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Closing the Carbon Cycle for
Sustainability

A Key Strategy for Environmental Protection, Energy
Security, and Economic Development

Peter Eisenberger
Columbia University & Global Thermostat
Rio+20
June 18, 2012
Table of Contents

• Closing the Carbon Cycle
• Current Approaches
• A Sustainable Solution: Energy from
  Atmospheric CO2
• Global Thermostat




               Global Thermostat - CONFIDENTIAL   2
3
Closing the Carbon Cycle
You need to know where you are going to get there…

 • Sustainability Requires Humans Close the Carbon Cycle
    – Climate Sustainability
    – Energy Security
    – Economic Development
 • A Human System that Closes The Carbon Cycle
    – Flexibility in location of sources and sinks
    – Connectivity between different components
    – Serve both todays fossil fuel and tomorrows renewables
    – Consistent with existing infrastructure
    – Provide net carbon negative technologies to offset carbon emitters
    – Value carbon so as to support positive feedbacks
    – New types of cooperation between countries and companies

                          Global Thermostat - CONFIDENTIAL                 4
Current Approaches to Climate Change
“Wedges” approach a good start…
   – Sensible, diversified strategy based on existing pathways
   – Portfolio of renewable energy and efficiency technologies
   – Potential to keep CO2 below 500ppm (still 2x pre-indust. level)

But may not be enough to avoid climate
change…
   –   Depends on continued net natural absorption rate
   –   Does not address 2000’s already elevated emissions
   –   Underestimates projected growth rate by factor of two
   –   No solution past 2055

Climate will change destructively on its own
   – Earth history has many climate disasters
   – New York City under a 1 mile high ice sheet

   A safe, effective, and affordable solution to climate change is still urgently
                                       needed
                                Global Thermostat - CONFIDENTIAL               5
Emissions Scenarios…




                       6
Future Atmospheric Concentrations…




                                     7
What Carbon Negative Can Achieve…




                                    8
The Cost of Atmospheric CO2…




                               9
The Need for Going Carbon Negative…
                Business as usual



Carbon Neutral is not enough
   – Neutralizing new and existing
     emissions Wedges (aggressive
                7
                  does not prevent
     atmospheric concentration of CO2
                renewable energy use,
     from further increasing
                efficiency, point-source
                sequestration)
   – It doesn’t solve the climate risk
     problem (reducingCarbon
                       Negative atmospheric
     concentrationsGlobal (such ppm)
                            below 500
                       Technology
                       as
Carbon-Negative Required
              Thermostat) with
              aggressive
   – To reduce atmospheric concentrations
                   renewable energy
     faster than the natural absorption rate
   – To achieve a safe level of CO2
     concentration

Air Capture Can Make Going
 Carbon Negative Possible
                                                              Pacala and Socolow, Science, Vol 305, 8/13/2004, Pg
                                                              969.
                                                              Note: 7 Wedges refers to the seven stabilization
                                                              wedges, created by Wigley, Richels & Edmonds,
                                                              necessary to achieve an atmospheric concentration of
                                    Global Thermostat - CONFIDENTIAL ppm by 2125.
                                                              CO2 of 500
                                                                                                                10
A Sustainable Solution
Close the carbon cycle – CO2 from air to make
the energy we need-

ENERGY SECURITY FOR ALL
  ̶AIR AND WATER MORE EQUABLY DISTRIBUTED


CONTROL HUMAN CO2 INPUT TO CARBON CYCLE
  ̶TEMPERATURE CONTROL


GREEN ENERGY FUND STIMULATES ECONOMIC GROWTH
  ̶STIMULATES TRANSITION TO CLOSING THE CARBON CYCLE
   ̶MONETIZE THE CO2 SO IT IS A VALUABLE AND NOT A POLLUTANT



                    Global Thermostat - CONFIDENTIAL           11
Applications & Markets for Captured CO2




Storage   Enhanced      Algae-               Hydroge    Products
          Oil           Based                n-Based    cement,
          Recovery                                      fertilizer,
                        Biofuels             Fuels      plastics,
                                                        greenhouses




                     Global Thermostat - CONFIDENTIAL                 12
Renewable 95: Closing the Carbon Cycle
                      CONVERTING CO2 FROM AIR &
                       HYDROGEN FROM WATER
                                 TO
                         95 OCTANE GASOLINE
                 Water Vapor and CO2

   CO2 Capture
         &
Hydrogen Conversion


                                      95
                                    Octane




                         Global Thermostat - CONFIDENTIAL   13
GT Project with Algae Systems
   GT is developing a fully-integrated biorefinery
      through a partnership with Algae Systems
 • Produces carbon negative transportation fuels (diesel, jet, etc)
 • Treats municipal wastewater and produces drinking water
 • Generates green electricity and biochar fertilizers

                                                                        Fuels,
         CO2                                                            Electr
                   Algae                                     Fuel        icity
 Solar                              Dewatering
                 Production                               Production      &
Energy                                                                  Bioch
     Waste                            Treat                               ar
                                                                         Drin
     water                             ed
                                                                        king
                                      Wast               Desalination
                                                                        Wate
                                      ewat
                                                                           r
                                       er
 This unique combination of technologies provides critical municipal
     services while producing energy in an embodiment that is
                      As Green As It Gets
                              Global Thermostat - CONFIDENTIAL                   14
Geothermal Electricity + CO2
Collaboration with Green Fire Energy
  – Uses CO2 instead of water
  – 10-20% of circulating CO2 sequestered


Using CO2 captured by Global Thermostat
  – Location flexibility of air capture
  – Economic advantage of locating near use
  – Increased geothermal locations accessible

Produces Carbon Negative electricity

                   Global Thermostat - CONFIDENTIAL   15
CLOSING THE CARBON CYCLE
FOR ENERGY, ECONOMIC, AND CLIMATE SUSTAINABILITY   16
Global Thermostat
Our goal is to provide technology to:
̶Facilitate the transition to a renewable future
    • Our Carburetor Technology to Clean Fossil Fuel Sources
̶Provide carbon for the renewable energy future
    • Our Direct Air Capture Technology to Close the Carbon Cycle
̶Provide a common technology platform
    •   Connects air and concentrated CO2 sources
̶Make money by doing good

We seek and welcome partners
    ̶They have already been essential to our efforts

We are committed to broad dissemination
    ̶Licensing model

                           Global Thermostat - CONFIDENTIAL         17
How GT Technology Works
  “GT CARBON SPONGE”
                                 Patented Carbon Sponge: porous
                                 block coated with proprietary amine
                                 sorbents

                                 Ambient air and/or flue gas goes through
                                 and binds to sorbent

                                 Carbon Sponge lowers into sealed
                                 chamber

                                 Low temperature process heat releases
                                 pure CO2 gas for collection
Pipes to oil well, algae, etc.
                                 And the cycle restarts…                 18
                                                                         18
Technology Operation
    Ambient air

         OR                         Monolith Contactors   Step 1
Air-flue gas blend
                                    + Sorbent                 Air Input
                                    “Cartridge”
     GT Module
                                                    •GT uses Corning
                     Adsorption                      monolith contactors
                     Phase                           similar to those in your
                                                     cars tailpipe
                                                    •Contactors provide high
                                                     surface contact areas
                                                     at low pressure drop
                     Regeneration                   •Enables movement of
                     Phase                           large volumes of air
                                                     with effective contact of
                                                     CO2 at low cost
                                                    •40 minute cycle


                                                                             19
                                                                             19
Technology Operation
    Ambient air

          OR
                                    Monolith Contactors   Step 2
Air-flue gas blend                  + Sorbent                   CO2
                                    “Cartridge”
      GT Module                                              Capture
                                                    •GT sorbents proven
                     Adsorption                      highly effective by
                     Phase                           Georgia Tech -
                                                     confirmed by SRI,
                                                     BASF, and NETL
                                                    •BASF process to
                                                     deposit immobilized
                     Regeneration
                                                     amines in pores of the
                     Phase
                                                     contactor walls at high
                                                     loading
                                                    •Dramatically reduces
                                                     heat required
                                                     compared to liquid
                                                     based CCS                 20
                                                                               20
Technology Operation

                              Monolith Contactors   Step 3
                              + Sorbent
                              “Cartridge”
 GT Module                                       Regenerati
                                              •CO2-rich sorbent is
                                                          on
               Adsorption                      heated with low-
                 Phase                         temperature process
                                               heat (90-105C) steam
                                              •CO2 is collected and
                                               sorbent is regenerated
               Regeneration                   •CO2 can be stored or
                  Phase                        used in multiple
                                               commercial applications
                                              •4 - 10 minute cycle
  105C Steam                  CO2 Collection



                                                                      21
                                                                      21
Technology Partners


        Partner                          Activity                     Relationship Terms
SRI International   Pilot plant operation and R&D; lab testing   Contract R&D

BASF                Sorbent development/supply; lab testing      Strategic Supplier

Corning             Monolith development/supply                  Strategic Supplier

Linde               Carburetor Pilot/EPC Contractor/Customer     EPC Contractor/Customer

Georgia Tech        Sorbent R&D; contactor testing               Contract R&D

Virgin Atlantic     Renewable jet fuel                           Commercialization partner, customer
Carmagen
                    System design, engineering, optimization     Contract consulting
Engineering
Summit Power        Project engineering                          Project development fee




                                                                                                       22
                                                                                                       22
Closing the Carbon Cycle is Key
For Sustainable Carbon-Based Life: Close the Carbon
Cycle…
Need Direct Air Capture
̶Carbon for a sustainable renewable energy future
 ̶Flexibility to provide sources and sinks
Need Negative Carbon
̶Climate Security
Need Carburetor for transition
̶Short term carbon free products
 ̶Long term carbon negative products
Need a Green Energy Fund
̶Global Economic Sustainability

                      Global Thermostat - CONFIDENTIAL   23
The Global Thermostat
                              Carbon dioxide
                              concentration
                              decreasing

        CO2            ENER
                        GY
       CAPTURE


Atmosphere
  800
Contact


                    Graciela Chichilnisky
                     Managing Director
                      chichilnisky1@gmail.com


                     Peter Eisenberger
                    Managing Director
                    peter.eisenberger@gmail.com


Global Thermostat              Confidential       25

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Rio+20 Peter Eisenberger Presentation

  • 1. Closing the Carbon Cycle for Sustainability A Key Strategy for Environmental Protection, Energy Security, and Economic Development Peter Eisenberger Columbia University & Global Thermostat Rio+20 June 18, 2012
  • 2. Table of Contents • Closing the Carbon Cycle • Current Approaches • A Sustainable Solution: Energy from Atmospheric CO2 • Global Thermostat Global Thermostat - CONFIDENTIAL 2
  • 3. 3
  • 4. Closing the Carbon Cycle You need to know where you are going to get there… • Sustainability Requires Humans Close the Carbon Cycle – Climate Sustainability – Energy Security – Economic Development • A Human System that Closes The Carbon Cycle – Flexibility in location of sources and sinks – Connectivity between different components – Serve both todays fossil fuel and tomorrows renewables – Consistent with existing infrastructure – Provide net carbon negative technologies to offset carbon emitters – Value carbon so as to support positive feedbacks – New types of cooperation between countries and companies Global Thermostat - CONFIDENTIAL 4
  • 5. Current Approaches to Climate Change “Wedges” approach a good start… – Sensible, diversified strategy based on existing pathways – Portfolio of renewable energy and efficiency technologies – Potential to keep CO2 below 500ppm (still 2x pre-indust. level) But may not be enough to avoid climate change… – Depends on continued net natural absorption rate – Does not address 2000’s already elevated emissions – Underestimates projected growth rate by factor of two – No solution past 2055 Climate will change destructively on its own – Earth history has many climate disasters – New York City under a 1 mile high ice sheet A safe, effective, and affordable solution to climate change is still urgently needed Global Thermostat - CONFIDENTIAL 5
  • 8. What Carbon Negative Can Achieve… 8
  • 9. The Cost of Atmospheric CO2… 9
  • 10. The Need for Going Carbon Negative… Business as usual Carbon Neutral is not enough – Neutralizing new and existing emissions Wedges (aggressive 7 does not prevent atmospheric concentration of CO2 renewable energy use, from further increasing efficiency, point-source sequestration) – It doesn’t solve the climate risk problem (reducingCarbon Negative atmospheric concentrationsGlobal (such ppm) below 500 Technology as Carbon-Negative Required Thermostat) with aggressive – To reduce atmospheric concentrations renewable energy faster than the natural absorption rate – To achieve a safe level of CO2 concentration Air Capture Can Make Going Carbon Negative Possible Pacala and Socolow, Science, Vol 305, 8/13/2004, Pg 969. Note: 7 Wedges refers to the seven stabilization wedges, created by Wigley, Richels & Edmonds, necessary to achieve an atmospheric concentration of Global Thermostat - CONFIDENTIAL ppm by 2125. CO2 of 500 10
  • 11. A Sustainable Solution Close the carbon cycle – CO2 from air to make the energy we need- ENERGY SECURITY FOR ALL ̶AIR AND WATER MORE EQUABLY DISTRIBUTED CONTROL HUMAN CO2 INPUT TO CARBON CYCLE ̶TEMPERATURE CONTROL GREEN ENERGY FUND STIMULATES ECONOMIC GROWTH ̶STIMULATES TRANSITION TO CLOSING THE CARBON CYCLE ̶MONETIZE THE CO2 SO IT IS A VALUABLE AND NOT A POLLUTANT Global Thermostat - CONFIDENTIAL 11
  • 12. Applications & Markets for Captured CO2 Storage Enhanced Algae- Hydroge Products Oil Based n-Based cement, Recovery fertilizer, Biofuels Fuels plastics, greenhouses Global Thermostat - CONFIDENTIAL 12
  • 13. Renewable 95: Closing the Carbon Cycle CONVERTING CO2 FROM AIR & HYDROGEN FROM WATER TO 95 OCTANE GASOLINE Water Vapor and CO2 CO2 Capture & Hydrogen Conversion 95 Octane Global Thermostat - CONFIDENTIAL 13
  • 14. GT Project with Algae Systems GT is developing a fully-integrated biorefinery through a partnership with Algae Systems • Produces carbon negative transportation fuels (diesel, jet, etc) • Treats municipal wastewater and produces drinking water • Generates green electricity and biochar fertilizers Fuels, CO2 Electr Algae Fuel icity Solar Dewatering Production Production & Energy Bioch Waste Treat ar Drin water ed king Wast Desalination Wate ewat r er This unique combination of technologies provides critical municipal services while producing energy in an embodiment that is As Green As It Gets Global Thermostat - CONFIDENTIAL 14
  • 15. Geothermal Electricity + CO2 Collaboration with Green Fire Energy – Uses CO2 instead of water – 10-20% of circulating CO2 sequestered Using CO2 captured by Global Thermostat – Location flexibility of air capture – Economic advantage of locating near use – Increased geothermal locations accessible Produces Carbon Negative electricity Global Thermostat - CONFIDENTIAL 15
  • 16. CLOSING THE CARBON CYCLE FOR ENERGY, ECONOMIC, AND CLIMATE SUSTAINABILITY 16
  • 17. Global Thermostat Our goal is to provide technology to: ̶Facilitate the transition to a renewable future • Our Carburetor Technology to Clean Fossil Fuel Sources ̶Provide carbon for the renewable energy future • Our Direct Air Capture Technology to Close the Carbon Cycle ̶Provide a common technology platform • Connects air and concentrated CO2 sources ̶Make money by doing good We seek and welcome partners ̶They have already been essential to our efforts We are committed to broad dissemination ̶Licensing model Global Thermostat - CONFIDENTIAL 17
  • 18. How GT Technology Works “GT CARBON SPONGE” Patented Carbon Sponge: porous block coated with proprietary amine sorbents Ambient air and/or flue gas goes through and binds to sorbent Carbon Sponge lowers into sealed chamber Low temperature process heat releases pure CO2 gas for collection Pipes to oil well, algae, etc. And the cycle restarts… 18 18
  • 19. Technology Operation Ambient air OR Monolith Contactors Step 1 Air-flue gas blend + Sorbent Air Input “Cartridge” GT Module •GT uses Corning Adsorption monolith contactors Phase similar to those in your cars tailpipe •Contactors provide high surface contact areas at low pressure drop Regeneration •Enables movement of Phase large volumes of air with effective contact of CO2 at low cost •40 minute cycle 19 19
  • 20. Technology Operation Ambient air OR Monolith Contactors Step 2 Air-flue gas blend + Sorbent CO2 “Cartridge” GT Module Capture •GT sorbents proven Adsorption highly effective by Phase Georgia Tech - confirmed by SRI, BASF, and NETL •BASF process to deposit immobilized Regeneration amines in pores of the Phase contactor walls at high loading •Dramatically reduces heat required compared to liquid based CCS 20 20
  • 21. Technology Operation Monolith Contactors Step 3 + Sorbent “Cartridge” GT Module Regenerati •CO2-rich sorbent is on Adsorption heated with low- Phase temperature process heat (90-105C) steam •CO2 is collected and sorbent is regenerated Regeneration •CO2 can be stored or Phase used in multiple commercial applications •4 - 10 minute cycle 105C Steam CO2 Collection 21 21
  • 22. Technology Partners Partner Activity Relationship Terms SRI International Pilot plant operation and R&D; lab testing Contract R&D BASF Sorbent development/supply; lab testing Strategic Supplier Corning Monolith development/supply Strategic Supplier Linde Carburetor Pilot/EPC Contractor/Customer EPC Contractor/Customer Georgia Tech Sorbent R&D; contactor testing Contract R&D Virgin Atlantic Renewable jet fuel Commercialization partner, customer Carmagen System design, engineering, optimization Contract consulting Engineering Summit Power Project engineering Project development fee 22 22
  • 23. Closing the Carbon Cycle is Key For Sustainable Carbon-Based Life: Close the Carbon Cycle… Need Direct Air Capture ̶Carbon for a sustainable renewable energy future ̶Flexibility to provide sources and sinks Need Negative Carbon ̶Climate Security Need Carburetor for transition ̶Short term carbon free products ̶Long term carbon negative products Need a Green Energy Fund ̶Global Economic Sustainability Global Thermostat - CONFIDENTIAL 23
  • 24. The Global Thermostat Carbon dioxide concentration decreasing CO2 ENER GY CAPTURE Atmosphere 800
  • 25. Contact Graciela Chichilnisky Managing Director chichilnisky1@gmail.com Peter Eisenberger Managing Director peter.eisenberger@gmail.com Global Thermostat Confidential 25

Notas del editor

  1. The main message of my presentation is that one cannot have sustainability without us hunans Closing the Carbon Cycle , by which is meant the carbon in our fuel comes from the air just as the carbon for the energy of life comes from the air. This promotes sustainability because there is no net impact on the planets carbon balance , the input to energy being the air is more equitably distributed promoting energy security and economic development. The green power fund can provide the market stimulus to trigger this virtuous cycle.
  2. Read it – 1 what does it mean practically to close the carbon cycle 2 review the current view of how to address the threat of climate change – conservAationand renewables –will not avert climate risk 3 nor will it address the underlying poor distribution of fossil fuel sources and the lck of energy security anmd conflict that arise form it 4 we propose to address all thoise conbscerns by being able to get co2 form the air as input to making our hydrocarbon fuels 5 describe our technology to do that
  3. Snapshot of carbon cycle Note positve input of humans of 6 gigatonnes of carbon about 24 gigatonnes of co2 Note large fluxes of co2 between the land and air and the sea and air – natural balance today is to reduce co2 –global cooling period Note today 3-2 gigatonnes of our contribution adsorbed by rest of system that will change over time could aggravate problem grealty –would effecively double the rate of increase- nature changes the balance on its own and destructively so But even in this fortunate situation our current approach will not work
  4. Point out –three virtous feedbacks A human system that mimics the natural carbon cycle would have the attributes listed
  5. 2005 pacala and socolow As a detailed analysis shows will not prevent co2 from increasing –bathtub model
  6. Too small Maybe bullet or two
  7. Bathtub explanation –will not solve climate problem or address underlying energy security and economic development components of sustainability
  8. What are the options? What are the useful products and fuels we can create
  9. Intro slide to the options Key transition slide – need to find a way to begin process of transition to a sustainable solution Monetize the co2 by either making it into carbion nuetral by making products from flue gas sources or carbon negative energy and products with co2 from the air-the same infrastructure works for both making the cost of the transition to a ustainable future less costly allowing money to be used for more broad based economic development the stimulus of the green power fund
  10. Tech pathways to harvest atmosphere—create value in closed loop
  11. Compare to other slide show
  12. Remove 20:1
  13. Use shorter titles and then have lead in statements