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ALPINE SKI HOUSE
RECYCLING OF
ACRYLIC
1
ALPINE SKI HOUSE
RECEP YARDIMCI-190108011025
IBRAHIM HALIL ORTATEPE-190108011018
2
ALPINE SKI HOUSE
DEFINE THE
PROBLEM
3
ALPINE SKI HOUSE
ALPINE SKI HOUSE
DEFINE THE
PROBLEM
 The chemicals used in the production
processes of textile fibers, water
consumption and greenhouse gas emissions
cause serious damage to nature.Every year,
over 100 million tons of fibers are produced
to be used in textile production in the
world. In this process, 1 million tons of
paint, 42 million tons of chemicals, 93
billion m3 of water are consumed and 1.2
billion tons of greenhouse gas emissions are
released. While 48 million tons of the
clothes produced after all these processes
are thrown away, 75% of these products,
which are thought to have expired, are
either incinerated or disposed of by burying
them in the ground.
4
ALPINE SKI HOUSE
ALPINE SKI HOUSE
DEFINE THE
PROBLEM
Extending the life of clothing, which has an
average lifespan of 3 years, by 3 months
reduces carbon, water footprint and waste
generation by 5 to 10 percent.
5
ALPINE SKI HOUSE
ALPINE SKI HOUSE
DEFINE THE PROBLEM
 Regular collection of textile waste with collection trucks
is another important step to raise awareness. In this
way, more and more attention is drawn to the
interaction of sustainability and fashion, and the trend
from fast fashion to slow fashion is increasing.
Consumers can contribute to reducing the effects of
environmental pollution and climate change caused by
the increasing solid waste landfills resulting from the
fast-wearing industry, by purchasing the products of
brands that are produced from longer-lasting fibers
such as Acrycycle and that promise to reduce their
negative effects on climate change.
 In our project ; With Acrycycle, it is aimed to reduce the
need for new products and to minimize the
consumption of natural resources required for
production. The next goal of Acrycycle, which does not
use any harmful chemicals in the recycling process, is to
include textile products that have completed their
useful life in the production process without losing their
value. In this way, it is aimed to increase the
contribution to nature by recycling more waste.
6
ALPINE SKI HOUSE
GATHER THE
INFORMATION
PAN is not a thermoplastic polymer like PE,
PP, polyester or polyamide that melt when
heated. With the PAN heated at a temperature
above 180ºC, the polymerization of the polymer
chain begins, making it rigid and dark. This
property makes PAN fiber the best-known
carbon fiber precursor.
Virtually everything that exists in the market
today containing PAN, are acrylic fibers and ABS
plastic, which, being considered a
thermoplastic, can be recycled in the same way
as conventional plastics.
7
ALPINE SKI HOUSE
ALPINE SKI HOUSE
GATHER THE
INFORMATION
PAN is not a thermoplastic polymer like PE,
PP, polyester or polyamide that melt when
heated. With the PAN heated at a temperature
above 180ºC, the polymerization of the
polymer chain begins, making it rigid and dark.
This property makes PAN fiber the best-known
carbon fiber precursor.
Virtually everything that exists in the market
today containing PAN, are acrylic fibers and ABS
plastic, which, being considered a
thermoplastic, can be recycled in the same way
as conventional plastics.
8
ALPINE SKI HOUSE
GATHER THE
INFORMATION
 Fabrics containing PAN fibers (acrylic fibers), in
most cases, do not use pure acrylic fiber, but a
mixture of other types of fibers such as cotton,
wool, polyester or polyamide with acrylic.
Mechanical recycling to separate the various
fibers of a fabric is very difficult and expensive,
due to the small diameter of the filaments (in
the order of a few microns), small difference in
density and the interweaving between them.
 Acrylic fibers in fabrics are almost always dyed
or pigmented and that is why PAN, if recovered
from such fibers by chemical method, will
always have coloring or opacity, which makes
this PAN unfeasible for reuse in wet and dry
spinning processes, that mostly produce white
fibers.
9
ALPINE SKI HOUSE
GATHER THE
INFORMATION
 As it is a very resistant and insoluble polymer,
there are few solvents that can be used
industrially in the chemical recycling of PAN by
dissolution, followed by its precipitation by
addition in water. PAN's main solvents are: DMF,
DMAc, nitric acid, sodium thiocyanate, zinc
chloride and ethylene carbonate. The use of
solvents in PAN's chemical recycling makes the
process expensive, mainly due to the need for
recycling for reuse and treatment of effluents
since they are toxic.
 Fabrics containing acrylic fibers cannot be
depolymerized or cracked by thermal
processes, due to the cyclization of the chain
with the formation of solid waste of high
carbon content in the reactor.
10
ALPINE SKI HOUSE
ALPINE SKI HOUSE
GATHER THE
INFORMATION
Acrylic fiber and its fabrics cannot be used as
fuel in ovens and should only be incinerated in
special equipment, since they produce
hydrocyanic acid (HCN) and ammonia (NH3),
which are highly toxic gases.
Not even in the companies that produce
acrylic fibers, their residues and production
losses are recycled - despite being made up
only of polyacrylonitrile -, since some
characteristics of the threads such as thickness,
presence of solvent, yellowing or coloring make
commercialization unfeasible.
11
ALPINE SKI HOUSE
 A PAN recycling method must be robust enough to use all
types of acrylic waste generated by the production chain,
which are:
 Polymerization process, which during launch produces
polymer out of specification.
 Start spinning, which produces fibers with solvents and
thicker filaments.
 Loss of spinning during yarn production and dyeing.
 Losses in the fabric cutting process for clothing
manufacturing.
GATHER THE INFORMATION
12
ALPINE SKI HOUSE
GENERATE MULTİPLE SOLUTIONS
* RAISE AWARENESS
* RECYCLİNG OF ACRYLİC
ALPINE SKI HOUSE
ANALYZE AND SELECT
A SOLUTİON
 Analyze the solution: First solution In recent years, many initiatives
have been initiated by non-governmental organizations, government
organizations and brands in order to ensure that the efforts to include
consumers in recycling are successful. As an example of these
initiatives; It can be mentioned about the responsibility of collecting
clothes that H&M and I:CO carry out together. In the process carried
out by the two institutions, consumers earn discount coupons that they
can use in their next shopping after delivering their old clothes to any
H&M store. As in this study, which can be given as an effective example
of increasing recycling in textiles, the aim is to increase social
awareness by explaining the importance and benefits of recycling.
 Apart from the projects carried out by brands such as H&M, many
companies' websites have educational content on the subject. In
addition to these, the collection of textile wastes with collection trucks
at regular intervals is another important step taken to raise awareness.
In this way, more and more attention is drawn to the interaction of
sustainability and fashion, and the trend from fast fashion to slow
fashion is increasing. Consumers can contribute to reducing the effects
of environmental pollution and climate change caused by the
increasing solid waste landfills resulting from the fast-wearing industry,
by purchasing the products of brands that are produced from longer-
lasting fibers such as Acrycycle and that promise to reduce their
negative effects on climate change
ALPINE SKI HOUSE
ANALYZE AND
SELECT A SOLUTION
Analyze the solution: Second solution
1)Picking
2)Decomposition
3)Processing
15
ALPINE SKI HOUSE
 Analyze the solution: PİCKİNG The collection
process is the first step of recycling. Collection
boxes placed in stores or collection of waste from
houses at regular intervals are the first actions to
be taken in this process. As a strategy to increase
the number of donations, collection boxes can be
placed in public, high-traffic and conspicuous
places. In this way, I:CO collected 17,000 tons of
clothing and shoes in 2015, of which 7,000 tons
were recycled.
ANALYZE AND SELECT
A SOLUTION
16
ALPINE SKI HOUSE
ALPINE SKI HOUSE
ANALYZE AND
SELECT A SOLUTION
Decomposition:The collected textiles are divided into
three categories by the people working in the sorting plants.
The sorting process, which is called second-hand use, use as a
cleaning cloth, and the part to be converted into raw materials,
and carried out in three categories, is generally done manually.
However, auxiliary systems such as belt conveyors and
collection boxes are also included in this process. Recently,
projects developed on automatic separation systems provide a
more sensitive separation process, allowing for higher quality
recycled materials to be obtained. That's why automatic sorting
machines play an important role in the recycling process. On
the other hand, textiles that cannot be separated sufficiently
due to technological deficiencies can generally be evaluated in
more value-added applications; It is used in less valuable
applications such as filling material, cleaning cloth production.
Automatic sorting technology was developed by the European
Commission's economic innovation initiative Textiles for
Textiles (T4T) project group to address the problem of using
textiles that cannot be separated sufficiently in applications
with relatively little added value.
17
ALPINE SKI HOUSE
ANALYZE AND
SELECT A SOLUTION
With this developed technology, textile raw
materials are separated according to their
composition and color with the NIR (Near
Infrared) spectroscopy device, which is also
frequently used in pet bottle recycling. This
project has an investment cost of 1.3 million
euros. After the textiles are roughly sorted to go
to the second-hand clothing industry and be
included in the recycling chain, they are taken
to the automatic sorting machine and cut. The
development process of this project continues
with the contributions of seven different
companies from the sector as the FIBERSORT
project. The success criterion of the project is
the precise separation speed per unit time.
18
ALPINE SKI HOUSE
ALPINE SKI HOUSE
ANALYZE AND
SELECT A SOLUTION
Processing: After the textiles are sorted
according to their composition and color, they
are cut. Separating the aforementioned
products according to their colors eliminates
the need for repainting, thus saving energy and
labor, as well as reducing pollutants originating
from paint. Then, the cut clothes are mixed
with the appropriate material according to
their usage areas. In this process, long fibers
are used in clothing and home textile
applications, while short fibers are used in
nonwoven applications such as personal care,
automotive and insulation.
19
ALPINE SKI HOUSE
ANALYZE AND
SELECT A SOLUTION
While mattress pads or filling materials in
furniture can be given as examples of home
textile applications, it is also possible to talk
about its use in applications such as thermal
insulation and panel lining in the automotive
industry. To talk about textile wastes consisting
of polyester, another fiber type; These wastes
are turned into granules after the cutting
process, and as a result, the raw material of
polyester fiber is produced.
20
ALPINE SKI HOUSE
TEST AND
IMPLEMENT
SOLUTION
Acrylic recycled
 With Acrycycle, the world's first recycled
acrylic fiber, wastes generated as a result of
production processes are converted into
products again. Environmental pollution is
prevented with Acrycycle, which ensures
that wastes are included in production
instead of burying them. It contributes to
the protection of nature with 30 percent
less CO2 emissions, 86 percent less water
consumption and 99.7 percent solvent
recycling rates. Products produced with
Acrycycle stand out with their long-lasting
and environmentally friendly features
21
ALPINE SKI HOUSE
ALPINE SKI HOUSE
TEST AND
IMPLEMENT
SOLUTION
1. By recycling acrylic materials, you drastically
reduce the environmental risks of these
materials.
2. This further boosts the effort to lessen the
carbon footprint.
3. Alongside that, recycling reduces the amount
of waste in our oceans.
4. By doing so, we ensure a safe and healthy
environment for marine life
5. Requires Less Energy and Helps Conserve
Natural Resources
22
ALPINE SKI HOUSE
ALPINE SKI HOUSE 24

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Recyclıng of acrylıc RH.pptx

  • 2. ALPINE SKI HOUSE RECEP YARDIMCI-190108011025 IBRAHIM HALIL ORTATEPE-190108011018 2
  • 3. ALPINE SKI HOUSE DEFINE THE PROBLEM 3
  • 4. ALPINE SKI HOUSE ALPINE SKI HOUSE DEFINE THE PROBLEM  The chemicals used in the production processes of textile fibers, water consumption and greenhouse gas emissions cause serious damage to nature.Every year, over 100 million tons of fibers are produced to be used in textile production in the world. In this process, 1 million tons of paint, 42 million tons of chemicals, 93 billion m3 of water are consumed and 1.2 billion tons of greenhouse gas emissions are released. While 48 million tons of the clothes produced after all these processes are thrown away, 75% of these products, which are thought to have expired, are either incinerated or disposed of by burying them in the ground. 4
  • 5. ALPINE SKI HOUSE ALPINE SKI HOUSE DEFINE THE PROBLEM Extending the life of clothing, which has an average lifespan of 3 years, by 3 months reduces carbon, water footprint and waste generation by 5 to 10 percent. 5
  • 6. ALPINE SKI HOUSE ALPINE SKI HOUSE DEFINE THE PROBLEM  Regular collection of textile waste with collection trucks is another important step to raise awareness. In this way, more and more attention is drawn to the interaction of sustainability and fashion, and the trend from fast fashion to slow fashion is increasing. Consumers can contribute to reducing the effects of environmental pollution and climate change caused by the increasing solid waste landfills resulting from the fast-wearing industry, by purchasing the products of brands that are produced from longer-lasting fibers such as Acrycycle and that promise to reduce their negative effects on climate change.  In our project ; With Acrycycle, it is aimed to reduce the need for new products and to minimize the consumption of natural resources required for production. The next goal of Acrycycle, which does not use any harmful chemicals in the recycling process, is to include textile products that have completed their useful life in the production process without losing their value. In this way, it is aimed to increase the contribution to nature by recycling more waste. 6
  • 7. ALPINE SKI HOUSE GATHER THE INFORMATION PAN is not a thermoplastic polymer like PE, PP, polyester or polyamide that melt when heated. With the PAN heated at a temperature above 180ºC, the polymerization of the polymer chain begins, making it rigid and dark. This property makes PAN fiber the best-known carbon fiber precursor. Virtually everything that exists in the market today containing PAN, are acrylic fibers and ABS plastic, which, being considered a thermoplastic, can be recycled in the same way as conventional plastics. 7
  • 8. ALPINE SKI HOUSE ALPINE SKI HOUSE GATHER THE INFORMATION PAN is not a thermoplastic polymer like PE, PP, polyester or polyamide that melt when heated. With the PAN heated at a temperature above 180ºC, the polymerization of the polymer chain begins, making it rigid and dark. This property makes PAN fiber the best-known carbon fiber precursor. Virtually everything that exists in the market today containing PAN, are acrylic fibers and ABS plastic, which, being considered a thermoplastic, can be recycled in the same way as conventional plastics. 8
  • 9. ALPINE SKI HOUSE GATHER THE INFORMATION  Fabrics containing PAN fibers (acrylic fibers), in most cases, do not use pure acrylic fiber, but a mixture of other types of fibers such as cotton, wool, polyester or polyamide with acrylic. Mechanical recycling to separate the various fibers of a fabric is very difficult and expensive, due to the small diameter of the filaments (in the order of a few microns), small difference in density and the interweaving between them.  Acrylic fibers in fabrics are almost always dyed or pigmented and that is why PAN, if recovered from such fibers by chemical method, will always have coloring or opacity, which makes this PAN unfeasible for reuse in wet and dry spinning processes, that mostly produce white fibers. 9
  • 10. ALPINE SKI HOUSE GATHER THE INFORMATION  As it is a very resistant and insoluble polymer, there are few solvents that can be used industrially in the chemical recycling of PAN by dissolution, followed by its precipitation by addition in water. PAN's main solvents are: DMF, DMAc, nitric acid, sodium thiocyanate, zinc chloride and ethylene carbonate. The use of solvents in PAN's chemical recycling makes the process expensive, mainly due to the need for recycling for reuse and treatment of effluents since they are toxic.  Fabrics containing acrylic fibers cannot be depolymerized or cracked by thermal processes, due to the cyclization of the chain with the formation of solid waste of high carbon content in the reactor. 10
  • 11. ALPINE SKI HOUSE ALPINE SKI HOUSE GATHER THE INFORMATION Acrylic fiber and its fabrics cannot be used as fuel in ovens and should only be incinerated in special equipment, since they produce hydrocyanic acid (HCN) and ammonia (NH3), which are highly toxic gases. Not even in the companies that produce acrylic fibers, their residues and production losses are recycled - despite being made up only of polyacrylonitrile -, since some characteristics of the threads such as thickness, presence of solvent, yellowing or coloring make commercialization unfeasible. 11
  • 12. ALPINE SKI HOUSE  A PAN recycling method must be robust enough to use all types of acrylic waste generated by the production chain, which are:  Polymerization process, which during launch produces polymer out of specification.  Start spinning, which produces fibers with solvents and thicker filaments.  Loss of spinning during yarn production and dyeing.  Losses in the fabric cutting process for clothing manufacturing. GATHER THE INFORMATION 12
  • 13. ALPINE SKI HOUSE GENERATE MULTİPLE SOLUTIONS * RAISE AWARENESS * RECYCLİNG OF ACRYLİC
  • 14. ALPINE SKI HOUSE ANALYZE AND SELECT A SOLUTİON  Analyze the solution: First solution In recent years, many initiatives have been initiated by non-governmental organizations, government organizations and brands in order to ensure that the efforts to include consumers in recycling are successful. As an example of these initiatives; It can be mentioned about the responsibility of collecting clothes that H&M and I:CO carry out together. In the process carried out by the two institutions, consumers earn discount coupons that they can use in their next shopping after delivering their old clothes to any H&M store. As in this study, which can be given as an effective example of increasing recycling in textiles, the aim is to increase social awareness by explaining the importance and benefits of recycling.  Apart from the projects carried out by brands such as H&M, many companies' websites have educational content on the subject. In addition to these, the collection of textile wastes with collection trucks at regular intervals is another important step taken to raise awareness. In this way, more and more attention is drawn to the interaction of sustainability and fashion, and the trend from fast fashion to slow fashion is increasing. Consumers can contribute to reducing the effects of environmental pollution and climate change caused by the increasing solid waste landfills resulting from the fast-wearing industry, by purchasing the products of brands that are produced from longer- lasting fibers such as Acrycycle and that promise to reduce their negative effects on climate change
  • 15. ALPINE SKI HOUSE ANALYZE AND SELECT A SOLUTION Analyze the solution: Second solution 1)Picking 2)Decomposition 3)Processing 15
  • 16. ALPINE SKI HOUSE  Analyze the solution: PİCKİNG The collection process is the first step of recycling. Collection boxes placed in stores or collection of waste from houses at regular intervals are the first actions to be taken in this process. As a strategy to increase the number of donations, collection boxes can be placed in public, high-traffic and conspicuous places. In this way, I:CO collected 17,000 tons of clothing and shoes in 2015, of which 7,000 tons were recycled. ANALYZE AND SELECT A SOLUTION 16
  • 17. ALPINE SKI HOUSE ALPINE SKI HOUSE ANALYZE AND SELECT A SOLUTION Decomposition:The collected textiles are divided into three categories by the people working in the sorting plants. The sorting process, which is called second-hand use, use as a cleaning cloth, and the part to be converted into raw materials, and carried out in three categories, is generally done manually. However, auxiliary systems such as belt conveyors and collection boxes are also included in this process. Recently, projects developed on automatic separation systems provide a more sensitive separation process, allowing for higher quality recycled materials to be obtained. That's why automatic sorting machines play an important role in the recycling process. On the other hand, textiles that cannot be separated sufficiently due to technological deficiencies can generally be evaluated in more value-added applications; It is used in less valuable applications such as filling material, cleaning cloth production. Automatic sorting technology was developed by the European Commission's economic innovation initiative Textiles for Textiles (T4T) project group to address the problem of using textiles that cannot be separated sufficiently in applications with relatively little added value. 17
  • 18. ALPINE SKI HOUSE ANALYZE AND SELECT A SOLUTION With this developed technology, textile raw materials are separated according to their composition and color with the NIR (Near Infrared) spectroscopy device, which is also frequently used in pet bottle recycling. This project has an investment cost of 1.3 million euros. After the textiles are roughly sorted to go to the second-hand clothing industry and be included in the recycling chain, they are taken to the automatic sorting machine and cut. The development process of this project continues with the contributions of seven different companies from the sector as the FIBERSORT project. The success criterion of the project is the precise separation speed per unit time. 18
  • 19. ALPINE SKI HOUSE ALPINE SKI HOUSE ANALYZE AND SELECT A SOLUTION Processing: After the textiles are sorted according to their composition and color, they are cut. Separating the aforementioned products according to their colors eliminates the need for repainting, thus saving energy and labor, as well as reducing pollutants originating from paint. Then, the cut clothes are mixed with the appropriate material according to their usage areas. In this process, long fibers are used in clothing and home textile applications, while short fibers are used in nonwoven applications such as personal care, automotive and insulation. 19
  • 20. ALPINE SKI HOUSE ANALYZE AND SELECT A SOLUTION While mattress pads or filling materials in furniture can be given as examples of home textile applications, it is also possible to talk about its use in applications such as thermal insulation and panel lining in the automotive industry. To talk about textile wastes consisting of polyester, another fiber type; These wastes are turned into granules after the cutting process, and as a result, the raw material of polyester fiber is produced. 20
  • 21. ALPINE SKI HOUSE TEST AND IMPLEMENT SOLUTION Acrylic recycled  With Acrycycle, the world's first recycled acrylic fiber, wastes generated as a result of production processes are converted into products again. Environmental pollution is prevented with Acrycycle, which ensures that wastes are included in production instead of burying them. It contributes to the protection of nature with 30 percent less CO2 emissions, 86 percent less water consumption and 99.7 percent solvent recycling rates. Products produced with Acrycycle stand out with their long-lasting and environmentally friendly features 21
  • 22. ALPINE SKI HOUSE ALPINE SKI HOUSE TEST AND IMPLEMENT SOLUTION 1. By recycling acrylic materials, you drastically reduce the environmental risks of these materials. 2. This further boosts the effort to lessen the carbon footprint. 3. Alongside that, recycling reduces the amount of waste in our oceans. 4. By doing so, we ensure a safe and healthy environment for marine life 5. Requires Less Energy and Helps Conserve Natural Resources 22

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