fibers. Such blended pashmina products are treated with thermoplastic softening
agents like silicone softener, nano-based softening agents, etc. in order to improve the
handle.
• The other important finishing treatments carried out on pashmina fabrics by few
dyers include anti-moth finishing and aroma finishing. Anti-moth chemical such as
Eulon is added during dyeing under acidic conditions. The aroma finishing is carried
out by using commercially available fragrance micro capsules.
T.I.T.&S BHIWANI 12
7.Designing and Embroidery
• Traditionally pashmina shawls are prepared with some unique designs. Hand
embroidery is done on pashmina shawls with unique design. The embroidery is
done with fine stitches using needles to intricate and unique designs.
• In some cases, block printing is also employed with the use of pigments, silver and
gold to decorate the fabrics with intricate designs. The Kashmir artisans use
different type of designing & techniques to produce the unique pashmina shawls
by hand jacquard, hand embroidery, block printing etc.
Embroidery on pashmina shawls
T.I.T.&S BHIWANI 13
MARKETING OF PASHMINAPRODUCTS
• Marketing of pashmina product is very important from consumer point of
view.
• Any product having soft feel and luster is being marketed in the name of
pashmina.
• Recently in order to check the sale of fake plain pashmina shawls,
Government of India has awarded the GI patent recognizing handmade
shawls of Kashmir origin. Under the GI of goods, Kashmiri handmade
pashmina shawls now can use their own logos.
GI registration was issued into two categories. In first category, the
entire process of shawl making would be hand made using vegetable colours
and the second category contain material process evolved over decades
would be permitted with both vegetable and synthetic colours.
T.I.T.&S BHIWANI 14
IDENTIFICATIONAND DIFFERENCE FROM OTHER FIBERS
• The pashmina fiber is one of the finest fibers in the world.
• It is an expensive resource for the textile industry which makes it susceptible to
falsifications. Instead of pashmina, the cheaper sheep wool is used and the product is
then declared as genuine pashmina.
• The products such as shawl and sweater made out of pashmina fiber are sold at about
10 times higher price compared to the similar products produced from merino
sheep wool.
• Therefore the textile industry and testing laboratories need detection methods which
guarantee reliable testing of cashmere products.
Fig-6 Pashmina wool fiber Fig-7 wool fiber
T.I.T.&S BHIWANI 15
• A fiber blend of pashmina and sheep wool
will give similar results in the
conventionally used textile testing
methods like light microscopic analysis,
chemical analysis, solvent method and
burning test. Chemically, there is little
difference between wool and pashmina.
At present, scanning electron
microscope (SEM) is used to differentiate
pashmina and wool fibers based on the
cuticle scale pattern. Cuticle scale
characteristics and scale height have
been used as the main diagnostic features
to classify wool and pashmina. Current
standard test methods for analyzing blends
of pashmina with sheep wool are based
on scanning electron microscopy
(SEM).
Microscopic Identification
Fig-8 Electron Microscope
T.I.T.&S BHIWANI 16
DNA ANALYSIS
• There are some fiber combinations, that even an experienced microscopist
cannot differentiate). Hence, several alternative methods like morphological
studies, protein and lipid analysis, DNA analysis etc. are developed by
the researchers.
• Molecular analyses of animal fibers for their amino acids, polypeptides and
lipids have been developed for the identification of different animal
fibers.
• The DNA analysis based method is promising one since pashmina and wool
are from different animal species. By this method, it is possible to distinguish
raw pashmina and wool.
T.I.T.&S BHIWANI 17
• Future Thrust Area of Research
• Several interventions made in processing and product development of pashmina
fiber by different agencies have increased productivity of spinning and weaving
processes which resulted in enhanced profitability of artisans engaged in this
sector.
• 1. Improvisation in Dehairing
• 2.Identification of Pashmina fiber
• 3.Cloning of pashmina goat(noori goat)
• 4. Introduction of Printed Designs
• 5. Improved Dyeing Techniques
T.I.T.&S BHIWANI
18
CONCLUSION
Pashmina is well known for its fineness, warmth & softness. It is
luxurious, softer and warmer than superfine merino wool. But it is
costlier then the other forms of wool fibers.
Due to similarities in physical, chemical and structural properties
of this fiber type with the other forms of wool fibers so it is
difficult to differentiate pashmina with other wool fiber, which
lead to the falsification in the pashmina products.
T.I.T.&S BHIWANI 19
REFERENCES
1. Indian Journal of fiber & Textile Research Vol. 38, June 2013, pp. 207-214
2. https://en.wikipedia.org/wiki/Pashmina
3. http://jksheephusbandrykashmir.nic.in/Pashmina_Wool.htm
4. https://en.wikipedia.org/wiki/Noori_(goat)
T.I.T.&S BHIWANI 20
THANK YOU

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Pashmina wool

  • 1. SEMINAR ON PASHMINAFIBER (PRODUCTION, PROCESSINGAND IDENTIFICATION) Name-Chaitanya Chaudhary Roll no.-12TT016 Date- 09-10-2015
  • 2. CONTENTS 1. Introduction 2. Production 3. Properties 4. Processing 5. Marketing 6. Identification and Differentiation 7. Future thrust area of research 8. Conclusion 9. References T.I.T.&S BHIWANI 1
  • 3. INTRODUCTION Pashmina, popularly known as ‘Cashmere’, is well known for its fineness, warmth & softness. It is luxurious, softer and warmer than superfine merino wool. The word pashmina is originated from a word ‘pashm’ means ‘soft gold’ in local language. India produces about 40-50 tones of fiber annually. The fiber is mostly used for preparing shawls with designs by the artisans of J&K and Himchal. T.I.T.&S BHIWANI 2
  • 4. PRODUCTION • The world-wide total production of pashmina fiber is about 10000- 15000 tons/annum. • The major fiber producing countries are China, Mongolia, Iran, Afghanistan, Pakistan, Nepal and India. • China is the major producer of pashmina with the share of 70% followed by Mongolia with 20% share. The rest 10% of the total production is from other countries including India, which produces less than 1% of the total production. In India, two pashmina producing goat breeds are found i.e. Changthangi and Chegu. Changthangi breed is domesticated in Ladakh region of Jammu and Kashmir and Chegu in Lahul and Spitti and Kinnaur region of Himachal Pradesh. T.I.T&S BHIWANI 3.
  • 5. PROPERTIES Physical Properties fiber fineness is the most important quality parameter giving value to pashmina fiber and differentiates it from the sheep wool. The average fiber fineness is 12-13 µ. The average fiber length is 35-40 mm. The fiber length depends on its source, origin and grade. The mean fiber length of guard hair varies from 25mm to 93 mm, which needs to be combed/sorted for better spin ability. Chemical Properties Pashmina fiber is a protein fiber with polyamide polymer made up of 18 amino acids with α- keratin arranged in helical structure like that in wool. Pashmina is more sensitive towards the chemicals due to its more hydrophilic groups and less hydrophobic groups than in wool. The breakdown of the fiber even at relatively low temperature and low concentration in alkali. T.I.T.&S BHIWANI 4
  • 6. Structural Properties The morphological structure of pashmina fiber is similar to fine wool fiber comprising outer cuticle and cortex. However, there is no medullation in the fiber. The cortex is the main fiber compound surrounded by outer cuticle scales. The morphological structure of the fiber is given in Fig. 1. The SEM of pashmina fiber is given in Fig. 2. It shows the pashmina fiber having even diameter and relatively distant & smooth cuticle scales. The mean scale frequency is 10-15 per 100µm. Fig. 1—Morphological structure of wool Fig. 2—SEM of (a) pashmina (b) wool fibers T.I.T.&S BHIWANI 5
  • 7. 1.fiber Harvesting and Marketing fiber harvesting • Raw pashmina is collected during spring moulting season when animals naturally shed their undercoat. • Combing is the major method of harvesting pashmina using special type of comb. • After harvesting, pashmina is dusted manually to remove adhered impurities like sand, dust, etc. Marketing • Generally, white fibers with long fiber length fetch higher price since longer fibers are easy to spin. • The price of the fiber mainly depends on its fineness, length, colour and fiber content. • The price of raw pashmina fiber is 10-15 times more than that of crossbred fine wool in India. PROCESSING T.I.T.&S BHIWANI 6
  • 8. 2. Dehairing • Dehairing is a process by which outer coat of guard hair is separated from the under coat fine fibers. • Raw pashmina fiber is having 50-60% guard hair. • The guard hair should be removed completely before processing for improving the spin ability and for development of best quality products. 3.Scouring • The pashmina fiber is scoured at fiber stage itself before dehairing. • The scouring is done by using 0.2 gpl non-ionic detergent at 50°C for 10 min. T.I.T.&S BHIWANI 7
  • 9. 4.Spinning  Hand spun yarn • On account of small availability of this specialty fiber, most of it is utilized locally with the help of specially designed manually operated traditional charkha locally known as yander. • Traditionally, combing is done by impaling dehaired raw pashmina repeatedly on an upright comb (10 cm wide, set on a wooden stand). • The yarn can be spun up to 108 Nm (92.6 tex). Generally, 2/64- 2/108 Nm yarn is spun for making high quality shawls.  Machine Spun yarn • The advent of technology, efforts have been made by the industries to spun 100% pashmina yarn by mixing with nylon fiber. • The resultant sliver is then converted into roving on last pre-spinning machine i.e. bobbiner. The roving is taken to ring frame for spinning. • In this process, the dehaired and carded sliver of pashmina fiber is passed through gill box 3-4 times to remove the short fibers and to parallelize them. Fig-3 hand spun yarn on charkha Fig-4 Machine spun yarn T.I.T.&S BHIWANI 8
  • 10. • Property Hand spun Machine spun • yarn yarn • Breaking strength, kg 4.964 4.975 • Extension, % 40.72 25.67 • Alkali solubility, % 38.00 46.00 • Abrasion loss, % 3.75 5.73 • Thermal insulation, tog 2.00 1.95 Difference between the Performance properties of pashmina fabrics produced from hand spun and machine spun yarns Spinning of Pashmina with PVA Pashmina fiber is also spun in machine using polyvinyl alcohol fiber (PVA) instead of nylon as carrier fiber. PVA fibers are soluble in hot water. To remove the PVA from the fabric, the fabric is treated with hot boiling water instead of hydrochloric acid. The advantage of this technique is that pashmina fiber does not get damaged in hot water as in case of HCl. This method of spinning is considered as ecofriendly but costly due to the higher price of PVA fiber. Compared to nylon and PVA fiber, the PVA based spinning of pashmina is ecofriendly due to the use of only hot water in place of hydrochloric acid used for removing nylon. T.I.T.&S BHIWANI 9
  • 11. 5.Weaving • The weaving of pashmina yarn into shawl is carried out in a special type of handloom. • Before weaving, pashmina yarn is sized with of starch/resin. • The handloom weaving of shawl is usually done by the skilled artisans. • The weight of the hand woven shawl is approximately 200 g. • The ends and picks per inch are generally kept between 50-60 and 46-56 respectively. • The fabric weight (GSM) is kept at 50-70g. • The shawl is produced with intricate and unique designs viz. chasme bulbul, ribbed weave etc. Some quantity of hand spun yarn is also used in knitting for manufacturing of pullover and sweaters. Fig-5 Weaving of pashmina shawl T.I.T.&S BHIWANI 10
  • 12. • . 6.Dyeing and Finishing a)Dyeing • The dyeing behavior of pashmina is identical with sheep wool. However, due to hydrophilic outer cuticle, the uptake of dye is faster. • The acid dyes, 1:1 metal-complex dyes, 1:2 metal-complex dyes and reactive dyes are used for dyeing pashmina fabrics. • Generally, pashmina fabrics are dyed with dark and bright colors like red, blue, yellow, green and black. • Dyeing with acid dyes is carried out at pH 2-3 with the addition of sulphuric acid. • The other important dye used for dyeing pashmina products is 1:2 metal complex dyes. (This class of dye provides excellent washing and light fastness to the pashmina fabrics. )The dyeing of shawls is carried out in a pot type vessel heated with gas stove by exhaust method. • The dyeing of shawl is done individually by hand dyeing technique. After dyeing the fabrics are air dried under relaxed condition. T.I.T.&S BHIWANI 11
  • 13. b)Finishing • Pashmina products have unique softness property along with lustre. Therefore, normally it does not require any finishing process. The addition of any type of finishing agent may spoil the unique softness of the product. However, now-a-days, the pashmina fabrics are produced out of machine spun yarn in blends with other fibers. Such blended pashmina products are treated with thermoplastic softening agents like silicone softener, nano-based softening agents, etc. in order to improve the handle. • The other important finishing treatments carried out on pashmina fabrics by few dyers include anti-moth finishing and aroma finishing. Anti-moth chemical such as Eulon is added during dyeing under acidic conditions. The aroma finishing is carried out by using commercially available fragrance micro capsules. T.I.T.&S BHIWANI 12
  • 14. 7.Designing and Embroidery • Traditionally pashmina shawls are prepared with some unique designs. Hand embroidery is done on pashmina shawls with unique design. The embroidery is done with fine stitches using needles to intricate and unique designs. • In some cases, block printing is also employed with the use of pigments, silver and gold to decorate the fabrics with intricate designs. The Kashmir artisans use different type of designing & techniques to produce the unique pashmina shawls by hand jacquard, hand embroidery, block printing etc. Embroidery on pashmina shawls T.I.T.&S BHIWANI 13
  • 15. MARKETING OF PASHMINAPRODUCTS • Marketing of pashmina product is very important from consumer point of view. • Any product having soft feel and luster is being marketed in the name of pashmina. • Recently in order to check the sale of fake plain pashmina shawls, Government of India has awarded the GI patent recognizing handmade shawls of Kashmir origin. Under the GI of goods, Kashmiri handmade pashmina shawls now can use their own logos. GI registration was issued into two categories. In first category, the entire process of shawl making would be hand made using vegetable colours and the second category contain material process evolved over decades would be permitted with both vegetable and synthetic colours. T.I.T.&S BHIWANI 14
  • 16. IDENTIFICATIONAND DIFFERENCE FROM OTHER FIBERS • The pashmina fiber is one of the finest fibers in the world. • It is an expensive resource for the textile industry which makes it susceptible to falsifications. Instead of pashmina, the cheaper sheep wool is used and the product is then declared as genuine pashmina. • The products such as shawl and sweater made out of pashmina fiber are sold at about 10 times higher price compared to the similar products produced from merino sheep wool. • Therefore the textile industry and testing laboratories need detection methods which guarantee reliable testing of cashmere products. Fig-6 Pashmina wool fiber Fig-7 wool fiber T.I.T.&S BHIWANI 15
  • 17. • A fiber blend of pashmina and sheep wool will give similar results in the conventionally used textile testing methods like light microscopic analysis, chemical analysis, solvent method and burning test. Chemically, there is little difference between wool and pashmina. At present, scanning electron microscope (SEM) is used to differentiate pashmina and wool fibers based on the cuticle scale pattern. Cuticle scale characteristics and scale height have been used as the main diagnostic features to classify wool and pashmina. Current standard test methods for analyzing blends of pashmina with sheep wool are based on scanning electron microscopy (SEM). Microscopic Identification Fig-8 Electron Microscope T.I.T.&S BHIWANI 16
  • 18. DNA ANALYSIS • There are some fiber combinations, that even an experienced microscopist cannot differentiate). Hence, several alternative methods like morphological studies, protein and lipid analysis, DNA analysis etc. are developed by the researchers. • Molecular analyses of animal fibers for their amino acids, polypeptides and lipids have been developed for the identification of different animal fibers. • The DNA analysis based method is promising one since pashmina and wool are from different animal species. By this method, it is possible to distinguish raw pashmina and wool. T.I.T.&S BHIWANI 17
  • 19. • Future Thrust Area of Research • Several interventions made in processing and product development of pashmina fiber by different agencies have increased productivity of spinning and weaving processes which resulted in enhanced profitability of artisans engaged in this sector. • 1. Improvisation in Dehairing • 2.Identification of Pashmina fiber • 3.Cloning of pashmina goat(noori goat) • 4. Introduction of Printed Designs • 5. Improved Dyeing Techniques T.I.T.&S BHIWANI 18
  • 20. CONCLUSION Pashmina is well known for its fineness, warmth & softness. It is luxurious, softer and warmer than superfine merino wool. But it is costlier then the other forms of wool fibers. Due to similarities in physical, chemical and structural properties of this fiber type with the other forms of wool fibers so it is difficult to differentiate pashmina with other wool fiber, which lead to the falsification in the pashmina products. T.I.T.&S BHIWANI 19
  • 21. REFERENCES 1. Indian Journal of fiber & Textile Research Vol. 38, June 2013, pp. 207-214 2. https://en.wikipedia.org/wiki/Pashmina 3. http://jksheephusbandrykashmir.nic.in/Pashmina_Wool.htm 4. https://en.wikipedia.org/wiki/Noori_(goat) T.I.T.&S BHIWANI 20