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METAL DECORATION BY DECORAL® TECHNOLOGY
       SUPERDURABLE WOOD GRAIN

              Alessandro Canevarolo




                           Bologna, 19 maggio 2011
Wood Grain - Comparative test


           Wood Effect




Sublimation Process (Heat transfer)
      on coated metal surface
Sublimation Process (Heat Transfer)

Phisical process by which some substances at given temperature move directly from
                                  solid to gas status.



Sublimatic ink support

Sublimatic ink (dyes)



Powder coating layer                        200°C

  Aluminum




                                         Sublimatic ink substrate
                                     Printed Sublimatic ink (dyes)
                                            Powder coating layer




                                                      Aluminium
Used Raw Materials




- Polyurethane Powder Coating


- Heat Transfer Film
(printed with sublimatic Ink)
Sublimation Process Advantage


       High print definition
Sublimation Process Advantage


Suitable to be applied to different shapes
Wood Grain Comparative tests



Wood Grain on Superdurable PUR Powder
                 vs
 Wood Grain on Standard PUR Powder
Superdurable Polyurethane Powder


   Series DS 04XX S & Series DS 07XX S


New formulation of powder coating including:
  - special resins
  - special combination of UV inibhitors
Samples Preparation

        Powder Coating + Decoral Process


- Powder coating, carried out in compliance with TDS
  temperature and time (20'@ 200°C)

- Decoration according to sublimatic film TDS
  (peak temperature 200°C)
Obtained Samples

               Two series of samples


- A1, B1, …, N1 serie made by Superdurable powder
  coating (green line)

-    A2, B2, …, N2 serie made by Standard powder
    coating (red line)
Tests

Accelerated Weathering Test – AWT
-   Decoral Laboratory
-   Controlled and repeatable
-   simulation of some natural exposure factor
-   3000 hours duration


Natural Exposure Test – NET
-   South Florida (AWSG)
-   Real enviroment
-   Unpredictable test
-   12 months exposure
Accelerated Weathering Test
Decoral Laboratory




                                   ISO 11304
                     - irradiation, 550 ± 20 W / m 2 (290-800 nm)
                     - black panel temperature, 65 ± 5 ° C
                     - wet cycle 18 minutes
                     - dry cycle 102 minutes.
Accelerated Weathering Test

            Evaluated Parameter
    every 100 hours until 3000 hours

-    Residual gloss % (60° angle, ISO 2813)


-    Colour Variation (ΔE CIELAB, ISO 7724/3)
AWT – Residual Gloss%




Remarks: 3000 hours are 3 times minimum required by international specification
AWT – Residual Gloss%


                                             Superdurable serie (DS 07XX S)




       -    Residual gloss % of Superdurable wood grain > 80% @ 3000 Hours


       -    Residual gloss % of Standard wood grain > 50% @ 1000 Hours



Remarks: 3000 hours are 3 times minimum required by international specification
AWT – Colour Variation




Remarks: 3000 hours are 3 times minimum required by international specification
AWT – Colour Variation




                                            Superdurable series (DS 07XX S)




       -    ΔE of Superdurable wood grain < 2 @ 3000 Hours (all pattern!)


       -    ΔE of Standard wood grain < 2 @ 1000 Hours



Remarks: 3000 hours are 3 times minimum required by international specification
AWT – Tested Samples – 3000 h

                                                                         Tested
                                                                        Samples




          D1                                   D2
(superdurable wood grain)              (standard wood grain)

 Remarks: 3000 hours are 3 times minimum required by international specification
AWT – Tested Samples – 3000 h

 Tested
 Samples




                                   I1                               I2
                        (superdurable wood grain)          (standard wood grain)

Remarks: 3000 hours are 3 times minimum required by international specification
Natural Exposure Test

        ATLAS
Weathering Service Site




                                         ISO 2813
                          -   - south Florida site
                          -   - 12 months exposure
                             - facing south
                             - tilt angle 5°
                             - open backing
Natural Exposure Test – 12 months

               Evaluated Parameters
(after 12 months exposure & cleaning process)

     -   Residual gloss % (60° angle, ISO 2813)


     -   Colour Variation (ΔE CIELAB, ISO 7724/3)
NET – Residual Gloss%
NET – Residual Gloss%




-   Residual gloss % of Superdurable wood grain > 90% after 12 months
    exposure

-   Residual gloss % of Standard wood grain > 50% after 12 months
    exposure
NET – Colour Variation
NET – Colour Variation




-   ΔE of Superdurable wood grain < 2 after 12 months exposure (all
    pattern!)
NET – Exposed Samples – 12 months

                            Unexposed
                               part




          D1                                    D2
(superdurable wood grain)               (standard wood grain)
NET – Exposed Samples – 12 months

                            Unexposed
                               part




           I1                                   I2
(superdurable wood grain)               (standard wood grain)
Conclusions


- Excellent results are linked to a new
  formulation experience
- Superdurable series (DS 04XX S & DS 07XX S)
  levels up the weathering resistance
- Performance improvement for a wide range
  of finishing (different wood grain)
Future




- Expand the exisiting market for heat-
  transfer technology
- Open new fields of application
- Complying with more strict requirements
More information at:

www.decoral-system.com

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Decoral System. Bologna 19-05-2011 - Aluminium 2000

  • 1. METAL DECORATION BY DECORAL® TECHNOLOGY SUPERDURABLE WOOD GRAIN Alessandro Canevarolo Bologna, 19 maggio 2011
  • 2. Wood Grain - Comparative test Wood Effect Sublimation Process (Heat transfer) on coated metal surface
  • 3. Sublimation Process (Heat Transfer) Phisical process by which some substances at given temperature move directly from solid to gas status. Sublimatic ink support Sublimatic ink (dyes) Powder coating layer 200°C Aluminum Sublimatic ink substrate Printed Sublimatic ink (dyes) Powder coating layer Aluminium
  • 4. Used Raw Materials - Polyurethane Powder Coating - Heat Transfer Film (printed with sublimatic Ink)
  • 5. Sublimation Process Advantage High print definition
  • 6. Sublimation Process Advantage Suitable to be applied to different shapes
  • 7. Wood Grain Comparative tests Wood Grain on Superdurable PUR Powder vs Wood Grain on Standard PUR Powder
  • 8. Superdurable Polyurethane Powder Series DS 04XX S & Series DS 07XX S New formulation of powder coating including: - special resins - special combination of UV inibhitors
  • 9. Samples Preparation Powder Coating + Decoral Process - Powder coating, carried out in compliance with TDS temperature and time (20'@ 200°C) - Decoration according to sublimatic film TDS (peak temperature 200°C)
  • 10. Obtained Samples Two series of samples - A1, B1, …, N1 serie made by Superdurable powder coating (green line) - A2, B2, …, N2 serie made by Standard powder coating (red line)
  • 11. Tests Accelerated Weathering Test – AWT - Decoral Laboratory - Controlled and repeatable - simulation of some natural exposure factor - 3000 hours duration Natural Exposure Test – NET - South Florida (AWSG) - Real enviroment - Unpredictable test - 12 months exposure
  • 12. Accelerated Weathering Test Decoral Laboratory ISO 11304 - irradiation, 550 ± 20 W / m 2 (290-800 nm) - black panel temperature, 65 ± 5 ° C - wet cycle 18 minutes - dry cycle 102 minutes.
  • 13. Accelerated Weathering Test Evaluated Parameter every 100 hours until 3000 hours - Residual gloss % (60° angle, ISO 2813) - Colour Variation (ΔE CIELAB, ISO 7724/3)
  • 14. AWT – Residual Gloss% Remarks: 3000 hours are 3 times minimum required by international specification
  • 15. AWT – Residual Gloss% Superdurable serie (DS 07XX S) - Residual gloss % of Superdurable wood grain > 80% @ 3000 Hours - Residual gloss % of Standard wood grain > 50% @ 1000 Hours Remarks: 3000 hours are 3 times minimum required by international specification
  • 16. AWT – Colour Variation Remarks: 3000 hours are 3 times minimum required by international specification
  • 17. AWT – Colour Variation Superdurable series (DS 07XX S) - ΔE of Superdurable wood grain < 2 @ 3000 Hours (all pattern!) - ΔE of Standard wood grain < 2 @ 1000 Hours Remarks: 3000 hours are 3 times minimum required by international specification
  • 18. AWT – Tested Samples – 3000 h Tested Samples D1 D2 (superdurable wood grain) (standard wood grain) Remarks: 3000 hours are 3 times minimum required by international specification
  • 19. AWT – Tested Samples – 3000 h Tested Samples I1 I2 (superdurable wood grain) (standard wood grain) Remarks: 3000 hours are 3 times minimum required by international specification
  • 20. Natural Exposure Test ATLAS Weathering Service Site ISO 2813 - - south Florida site - - 12 months exposure  - facing south  - tilt angle 5°  - open backing
  • 21. Natural Exposure Test – 12 months Evaluated Parameters (after 12 months exposure & cleaning process) - Residual gloss % (60° angle, ISO 2813) - Colour Variation (ΔE CIELAB, ISO 7724/3)
  • 23. NET – Residual Gloss% - Residual gloss % of Superdurable wood grain > 90% after 12 months exposure - Residual gloss % of Standard wood grain > 50% after 12 months exposure
  • 24. NET – Colour Variation
  • 25. NET – Colour Variation - ΔE of Superdurable wood grain < 2 after 12 months exposure (all pattern!)
  • 26. NET – Exposed Samples – 12 months Unexposed part D1 D2 (superdurable wood grain) (standard wood grain)
  • 27. NET – Exposed Samples – 12 months Unexposed part I1 I2 (superdurable wood grain) (standard wood grain)
  • 28. Conclusions - Excellent results are linked to a new formulation experience - Superdurable series (DS 04XX S & DS 07XX S) levels up the weathering resistance - Performance improvement for a wide range of finishing (different wood grain)
  • 29. Future - Expand the exisiting market for heat- transfer technology - Open new fields of application - Complying with more strict requirements