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CONTENTS

       FOREWORD                                                  iii
       PREFACE                                                    V




Unit 10 Haloalkanes and Haloarenes                              281
        10.1     Classification                                 282
        10.2     Nomenclature                                   283
        10.3     Nature of C–X Bond                             285
        10.4     Methods of Preparation                         286
        10.5     Physical Properties                            289
        10.6     Chemical Reactions                             291
        10.7     Polyhalogen Compounds                          308

Unit 11 Alcohols, Phenols and Ethers                            315
        11.1     Classification                                 316
        11.2     Nomenclature                                   317
        11.3     Structures of Functional Groups                320
        11.4     Alcohols and Phenols                           321
        11.5     Some Commercially Important Alcohols           336
        11.6     Ethers                                         337

Unit 12 Aldehydes, Ketones and Carboxylic Acids                 349
        12.1     Nomenclature and Structure of Carbonyl Group   350
        12.2     Preparation of Aldehydes and Ketones           353
        12.3     Physical Properties                            357
        12.4     Chemical Reactions                             358
        12.5     Uses of Aldehydes and Ketones                  365
        12.6     Nomenclature and Structure of Carboxyl Group   366
        12.7     Methods of Preparation of Carboxylic Acids     367
        12.8     Physical Properties                            371
        12.9     Chemical Reactions                             371
        12.10 Uses of Carboxylic Acids                          376


                                          xi
Unit 13 Amines                                                    381
        13.1   Structure of Amines                                381
        13.2   Classification                                     382
        13.3   Nomenclature                                       382
        13.4   Preparation of Amines                              384
        13.5   Physical Properties                                387
        13.6   Chemical Reactions                                 388
        13.7   Method of Preparation of Diazonium Salts           396
        13.8   Physical Properties                                397
        13.9   Chemical Reactions                                 397
        13.10 Importance of Diazonium Salts in Synthesis of       398
               Aromatic Compounds

Unit 14 Biomolecules                                              403
        14.1   Carbohydrates                                      403
        14.2   Proteins                                           412
        14.3   Enzymes                                            417
        14.4   Vitamins                                           417
        14.5   Nucleic Acids                                      419

Unit 15 Polymers                                                  425
        15.1   Classification of Polymers                         426
        15.2   Types of Polymerisation                            428
        15.3   Molecular Mass of Polymers                         435
        15.4   Biodegradable Polymers                             435
        15.5   Polymers of Commercial Importance                  436

Unit 16 Chemistry in Everyday Life                                439
        16.1   Drugs and their Classification                     439
        16.2   Drug-Target Interaction                            440
        16.3   Therapeutic Action of Different Classes of Drugs   443
        16.4   Chemicals in Food                                  449
        16.5   Cleansing Agents                                   450

Answers to Some Questions in Exercises                            456

Index                                                             461




                                       xii

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Contents

  • 1. CONTENTS FOREWORD iii PREFACE V Unit 10 Haloalkanes and Haloarenes 281 10.1 Classification 282 10.2 Nomenclature 283 10.3 Nature of C–X Bond 285 10.4 Methods of Preparation 286 10.5 Physical Properties 289 10.6 Chemical Reactions 291 10.7 Polyhalogen Compounds 308 Unit 11 Alcohols, Phenols and Ethers 315 11.1 Classification 316 11.2 Nomenclature 317 11.3 Structures of Functional Groups 320 11.4 Alcohols and Phenols 321 11.5 Some Commercially Important Alcohols 336 11.6 Ethers 337 Unit 12 Aldehydes, Ketones and Carboxylic Acids 349 12.1 Nomenclature and Structure of Carbonyl Group 350 12.2 Preparation of Aldehydes and Ketones 353 12.3 Physical Properties 357 12.4 Chemical Reactions 358 12.5 Uses of Aldehydes and Ketones 365 12.6 Nomenclature and Structure of Carboxyl Group 366 12.7 Methods of Preparation of Carboxylic Acids 367 12.8 Physical Properties 371 12.9 Chemical Reactions 371 12.10 Uses of Carboxylic Acids 376 xi
  • 2. Unit 13 Amines 381 13.1 Structure of Amines 381 13.2 Classification 382 13.3 Nomenclature 382 13.4 Preparation of Amines 384 13.5 Physical Properties 387 13.6 Chemical Reactions 388 13.7 Method of Preparation of Diazonium Salts 396 13.8 Physical Properties 397 13.9 Chemical Reactions 397 13.10 Importance of Diazonium Salts in Synthesis of 398 Aromatic Compounds Unit 14 Biomolecules 403 14.1 Carbohydrates 403 14.2 Proteins 412 14.3 Enzymes 417 14.4 Vitamins 417 14.5 Nucleic Acids 419 Unit 15 Polymers 425 15.1 Classification of Polymers 426 15.2 Types of Polymerisation 428 15.3 Molecular Mass of Polymers 435 15.4 Biodegradable Polymers 435 15.5 Polymers of Commercial Importance 436 Unit 16 Chemistry in Everyday Life 439 16.1 Drugs and their Classification 439 16.2 Drug-Target Interaction 440 16.3 Therapeutic Action of Different Classes of Drugs 443 16.4 Chemicals in Food 449 16.5 Cleansing Agents 450 Answers to Some Questions in Exercises 456 Index 461 xii