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Using thermocline manipulation to
remediate mercury-contaminated
reservoirs in southwestern Utah
Using thermocline manipulation to
remediate mercury-contaminated
reservoirs in southwestern Utah
USGS, Utah/Wisconsin/Arkansas Water Science Centers
Utah DNR/DWR
Utah DEQ/DWQ
Finnish Environment Institute
USGS, Utah/Wisconsin/Arkansas Water Science Centers
Utah DNR/DWR
Utah DEQ/DWQ
Finnish Environment Institute
PROBLEM
TOPICSTOPICS
♦Thermocline manipulation in Finland
♦Application to reservoirs in Utah
♦Remediation objectives
♦Thermocline manipulation in Finland
♦Application to reservoirs in Utah
♦Remediation objectives
METHYL Hg PROFILEMETHYL Hg PROFILE
FromForsiusandothers,2006
THERMOCLINE DEPRESSIONTHERMOCLINE DEPRESSIONFromForsiusandothers,2006
Pretreatment
epilimnion
Post-treatment
epilimnion
Post-treatment
hypolimnion
EQUIPMENTEQUIPMENT
♦Experiment originally
designed for climate
change
♦Artificially decrease
thermocline volume
♦Increase depth of
oxygen penetration
during summer
stratification
♦More amenable to wind
erosion
Thermocline mixing equipment
(MIXOX).
FromForsiusandothers,2006
MIXOX DEPLOYMENTMIXOX DEPLOYMENT
♦Cost is about 2,000 EU
♦Powered via lake bottom
cable from on-shore
power source
♦Platform provides for
easy deployment of
additional instruments
♦Powered via
wind/solar/hydroelectric
at remote reservoir sites
Deployment of mixing equipment and
surface platform
FromForsiusandothers,2006
DEPRESSION = 2.0 METERSDEPRESSION = 2.0 METERS
DEPTHBELOWLAKESURFACE,INM
T, oC
DECREASE IN METHYL Hg
(Rask and others, in review)
DECREASE IN METHYL Hg
(Rask and others, in review)
Fish tissue Water
(small perch, 70-80 mm) (epilimnion)
0.6
0.4
0.2
0.0
MeHg,ng/L
Before During/after
pumping pumping
Thermocline
pumping
X = 0.54
X = 0.16
DECREASE IN METHYL HgDECREASE IN METHYL Hg
♦Decreased volume
of anoxic
hypolimnion
♦Increased volume of
oxic epilimnion
♦Decreased surface
area of anoxic
sediment
♦Longer ice-free
season
Pre-pumping
Post-pumping
POTENTIAL
APPLICATION TO SMALL
RESERVOIRS IN UTAH
POTENTIAL
APPLICATION TO SMALL
RESERVOIRS IN UTAH
NEWCASTLE RESERVOIRNEWCASTLE RESERVOIR
Water/sediment
sampling site
♦Reservoir dam
completed in 1956
♦Small reservoir (66
hectares)
♦Mean depth = 7.2
meters
♦Water and sediment
sampled during July
2007
♦Trout/wipers
accumulating high
Hg levels in 3
months
NEWCASTLE BIOTANEWCASTLE BIOTA
10
8
6
4
2
0
14 16 18 20 22
WATER TEMPERATURE,
o
C
DEPTHBELOWWATERSURFACE,INMETERS THERMOCLINETHERMOCLINE
Hg(inorg)
CH3Hg
[HgTot]
whole water
[1.45 ng/L]
[2.91 ng/L]
Explanation
2.5 ng/L
0.2 ng/L
HISTORIC MERCURY
DEPOSITION RATES
HISTORIC MERCURY
DEPOSITION RATES
1930
1940
1950
1960
1970
1980
1990
2000
2010
0.00 0.01 0.02 0.03 0.04
Hg DEPOSITION (UG/CM
2
/YR)
YEAROFSEDIMENTDEPOSITION
Dam
completion
Sediment core, Newcastle
Reservoir, Utah
Dry mass (g/cm2) * Hg conc. (μg/g)
deposition period (yrs)
Spillway
raised
NEWCASTLE REMEDIATION
OBJECTIVES
NEWCASTLE REMEDIATION
OBJECTIVES
1. Calibrate a hydrodynamic model to simulate the naturally
induced thermal stratification in Newcastle Reservoir over
an annual cycle
2. Utilize the calibrated hydrodynamic model to determine the
optimal location(s) and pumping rates needed to depress the
thermocline elevation by 1 to 2 meters
3. Utilize results from objective 2 to design a field experiment
to depress the thermocline in the experimental reservoir
4. Utilize pre-pumping and pumping data to determine if the
thermocline manipulation has resulted in a measurable
decrease in mercury concentration in water, sediment, and
biota
NEWCASTLE REMEDIATION
YR 1 TASKS/SCHEDULE
NEWCASTLE REMEDIATION
YR 1 TASKS/SCHEDULE
National Park Service QW
sampling boat, Lake Powell,
Utah
♦Baseline Hg data
♦Determine if
pumping will work
NEWCASTLE REMEDIATION
YR 2 TASKS/SCHEDULE
NEWCASTLE REMEDIATION
YR 2 TASKS/SCHEDULE
Limnology profiling, Lake
Powell, Utah
♦Conduct pumping
experiment
♦Model observed
pumping results
NEWCASTLE REMEDIATION
YR 3 TASKS/SCHEDULE
NEWCASTLE REMEDIATION
YR 3 TASKS/SCHEDULE
Sediment coring platform, Newcastle
Reservoir, Utah
♦Continue field
experiment/modeling
♦Decide if results warrant
implementation
Hg IN UTAH RESERVOIRSHg IN UTAH RESERVOIRS
♦Many small reservoirs
with fish advisories for
Hg
♦Cost effective
($4,000/pump to
remediate a fishery)
♦Baseline (pre-treatment)
fish data already
collected
♦Alternative remediation
options??

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Using thermocline manipulation to remediate mercury-contaminated reservoirs in southwestern Utah

  • 1. Using thermocline manipulation to remediate mercury-contaminated reservoirs in southwestern Utah Using thermocline manipulation to remediate mercury-contaminated reservoirs in southwestern Utah USGS, Utah/Wisconsin/Arkansas Water Science Centers Utah DNR/DWR Utah DEQ/DWQ Finnish Environment Institute USGS, Utah/Wisconsin/Arkansas Water Science Centers Utah DNR/DWR Utah DEQ/DWQ Finnish Environment Institute
  • 3. TOPICSTOPICS ♦Thermocline manipulation in Finland ♦Application to reservoirs in Utah ♦Remediation objectives ♦Thermocline manipulation in Finland ♦Application to reservoirs in Utah ♦Remediation objectives
  • 4.
  • 5. METHYL Hg PROFILEMETHYL Hg PROFILE FromForsiusandothers,2006
  • 7. EQUIPMENTEQUIPMENT ♦Experiment originally designed for climate change ♦Artificially decrease thermocline volume ♦Increase depth of oxygen penetration during summer stratification ♦More amenable to wind erosion Thermocline mixing equipment (MIXOX). FromForsiusandothers,2006
  • 8. MIXOX DEPLOYMENTMIXOX DEPLOYMENT ♦Cost is about 2,000 EU ♦Powered via lake bottom cable from on-shore power source ♦Platform provides for easy deployment of additional instruments ♦Powered via wind/solar/hydroelectric at remote reservoir sites Deployment of mixing equipment and surface platform FromForsiusandothers,2006
  • 9. DEPRESSION = 2.0 METERSDEPRESSION = 2.0 METERS DEPTHBELOWLAKESURFACE,INM T, oC
  • 10. DECREASE IN METHYL Hg (Rask and others, in review) DECREASE IN METHYL Hg (Rask and others, in review) Fish tissue Water (small perch, 70-80 mm) (epilimnion) 0.6 0.4 0.2 0.0 MeHg,ng/L Before During/after pumping pumping Thermocline pumping X = 0.54 X = 0.16
  • 11. DECREASE IN METHYL HgDECREASE IN METHYL Hg ♦Decreased volume of anoxic hypolimnion ♦Increased volume of oxic epilimnion ♦Decreased surface area of anoxic sediment ♦Longer ice-free season Pre-pumping Post-pumping
  • 12. POTENTIAL APPLICATION TO SMALL RESERVOIRS IN UTAH POTENTIAL APPLICATION TO SMALL RESERVOIRS IN UTAH
  • 13. NEWCASTLE RESERVOIRNEWCASTLE RESERVOIR Water/sediment sampling site ♦Reservoir dam completed in 1956 ♦Small reservoir (66 hectares) ♦Mean depth = 7.2 meters ♦Water and sediment sampled during July 2007 ♦Trout/wipers accumulating high Hg levels in 3 months
  • 15. 10 8 6 4 2 0 14 16 18 20 22 WATER TEMPERATURE, o C DEPTHBELOWWATERSURFACE,INMETERS THERMOCLINETHERMOCLINE Hg(inorg) CH3Hg [HgTot] whole water [1.45 ng/L] [2.91 ng/L] Explanation 2.5 ng/L 0.2 ng/L
  • 16. HISTORIC MERCURY DEPOSITION RATES HISTORIC MERCURY DEPOSITION RATES 1930 1940 1950 1960 1970 1980 1990 2000 2010 0.00 0.01 0.02 0.03 0.04 Hg DEPOSITION (UG/CM 2 /YR) YEAROFSEDIMENTDEPOSITION Dam completion Sediment core, Newcastle Reservoir, Utah Dry mass (g/cm2) * Hg conc. (μg/g) deposition period (yrs) Spillway raised
  • 17. NEWCASTLE REMEDIATION OBJECTIVES NEWCASTLE REMEDIATION OBJECTIVES 1. Calibrate a hydrodynamic model to simulate the naturally induced thermal stratification in Newcastle Reservoir over an annual cycle 2. Utilize the calibrated hydrodynamic model to determine the optimal location(s) and pumping rates needed to depress the thermocline elevation by 1 to 2 meters 3. Utilize results from objective 2 to design a field experiment to depress the thermocline in the experimental reservoir 4. Utilize pre-pumping and pumping data to determine if the thermocline manipulation has resulted in a measurable decrease in mercury concentration in water, sediment, and biota
  • 18. NEWCASTLE REMEDIATION YR 1 TASKS/SCHEDULE NEWCASTLE REMEDIATION YR 1 TASKS/SCHEDULE National Park Service QW sampling boat, Lake Powell, Utah ♦Baseline Hg data ♦Determine if pumping will work
  • 19. NEWCASTLE REMEDIATION YR 2 TASKS/SCHEDULE NEWCASTLE REMEDIATION YR 2 TASKS/SCHEDULE Limnology profiling, Lake Powell, Utah ♦Conduct pumping experiment ♦Model observed pumping results
  • 20. NEWCASTLE REMEDIATION YR 3 TASKS/SCHEDULE NEWCASTLE REMEDIATION YR 3 TASKS/SCHEDULE Sediment coring platform, Newcastle Reservoir, Utah ♦Continue field experiment/modeling ♦Decide if results warrant implementation
  • 21. Hg IN UTAH RESERVOIRSHg IN UTAH RESERVOIRS ♦Many small reservoirs with fish advisories for Hg ♦Cost effective ($4,000/pump to remediate a fishery) ♦Baseline (pre-treatment) fish data already collected ♦Alternative remediation options??