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2.12 This Problem is adopted from Safety Health and Loss Prevention in Chemical Processes by
the AIChE. Trichloroethylene(TCE) has a molecular mom of 131.5 g/mol so the vapors are much
more dense than air. density of air at 25 C and 1 atm is Rho air=1.178 kg/m^3, while the density
of TCE is Rho TCE= 5.37 kg/m^3 . Being much denser, than air,one would expect TCF to
descend to the floor where it would be relatively harmless. However, gases easily mix under
most circumstances, and at toxic concentrations the difference in density of a toxic mixture with
respect to air is negligible Assume that the gas mixture is ideal (see Sec. 5-1)and compute the
density of a mixture of TCE and air at the following conditions a) The time-weighted average of
PEL (see Problem 2-11) for 8 hours exposure, Rho=100 ppm. (b) The 15 minute ceiling
exposure of Rho= 200 ppm. (c) The 5 minute peak exposure of Rhomix = 300 ppm.
Solution
did you ever get the answer to this?

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2.12 This Problem is adopted from Safety Health and Loss Prevention i.pdf

  • 1. 2.12 This Problem is adopted from Safety Health and Loss Prevention in Chemical Processes by the AIChE. Trichloroethylene(TCE) has a molecular mom of 131.5 g/mol so the vapors are much more dense than air. density of air at 25 C and 1 atm is Rho air=1.178 kg/m^3, while the density of TCE is Rho TCE= 5.37 kg/m^3 . Being much denser, than air,one would expect TCF to descend to the floor where it would be relatively harmless. However, gases easily mix under most circumstances, and at toxic concentrations the difference in density of a toxic mixture with respect to air is negligible Assume that the gas mixture is ideal (see Sec. 5-1)and compute the density of a mixture of TCE and air at the following conditions a) The time-weighted average of PEL (see Problem 2-11) for 8 hours exposure, Rho=100 ppm. (b) The 15 minute ceiling exposure of Rho= 200 ppm. (c) The 5 minute peak exposure of Rhomix = 300 ppm. Solution did you ever get the answer to this?