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Welcome
Association of
Energy Engineers


Presented by
James McDonald, PE, CWT
2
Squeezing $$ out of
Boiler Water
The Water/Energy Nexus
1

Water Energy Nexus
Water Value & Uses




                     4
Value $$ of Water?

                            Water




        Energy                                 Sewer




             Pretreatment           Chemical


                                                       5
Water Uses = Energy
 Heat
 Cool
 Clean
 Cut
 Drive turbine
 Product component




                      6
2

Water Energy Nexus
Boilers




                     7
Heat: Boilers
 Heat water
 • Steam
 • Hot water
 Types
 • Watertube
 • Firetube




                8
Boilers Heat Water
 Makeup Temperature: 60°F
 • 28 BTU/lb
 Boiling Point: 212°F at 0 psig
 • 180 BTU/lb                         9


 Steam: 212°F at 0 psig
 • 1,150.2 BTU/lb




                                  9
Boilers Heat Water @ 150 psig
 Makeup Temperature: 60°F
 • 28 BTU/lb
 Boiling Point: 366°F at 150 psig
 • 338.47BTU/lb                          1
                                         0

 Steam: 212°F at 0 psig
 • 1,196 BTU/lb




                                    10
Boiler System Operating Costs




                                11
Eureka! We have Steam!!!!
 Mass Balance
     Makeup Water In = Steam Out
 Energy Balance
   Fuel Energy In = Steam Energy Out




                                       12
Water Mass Balance
 Makeup Water In = Steam Out??????
 What’s left behind?
 • Contaminants
    Dissolved Solids: Calcium, magnesium, sodium, chloride, phosphate,
    bicarbonate, carbonate, iron, manganese, etc.
    –Retrograde solubility
    Suspended Solids: Silts, corrosion by-products, precipitated salts, etc.




                                                                               13
Boilers Cycles




Cycles begin when water evaporates.      As water evaporates, solids stay behind.




When the solids = twice the MU solids,         So forth, and so on.
you have 2 cycles of concentration.
3

Water Energy Nexus
Scale & Deposits




                     15
Scale & Deposits




                   16
                        1
Scale = More Fuel

                                                       Monthly Savings
                                            (If your Fuel Costs average $1,000 per
     Thickness of Scale   Extra Fuel Cost    month, a clean Boiler would give you
          (inches)           (Percent)           these corresponding savings)

           1/32"              8.50%                        $85.00

           1/25"              9.30%                        $93.00

           1/20"             11.10%                       $110.00

           1/16"             12.40%                       $124.00

           1/8"              25.00%                       $250.00

           1/4"              40.00%                       $400.00

           3/8"              55.00%                       $550.00

           1/2"              70.00%                       $700.00




                                                                                     17
Scale = More Energy




                      18
How to Control Scale?
 Blowdown
 • Continuous/surface blowdown
    Control dissolved solids/conductivity
 • Bottom blowdown
    Control sludge
 New Mass Balance
 • Makeup Water In = Steam + Blowdown
 New Energy Balance
 • Fuel Energy In = Steam Energy Out + Blowdown Energy Out
    + radiant losses + stack losses + combustion inefficiencies




                                                                  19
4

Water Energy Nexus
Boiler Blowdown




                     20
Blowdown vs. Cycles of Concentration
 10 Cycles of Concentration = 10% Blowdown
 • 10% of the boiler makeup water is going down the drain
 20 Cycles of Concentration = 5 % Blowdown
 • 5% of the boiler makeup water is going down the drain
 50 Cycles of Concentration = 2% Blowdown
 • 2% of the boiler makeup water is going down the drain
 100 Cycles of Concentration = 1% Blowdown
 • 1% of the boiler makeup water is going down the drain
 How high can you go?
 • American Society of Mechanical Engineers (ASME) Guidelines
 • Steam quality
 • Scale forming salts solubility
 • Current boiler conditions
 • ASME recommends 100 maximum                                  21
Wait!!! There’s More!
 Maximizing Cycles of Concentration
 • Saves water
 • Saves FUEL!
 Boiler @ 50 psig
 • Blowdown heat content = 267 BTU/lb
 Boiler @ 150 psig
 • Blowdown heat content = 338 BTU/lb
 Boiler @ 250 psig
 • Blowdown heat content = 381 BTU/lb
 Maximizing Cycles of Concentration Minimizes the Heat
 Going Down the Drain!



                                                         22
Maximizing Cycles of Concentration
 Improve Makeup Water Quality
 • ASME: “Where a choice is available, the reduction or removal of
   objectionable constituents by pretreatment external to the boiler
   is always preferable to, and more reliable than, management of
   these constituents within the boiler by internal chemical
   treatment.”
 • Water Softener
 • Dealkalizer
 • Demineralization
 • Reverse Osmosis




                                                                       23
Maximizing Cycles of Concentration
 Maximize Control of Cycles
 • Automatic blowdown controller




                                     24
Maximizing Cycles of Concentration
 Chemicals
 • Prevent scale formation
    Chelants
    Polymers
    Phosphates
    Phosphonates




                                     25
Maximizing Cycles of Concentration
 Maximizing Condensate
 Return
 • High purity water source
 • Condensate Value = Water + Sewer
   + Fuel + Pretreatment + Chemistry
   + Effects on Boiler Cycles
 • $10-$20+ per 1,000 gallons
 New Mass Balance
 • Makeup + Condensate =
   Steam + Blowdown




                                       26
Condensate Value
 Higher Fuel Costs = Higher Value
 Higher % Return = Greater Potential Effect on Boiler
 Blowdown
            Figure 1: Total Condensate Value



    2%     16%            9%
                                               Water
                                    18%        Sewer
   1%
                                               Fuel
                                               Chemical
                                               Pretreatment

                 54%                           Blowdown




                                                              27
Whew!
 So far…
 • Kept boiler surfaces scale/deposit free
 • Minimized blowdown
 • What next?




                                             28
5

Water Energy Nexus
More Energy Savings




                      29
Economizers
 Extract more heat from fuel
 Not all energy absorbed by boiler
 Economizer transfers waste boiler stack heat to boiler
 feedwater
 For every 40-50°F drop in stack temperature
 • 1% gain in boiler efficiency
 Dew point of acids and water the limiting factor
 • Unless use corrosion resistant materials




                                                          30
Blowdown Flash Tank & Heat Exchanger
 Recover heat from the blowdown!
 • Example: 150 psig Blowdown heat content = 338 BTU/lb
    366°F

 Blowdown Flash Tank
 • Lower Pressure = Flashing of portion of blowdown to low pressure
   steam.
    Can use in Deaerator
    –E.g., 10 psig at 240°F

 Blowdown Heat Exchanger
 • Exchange remaining heat with incoming
   makeup water
 • 20°F approach temperature
 Typically, 80% of waste heat in
 blowdown can be recovered

                                                                      31
Maintain Boilers (Water Side)
 Corrosion control
 • Oxygen pitting
 • Acid corrosion
 • Under-deposit corrosion
 • Caustic corrosion




                                32
6

Water Energy Nexus
Energy Saving Summary




                        33
Energy Saving Summary
 Maximize Cycles of Concentration
 • Pretreatment
 • Automatic blowdown control
 • Chemicals
 • Maximize condensate return
 Economizers
 • Extract remaining amount of heat out of fuel
 Blowdown Flash Tank & Heat Exchanger
 • Keep heat from going down the drain




                                                  34
7

Water Energy Nexus
Resources




                     35
Resources
 DOE Steam Systems Tool Suit
 • Steam System Assessment Tool (SSAT)
 • http://www1.eere.energy.gov/industry/bestpractices/software_ss
   at.html#ssat
 • DOE offers classes
 Crown Solutions Website
 • www.crownsolutions.com
 • RESOUCES  TECHNICAL PAPERS
    Drop by Drop: Articles on Industrial Water Treatment
 Excel Workbooks
 • BP Save
    Proprietary: Call Crown
 • AWT Reverse Osmosis Calculation Workbook
    Members Only, but…

                                                                    36
Thank You
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Water Energy Nexus 10 18 11

  • 2. 2
  • 3. Squeezing $$ out of Boiler Water The Water/Energy Nexus
  • 4. 1 Water Energy Nexus Water Value & Uses 4
  • 5. Value $$ of Water? Water Energy Sewer Pretreatment Chemical 5
  • 6. Water Uses = Energy Heat Cool Clean Cut Drive turbine Product component 6
  • 8. Heat: Boilers Heat water • Steam • Hot water Types • Watertube • Firetube 8
  • 9. Boilers Heat Water Makeup Temperature: 60°F • 28 BTU/lb Boiling Point: 212°F at 0 psig • 180 BTU/lb 9 Steam: 212°F at 0 psig • 1,150.2 BTU/lb 9
  • 10. Boilers Heat Water @ 150 psig Makeup Temperature: 60°F • 28 BTU/lb Boiling Point: 366°F at 150 psig • 338.47BTU/lb 1 0 Steam: 212°F at 0 psig • 1,196 BTU/lb 10
  • 12. Eureka! We have Steam!!!! Mass Balance Makeup Water In = Steam Out Energy Balance Fuel Energy In = Steam Energy Out 12
  • 13. Water Mass Balance Makeup Water In = Steam Out?????? What’s left behind? • Contaminants Dissolved Solids: Calcium, magnesium, sodium, chloride, phosphate, bicarbonate, carbonate, iron, manganese, etc. –Retrograde solubility Suspended Solids: Silts, corrosion by-products, precipitated salts, etc. 13
  • 14. Boilers Cycles Cycles begin when water evaporates. As water evaporates, solids stay behind. When the solids = twice the MU solids, So forth, and so on. you have 2 cycles of concentration.
  • 15. 3 Water Energy Nexus Scale & Deposits 15
  • 17. Scale = More Fuel Monthly Savings (If your Fuel Costs average $1,000 per Thickness of Scale Extra Fuel Cost month, a clean Boiler would give you (inches) (Percent) these corresponding savings) 1/32" 8.50% $85.00 1/25" 9.30% $93.00 1/20" 11.10% $110.00 1/16" 12.40% $124.00 1/8" 25.00% $250.00 1/4" 40.00% $400.00 3/8" 55.00% $550.00 1/2" 70.00% $700.00 17
  • 18. Scale = More Energy 18
  • 19. How to Control Scale? Blowdown • Continuous/surface blowdown Control dissolved solids/conductivity • Bottom blowdown Control sludge New Mass Balance • Makeup Water In = Steam + Blowdown New Energy Balance • Fuel Energy In = Steam Energy Out + Blowdown Energy Out + radiant losses + stack losses + combustion inefficiencies 19
  • 21. Blowdown vs. Cycles of Concentration 10 Cycles of Concentration = 10% Blowdown • 10% of the boiler makeup water is going down the drain 20 Cycles of Concentration = 5 % Blowdown • 5% of the boiler makeup water is going down the drain 50 Cycles of Concentration = 2% Blowdown • 2% of the boiler makeup water is going down the drain 100 Cycles of Concentration = 1% Blowdown • 1% of the boiler makeup water is going down the drain How high can you go? • American Society of Mechanical Engineers (ASME) Guidelines • Steam quality • Scale forming salts solubility • Current boiler conditions • ASME recommends 100 maximum 21
  • 22. Wait!!! There’s More! Maximizing Cycles of Concentration • Saves water • Saves FUEL! Boiler @ 50 psig • Blowdown heat content = 267 BTU/lb Boiler @ 150 psig • Blowdown heat content = 338 BTU/lb Boiler @ 250 psig • Blowdown heat content = 381 BTU/lb Maximizing Cycles of Concentration Minimizes the Heat Going Down the Drain! 22
  • 23. Maximizing Cycles of Concentration Improve Makeup Water Quality • ASME: “Where a choice is available, the reduction or removal of objectionable constituents by pretreatment external to the boiler is always preferable to, and more reliable than, management of these constituents within the boiler by internal chemical treatment.” • Water Softener • Dealkalizer • Demineralization • Reverse Osmosis 23
  • 24. Maximizing Cycles of Concentration Maximize Control of Cycles • Automatic blowdown controller 24
  • 25. Maximizing Cycles of Concentration Chemicals • Prevent scale formation Chelants Polymers Phosphates Phosphonates 25
  • 26. Maximizing Cycles of Concentration Maximizing Condensate Return • High purity water source • Condensate Value = Water + Sewer + Fuel + Pretreatment + Chemistry + Effects on Boiler Cycles • $10-$20+ per 1,000 gallons New Mass Balance • Makeup + Condensate = Steam + Blowdown 26
  • 27. Condensate Value Higher Fuel Costs = Higher Value Higher % Return = Greater Potential Effect on Boiler Blowdown Figure 1: Total Condensate Value 2% 16% 9% Water 18% Sewer 1% Fuel Chemical Pretreatment 54% Blowdown 27
  • 28. Whew! So far… • Kept boiler surfaces scale/deposit free • Minimized blowdown • What next? 28
  • 29. 5 Water Energy Nexus More Energy Savings 29
  • 30. Economizers Extract more heat from fuel Not all energy absorbed by boiler Economizer transfers waste boiler stack heat to boiler feedwater For every 40-50°F drop in stack temperature • 1% gain in boiler efficiency Dew point of acids and water the limiting factor • Unless use corrosion resistant materials 30
  • 31. Blowdown Flash Tank & Heat Exchanger Recover heat from the blowdown! • Example: 150 psig Blowdown heat content = 338 BTU/lb 366°F Blowdown Flash Tank • Lower Pressure = Flashing of portion of blowdown to low pressure steam. Can use in Deaerator –E.g., 10 psig at 240°F Blowdown Heat Exchanger • Exchange remaining heat with incoming makeup water • 20°F approach temperature Typically, 80% of waste heat in blowdown can be recovered 31
  • 32. Maintain Boilers (Water Side) Corrosion control • Oxygen pitting • Acid corrosion • Under-deposit corrosion • Caustic corrosion 32
  • 33. 6 Water Energy Nexus Energy Saving Summary 33
  • 34. Energy Saving Summary Maximize Cycles of Concentration • Pretreatment • Automatic blowdown control • Chemicals • Maximize condensate return Economizers • Extract remaining amount of heat out of fuel Blowdown Flash Tank & Heat Exchanger • Keep heat from going down the drain 34
  • 36. Resources DOE Steam Systems Tool Suit • Steam System Assessment Tool (SSAT) • http://www1.eere.energy.gov/industry/bestpractices/software_ss at.html#ssat • DOE offers classes Crown Solutions Website • www.crownsolutions.com • RESOUCES  TECHNICAL PAPERS Drop by Drop: Articles on Industrial Water Treatment Excel Workbooks • BP Save Proprietary: Call Crown • AWT Reverse Osmosis Calculation Workbook Members Only, but… 36