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Ce$ificate l{o. 02402itBAPAC %'
lii*
&liWJ*+i$$slL;r,;;''
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Date: I'Jay 28, :003 i:'i lq4 "'' i:l:n'r-" !r
issuing Ciflce:
SuCCf il,lDO l3ulidirig. ii. Raden Pata:"r I'jo. S.1 , Baloi Batam isiand 29432, lndcnesia
Pnone/Facs: +62 77 I 1,5657 51456?92
Ema!i: jurn. btm@sucofindo.cr:.!d
RffiP#RT *F ,S'gUALYSf;$
PRiNCiPIiL CV. TNB Chemicals Ind*nesia
Konrp. Guciang $eiu Blok A ic.7 i.- .
Batarn Centre - Batam
SUtsJFCT Said to be Chemicai
T[STER FOR Lead, Cadmium, ,Vercury, and Chicnnium Vl Anaiysls
TES]"TD idETHOD '1. Refe:-ence ta US EFA 305$ B, lor Leai Conteir'i
Analysis was pei'formed by Atomic Absorption Spectronreter
2, iteference to BS EhJ 1 122 :2AA1, Method B fos" Caclrnium Ccntent
Analysis was perl'ortneci by Atornic Abscrption Spectlcnieier
3. Reference to US S?A74718, fcr lr/iercury Ccntent
Ailalysis vras pertoffried lly Atomic Abs':r^pticn Spectioi-nei*r
4. Reference tc US EpA 30G0A - Meti":oci 7195, for l-lexavaie;:l Chrc;';':iuni
Analysis was perfo*-,led by $pectrcpirci'irneteI
DATE OF RECEIVING 26i05i2009
DA-TE CF ANALYSiS 26/0512009 to 28/0512009
SAfu'iPLE NAME lPA, l-{exane, Devesgi 1425, Methano}, De - l"latured Ethyl Alccirc'i, Etirartoi
99.5%, Ethanol 99.9%, lV'lethylene Chioride , D - 1 131
FsEsEi
Fana;Treters [."lrrit i Results
I Cadmiunr (CC
- Mercury (Hg) ppm l < C.CC01
- Ch;"onnium l--lexavalent (Cr6*) ppm | ' 0.01
ThiSCefi{icatel|epoiiisiSsu€dunneiourGenelaiTeintsaldConoi|ions,Copyci'.ihjCiisavaiiableup0ireqUes|orr,aybeaccessecat./vt1'su00f:f00'oo':d
Sn* Cqelpq,al Seririces
1l'ri
f1u'''l''
ETh,i. LJ U.0SC]"3.200 g s$qan*;
Chctnlcalt
iSiiii
2. I'IATERIAL SAFETY DATA SHSET ExxonHobil Chenical
PRODUCT NAME: EXXSOL DSP 80/100 FTUID . PAGE 1 OF LL
{,-
(novssol 1425) MSDS NUMBERI ITDHP-C-60260
REVISIOiiI: 12 llarch 2004
1 CHE!TCAL PRODUCT AND COMPANY TDENIIFICATION
IDENTIFICATION OP THE SUBSTANCE: EXXSCL DSP 8O/1OO PLUTD
This is a petroler-lh-rJetiued r:ompler sr.rb.5ta$ce
CIIEMICAL FAIIILY: Alj.phatlc. cycloparaffinie hydrocarbons
PRODUC? DSSCRIPTION'
Clear col.ourless J-iquid
SUPPLIER:
Exxonltobil cbemical Asia Pacific (Regn. No. 52893?2qc)
(A division of ExxoDMobil Asia Pacific Pte Ltd - Regn- No. 196800312N)
Internediates
1 HarbourFront Place, #06-00 HarbourFront ?ower One
singapore 098633
Telephone: 65-6885 8005
Facei-niIe: 65-6885 8233
EHERGENCY TEI,EPI'ONE }IUMEER:
65-6885 8005 (office hours)
65-966 50900 (outside of,fice hours)
2 COI4POSIT]ON/INFORHATION ON INGREDIENTS
CAS NUUBER: 6{?42-49-0
HAZARDOUS COMFONENTS SYMBOL/R-PHRASE Wtt
tand/or c[s NUMBERS) OR OEt
N-HEXANE 15.0-20.0
110-5{-3 F,Xn,xi,H,R11'R38'R{8/?0,R51153rR62,R65,R6?
HEpTANE AND ISOIIERS 32.0-36-0
F, Xn, Xi, N, R11, R38, R50/53, R65, R67
cycLoHExANs 25.0-27.0
110*82-? F,Xn,Xi,N,R11,R38.R50/53,R65'R67
Sxxon UoLit Corporation includes Exxontlobil Chemical Company and the Exxonllobil
Chenical Affiliates-
PR1NT DAIE: 16 Apcil 2004 Cont.
@nNH
CV. TNB CHEMICALSINDONESIA
3. MATERIAL SAFETY DA?A SHEET ExxonMobil Chemical
PRODUCT NAI'IE: EXXSOT DsP 801100 FTUID PAGE 2 OF ].1
NUUBtnt fiDHP-C-60260
MSDS
REVISION: 12 March 2004
METHYTCYCTOI{EXANE 3.0- ?.0
108-8?-2 Xn, Xi,N. R38, R51/53, R65, R5?
3 I{AZARDS IDENTIFICATION
HEALfII HAZARDS
Irrj-tating to skin
Ilarmful : danger of serious danrage to health by prolonged exposure through
inhal ation.
Possible risk of impaired fert.ility.
Harmful : may cause lung damage if swallowed-
Vapours may cause drowsiness and dizziness
ENVIRONMENTAI, HASARDS
Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environrneot.
P}IYSICAI A}ID CHEUICAL ITAZARDS / FIRE AND EXPLOSION HAZARDS
g Extreme hazard. Leaks of gas or spills of liquid can readily form
flanntnable mixtures at temperatures at or above the flash poirt.
o static Discharge, Product can accumufat€ static charqes which can
cause an incendiary el-ectrica] discharge.
4 FIRST AID MEASORES
INHALATION:
o lJsing proper respiratory protection, innrediatery remove the affected
victim from exposure. Administ,er artificial respirati.on if br€athing
is stopped. Keep at re$t, Call for prompt medical attention.
SKIN CONTACT:
o Flush with large amounts of rrater; use soap if availabLe.
o Remove grossly contaminated clothing, including shoes, and launder
before reuse.
EYE CONTACT:
o Flush eyes with large amounts of r.rater until irritatj.on subsides. ff
PRINT DATE: I-6 April 2004 Cont.
MATERIAL SAEE?Y DA?A SIiEET ExxonMobil Cherarcal
ffiu*
4. PAGE 3 OF 11
PRODUCT NAME: EXXSOL DsP 801100 F'LUID
MSDS NUMBER: HDHP-C-60260
REVISION: t2 March 2004
irritation Persists, get medical attention'
1NGESTION:
o If snallowed, DO NOT induce voniting' Keep at rest. Get ProftPt
rnedlcal attention'
--l--llT:lTT:::-Yi::Y:------
FIRE FIGHTING PROCEDURES:
oUse$ater=p'aytocoolfireexposedsutfacesandLoProtect has not
personnel. Sfrut off "fuel" to fire' If a leak or spj-ll prolect men
igniled, ,r""-t"a,*t sptay to disperse the vapors and to
aitenPting to stop a leak'
oEltherallowfire.toburaundercontrol}edconditionsorextinguish
with foam ot aiy chernical' Try to cover liquid spilLs
wiLh foam'
SPECIAL FIRE PRECAUTIONS:
o Al'oict ditectly into storage contalners due to danget of
"pr-yiig-"uter
boilover. 10 "STABILITY
o see also Section 4 trPIRST AID MEAsuREs" as He1} as Section
AND REACTIVITY".
HEZARDOUS COMBUSTION PRODUCTS:
No unusual
- -: - -l::i::::i:-::::i:: -Yi::Y: - -
I,AND SPIIL: downwind areas of
o Elirninate sources of ignition' l{arn occupants of
fireandexplosionhazird.Preventliguidfromenteringsewers,
ratercourses, or low areas' so t'ithout hazard'
o Keep public ttiy' sftut off source if entered a to do
possible
watercourse or sewer or
Advise authorities if substance has
haseontaminatedsoilorvegetation.Takenreasurestominimizethe
effect on the ground nater'
o Contain spilled liguid with sand or earth' or hand putnP) or with a
o Recover uV p"*pins'irr" "n explosion proof for purnping, scraPe uP
suiLable .u"oiteni_ If liquid is too viscous
uithst,o.,ers-o'pallsandplaeeinsuitablecontainersforrecycleor
disPosal -
oconsul|anexPertondisposalofrecoverednaterialandensure
conformity to loeal disposal regulaiions'
ExxonMobil Chemicaf
MATER]hL SAFEIY D}JA SIiEEf
TNB
Chemicols
CV. TNB CHEMICALS INDONESIA
5. PRODUCT NAME: EXxsoL DSP 80/100 l"tulD PAGE 4 OF 11
l.tSDS NUI4BER: llDltP-C-60260
REVISION: 12 March 200t1
well as SeCtiON 10 DSTABILITY
o See Section 4 "FIRST AID MEASURES" as AND
REACTIVITY" -
I{AIER SPILL:
o Eliminate aources of ignition. ?ilarn occupants and shipping in downwind
.areas of fire anal explosion hazard and request them to stay clear'
o Notify port or relevant authority and keep Public away. shut off source
ifpossibletodosowit'houthazard.Confineifpossible.
o Renove fron surface by skimming or nith suitable absorbent$' IfsuiEable
allowed
by local authorities and environmentai agencies sinking ancllor
dispersaats nay be used in non-conEined waters'
o Consult an expert on dispOSal Of any recovered material arrd ensure
conformity to ]ocal disposal regulations
o See atso section 4 "flRST AID I{EASURES" and Section 10 'STAEILITY AND
REACTIVITY".
? IIANDLTNG AND STORAGE
STORAGE TEMPERATURE (DegC) : Ambient
TRAIISPORT TEMPERATURE tDeqc) : Anbient
LOADING/UNI,OADING TEIIPERATURE (DeSC} : ANbiENt
VISCOSITY (cst) I 0.56
STORAGE/TRANSPORT PRESSTIRE (KPA} : AIMOSPhETiC
ELBCTROSTATIC ACCUMUTArION HAZARD? Yes, use proPer grounding procedure
UST'AL SHIPPING CONTAINERS:
Rail wagons, barges or drums
HA?ERIALS AND COATINGS SUITABTE:
Carbon Stee]
StainlesE Steel
PolyethYlene
PolyproPylene
Telfon
MATERIALS AND COATINGS UNSUITABLE:
Natural Rubber
Buty1 Rubber
EPDU
PolYstYrene
!.{A?ERIAL S}FETY DAT} SIIEET
ExxonMobil Chenical
ffinu*
6. PRODUCT NAME: EXXSOL DSP 80/100 FLUID PAGE 5 OF 11
MSDS NUMBER: ttDtlP-C-50260
REVISION: 12 l.{arch 2004
Cornpatibility with Plastic !{aterials ean vaty; we t.herefore tcconmend
that compatlbility is tested prior to use.
STORAGE I HENDLING, GEI{ERAI NOTES
o Keep concainer closed. Handle containers with care. Open slowly in
order to cont.rol possible pressure release- Store in a cool,
well-ventilated place away from inconpatible materials.
o DO NOT handle, store or open neax an open flame. sources of beat or
sources of igniti.on. Protecb materi,al from direct sunlight'
o l{ateria} r.rill accumulate static eharges trhich may cause an electrical
spark (ignition sourcel, Use proper bonding and./or grounding procedures.
o D0 NOT pressurize, cut, heat' or weld containers. EmPty Product
containers may contain product residue. Do Nof reuse empty containers
*ithout cornmercial cleaning or reconditioning-
ADDITIObIAL $ARNINGS
Container remains hazardous uhen etnpty. Continue to observe all
precautions.
8 EXPOSURE CONTROI,S/PERSONAL PROTECTION
SNGINEERING CONTROL MEASURES / VEIITILATION
The use of local exhaust ventilation is recorunended to control process
emj.ssions nea! f,he source. Laboratory sarnples should be handled in a lab
hsod- Provide rnechanical venti.lation of confined spaces. Use
explosion-proof ventj.]ation equiplent'
OCCUPR?IONAL EXPOSURE L1I4IT5
Exxonuotil recorsnends, for t.otal hydrocafbons, based on composition and
using the Reciprocal Calculation Procedure {RCP):
Naphtha {Petroleunl, hydrotreated light;
tlIA: 600 rng/n3 (159 ppm), ExxonMobil (2000) .
This product is a complex substance wbicb contains Ehe following
eonponent(s) nith a recognised or recornmended oEL value:
Cyclohexane;
TwA: 100 ppn {344 ng/m3), ACGIH {2002) .
PRINT DATE: 16 April 2004 Cont.
YIA"ERIAL SAFETY DAA SHEET ExxonMobil Chemical
PRODUCT I'IAHE: EXxsoL DSP 80,/100 FLUID PAGS 6 OF 11
@rNB
-/ chemicots
CV. TNB CHEMICALS INDONESIA
7. MSDS NUMBER: IIDHP-C-60260
REVISION: 1? March 2004
Heptane;
TwA: 400 pprr (1640 mq/mi) StEL: 500 ppn t2050 ftS/m3), €qr n-lleptane'
ACGIH (2002).
n-Ilexane;
TWA: 50 pptn (1?6 mg/n3) {SKIN} , ACGIH {2002't .
PERSONAL PROTECTION
GENERAT ADVICE
The use and choice o: Fersonal ?rotection equipment is reialed to the
hazard of the product, the uorkplace, and the way the product is handled.
In general, $e recoflunend as a nininum safety precaution that safety
glasses with slde-shields and workclothes proteeting arns, legs and body
be used, In addigion, any person visiting an area r*here this product is
'handled or processed slrould at f,east wear safety glassee uith
side-shields.
SPECIAL ADVICE
Based on and linrited to ExxonMobil's experience of this product as such.
the fo]louing special advi.ce is belj.eved to provide satisfactory
protection for the industrial user or handler-
F€SPIRATORY PROTECTION
Whele concentrations in air may exceed the limiEs given in this sectioo,
it j:s to use a half face filtet ltask to plotect from
reconnended
overexposure by inbalation. Suitable filter material depends on the
amount aod type of chemicaLs be5.ng handled in the worhplace, but filter
material of type trArt or sirnilar may be considered for use.
H}ND PROTECTION
When handling this product, it is recornrnended to *ear chernical resistant
gloves. The choice of suitable protective glgves depends on uork
conditions and ehat chemicals are handled, but we have positive experience
wlth gloves made of Nitrile. Gloves should be replaced immediately if
sign of degradation is observed.
EYE PROTECTION
See general advice.
SRIN/BODY PROTECTION
See general advice.
16 Apri
MATERIAL SEFETY DATA SitEEI Exxon!1obil Chernical
PRCDUCT NArrlE: EXXSOL DSP 801100 FLUID PAGE 7 OF }1
.ffi
{f'w}TNB
chemicols
V
CV, TNB CHEMICALS INDONEsIA
8. MSDS NUIIBER: HDHP-C-60260
REVISION: 12 Harch 2004
_-:-_:i:::::_i::_:i:::i:-:i::::::::-_--_-__ -----&3---
These are indicatirre values only. Please refer also to the product
specification sheet.
9.1 General Information
PHYSICAL STATE: LiqUid
FOR}1,/COIOUR: Clear colourless liquid
ODOR: Mild odour
FRuEZ./MELT/Potxr: <0 DegC
BoILING POINT RANGE: between 75 and 115 DegC
VAPOR PRESSURE {20 DegC}: 8.65 kPa
VAPOR PRESSURE (38 DeqC): 19.44 kPa
VAPOR PRESSURE {50 DegC}: 31.4? kPa
DENSITY (15 Deqc): 0.?20 kg/dm3 ASTM D{052
VAPOR DENSI?Y t101.3 kPa/air=l): Not ava.ilable
VISCOSITY (25 DegC): 0.56 cSt ASTM D445
{40 DegC}: 0.43 cst Approxinate
EVAPORATISN RATE (n-Bu Acetate= 1): 6.000
9.2 Health, Safety 6 Environrnental Information
FLAST{POINT{): -15 DegC
AUTOIGNITION TEMPERAfURE: ) 200 DegC
SXPLOSM IIUITS (in air): betreen 1 and ? Volt
SoIUBIIITY IN WATER (20 DegC): 0'00 l{tt
9.3 Otber Inforrnation
I4OI,ECUIAR 9JEIGIIT: 94 Estimated
COEFF. OF THERHAL EXPANSION (L'q.}: 0.00126 DegC
IS MATERIAL HYGROSCOPIC: NO
PRINT DATE: 16 April 2004 Con!.
XE.TERT,AL SAFETY DATA SHEET ExxonMobil Cheni.ca1
PRODUCT NAI{E: EXXSOT DSP 80/100 FIUID PAGE 8 OF 11
MSDS NUMBER: HDHP-C-60250
REVISION: !.2 !4arch 2004
10 S"EBII,ITY AND REACTTVITY
@rhrn
CV TNB CHEMICALS
TNDONESIA
9. TIAZARDOUS POTYMERIZATTON? No
CONDITIONS TO AVOID POLYMERTZATION:
Not Applicable.
STABTTITY: StabLe
CONDITIONS TO AVOID INSTABITITY:
Not Applicable.
MATERIALS AND CONDITIONS TO AVOID (INCOMPATTBILITY):
Serong oxidizing agents.
HAZARDOUS DECOMPOSITIQN PRODUCTS :
Non€
11 TOXICOISGICAT INFONMETION
ACUTE:
INHALATTON:
o Vapor concentrations above recommended exposure levels nay be irritating
to the eyes and the respiratory tract, may cause headaches and
dizziness, could be anesthetic and may have other central nerv$us system
effects.
SKIN CONTACT:
o Low order of toxiciby.
o Frequent or prolonged contact. may defat and dry the skin, Ieadlng to
discomfort and dermatitis.
EYE CONTACT:
o Will eause eye discomfort, but will not injure eye tissue.
1NGESTION:
o Minirnal toxicity.
o Small amounts of liquid aspirated into the respiratory systen during
ingestion or from vonit,ing may cause bronchopneumonia or pul.nonary
edema.
CHRONIC:
This product contains n-hexane. Overexposure to n-hexane may cause
progressive and potentlally irreversi.bl.e damage to the peripheral nervous
system, particularly in the arms aod 1egs.
PRINT DATE: 16 Apri.l 2004 Cont.
I4ATERIAL SAFETY DATA SEEET Exxont'tobiL Chemica-L
FRODUC1 NAHE: BXX9or DSP 80,/100 FtUlD PA6E 9 OF 11
MSDS NUMBER: HDHP-C-60260
REVISfON: 12 !{arch 2004
Additional. info:mation is a'.'ailable on speclal request.
@R'rH
CV. TNB CHEMICALSINDONESIA
10. L2 ECOI.OGICAT INFORN'ATION
ENVI RONI.IENTAI MOB I LITY
This producL ie highly volatile and will rapidly evaporatb*to tlte air if
released into the nater-
EWIRONMENIEL DEGRADAB]TITY
This product can degrade rapidly in air.
this substance is expected to be removed in a $astei{ater treatment
facility-
Sased upon data for a simifar component or preparation, or estirnated data.
This product is exp€cEed to biodegrade raFidly and be "readily"
biodegradable according to oEcD guidelines.
ECO?OXICITY AND BIOACCUHUIAT]ON
Based upon daba for a sinilar component or preparation, or estinated data-
Expected to be toxic to aquatic organisms.
Long Lerrn adverse effects to aguatie organisns are possible if continuous
exposure is maintained.
13 DISPOSAL CONSIDSRATIONS
The following advice only appliee to the product as supplied.
Codbination pith other materials may well indicate another route of
disposal- If in doubt' contact the local Exxon}lobil affiliate
or local AuthoriEies.
Bnpty packaging should be taken for recycling, recovery or disposal through
a euitably gualified or licensed contractor.
Care should in any case be taken to ensure eompliance ritb nati'onal
and local regulations.
This producE is NOT suitable for disposal hy either landfill or via
nunicipal seuers, drains, natural st,reams or rj"vers.
This produet is ashless and can be burned directly in aPptoprlate
equipment.
I'{ATERIAI SATEfY DATA SHEET ExxonMobil Chenica]
PRODUCT NAME: EXXSOT DSP g0/100 Ftur,D PAGB 10 OF 11
ttSDS F.IMBERT HDHP-C-60260
REVISIoN: 12 }larch 2006
14 TRANSPOR! INFORMATION
@IHH
CV. TNB CHEMICALS INDONESIA
11. tAND
CLASS: 3 PG: II UN.NUHBER: 3295
. HAZCHEM CODE: 3eIE SUBSIDIARY RISK:
TRANSPORT DOCUF1ENT NAME:
IIYDROCARBONS, IIQUID, N.O-S. (n-hexane), CLASS 3, UN 3295. PG Ir
(-15 DegC c-c.) *r' '
SEA - II.IDG {PACKAGED GOODS AND BLCs)
CTASS: 3 PG: fI UN NUMBER: 3295
I,IARINE POI,LUTANT: NO E!,S HUMBER: F-E, S-D
RISK TABEL: 3 SUBSIDIARY RISK:
TRANSPORI DOCUMENT NAME:
HYDROCARBONS, LIQUID, N.O.S. (n-hexane), 3, UN 3295' PG II, (-15 DegC
c.c. )
AIR {1UA0/rAIA}
CTASS: 3 PG: fI UN NU!{BER: 3295
PROPER SHIPPING NAF1E:
IIYDROCARBONS, IIQUID, l,l .O.S. (n-hexane)
15 REGULATORY INFORT"{ATION
CI,ASSIT'TCATION AI{D LABELLINC ACCORDING TO EUROPEAN DIRECTIVES
CLASSTTICATTON/ sYMEoL : HIGHLY FI"AI"TMABLE /F
CLASSIFICATION/SYMBOL: HARHFUL./Xn
CLASSIFICATIONISYMBOL: DANGEROUS FOR rHE ENVIRONMENT/N
GOVERNTNG DIRECTIVE:
Dangerous Substances Directive 67l548lEC' as modified.
NATURE OT SPECIAT RISK
R11 Highly flanrnable
R38 Irritating to skin
R48/20
Harnful : danger of serious danage to health by prolonged exposure through
inhalation.
PBINT DATE: 16 Apt1l 200{ Cont.
MATER]AI SAFETY DATA SHEET ExxonMobil Chenical
PRODUCT NAHE: EXXSOL DSP 80/100 FTUID PAGE 11 OF 11
MSDS NUMBER: !IDHP-C-60260
REVISION: 12 llarch 2004
R51 /53
Toxj.c to aquatic organisms. may eause long-term adverse effects in the
aguatic environnenE.
PossibLe risk of :npaired fertility.
".62
@n*{H
CV. TNB CHEMICALS INDONESIA
12. R65 Harmful : may cause lung damage if swallowed.
R6? vapours may cause drowsiness and dizziness
SAFETY ADVICE
S09 Keep containeE in a rell ventilated place
516 Keep away from sources of ignition-No Snoking
S23 Do not breathe gas,/furnes/vapour,/spray '-i
S24 Avoid contact Hith skin
S43A In case of f,ire use sand, earth, chemical powder or foam
s5?
Use appropriate contain€r to avoid environmental contamination.
s60
This naterial and/or its container must be disposed of as hazardous waste.
s62
If, swal.Iowed, do not induce vomitinq : seek medieal advice innediately
and shor* this container or label.
15 OTI{ER INFORI,IATION
RSVISION SUMMARY:
Since 2{ December 2003, this MSDS has been revi.sed in Section(s):
9
This information relat€s only to the specific material designated and may not
be valid for such material. used in combination uith any other materials or in'
any process. Such infornration is to the best of ExxonMobil Chemical Cornpany's
knowledge and believed accurate and reliable as of the date indicated.
Honever, no representation, parfanty or guarantee is nade as to its accoFdclr
reliability or completeness. It is the user's responsibiliCy to satisfy
himself as to the suitabiliEy and corryleteness of such j.nformation for his onn
particular use.
PRMT Df,,TE: 1.6 April 2004
ffin,ur'