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K.Sudheer Kumar,
Assistant professor.
Dept.of Pharmacognosy
Chilkur Balaji college of Pharmacy
Hyderabad.
E-mail:sudheer.y2k8@gmail.com
NATURAL DYES
Natural dyes are derived from naturally occurring sources such as plants (e.g., indigo
and saffron)
Insects (e.g., cochineal beetles and lac scale insects)
Animals (e.g., some species of mollusks or shellfish)
Minerals (e.g., ferrous sulfate, ochre, and clay)
without any chemical treatment.
A spectrum of beautiful natural colors ranging from yellow to black exists in the
above sources.
These colors are exhibited by various organic and inorganic molecules (pigments) and
their mixtures are due to the absorption of light in the visible region of 400-800 nm.
This absorption of light depends on the structure or constituents of the colouring
pigment/ molecules contain various chromophores present in the dye yielding plant to
display the of colors
Natural dyes are derived from naturally occurring sources such as plants (e.g., indigo
and saffron)
Insects (e.g., cochineal beetles and lac scale insects)
Animals (e.g., some species of mollusks or shellfish)
Minerals (e.g., ferrous sulfate, ochre, and clay)
without any chemical treatment.
A spectrum of beautiful natural colors ranging from yellow to black exists in the
above sources.
These colors are exhibited by various organic and inorganic molecules (pigments) and
their mixtures are due to the absorption of light in the visible region of 400-800 nm.
This absorption of light depends on the structure or constituents of the colouring
pigment/ molecules contain various chromophores present in the dye yielding plant to
display the of colors
The use of natural products together with their therapeutic properties is as
ancient as human civilization and for a long time, mineral, plant and animal
products were the main sources of drugs
The current preference for naturally derived colorants is due to their
healthfulness and excellent performance.
Several synthetic colorants have been banned because they cause allergy-like
symptoms or are carcinogens.
Nowadays, natural dyes are commonly used in the cosmetic industry due to no
side effects, UV protection and anti-aging properties.
In India, there are more than 450 plants that can yield dyes. In addition to their
dye-yielding characteristics, some of these plants also possess medicinal value.
The use of natural products together with their therapeutic properties is as
ancient as human civilization and for a long time, mineral, plant and animal
products were the main sources of drugs
The current preference for naturally derived colorants is due to their
healthfulness and excellent performance.
Several synthetic colorants have been banned because they cause allergy-like
symptoms or are carcinogens.
Nowadays, natural dyes are commonly used in the cosmetic industry due to no
side effects, UV protection and anti-aging properties.
In India, there are more than 450 plants that can yield dyes. In addition to their
dye-yielding characteristics, some of these plants also possess medicinal value.
Natural dyes are environment friendly for example, turmeric, the brightest of
naturally occurring yellow dyes is a powerful antiseptic which revitalizes the
skin, while indigo gives a cooling sensation.
Many of the plants used for dye extraction are classified as medicinal and
some of these have recently been shown to possess antimicrobial activity.
Many other common natural dyes are reported as potent antimicrobial agents
owing to the presence of a large amount of tannins.
Natural dyes are environment friendly for example, turmeric, the brightest of
naturally occurring yellow dyes is a powerful antiseptic which revitalizes the
skin, while indigo gives a cooling sensation.
Many of the plants used for dye extraction are classified as medicinal and
some of these have recently been shown to possess antimicrobial activity.
Many other common natural dyes are reported as potent antimicrobial agents
owing to the presence of a large amount of tannins.
TURMERIC
Scientific classification
Kingdom : Plantae
Division : Magnoliophyta
Class : Liliopsida
Subclass : Zingiberidae
Order : Zingiberales
Family : Zingiberaceae
Genus : Curcuma
Species : C. longa
Turmeric is commonly known as Indian
saffron. It consists of dried, as well as fresh
rhizomes of the plant Curcuma longa Linn.
Turmeric is commonly known as Indian
saffron. It consists of dried, as well as fresh
rhizomes of the plant Curcuma longa Linn.
Chemistry of pigments:
Turmeric contains about 5% of volatile oil, resin and yellow colouring substances
known as curcuminoids. The chief component of curcuminoids is known as
“curcumin”. Chemically curcuma species contain volatile oils, starch and curcumin
(50 – 60 %).Curcumin and other related curcuminoids are reported to be
responsible for yellow colour of the dye.
Chemistry of pigments:
Turmeric contains about 5% of volatile oil, resin and yellow colouring substances
known as curcuminoids. The chief component of curcuminoids is known as
“curcumin”. Chemically curcuma species contain volatile oils, starch and curcumin
(50 – 60 %).Curcumin and other related curcuminoids are reported to be
responsible for yellow colour of the dye.
Structure of curcuminStructure of curcumin
Curcumin from Curcuma longa has antioxidant, anti-inflammatory, anti cancer
and Hepatoprotective.
The pharmacological activities of cucrcumnoids are due to unique molecular
structure.
The phenolic yellow curry pigment curcumin used in the Alzheimer's disease,
It has anti-inflammatory effects in arthritis, possibly inhibits prostaglandin
synthesis pathway of Cox-2 without causing ulcers in the GI tract.
it has anti-platelet, anti viral, anti fungal, anti bacterial effects
(inhibits Helicobacter Pylori) and powerful antiseptic agent
Curcumin from Curcuma longa has antioxidant, anti-inflammatory, anti cancer
and Hepatoprotective.
The pharmacological activities of cucrcumnoids are due to unique molecular
structure.
The phenolic yellow curry pigment curcumin used in the Alzheimer's disease,
It has anti-inflammatory effects in arthritis, possibly inhibits prostaglandin
synthesis pathway of Cox-2 without causing ulcers in the GI tract.
it has anti-platelet, anti viral, anti fungal, anti bacterial effects
(inhibits Helicobacter Pylori) and powerful antiseptic agent
UsesUses
SAFFRONSAFFRON
Scientific classification
Kingdom : Plantae
(unranked) : Angiosperms
(unranked) : Monocots
Order : Asparagales
Family : Iridaceae
Subfamily : Crocoideae
Genus : Crocus
Species : C. sativus
It is commonly known as crocus, it consists of
dried stigmas and upper parts of styles of plant
Crocus sativus Linn. It is a widely used as
natural dye in food and cosmetic industry.
It is commonly known as crocus, it consists of
dried stigmas and upper parts of styles of plant
Crocus sativus Linn. It is a widely used as
natural dye in food and cosmetic industry.
Chemistry of pigments:The main constituents of saffron are crocin, crocetin,
picrocrocin and safranal. α-crocin is a carotenoid pigment which is primarily
responsible for saffron’s golden yellow-orange colour.The bitter glycoside
picrocrocin is responsible for saffron's flavour. It is a union of an aldehyde sub-
element known as safranal, which is responsible for the aroma of the saffron
Chemistry of pigments:The main constituents of saffron are crocin, crocetin,
picrocrocin and safranal. α-crocin is a carotenoid pigment which is primarily
responsible for saffron’s golden yellow-orange colour.The bitter glycoside
picrocrocin is responsible for saffron's flavour. It is a union of an aldehyde sub-
element known as safranal, which is responsible for the aroma of the saffron
MEDICINAL IMPORTANCE
Saffron is used in folk medicine as an antispasmodic, eupeptic, gingival
sedative.
Anticatarrhal, nerve sedative, carminative, diaphoretic, expectorant, stimulant,
stomachic, aphrodisiac and emmenagogue.
Its active constituents have anticonvulsant, antidepressant, anti-inflammatory
and antitumor properties, radical scavenger as well as learning and memory
improving properties and promote the diffusivity of oxygen in different tissues.
Crocus sativus has been shown to have antidepressant effects; two active
ingredients are crocin and safranal.
Crocin analogs isolated from saffron significantly increased the blood flow in
the retina and choroid as well as facilitated retinal function recovery and it could
be used to treat ischemic retinopathy and/or age-related macular degeneration.
Picrocrocin and safranal in patients with coronary artery disease indicates the
potential of saffron as an antioxidant.
Antiparkinsonian effect of Crocetin, which is an important ingredient of
saffron, may be helpful in preventing Perkinsonism.
SAFFLOWER
Scientific classification
Kingdom : Plantae
Phylum : Magnoliophyta
Class : Magnoliopsida
Order : Asterales
Family : Asteraceae
Genus : Carthamus
Species : C. tinctorius
Safflower (Carthamus tinctorius L.) has a long
history of cultivation as an oilseed crop and as a
source of red dye (carthamin).
Safflower (Carthamus tinctorius L.) has a long
history of cultivation as an oilseed crop and as a
source of red dye (carthamin).
Chemistry of pigments: The main constituents of the safflower are carthamin and
carthamidin. And other constituents are safflor yellow, arctigenin, tacheloside, N-
feruloyl tryptamine, N-feruloylserotonin, steroids, flavonoids, polyacetylenes.
Carthamin is responsible for to produce water-insoluble red dye and carthamidin for
water-soluble yellow colour dye
MEDICINAL IMPORTANCE
Carthamin is extracted from its flowers and it is used for treatment in the
form of infusion for circulatory system related diseases.
In addition to the colouring properties, safflower petals are used for curing
several chronic diseases such as hypertension, coronary heart ailments,
rheumatism, male and female fertility problems.
The chief constituent Carthamin has uterine stimulating, coronary dilating
and hypertensive.
It also has the cytotoxic, antigenic and anti-platelet activities
Scientific classification
Kingdom : Plantae
(unranked) : Angiosperms
(unranked) : Eudicots
(unranked) : Rosids
Order : Malvales
Family : Bixaceae
Genus : Bixa
Species : B. orellana
Among the naturally occurring colourants, an important one
is annatto. It is a carotenoid based dye, extracted from the
outer coatings of the seeds of Bixa orellana L. The images
of the annatto plant and dye
Chemistry of pigments:Phytochemicals investigations have revealed the presence
of several carotenoid derivatives including bixin and norbixin,some terpenoid,
tocotrienols,arenes and falvonoids (including luteolin and apigenin) in Bixa
orellana seeds. The reddish orange colour dye of the annatto is mainly comes from
the resinous outer covering of the seeds of the plant (bixin, norbixin and their
esters).
MEDICINAL IMPORTANCE
Annato seeds are used as purgative, antipruritic and for buccal tumours.
These are also used as cordial, astringent, febrifuge and a good remedy for
gonorrhea.
The seed extracts have been reported to exhibit chemo preventive and
antioxidant activity.
Bixin has also been found to have anticlastogenic activity
POMEGRANATEPOMEGRANATE
Scientific classification
Kingdom : Plantae
Division Magnoliophyta
Class : Magnoliopsida
Subclass : Rosidae
Order : Myrtales
Family : Lythraceae
Genus : Punica
Species : P. granatum
It consists of fresh and dried fruits of the plant Punica
granatum.
It consists of fresh and dried fruits of the plant Punica
granatum.
Chemistry of pigments
 Anthocyanins are water-soluble pigments primarily responsible for the attractive red
purple colour of pomegranate juice.
 It contains chief constituents such as punicalagin, punicalin, gallagic and ellagic acids.
 It also contains alkaloids like isopelletierine.
 Punica granatum dye and many other common natural dyes are reported as potent
 antimicrobial agents owing to the presence of a large amount of tannins.
MEDICINAL IMPORTANCE
 Pomegranate fruit not only used as natural dye it also having traditional medicinal
value is now supported by data obtained from modern science showing that the fruit
contains anti-carcinogenic, anti-microbial and anti-viral compounds.
 Recent Biological studies have proven that certain compounds contained in
pomegranate juice, which has been shown to reduce blood pressure, are anti-
atherosclerotic and significantly reduce LDL oxidation.
 These activities are attributed to the pomegranate’s high level of antioxidant activity
and high total Phenolic content It is also used as bactericide and stimulant.
 Because of their tannin content, extracts of the bark, leaves, immature fruit and fruit
rind have been given as astringents to halt diarrhea, dysentery and hemorrhages. It also
shows hypertensive, antispasmodic and anthelmintic activity in bioassay of leaves,
seeds, roots and bark.
MEDICINAL IMPORTANCE
 Pomegranate fruit not only used as natural dye it also having traditional medicinal
value is now supported by data obtained from modern science showing that the fruit
contains anti-carcinogenic, anti-microbial and anti-viral compounds.
 Recent Biological studies have proven that certain compounds contained in
pomegranate juice, which has been shown to reduce blood pressure, are anti-
atherosclerotic and significantly reduce LDL oxidation.
 These activities are attributed to the pomegranate’s high level of antioxidant activity
and high total Phenolic content It is also used as bactericide and stimulant.
 Because of their tannin content, extracts of the bark, leaves, immature fruit and fruit
rind have been given as astringents to halt diarrhea, dysentery and hemorrhages. It also
shows hypertensive, antispasmodic and anthelmintic activity in bioassay of leaves,
seeds, roots and bark.
TOMATO
It is widely used in worldwide food industry and it has
potent anti cancer property. It consists of fresh ripen
fruits of plant Solanum lycopersicum.
It is widely used in worldwide food industry and it has
potent anti cancer property. It consists of fresh ripen
fruits of plant Solanum lycopersicum.
Scientific classification
Kingdom : Plantae
(unranked) : Angiosperms
(unranked) : Eudicots
Order : Solanales
Family : Solanaceae
Genus : Solanum
Species : S. lycopersicum
CHEMISTRY OF PIGMENTS
The major constituents of the tomato are lycopene, α and β-carotene, lutein,
zeaxanthin and b-crypto xanthin Lycopene is a carotenoid that is present in
tomatoes is responsible red colour of the fruit. It constitutes about 80–90% of
the total carotenoid content of red ripe tomatoes.carotene, the yellow pigment
of the carrot is the isomer of lycopene.
CHEMISTRY OF PIGMENTS
The major constituents of the tomato are lycopene, α and β-carotene, lutein,
zeaxanthin and b-crypto xanthin Lycopene is a carotenoid that is present in
tomatoes is responsible red colour of the fruit. It constitutes about 80–90% of
the total carotenoid content of red ripe tomatoes.carotene, the yellow pigment
of the carrot is the isomer of lycopene.
MEDICINAL IMPORTANCE
 In recent studies serum and tissue levels of lycopene were shown to be
inversely associated with the risk of breast cancer and prostate cancer
and also it is used to prevent all types of cancers in the body.
 Lycopene is the most efficient antioxidant among carotenoids through its
quenching activity of singlet oxygen and scavenging of peroxyl radicals.
 Tomatos are also used for the rich source of Vitamin-A.
Scientific classification
Kingdom : Plantae
(unranked) : Angiosperms
(unranked) : Eudicots
(unranked) :Asterids
Order : Solanales
Family : Solanaceae
Genus : Capsicum
Species : C. annuum
PAPRICA
Paprica is obtained from the fruits of selectively
bred varieties of ‘sweet peppers’, Capsicum
annuum L. The fruits are large, fleshy with an
intense red colour and it has many medicinal
uses.
Paprica is obtained from the fruits of selectively
bred varieties of ‘sweet peppers’, Capsicum
annuum L. The fruits are large, fleshy with an
intense red colour and it has many medicinal
uses.
Structure of CapsanthinStructure of Capsanthin
CHEMISTRY OF PIGMENTS
 The pigments present in paprika are a mixture of carotenoids, in which
Capsanthin and capsorubin are the main compounds responsible for the red
colour of the dye.
 The pungent compounds of the Capsicum fruit are called capsaicinoids such
as capsaicin and its analogs.
 It has a long history as a source of biologically active compounds, such as
flavonoids, phenols, carotenoids, capsaicinoids and vitamins.
 Capsicum fruits contain colouring pigments, pungent principles, resins,
protein, cellulose, pentosans, mineral elements and very little volatile oil,
while seeds contain fixed (non-volatile) oil.
MEDICINAL IMPORTANCE
Paprica is employed in medicine, in combination with Cinchona in intermittent
and lethargic affections, and also gout, dyspepsia accompanied by flatulence,
tympanitis, paralysis etc.
It is used as a carminative, an appetizer, stomachic and also used in spices.
Externally it is used as a counter irritant in the treatment of rheumatism,
lumbago and neuralgia
TAGETUSTAGETUS
Tagetes is popularly known as marigold, it contains
carotenoid pigments from Tagetes erecta are useful in
food coloring and it has medicinal activities.
Tagetes is popularly known as marigold, it contains
carotenoid pigments from Tagetes erecta are useful in
food coloring and it has medicinal activities.
Scientific classification
Kingdom : Plantae
(unranked) : Angiosperms
(unranked) : Eudicots
(unranked) : Asterids
Order : Asterales
Family : Asteraceae
Genus : Tagetes Species :T.
erecta
Chemistry of pigments:The principle colouring component of marigold flower is
lutein, a fat-soluble carotenoid, which is responsible for the yellow to orange colour
of the dye. It also contains galenine, lycopene, α-carotene, β-carotene and γ-
carotene.
Chemistry of pigments:The principle colouring component of marigold flower is
lutein, a fat-soluble carotenoid, which is responsible for the yellow to orange colour
of the dye. It also contains galenine, lycopene, α-carotene, β-carotene and γ-
carotene.
structure of lutein
MEDICINAL IMPORTANCE
The whole herb is anthelmintic, aromatic, digestive, diuretic, emmenagogue,
sedative and stomachic.
It is used internally in the treatment of indigestion, colic, severe constipation,
coughs and dysentery.
Externally, it is used to treat sores, ulcers, eczema, sore eyes and rheumatism.
The carotenoid extracts are acceptable for use in foods, pharmaceuticals and
cosmetics
HENNA
Henna is widely used in the cosmetic industry as dyeing
agent. It consists of fresh or dried leaves of the plant
Lawsonia inermis.It has medicinal importance along with
dyeing property
Scientific classification
Kingdom : Plantae
Subkingdom : Tracheobionta
Division : Magnoliophyta
Class : Magnoliopsida
Order : Myrtales
Family : Lythraceae
Genus : Lawsonia
Species : L.inermis
chemistry of pigments:
The active constituents of the leaf is lawsone(0.5- 1.0%).Other constituents are 5-
10% gallic acid,white resin, tannin and xanthones are the other contents of the
leaves.The ‘Lawsone’ is principally responsible for the colourant property of the
henna leaves.
MEDICINAL IMPORTANCE
Henna is worldwide known as cosmetic agent with anticarcinogenic, anti-
inflammatory, analagesic and antipyretic properties. Alcoholic extracts of
henna leaves showed mild antibacterial activity against Eschericia coli.
The tannin and the gallic acid seem to have a complimentary beneficial
effect.
Structure of Lawsone
Scientific classification
Kingdom: Plantae
(unranked): Angiosperms
(unranked): Eudicots
unranked): Rosids
Order: Fabales
Family: Fabaceae
Subfamily: Faboideae
Tribe: Indigofereae
Genus: Indigofera
Indigofera is a large genus of over 750 species of flowering plants belonging to
the family Fabaceae. They are widely distributed throughout the tropical and
subtropical regions of the world Indigofera tinctoria
Indigofera is a large genus of over 750 species of flowering plants belonging to
the family Fabaceae. They are widely distributed throughout the tropical and
subtropical regions of the world Indigofera tinctoria
A galactomannan, composed of galactose and
mannose in molar ratio of
1:1.52,Glycoside(Indian),Coloring
matter(Indigotin),Flavonoids,terpinoids,alkaloi
ds&glycosides,Indigotine,Indiruben,rotenoids.
A galactomannan, composed of galactose and
mannose in molar ratio of
1:1.52,Glycoside(Indian),Coloring
matter(Indigotin),Flavonoids,terpinoids,alkaloi
ds&glycosides,Indigotine,Indiruben,rotenoids.
CHEMISTRY OF PIGMENTS
INDIGO
USES
The Indigo Leaves are used to make hair dye as well as prepare medicated hair
oil. Leaf powder is used as natural black color dye for hair. Indigofera make your
hair more manageable, moisturized, protected with radiant shine.
Dye is obtained from the processing of the plant's leaves, Indigo is among the
oldest dyes to be used for textile dyeing and printing.
The root is crushed and prepared into decoction, and given for abdominal
disorders,leucorrhoea,all types of toxicities etc.The leaves are crushed, prepared
into decoction and given for toxicities,fever,arthritis etc.
The leaf juice is given in the dose of 10-20ml along with honey twice daily for
jaundice, inflammation of liver etc.For poisonous bites the samoolam or the whole
plant is ground and applied as a paste over the bitten area. Also the leaf juice is
given internally to the patient.
Mushroom Color inducer Color created
Oyster mushroom iron pot/ammonia greyish-green
Horse mushroom salt water yellowish green
Meadow mushroom salt water yellowish green
Turkey tail ammonia
color depends on
fungus's color
NATURAL DYES FROM MUSHROOMS
NATURAL DYES FROM INSECTSNATURAL DYES FROM INSECTS
COCHINEALCOCHINEAL
The cochineal is a scale insect , from which the crimson-coloured dye carmine is derived. A
primarily sessile parasite native to tropical and subtropical South America and Mexico
known as Dactylopius coccus.
The cochineal is a scale insect , from which the crimson-coloured dye carmine is derived. A
primarily sessile parasite native to tropical and subtropical South America and Mexico
known as Dactylopius coccus.
CHEMICAL CONSTITUENT&USES
Carmine is today primarily used as a food
colouring and for cosmetics, especially as a
lipstick colouring.
CHEMICAL CONSTITUENT&USES
Carmine is today primarily used as a food
colouring and for cosmetics, especially as a
lipstick colouring.
NATURAL DYES FROM SEA SNAILS
TYRIAN PURPLETYRIAN PURPLE
Tyrian purple also known as royal purple, imperial purple or imperial dye, is a
reddish-purple natural dye.which is a secretion produced by a certain species of
predatory sea snails in the family Muricidae a type of rock snail by the name Murex.
This dye was possibly first used by the ancient Phoenicians as early as 1570 BC.The
dye was greatly prized in antiquity because the colour did not easily fade, but instead
became brighter with weathering and sunlight.
Tyrian purple also known as royal purple, imperial purple or imperial dye, is a
reddish-purple natural dye.which is a secretion produced by a certain species of
predatory sea snails in the family Muricidae a type of rock snail by the name Murex.
This dye was possibly first used by the ancient Phoenicians as early as 1570 BC.The
dye was greatly prized in antiquity because the colour did not easily fade, but instead
became brighter with weathering and sunlight.
PURPLE PIGMENTS
NATURAL DYES FROM MINERALSNATURAL DYES FROM MINERALS
Aluminum pigments
Ultramarine violet:
Silicate of sodium and aluminum containing sulfur.
Copper pigments
Han Purple: BaCuSi2O6.
Cobalt pigments
Cobalt Violet: cobalt phosphate.
Manganese pigments
Manganese Violet
(PV16) Manganese ammonium phosphate.
Aluminum pigments
Ultramarine: a complex naturally occurring pigment of sulfur-
containing sodio-silicate(Na8-10Al6Si6O24S2-4)
Cobalt pigments
Cobalt Blue (PB28) and Cerulean Blue: cobalt(II) stannate
Copper pigments
Egyptian Blue: a synthetic pigment of calcium copper silicate
(CaCuSi4O10). Thought to be the first synthetically produced
pigment.
Han Blue: BaCuSi4O10
Iron pigments
Prussian Blue: a synthetic pigment of ferric hexa cyanoferrate
(Fe7(CN)18). The dye Marking blue is made by mixing Prussian
Blue and alcohol.
BLUE PIGMENTS
Cadmium pigments
Cadmium Green: a light green pigment consisting of a mixture of Cadmium
Yellow (CdS) and Viridian (Cr2O3)
Chromium pigments
Chrome Green
Viridian: a dark green pigment of hydrated chromium(III) oxide (Cr2O3)
Copper pigments
Paris Green: copper(II) acetoarsenite
(Cu(C2H3O2)2·3Cu(AsO2)2)
Scheele's Green (also called Schloss Green): copper arsenite CuHAsO3
Lead pigments:Naples Yellow (PY41)
Titanium pigments:Titanium Yellow
Tin Pigments: Mosaic gold: stannic sulfide(SnS2)
GREEN PIGMENTS
Arsenic pigments
Orpiment natural monoclinic arsenic sulfide (As2S3),
Cadmium pigments
Cadmium Yellow: cadmium sulfide(CdS)
Chromium pigments
Chrome Yellow: natural pigment of lead(II) chromate (PbCrO4).
Cobalt pigments: Aureolin(also called Cobalt Yellow): Potassium
cobaltinitrite(Na3Co(NO2)6.
Iron Pigments
Yellow Ochre: a naturally occurring clay of hydrated iron oxide (Fe2O3.H2O)
YELLOW PIGMENTS
Clay earth pigments (naturally formed iron oxides)
Raw Umber (PBr7): a natural clay pigment consisting of iron oxide,
manganese oxide and aluminum oxide: Fe2O3 + MnO2 + nH2O + Si + AlO3.
When calcined (heated) it is referred to as Burnt Umber and has more intense
colors.
Raw Sienna (PBr7): a naturally occurring yellow-brown pigment from limonite
clay. Used in art since prehistoric times.
BROWN PIGMENTS
Cadmium pigments
Cadmium Orange: an intermediate
between cadmium red and cadmium
yellow: cadmium sulfoselenide.
Chromium pigments
Chrome Orange: a naturally occurring
pigment mixture composed of lead(II)
chromate and lead(II) oxide.
(PbCrO4 + PbO)
Antimony White: Sb2
O3
Barium pigments
Barium sulfate
Lead pigments: (toxic)
White Lead: (PbCO3
)2
·Pb(OH)2
Titanium pigments
Titanium White: titanium(IV) oxide TiO2
Zinc pigments
Zinc White : Zinc Oxide (ZnO)
Carbon pigments Iron Pigments
Carbon Black Iron black : Fe3
O4
Ivory Black Titanium pigments
Vine Black Titanium Black
Lamp Black
BLACK PIGMENTS
ORANGE PIGMENTS
Cadmium pigments
Cadmium Red: cadmium selenide (CdSe)
Iron oxide pigments
Sanguine, Caput Mortuum, Venetian Red, Oxide Red (PR102)
Red Ochre: anhydrous Fe2O3
Burnt Sienna: a pigment produced by heating Raw Sienna.
Lead pigments (toxic)
Red Lead: lead tetroxide, Pb3O4
Mercury pigments (toxic)
Vermilion: Synthetic and natural pigment: Occurs naturally in mineral cinnabar.
Mercuric sulfide (HgS)
RED PIGMENTS
NATURAL DYES

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NATURAL DYES

  • 1. K.Sudheer Kumar, Assistant professor. Dept.of Pharmacognosy Chilkur Balaji college of Pharmacy Hyderabad. E-mail:sudheer.y2k8@gmail.com
  • 2. NATURAL DYES Natural dyes are derived from naturally occurring sources such as plants (e.g., indigo and saffron) Insects (e.g., cochineal beetles and lac scale insects) Animals (e.g., some species of mollusks or shellfish) Minerals (e.g., ferrous sulfate, ochre, and clay) without any chemical treatment. A spectrum of beautiful natural colors ranging from yellow to black exists in the above sources. These colors are exhibited by various organic and inorganic molecules (pigments) and their mixtures are due to the absorption of light in the visible region of 400-800 nm. This absorption of light depends on the structure or constituents of the colouring pigment/ molecules contain various chromophores present in the dye yielding plant to display the of colors Natural dyes are derived from naturally occurring sources such as plants (e.g., indigo and saffron) Insects (e.g., cochineal beetles and lac scale insects) Animals (e.g., some species of mollusks or shellfish) Minerals (e.g., ferrous sulfate, ochre, and clay) without any chemical treatment. A spectrum of beautiful natural colors ranging from yellow to black exists in the above sources. These colors are exhibited by various organic and inorganic molecules (pigments) and their mixtures are due to the absorption of light in the visible region of 400-800 nm. This absorption of light depends on the structure or constituents of the colouring pigment/ molecules contain various chromophores present in the dye yielding plant to display the of colors
  • 3. The use of natural products together with their therapeutic properties is as ancient as human civilization and for a long time, mineral, plant and animal products were the main sources of drugs The current preference for naturally derived colorants is due to their healthfulness and excellent performance. Several synthetic colorants have been banned because they cause allergy-like symptoms or are carcinogens. Nowadays, natural dyes are commonly used in the cosmetic industry due to no side effects, UV protection and anti-aging properties. In India, there are more than 450 plants that can yield dyes. In addition to their dye-yielding characteristics, some of these plants also possess medicinal value. The use of natural products together with their therapeutic properties is as ancient as human civilization and for a long time, mineral, plant and animal products were the main sources of drugs The current preference for naturally derived colorants is due to their healthfulness and excellent performance. Several synthetic colorants have been banned because they cause allergy-like symptoms or are carcinogens. Nowadays, natural dyes are commonly used in the cosmetic industry due to no side effects, UV protection and anti-aging properties. In India, there are more than 450 plants that can yield dyes. In addition to their dye-yielding characteristics, some of these plants also possess medicinal value.
  • 4. Natural dyes are environment friendly for example, turmeric, the brightest of naturally occurring yellow dyes is a powerful antiseptic which revitalizes the skin, while indigo gives a cooling sensation. Many of the plants used for dye extraction are classified as medicinal and some of these have recently been shown to possess antimicrobial activity. Many other common natural dyes are reported as potent antimicrobial agents owing to the presence of a large amount of tannins. Natural dyes are environment friendly for example, turmeric, the brightest of naturally occurring yellow dyes is a powerful antiseptic which revitalizes the skin, while indigo gives a cooling sensation. Many of the plants used for dye extraction are classified as medicinal and some of these have recently been shown to possess antimicrobial activity. Many other common natural dyes are reported as potent antimicrobial agents owing to the presence of a large amount of tannins.
  • 5. TURMERIC Scientific classification Kingdom : Plantae Division : Magnoliophyta Class : Liliopsida Subclass : Zingiberidae Order : Zingiberales Family : Zingiberaceae Genus : Curcuma Species : C. longa Turmeric is commonly known as Indian saffron. It consists of dried, as well as fresh rhizomes of the plant Curcuma longa Linn. Turmeric is commonly known as Indian saffron. It consists of dried, as well as fresh rhizomes of the plant Curcuma longa Linn. Chemistry of pigments: Turmeric contains about 5% of volatile oil, resin and yellow colouring substances known as curcuminoids. The chief component of curcuminoids is known as “curcumin”. Chemically curcuma species contain volatile oils, starch and curcumin (50 – 60 %).Curcumin and other related curcuminoids are reported to be responsible for yellow colour of the dye. Chemistry of pigments: Turmeric contains about 5% of volatile oil, resin and yellow colouring substances known as curcuminoids. The chief component of curcuminoids is known as “curcumin”. Chemically curcuma species contain volatile oils, starch and curcumin (50 – 60 %).Curcumin and other related curcuminoids are reported to be responsible for yellow colour of the dye.
  • 6. Structure of curcuminStructure of curcumin Curcumin from Curcuma longa has antioxidant, anti-inflammatory, anti cancer and Hepatoprotective. The pharmacological activities of cucrcumnoids are due to unique molecular structure. The phenolic yellow curry pigment curcumin used in the Alzheimer's disease, It has anti-inflammatory effects in arthritis, possibly inhibits prostaglandin synthesis pathway of Cox-2 without causing ulcers in the GI tract. it has anti-platelet, anti viral, anti fungal, anti bacterial effects (inhibits Helicobacter Pylori) and powerful antiseptic agent Curcumin from Curcuma longa has antioxidant, anti-inflammatory, anti cancer and Hepatoprotective. The pharmacological activities of cucrcumnoids are due to unique molecular structure. The phenolic yellow curry pigment curcumin used in the Alzheimer's disease, It has anti-inflammatory effects in arthritis, possibly inhibits prostaglandin synthesis pathway of Cox-2 without causing ulcers in the GI tract. it has anti-platelet, anti viral, anti fungal, anti bacterial effects (inhibits Helicobacter Pylori) and powerful antiseptic agent UsesUses
  • 7. SAFFRONSAFFRON Scientific classification Kingdom : Plantae (unranked) : Angiosperms (unranked) : Monocots Order : Asparagales Family : Iridaceae Subfamily : Crocoideae Genus : Crocus Species : C. sativus It is commonly known as crocus, it consists of dried stigmas and upper parts of styles of plant Crocus sativus Linn. It is a widely used as natural dye in food and cosmetic industry. It is commonly known as crocus, it consists of dried stigmas and upper parts of styles of plant Crocus sativus Linn. It is a widely used as natural dye in food and cosmetic industry. Chemistry of pigments:The main constituents of saffron are crocin, crocetin, picrocrocin and safranal. α-crocin is a carotenoid pigment which is primarily responsible for saffron’s golden yellow-orange colour.The bitter glycoside picrocrocin is responsible for saffron's flavour. It is a union of an aldehyde sub- element known as safranal, which is responsible for the aroma of the saffron Chemistry of pigments:The main constituents of saffron are crocin, crocetin, picrocrocin and safranal. α-crocin is a carotenoid pigment which is primarily responsible for saffron’s golden yellow-orange colour.The bitter glycoside picrocrocin is responsible for saffron's flavour. It is a union of an aldehyde sub- element known as safranal, which is responsible for the aroma of the saffron
  • 8. MEDICINAL IMPORTANCE Saffron is used in folk medicine as an antispasmodic, eupeptic, gingival sedative. Anticatarrhal, nerve sedative, carminative, diaphoretic, expectorant, stimulant, stomachic, aphrodisiac and emmenagogue. Its active constituents have anticonvulsant, antidepressant, anti-inflammatory and antitumor properties, radical scavenger as well as learning and memory improving properties and promote the diffusivity of oxygen in different tissues. Crocus sativus has been shown to have antidepressant effects; two active ingredients are crocin and safranal.
  • 9. Crocin analogs isolated from saffron significantly increased the blood flow in the retina and choroid as well as facilitated retinal function recovery and it could be used to treat ischemic retinopathy and/or age-related macular degeneration. Picrocrocin and safranal in patients with coronary artery disease indicates the potential of saffron as an antioxidant. Antiparkinsonian effect of Crocetin, which is an important ingredient of saffron, may be helpful in preventing Perkinsonism.
  • 10. SAFFLOWER Scientific classification Kingdom : Plantae Phylum : Magnoliophyta Class : Magnoliopsida Order : Asterales Family : Asteraceae Genus : Carthamus Species : C. tinctorius Safflower (Carthamus tinctorius L.) has a long history of cultivation as an oilseed crop and as a source of red dye (carthamin). Safflower (Carthamus tinctorius L.) has a long history of cultivation as an oilseed crop and as a source of red dye (carthamin). Chemistry of pigments: The main constituents of the safflower are carthamin and carthamidin. And other constituents are safflor yellow, arctigenin, tacheloside, N- feruloyl tryptamine, N-feruloylserotonin, steroids, flavonoids, polyacetylenes. Carthamin is responsible for to produce water-insoluble red dye and carthamidin for water-soluble yellow colour dye
  • 11. MEDICINAL IMPORTANCE Carthamin is extracted from its flowers and it is used for treatment in the form of infusion for circulatory system related diseases. In addition to the colouring properties, safflower petals are used for curing several chronic diseases such as hypertension, coronary heart ailments, rheumatism, male and female fertility problems. The chief constituent Carthamin has uterine stimulating, coronary dilating and hypertensive. It also has the cytotoxic, antigenic and anti-platelet activities
  • 12. Scientific classification Kingdom : Plantae (unranked) : Angiosperms (unranked) : Eudicots (unranked) : Rosids Order : Malvales Family : Bixaceae Genus : Bixa Species : B. orellana Among the naturally occurring colourants, an important one is annatto. It is a carotenoid based dye, extracted from the outer coatings of the seeds of Bixa orellana L. The images of the annatto plant and dye Chemistry of pigments:Phytochemicals investigations have revealed the presence of several carotenoid derivatives including bixin and norbixin,some terpenoid, tocotrienols,arenes and falvonoids (including luteolin and apigenin) in Bixa orellana seeds. The reddish orange colour dye of the annatto is mainly comes from the resinous outer covering of the seeds of the plant (bixin, norbixin and their esters).
  • 13. MEDICINAL IMPORTANCE Annato seeds are used as purgative, antipruritic and for buccal tumours. These are also used as cordial, astringent, febrifuge and a good remedy for gonorrhea. The seed extracts have been reported to exhibit chemo preventive and antioxidant activity. Bixin has also been found to have anticlastogenic activity
  • 14. POMEGRANATEPOMEGRANATE Scientific classification Kingdom : Plantae Division Magnoliophyta Class : Magnoliopsida Subclass : Rosidae Order : Myrtales Family : Lythraceae Genus : Punica Species : P. granatum It consists of fresh and dried fruits of the plant Punica granatum. It consists of fresh and dried fruits of the plant Punica granatum. Chemistry of pigments  Anthocyanins are water-soluble pigments primarily responsible for the attractive red purple colour of pomegranate juice.  It contains chief constituents such as punicalagin, punicalin, gallagic and ellagic acids.  It also contains alkaloids like isopelletierine.  Punica granatum dye and many other common natural dyes are reported as potent  antimicrobial agents owing to the presence of a large amount of tannins.
  • 15. MEDICINAL IMPORTANCE  Pomegranate fruit not only used as natural dye it also having traditional medicinal value is now supported by data obtained from modern science showing that the fruit contains anti-carcinogenic, anti-microbial and anti-viral compounds.  Recent Biological studies have proven that certain compounds contained in pomegranate juice, which has been shown to reduce blood pressure, are anti- atherosclerotic and significantly reduce LDL oxidation.  These activities are attributed to the pomegranate’s high level of antioxidant activity and high total Phenolic content It is also used as bactericide and stimulant.  Because of their tannin content, extracts of the bark, leaves, immature fruit and fruit rind have been given as astringents to halt diarrhea, dysentery and hemorrhages. It also shows hypertensive, antispasmodic and anthelmintic activity in bioassay of leaves, seeds, roots and bark. MEDICINAL IMPORTANCE  Pomegranate fruit not only used as natural dye it also having traditional medicinal value is now supported by data obtained from modern science showing that the fruit contains anti-carcinogenic, anti-microbial and anti-viral compounds.  Recent Biological studies have proven that certain compounds contained in pomegranate juice, which has been shown to reduce blood pressure, are anti- atherosclerotic and significantly reduce LDL oxidation.  These activities are attributed to the pomegranate’s high level of antioxidant activity and high total Phenolic content It is also used as bactericide and stimulant.  Because of their tannin content, extracts of the bark, leaves, immature fruit and fruit rind have been given as astringents to halt diarrhea, dysentery and hemorrhages. It also shows hypertensive, antispasmodic and anthelmintic activity in bioassay of leaves, seeds, roots and bark.
  • 16. TOMATO It is widely used in worldwide food industry and it has potent anti cancer property. It consists of fresh ripen fruits of plant Solanum lycopersicum. It is widely used in worldwide food industry and it has potent anti cancer property. It consists of fresh ripen fruits of plant Solanum lycopersicum. Scientific classification Kingdom : Plantae (unranked) : Angiosperms (unranked) : Eudicots Order : Solanales Family : Solanaceae Genus : Solanum Species : S. lycopersicum CHEMISTRY OF PIGMENTS The major constituents of the tomato are lycopene, α and β-carotene, lutein, zeaxanthin and b-crypto xanthin Lycopene is a carotenoid that is present in tomatoes is responsible red colour of the fruit. It constitutes about 80–90% of the total carotenoid content of red ripe tomatoes.carotene, the yellow pigment of the carrot is the isomer of lycopene. CHEMISTRY OF PIGMENTS The major constituents of the tomato are lycopene, α and β-carotene, lutein, zeaxanthin and b-crypto xanthin Lycopene is a carotenoid that is present in tomatoes is responsible red colour of the fruit. It constitutes about 80–90% of the total carotenoid content of red ripe tomatoes.carotene, the yellow pigment of the carrot is the isomer of lycopene.
  • 17. MEDICINAL IMPORTANCE  In recent studies serum and tissue levels of lycopene were shown to be inversely associated with the risk of breast cancer and prostate cancer and also it is used to prevent all types of cancers in the body.  Lycopene is the most efficient antioxidant among carotenoids through its quenching activity of singlet oxygen and scavenging of peroxyl radicals.  Tomatos are also used for the rich source of Vitamin-A.
  • 18. Scientific classification Kingdom : Plantae (unranked) : Angiosperms (unranked) : Eudicots (unranked) :Asterids Order : Solanales Family : Solanaceae Genus : Capsicum Species : C. annuum PAPRICA Paprica is obtained from the fruits of selectively bred varieties of ‘sweet peppers’, Capsicum annuum L. The fruits are large, fleshy with an intense red colour and it has many medicinal uses. Paprica is obtained from the fruits of selectively bred varieties of ‘sweet peppers’, Capsicum annuum L. The fruits are large, fleshy with an intense red colour and it has many medicinal uses. Structure of CapsanthinStructure of Capsanthin
  • 19. CHEMISTRY OF PIGMENTS  The pigments present in paprika are a mixture of carotenoids, in which Capsanthin and capsorubin are the main compounds responsible for the red colour of the dye.  The pungent compounds of the Capsicum fruit are called capsaicinoids such as capsaicin and its analogs.  It has a long history as a source of biologically active compounds, such as flavonoids, phenols, carotenoids, capsaicinoids and vitamins.  Capsicum fruits contain colouring pigments, pungent principles, resins, protein, cellulose, pentosans, mineral elements and very little volatile oil, while seeds contain fixed (non-volatile) oil.
  • 20. MEDICINAL IMPORTANCE Paprica is employed in medicine, in combination with Cinchona in intermittent and lethargic affections, and also gout, dyspepsia accompanied by flatulence, tympanitis, paralysis etc. It is used as a carminative, an appetizer, stomachic and also used in spices. Externally it is used as a counter irritant in the treatment of rheumatism, lumbago and neuralgia
  • 21. TAGETUSTAGETUS Tagetes is popularly known as marigold, it contains carotenoid pigments from Tagetes erecta are useful in food coloring and it has medicinal activities. Tagetes is popularly known as marigold, it contains carotenoid pigments from Tagetes erecta are useful in food coloring and it has medicinal activities. Scientific classification Kingdom : Plantae (unranked) : Angiosperms (unranked) : Eudicots (unranked) : Asterids Order : Asterales Family : Asteraceae Genus : Tagetes Species :T. erecta Chemistry of pigments:The principle colouring component of marigold flower is lutein, a fat-soluble carotenoid, which is responsible for the yellow to orange colour of the dye. It also contains galenine, lycopene, α-carotene, β-carotene and γ- carotene. Chemistry of pigments:The principle colouring component of marigold flower is lutein, a fat-soluble carotenoid, which is responsible for the yellow to orange colour of the dye. It also contains galenine, lycopene, α-carotene, β-carotene and γ- carotene. structure of lutein
  • 22. MEDICINAL IMPORTANCE The whole herb is anthelmintic, aromatic, digestive, diuretic, emmenagogue, sedative and stomachic. It is used internally in the treatment of indigestion, colic, severe constipation, coughs and dysentery. Externally, it is used to treat sores, ulcers, eczema, sore eyes and rheumatism. The carotenoid extracts are acceptable for use in foods, pharmaceuticals and cosmetics
  • 23. HENNA Henna is widely used in the cosmetic industry as dyeing agent. It consists of fresh or dried leaves of the plant Lawsonia inermis.It has medicinal importance along with dyeing property Scientific classification Kingdom : Plantae Subkingdom : Tracheobionta Division : Magnoliophyta Class : Magnoliopsida Order : Myrtales Family : Lythraceae Genus : Lawsonia Species : L.inermis chemistry of pigments: The active constituents of the leaf is lawsone(0.5- 1.0%).Other constituents are 5- 10% gallic acid,white resin, tannin and xanthones are the other contents of the leaves.The ‘Lawsone’ is principally responsible for the colourant property of the henna leaves.
  • 24. MEDICINAL IMPORTANCE Henna is worldwide known as cosmetic agent with anticarcinogenic, anti- inflammatory, analagesic and antipyretic properties. Alcoholic extracts of henna leaves showed mild antibacterial activity against Eschericia coli. The tannin and the gallic acid seem to have a complimentary beneficial effect. Structure of Lawsone
  • 25. Scientific classification Kingdom: Plantae (unranked): Angiosperms (unranked): Eudicots unranked): Rosids Order: Fabales Family: Fabaceae Subfamily: Faboideae Tribe: Indigofereae Genus: Indigofera Indigofera is a large genus of over 750 species of flowering plants belonging to the family Fabaceae. They are widely distributed throughout the tropical and subtropical regions of the world Indigofera tinctoria Indigofera is a large genus of over 750 species of flowering plants belonging to the family Fabaceae. They are widely distributed throughout the tropical and subtropical regions of the world Indigofera tinctoria A galactomannan, composed of galactose and mannose in molar ratio of 1:1.52,Glycoside(Indian),Coloring matter(Indigotin),Flavonoids,terpinoids,alkaloi ds&glycosides,Indigotine,Indiruben,rotenoids. A galactomannan, composed of galactose and mannose in molar ratio of 1:1.52,Glycoside(Indian),Coloring matter(Indigotin),Flavonoids,terpinoids,alkaloi ds&glycosides,Indigotine,Indiruben,rotenoids. CHEMISTRY OF PIGMENTS INDIGO
  • 26. USES The Indigo Leaves are used to make hair dye as well as prepare medicated hair oil. Leaf powder is used as natural black color dye for hair. Indigofera make your hair more manageable, moisturized, protected with radiant shine. Dye is obtained from the processing of the plant's leaves, Indigo is among the oldest dyes to be used for textile dyeing and printing. The root is crushed and prepared into decoction, and given for abdominal disorders,leucorrhoea,all types of toxicities etc.The leaves are crushed, prepared into decoction and given for toxicities,fever,arthritis etc. The leaf juice is given in the dose of 10-20ml along with honey twice daily for jaundice, inflammation of liver etc.For poisonous bites the samoolam or the whole plant is ground and applied as a paste over the bitten area. Also the leaf juice is given internally to the patient.
  • 27. Mushroom Color inducer Color created Oyster mushroom iron pot/ammonia greyish-green Horse mushroom salt water yellowish green Meadow mushroom salt water yellowish green Turkey tail ammonia color depends on fungus's color NATURAL DYES FROM MUSHROOMS
  • 28. NATURAL DYES FROM INSECTSNATURAL DYES FROM INSECTS COCHINEALCOCHINEAL The cochineal is a scale insect , from which the crimson-coloured dye carmine is derived. A primarily sessile parasite native to tropical and subtropical South America and Mexico known as Dactylopius coccus. The cochineal is a scale insect , from which the crimson-coloured dye carmine is derived. A primarily sessile parasite native to tropical and subtropical South America and Mexico known as Dactylopius coccus. CHEMICAL CONSTITUENT&USES Carmine is today primarily used as a food colouring and for cosmetics, especially as a lipstick colouring. CHEMICAL CONSTITUENT&USES Carmine is today primarily used as a food colouring and for cosmetics, especially as a lipstick colouring.
  • 29. NATURAL DYES FROM SEA SNAILS TYRIAN PURPLETYRIAN PURPLE Tyrian purple also known as royal purple, imperial purple or imperial dye, is a reddish-purple natural dye.which is a secretion produced by a certain species of predatory sea snails in the family Muricidae a type of rock snail by the name Murex. This dye was possibly first used by the ancient Phoenicians as early as 1570 BC.The dye was greatly prized in antiquity because the colour did not easily fade, but instead became brighter with weathering and sunlight. Tyrian purple also known as royal purple, imperial purple or imperial dye, is a reddish-purple natural dye.which is a secretion produced by a certain species of predatory sea snails in the family Muricidae a type of rock snail by the name Murex. This dye was possibly first used by the ancient Phoenicians as early as 1570 BC.The dye was greatly prized in antiquity because the colour did not easily fade, but instead became brighter with weathering and sunlight.
  • 30. PURPLE PIGMENTS NATURAL DYES FROM MINERALSNATURAL DYES FROM MINERALS Aluminum pigments Ultramarine violet: Silicate of sodium and aluminum containing sulfur. Copper pigments Han Purple: BaCuSi2O6. Cobalt pigments Cobalt Violet: cobalt phosphate. Manganese pigments Manganese Violet (PV16) Manganese ammonium phosphate.
  • 31. Aluminum pigments Ultramarine: a complex naturally occurring pigment of sulfur- containing sodio-silicate(Na8-10Al6Si6O24S2-4) Cobalt pigments Cobalt Blue (PB28) and Cerulean Blue: cobalt(II) stannate Copper pigments Egyptian Blue: a synthetic pigment of calcium copper silicate (CaCuSi4O10). Thought to be the first synthetically produced pigment. Han Blue: BaCuSi4O10 Iron pigments Prussian Blue: a synthetic pigment of ferric hexa cyanoferrate (Fe7(CN)18). The dye Marking blue is made by mixing Prussian Blue and alcohol. BLUE PIGMENTS
  • 32. Cadmium pigments Cadmium Green: a light green pigment consisting of a mixture of Cadmium Yellow (CdS) and Viridian (Cr2O3) Chromium pigments Chrome Green Viridian: a dark green pigment of hydrated chromium(III) oxide (Cr2O3) Copper pigments Paris Green: copper(II) acetoarsenite (Cu(C2H3O2)2·3Cu(AsO2)2) Scheele's Green (also called Schloss Green): copper arsenite CuHAsO3 Lead pigments:Naples Yellow (PY41) Titanium pigments:Titanium Yellow Tin Pigments: Mosaic gold: stannic sulfide(SnS2) GREEN PIGMENTS
  • 33. Arsenic pigments Orpiment natural monoclinic arsenic sulfide (As2S3), Cadmium pigments Cadmium Yellow: cadmium sulfide(CdS) Chromium pigments Chrome Yellow: natural pigment of lead(II) chromate (PbCrO4). Cobalt pigments: Aureolin(also called Cobalt Yellow): Potassium cobaltinitrite(Na3Co(NO2)6. Iron Pigments Yellow Ochre: a naturally occurring clay of hydrated iron oxide (Fe2O3.H2O) YELLOW PIGMENTS
  • 34. Clay earth pigments (naturally formed iron oxides) Raw Umber (PBr7): a natural clay pigment consisting of iron oxide, manganese oxide and aluminum oxide: Fe2O3 + MnO2 + nH2O + Si + AlO3. When calcined (heated) it is referred to as Burnt Umber and has more intense colors. Raw Sienna (PBr7): a naturally occurring yellow-brown pigment from limonite clay. Used in art since prehistoric times. BROWN PIGMENTS
  • 35. Cadmium pigments Cadmium Orange: an intermediate between cadmium red and cadmium yellow: cadmium sulfoselenide. Chromium pigments Chrome Orange: a naturally occurring pigment mixture composed of lead(II) chromate and lead(II) oxide. (PbCrO4 + PbO) Antimony White: Sb2 O3 Barium pigments Barium sulfate Lead pigments: (toxic) White Lead: (PbCO3 )2 ·Pb(OH)2 Titanium pigments Titanium White: titanium(IV) oxide TiO2 Zinc pigments Zinc White : Zinc Oxide (ZnO) Carbon pigments Iron Pigments Carbon Black Iron black : Fe3 O4 Ivory Black Titanium pigments Vine Black Titanium Black Lamp Black BLACK PIGMENTS ORANGE PIGMENTS
  • 36. Cadmium pigments Cadmium Red: cadmium selenide (CdSe) Iron oxide pigments Sanguine, Caput Mortuum, Venetian Red, Oxide Red (PR102) Red Ochre: anhydrous Fe2O3 Burnt Sienna: a pigment produced by heating Raw Sienna. Lead pigments (toxic) Red Lead: lead tetroxide, Pb3O4 Mercury pigments (toxic) Vermilion: Synthetic and natural pigment: Occurs naturally in mineral cinnabar. Mercuric sulfide (HgS) RED PIGMENTS