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Nine DOT Hazard Classes
Acronym To Help Memorize
Albert V. Condello III CHMM
University of Houston Downtown
Introduction
 There are nine (9) hazard classes that DOT requires
when placarding a vehicle as well as labeling the
container.
 We will discuss an easy way to memorize those nine
hazard classes in the correct order.
 Remember, there might be a need to placard with
more than one if the HMT requires the secondary
hazard to also be noted.
DOT Chart 15
 Refer to Hand Out
 2012 Emergency Response Guidebook
(Page 4) Hazard Classification System
 http://youtu.be/wlZTc7z7yjI
Nine DOT Hazard Classes
Explosives Class 1
Flammable/Combustible
Gases Class 2
Flammable/Combustible
Liquids Class 3
Flammable
Solids/Dangerous
When Wet Class 4
Oxidizers/Organic
Peroxides Class 5
Toxic/Infection
Substances Class 6
Radioactive Materials
Class 7
Corrosives Class 8
Other Regulated
Materials (ORM) Class
9
Acronym
Every Good Fire Fighter Ought To Receive Cash
Money
Remember these nine (9) phases, they will help you
to know what is the DOT Hazard Classes in the
correct order.
Every
Class 1 - Explosives
Division 1.1 Explosives with a mass explosion hazard
Division 1.2 Explosives with a projection hazard
Division 1.3 Explosives with predominantly a fire hazard
Division 1.4 Explosives with no significant blast hazard
Division 1.5 Very insensitive explosives with a mass
explosion hazard
Division 1.6 Extremely insensitive articles
Good
Class 2 - Gases
Division 2.1 Flammable gases
Division 2.2 Non-flammable, non-toxic* gases
Division 2.3 Toxic* gases
§172.528 ,§172.530, §172.532, §172.540
Fire
Class 3 - Flammable liquids (and
Combustible liquids [U.S.])
§172.542, §172.544
Fighter
Class 4 - Flammable solids; Spontaneously
combustible materials; and Dangerous when wet
materials/Water-reactive substances
Division 4.1 Flammable solids
Division 4.2 Spontaneously combustible materials
Division 4.3 Water-reactive substances/Dangerous
when wet materials
§172.546, §172.547, §172.548
Ought
Class 5 - Oxidizing substances and Organic
peroxides
Division 5.1 Oxidizing substances
Division 5.2 Organic peroxides
§172.550, §172.552
To
Class 6 – Poison (Toxic) substances and
Infectious substances & Poisonous
Inhalation Hazards
Division 6.1 Toxic substances
Division 6.2 Infectious substances
§172.504(f)(10), §172.554, §172.555
Receive
Class 7 - Radioactive materials
§172.556
Cash
Class 8 - Corrosive substances
§172.558
Money
Class 9 - Miscellaneous hazardous
materials/Products, Substances or
Organisms
A/k/a (ORM) Otherwise Regulated Materials
§172.560
Question
HOW MANY DIVISIONS PER GROUPS OF
PLACARDS ?
Answer: 6,3,2,3,2,2 (Class 1 thru 6)
Proof: 6 (Class 1) 3(Class 2) 2(Class 3) 3(Class 4) 2
(Class 5) 2(Class 6)
Dangerous Placard
 §172.521
A freight container, unit load device, transport
vehicle, or rail car which contains non-bulk
packages with two or more categories of
hazardous materials that require different placards
specified in table 2 §172.504(e) may be
placarded with Dangerous placards instead
of the specific placards required for each of the
materials in table 2. However, when 1,000 kg
(2,205 lbs) or more of one category of material
is loaded at one loading facility, the placard
specified in table 2 must be applied.
Limited Qty
§172.315(a)(2)
(Vessel transport only)
When shipping by air
Environmental Pollutant
 These Environmentally
Hazardous Substance
Markings are designed to
help shippers and
transporters easily identify
any liquid or solid material,
including its mixtures and
solutions that are classified
as marine pollutants.
For Further Info
Please feel free to contact
Albert V. Condello III CHMM
Professor – Safety & Fire Protection
Engineering
University of Houston Downtown
Email: Condelloa@uhd.edu
Cell 979-412-2219

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Nine US DOT Hazard Classes

  • 1. Nine DOT Hazard Classes Acronym To Help Memorize Albert V. Condello III CHMM University of Houston Downtown
  • 2. Introduction  There are nine (9) hazard classes that DOT requires when placarding a vehicle as well as labeling the container.  We will discuss an easy way to memorize those nine hazard classes in the correct order.  Remember, there might be a need to placard with more than one if the HMT requires the secondary hazard to also be noted.
  • 3. DOT Chart 15  Refer to Hand Out  2012 Emergency Response Guidebook (Page 4) Hazard Classification System  http://youtu.be/wlZTc7z7yjI
  • 4. Nine DOT Hazard Classes Explosives Class 1 Flammable/Combustible Gases Class 2 Flammable/Combustible Liquids Class 3 Flammable Solids/Dangerous When Wet Class 4 Oxidizers/Organic Peroxides Class 5 Toxic/Infection Substances Class 6 Radioactive Materials Class 7 Corrosives Class 8 Other Regulated Materials (ORM) Class 9
  • 5. Acronym Every Good Fire Fighter Ought To Receive Cash Money Remember these nine (9) phases, they will help you to know what is the DOT Hazard Classes in the correct order.
  • 6. Every Class 1 - Explosives Division 1.1 Explosives with a mass explosion hazard Division 1.2 Explosives with a projection hazard Division 1.3 Explosives with predominantly a fire hazard Division 1.4 Explosives with no significant blast hazard Division 1.5 Very insensitive explosives with a mass explosion hazard Division 1.6 Extremely insensitive articles
  • 7. Good Class 2 - Gases Division 2.1 Flammable gases Division 2.2 Non-flammable, non-toxic* gases Division 2.3 Toxic* gases §172.528 ,§172.530, §172.532, §172.540
  • 8. Fire Class 3 - Flammable liquids (and Combustible liquids [U.S.]) §172.542, §172.544
  • 9. Fighter Class 4 - Flammable solids; Spontaneously combustible materials; and Dangerous when wet materials/Water-reactive substances Division 4.1 Flammable solids Division 4.2 Spontaneously combustible materials Division 4.3 Water-reactive substances/Dangerous when wet materials §172.546, §172.547, §172.548
  • 10. Ought Class 5 - Oxidizing substances and Organic peroxides Division 5.1 Oxidizing substances Division 5.2 Organic peroxides §172.550, §172.552
  • 11. To Class 6 – Poison (Toxic) substances and Infectious substances & Poisonous Inhalation Hazards Division 6.1 Toxic substances Division 6.2 Infectious substances §172.504(f)(10), §172.554, §172.555
  • 12. Receive Class 7 - Radioactive materials §172.556
  • 13. Cash Class 8 - Corrosive substances §172.558
  • 14. Money Class 9 - Miscellaneous hazardous materials/Products, Substances or Organisms A/k/a (ORM) Otherwise Regulated Materials §172.560
  • 15. Question HOW MANY DIVISIONS PER GROUPS OF PLACARDS ? Answer: 6,3,2,3,2,2 (Class 1 thru 6) Proof: 6 (Class 1) 3(Class 2) 2(Class 3) 3(Class 4) 2 (Class 5) 2(Class 6)
  • 16. Dangerous Placard  §172.521 A freight container, unit load device, transport vehicle, or rail car which contains non-bulk packages with two or more categories of hazardous materials that require different placards specified in table 2 §172.504(e) may be placarded with Dangerous placards instead of the specific placards required for each of the materials in table 2. However, when 1,000 kg (2,205 lbs) or more of one category of material is loaded at one loading facility, the placard specified in table 2 must be applied.
  • 17. Limited Qty §172.315(a)(2) (Vessel transport only) When shipping by air
  • 18. Environmental Pollutant  These Environmentally Hazardous Substance Markings are designed to help shippers and transporters easily identify any liquid or solid material, including its mixtures and solutions that are classified as marine pollutants.
  • 19. For Further Info Please feel free to contact Albert V. Condello III CHMM Professor – Safety & Fire Protection Engineering University of Houston Downtown Email: Condelloa@uhd.edu Cell 979-412-2219

Notas del editor

  1. For nOn-FLAMMABLE gAS, OxygEn (compressed gas or refrigerated liquid), and FLAMMABLE gAS, placard 454 kg (1,001 lbs) or more gross weight. For POISOn gAS (Division 2.3), placard any quantity.
  2. For FLAMMABLE, placard 454 kg (1,001 lbs) or more. gASOLInE may be used in place of FLAMMABLE placard displayed on a cargo tank or portable tank transporting gasoline by highway. Placard combustible liquid transported in bulk. See §172.504(f)(2) for use of FLAMMABLE placard in place of COMBuStIBLE. FuEL OIL may be used in place of COMBuStIBLE on a cargo or portable tank transporting fuel oil not classed as a flammable liquid by highway.
  3. For FLAMMABLE SOLID and SPOntAnEOuSLy COMBuStIBLE, placard 454 kg (1,001 lbs) or more. For DAngEROuS WHEn WEt (Division 4.3), placard any quantity.
  4. For OxIDIZER and ORgAnIC PEROxIDE (other than tyPE B, temperature controlled), placard 454 kg (1,001 lbs) or more. For ORgAnIC PEROxIDE (Division 5.2), type B, temperature controlled, placard any quantity.
  5. For Regulated Medical Waste (RMW), an Infectious Substance label is not required on an outer packaging if the OSHA Biohazard marking is used as prescribed in 29 CFR 1910.1030(g). CDC Etiologic Agent label must be used as prescribed in 42 CFR 72.3 and 72.6. A bulk package of RMW must display a BIOHAZARD marking. For POISOn (Pgl or PgII, other than inhalation hazard) and POISOn (PgIII), placard 454 kg (1,001 lbs) or more. For POISOn-InHALAtIOn HAZARD (Division 6.1), inhalation hazard only, placard any quantity.
  6. Placard any quantity - packages bearing RADIOACtIVE yELLOW-III labels only. Certain low specific activity radioactive materials in “exclusive use” will not bear the label, but the radioactive placard is required for exclusive use shipments of low specific activity material and surface contaminated objects transported in accordance with §172.504(e) table 1 and §173.427(a)(6).
  7. For CORROSIVE, placard 454 kg (1,001 lbs) or more.
  8. not required for domestic transportation. A bulk packaging containing a Class 9 material must be marked with the appropriate ID number displayed on a Class 9 placard, an orange panel, or a white square-on-point display
  9. Use these Blank Limited Quantity labels when shipping limited quantities of dangerous goods by ground or water after 1/1/11. The labels including the "Y" symbol must be used when shipping limited quantities by air.
  10. These dead tree, dead fish markings are part of the Globally Harmonized System (GHS) and were incorporated into the 14th edition of the United Nations Model Regulations. The eye-catching illustrations of a dead tree, dead fish provide a visible concept of how contaminants from solid waste enter the soil and ground water systems.