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Twins and
  Defects
Twinning
A twin is a symmetrical intergrowth of two or more
crystals of the same substance

Twinning can be considered a type of planar defect

The surface on which two individuals are united is
known as the composition surface. If this surface is
a plane, it is called the composition plane and can
be irregular or regular
Twinning
The operations that relate a crystal to its twinned
counterpart are symmetry operations:

‣   twin plane - reflection by a mirror plane

‣   twin axis - rotation about a crystal direction common
    to both, with the angular rotation normally 180°

‣   twin center - inversion about a point
Twin Classification
4 types of twins:

✦   Contact       ✦   Polysynthetic
✦   Penetration   ✦   Cyclic
Contact & Penetration
 Contact twins have a regular composition surface
 separating the two individuals; the twin is defined by
 a twin plane

 Penetration twins are made up of interpenetrating
 individuals having an irregular composition surface,
 and the twin law is usually defined by a twin axis
 direction
Polysynthetic & Cyclic
 Multiple twins that have three or more individual
 crystals twinned according to the same law and if all
 the composition surfaces are parallel, the resulting
 group is a polysynthetic twin

 If successive composition planes are not parallel, a
 cyclic twin results
Common Twins




Swallowtail Polysynthethic Penetration
Twin Gypsum   Albite Twin  Twin Galena
Common Twins




Penetration   Penetration   Carlsbad Twin
Twin Pyrite      Twins      Orthoclase
              Staurolite
Causes of Twinning
Growth twins - error in stacking of unit cells when
crystal first start to grow

Transformation twin - variations in temperature and
pressure stresses the lattice - lattice relieves the
stress by “warping”

Deformation twin - some kind of stress is put on the
crystal structure - crystal relieves stress by twinning
Structural Defects
 As a crystal grows, structural defects are
 incorporated into the mineral

 Such imperfections affect growth rate, crystal
 morphology, and basic properties of crystalline
 materials, such as strength, conductivity,
 mechanical deformation, and color
Structural Defects
  3 Types:
        point
        line
        plane
Point Defects
Frenkel & Shottky
     Defects




Frenkel   Shottky
Line Defects

     Edge
     Screw
Edge Dislocation
Screw Dislocation
Planar Defects
Grain Boundaries

Twin Planes

Sub-grain Boundaries
Grain Boundaries
Twin Planes
Subgrain Boundaries
Crystal Deformation
Crystal Deformation
  Dislocation Slip
Migration of Vacancies thru Crystal Lattice
Dislocations Quartz




Transmission Electron Microscope Photos
Dislocations Quartz




Transmission Electron Microscope Photos
Dislocations Quartz




 Strain-free Neoblasts
Subgrain Boundaries
Order-Disorder

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Lecture11 twins-defects-creep

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