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ENHANCED OIL RECOVERY
IS
The introduction of a fluid into a pressure-depleted
oil reservoir to increase its pressure and
ultimate oil recovery
Contact:
Larry@TexasEOR.com
EXHAUST GAS INJECTION CO2 EOR
N2+CO2 Exhaust Gas Injection EOR
 Proven – production increases up to 50X current production.
 Mobile - generate gas at wellhead, no gas or CO2 pipeline cost.
 Green – recycles engine exhaust; zero-emissions; uses no water
 Volume – 1-Mmcfd modular units, trainable to any volume/flowrate
 Pressure – as required, from low pressure to >2,000-psi injection.
 CO2 – lowers oil viscosity; swells oil up to 50% for greater mobility.
 Nitrogen – N2 forms Gas Drive - pushes Oil/CO2 thru pore-space
 Thermal – gas up to 900*, alternative to Steam Flood, without water.
 Patented Process – Weatherford Intl, exclusive licensing partner.
Exhaust Gas EOR (CO2+N2)
• Combustion gas from a standard internal combustion engine provides an
ideal gas for enhanced oil recovery. Combustion gas is comprised of
approximately 13% CO2 and 87% Nitrogen.
• Researchers at Louisiana State University compared the exhaust gas to pure
100% CO2 in simulated conditions and found that exhaust gas has
significantly better performance than pure CO2 in the recovery of crude oil.
• In a pure CO2 flood, the CO2 combines with the oil under miscible pressure,
doubling the volume of the oil and reducing the viscosity. This allows the oil
to flow more freely towards the producing well. The CO2, however, does not
provide drive. In a pure CO2 flood, gas injection is followed by water (WAG,
Water And Gas) , which provides pressure and drive to push the oil towards a
producing well.
• In an exhaust gas flood the 13% CO2 separates from the Nitrogen, and
combines with the oil under pressure, providing the needed swelling and
increase in oil flow. Meanwhile, the 87% Nitrogen gas rises to the top of the
reservoir, providing a pressure source which is more effective than water at
driving oil towards a producing well.
Gas Efficiencies
% of CO2 in N2 Pure Gas
N2+CO2 Exhaust Gas Is
2X more efficient in oil
recovery then pure CO2-only
SPE Paper # 36687
LSU, U of M Rolla
Engine Exhaust Gas Injection EOR Systems –
Process Flow
Fossil Bay Energy
Exhaust Gas Generators (EGPs)
 82% N2, 15% CO2, < 2% CO, < 75ppm O2
 Minimal corrosion considerations
compared to 100% CO2 used in CO2 flooding
 No combustion or explosive risks
compared to 100% CO2 used in CO2 flooding
 Wide range of operational parameters
 Variable Injection rates and Pressures
 Fuel sources either methane or propane
 PORTABLE – no infrastructure needed
 COMPRESSION – part of the process.
Remote Operated Unit
 Injection rate: 10 m3/m (1 mmcf/d)
 Injection pressure: 3800 kPa (550 psi)
Exhaust Gas Generator
Remote Operated Portable Unit
Enhanced Oil Recovery
 Pinnacle reefs, primary recovery 25%
 Most conventional reservoirs are candidates
 Unconventional Shales – new studies show 10% added EUR
 Incremental oil recovery after water-flood
 CHOPs – re-pressurization & heating
 Alternate EOR versus water-flood
Enhanced Gas Recovery – EGR
 Re-pressure depleted natural gas reservoirs
 Sweep gas for natural gas reservoirs (CBM)
 Gas over oil replacement (Surmont)
Thermal applications
 Gas temperature up to 900*
 low Gravity – Heavy Oil reservoirs
 Alternative to SAGD
Exhaust Gas Applications
GAS INJECTION EOR
Common Techniques
 CO2 – most common gas used, competition for limited
supplies; high infrastructure cost requires large
reservoirs only - limited by sparse availability of
CO2 pipelines to provide services to EOR-worthy fields
 CH4 (Methane) used mainly during primary production-pressure
maintenance, costly to strip liquids, added supply
cost of royalties owed for produced-gas used
 N2 - miscible at high pressure of 4000-psi, and expensive
to separately produce large N2 volumes; best used in
immiscible form as drive to push CO2 and oil through
reservoir pore space.
 Best Gas Injection Technology
 Exhaust Gas- N/2-CO2 mixture (85%-15%)
Unlimited supply
Field Proven
CO2 Gas Flooding
CO2 Pipeline Supply Issues (current demand for EOR exceeds supply)
80+ Projects in Operation = 290,000 BOPD - Large Reservoirs only (>10 MMBO)
Recoveries Exceeding 50% OOIP – High Project Costs (>100’s of millions of $$$)
100% CO2 Only - No Drive Mechanism- Suffers Early gas breakthrough
Horizontal Flooding – fluid override lowers recovery
MICHIGAN CO2 FLOOD – N.REEF
Horizontal Producer - +500 BOPD Average first 2 years
MICHIGAN CO2 FLOOD – N.REEF
Vertical Producer – Averaged 190 bopd, first 4 years
Springhill Grove Exhaust Gas Projects
The Spring Grove field was discovered in 1958 and the two wells produced
1-2 bopd. In 1961, the operator bought an 80mcfd Exhaust Gas
Processor, and production went up to 6bopd. In 1964, the field was
bought, the new operators bought other EGP’s for a total of 200mcfd and
started injection. Within 4 months the Spring Grove field was producing at
rates over 5000 bopm. The offsetting Boswell-Walker Leases saw
production increases from 150bopm to 1300bopm by virtue of the exhaust
being injected in the Hart Lease. In 1964, a full scale development was
initiated on this lease.
Gas Cap Injection + Gravity Drainage
Injected Gas Mixture (CO2+N2) Fills Reservoir Gas Cap
N2 Pushes CO2 to Mix With Oil and Flow to Production Well
N2
Oil & CO2
Miscibility
Gas Flooding EOR -- also known as miscible gas flooding -- is
one of the leading enhanced oil recovery (EOR) technologies employed for
recovering the stranded, trapped oil, left behind in pressure-depleted oil
reservoirs after initial primary oil recovery has ended.
Gas flooding typically includes CO2, natural gas or N2 nitrogen as the gas that
is injected.
Gas flooding is an "enhanced oil recovery" application for injecting miscible
(and immiscible) gases into an oil reservoir to increase oil production by re-
pressurizing the reservoir to push the oil to the production wells.
Miscible means that the injected-gas "mixes" with the oil, thereby reducing its
viscosity and interfacial tension of the oil and rock. Miscible gas flooding
also increases oil "swelling" and localized pressure or drive within the
reservoir.
"Immiscible" flooding means that the injected-gas does not mix or go into
solution, but instead provides the energy “push” (drive) by increased
pressure. Immiscible flooding does not produce as much oil as miscible gas
flooding, however there are certain applications and reservoirs wherein
immiscible flooding is well-suited

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Larry Shultz presents TexasEOR.com Exhaust Gas Injection CO2 Enhanced Oil Recovery Technology Primer

  • 1. ENHANCED OIL RECOVERY IS The introduction of a fluid into a pressure-depleted oil reservoir to increase its pressure and ultimate oil recovery Contact: Larry@TexasEOR.com
  • 3. N2+CO2 Exhaust Gas Injection EOR  Proven – production increases up to 50X current production.  Mobile - generate gas at wellhead, no gas or CO2 pipeline cost.  Green – recycles engine exhaust; zero-emissions; uses no water  Volume – 1-Mmcfd modular units, trainable to any volume/flowrate  Pressure – as required, from low pressure to >2,000-psi injection.  CO2 – lowers oil viscosity; swells oil up to 50% for greater mobility.  Nitrogen – N2 forms Gas Drive - pushes Oil/CO2 thru pore-space  Thermal – gas up to 900*, alternative to Steam Flood, without water.  Patented Process – Weatherford Intl, exclusive licensing partner.
  • 4. Exhaust Gas EOR (CO2+N2) • Combustion gas from a standard internal combustion engine provides an ideal gas for enhanced oil recovery. Combustion gas is comprised of approximately 13% CO2 and 87% Nitrogen. • Researchers at Louisiana State University compared the exhaust gas to pure 100% CO2 in simulated conditions and found that exhaust gas has significantly better performance than pure CO2 in the recovery of crude oil. • In a pure CO2 flood, the CO2 combines with the oil under miscible pressure, doubling the volume of the oil and reducing the viscosity. This allows the oil to flow more freely towards the producing well. The CO2, however, does not provide drive. In a pure CO2 flood, gas injection is followed by water (WAG, Water And Gas) , which provides pressure and drive to push the oil towards a producing well. • In an exhaust gas flood the 13% CO2 separates from the Nitrogen, and combines with the oil under pressure, providing the needed swelling and increase in oil flow. Meanwhile, the 87% Nitrogen gas rises to the top of the reservoir, providing a pressure source which is more effective than water at driving oil towards a producing well.
  • 5. Gas Efficiencies % of CO2 in N2 Pure Gas N2+CO2 Exhaust Gas Is 2X more efficient in oil recovery then pure CO2-only SPE Paper # 36687 LSU, U of M Rolla
  • 6. Engine Exhaust Gas Injection EOR Systems – Process Flow
  • 7. Fossil Bay Energy Exhaust Gas Generators (EGPs)  82% N2, 15% CO2, < 2% CO, < 75ppm O2  Minimal corrosion considerations compared to 100% CO2 used in CO2 flooding  No combustion or explosive risks compared to 100% CO2 used in CO2 flooding  Wide range of operational parameters  Variable Injection rates and Pressures  Fuel sources either methane or propane  PORTABLE – no infrastructure needed  COMPRESSION – part of the process.
  • 8. Remote Operated Unit  Injection rate: 10 m3/m (1 mmcf/d)  Injection pressure: 3800 kPa (550 psi) Exhaust Gas Generator Remote Operated Portable Unit
  • 9. Enhanced Oil Recovery  Pinnacle reefs, primary recovery 25%  Most conventional reservoirs are candidates  Unconventional Shales – new studies show 10% added EUR  Incremental oil recovery after water-flood  CHOPs – re-pressurization & heating  Alternate EOR versus water-flood Enhanced Gas Recovery – EGR  Re-pressure depleted natural gas reservoirs  Sweep gas for natural gas reservoirs (CBM)  Gas over oil replacement (Surmont) Thermal applications  Gas temperature up to 900*  low Gravity – Heavy Oil reservoirs  Alternative to SAGD Exhaust Gas Applications
  • 10. GAS INJECTION EOR Common Techniques  CO2 – most common gas used, competition for limited supplies; high infrastructure cost requires large reservoirs only - limited by sparse availability of CO2 pipelines to provide services to EOR-worthy fields  CH4 (Methane) used mainly during primary production-pressure maintenance, costly to strip liquids, added supply cost of royalties owed for produced-gas used  N2 - miscible at high pressure of 4000-psi, and expensive to separately produce large N2 volumes; best used in immiscible form as drive to push CO2 and oil through reservoir pore space.  Best Gas Injection Technology  Exhaust Gas- N/2-CO2 mixture (85%-15%) Unlimited supply Field Proven
  • 11. CO2 Gas Flooding CO2 Pipeline Supply Issues (current demand for EOR exceeds supply) 80+ Projects in Operation = 290,000 BOPD - Large Reservoirs only (>10 MMBO) Recoveries Exceeding 50% OOIP – High Project Costs (>100’s of millions of $$$) 100% CO2 Only - No Drive Mechanism- Suffers Early gas breakthrough Horizontal Flooding – fluid override lowers recovery
  • 12. MICHIGAN CO2 FLOOD – N.REEF Horizontal Producer - +500 BOPD Average first 2 years
  • 13. MICHIGAN CO2 FLOOD – N.REEF Vertical Producer – Averaged 190 bopd, first 4 years
  • 14. Springhill Grove Exhaust Gas Projects The Spring Grove field was discovered in 1958 and the two wells produced 1-2 bopd. In 1961, the operator bought an 80mcfd Exhaust Gas Processor, and production went up to 6bopd. In 1964, the field was bought, the new operators bought other EGP’s for a total of 200mcfd and started injection. Within 4 months the Spring Grove field was producing at rates over 5000 bopm. The offsetting Boswell-Walker Leases saw production increases from 150bopm to 1300bopm by virtue of the exhaust being injected in the Hart Lease. In 1964, a full scale development was initiated on this lease.
  • 15. Gas Cap Injection + Gravity Drainage Injected Gas Mixture (CO2+N2) Fills Reservoir Gas Cap N2 Pushes CO2 to Mix With Oil and Flow to Production Well N2 Oil & CO2 Miscibility
  • 16. Gas Flooding EOR -- also known as miscible gas flooding -- is one of the leading enhanced oil recovery (EOR) technologies employed for recovering the stranded, trapped oil, left behind in pressure-depleted oil reservoirs after initial primary oil recovery has ended. Gas flooding typically includes CO2, natural gas or N2 nitrogen as the gas that is injected. Gas flooding is an "enhanced oil recovery" application for injecting miscible (and immiscible) gases into an oil reservoir to increase oil production by re- pressurizing the reservoir to push the oil to the production wells. Miscible means that the injected-gas "mixes" with the oil, thereby reducing its viscosity and interfacial tension of the oil and rock. Miscible gas flooding also increases oil "swelling" and localized pressure or drive within the reservoir. "Immiscible" flooding means that the injected-gas does not mix or go into solution, but instead provides the energy “push” (drive) by increased pressure. Immiscible flooding does not produce as much oil as miscible gas flooding, however there are certain applications and reservoirs wherein immiscible flooding is well-suited