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Article on Smithson Tennant – discoverer 
of iridium & osmium elements 
WRITTEN AND PUBLISHED 
BY 
WWW.WORLDOFCHEMICALS.COM
Biography 
 Smithson Tennant was born on November 30, 1761 – 
died on February 22, 1815. 
 Tennant is best known for his discovery of the 
elements iridium and osmium. 
 He also contributed to the proof of the identity of 
diamond and charcoal. 
 The mineral tennantite is named after him.
Contributions 
 Following research work done by tenant which leads to 
the discovery of osmium and iridium elements. 
 Tennant fused the insoluble residue with alkali at high 
temperature and dissolved the resulting cooled solid in 
water, producing a further black solid and a yellow 
solution. 
 The yellow solution was probably a basic form of osmium 
tetroxide, OsO4. The black solid was further treated with 
hydrochloric acid, the solid produced was fused with 
caustic soda and further treatment with acid obtained red 
crystals. 
 These are most likely to have been Na2[IrCl6].nH2O. On 
heating these, a white powder of an unknown element was 
obtained, which was later identified as iridium element.
Facts about Osmium element 
 Osmium is a hard, brittle, bluish-white transition metal 
in the platinum group. Its alloys with platinum, iridium 
and other platinum group metals are employed in 
fountain pen nibs, electrical contacts, and other 
applications. 
 Osmium is a hard but brittle metal that remains lustrous 
even at high temperatures. It has a very low 
compressibility. 
 The most common oxidation states of osmium element 
include +2, +3, +4, and +8. It can be dissolved by fused 
alkalies, especially if an oxidizing agent such as sodium 
chlorate is present. Osmium will react at 200° C with air 
or oxygen to form OsO4. Osmium has high reflectivity in 
the ultraviolet range of the electromagnetic spectrum.
Chemical properties of Osmium 
 AppearanceBlue - Gray or Blue-Black Metal 
 Atomic Number - 76 
 Atomic Weight - 190.23 g/mol 
 Boiling Point - 5012 °C 
 CAS Number - 7440-04-2 
 Density - 22.59 
 Melting Point - 3033 °C 
 Find here Complete osmium chemical properties
Facts about iridium element 
 Iridium is a very hard, brittle, silvery-white transition metal of 
the platinum family. It is the only metal to maintain good 
mechanical properties in air at temperatures above 1600 °C. 
 The most important iridium compounds in use are the salts 
and acids it forms with chlorine, though iridium also forms a 
number of organometallic compounds used in industrial 
catalysis, and in research. 
 Iridium metal is employed when high corrosion resistance at 
high temperatures is needed, as in high-performance spark 
plugs, crucibles for recrystallization of semiconductors at high 
temperatures, and electrodes for the production of chlorine in 
the chloralkali process. 
 Iridium radioisotopes are used in some radioisotope 
thermoelectric generators.
Facts about iridium element Cont… 
 Iridium forms compounds in oxidation states 
between −3 and +9. Iridium has two naturally 
occurring, stable isotopes, 191Ir and 193Ir, with 
natural abundances of 37.3% and 62.7%, 
respectively. 
 Iridium is one of the nine least abundant stable 
elements in Earth's crust, having an average mass 
fraction of 0.001 ppm in crustal rock. Iridium is 
obtained commercially as a by-product from nickel 
and copper mining and processing.
Chemical properties of Iridium 
 Appearance - Silver-White Metallic Solid 
 Atomic Number – 77 
 Atomic Weight - 192.217 g/mol 
 Boiling Point - 4428 °C 
 CAS Number - 7439-88-5 
 Melting Point - 2466 °C 
 Find here complete Iridium chemical properties
References 
 http://www.worldofchemicals.com/462/chemistry-articles/ 
smithson-tennant-discoverer-of-iridium-osmium- 
elements.html 
 Iridium Chemical suppliers 
 Osmium chemical suppliers 
 osmium chemical properties 
 Iridium chemical properties

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Article on smithson tennant - discoverer of iridium & osmium elements

  • 1. Article on Smithson Tennant – discoverer of iridium & osmium elements WRITTEN AND PUBLISHED BY WWW.WORLDOFCHEMICALS.COM
  • 2. Biography  Smithson Tennant was born on November 30, 1761 – died on February 22, 1815.  Tennant is best known for his discovery of the elements iridium and osmium.  He also contributed to the proof of the identity of diamond and charcoal.  The mineral tennantite is named after him.
  • 3. Contributions  Following research work done by tenant which leads to the discovery of osmium and iridium elements.  Tennant fused the insoluble residue with alkali at high temperature and dissolved the resulting cooled solid in water, producing a further black solid and a yellow solution.  The yellow solution was probably a basic form of osmium tetroxide, OsO4. The black solid was further treated with hydrochloric acid, the solid produced was fused with caustic soda and further treatment with acid obtained red crystals.  These are most likely to have been Na2[IrCl6].nH2O. On heating these, a white powder of an unknown element was obtained, which was later identified as iridium element.
  • 4. Facts about Osmium element  Osmium is a hard, brittle, bluish-white transition metal in the platinum group. Its alloys with platinum, iridium and other platinum group metals are employed in fountain pen nibs, electrical contacts, and other applications.  Osmium is a hard but brittle metal that remains lustrous even at high temperatures. It has a very low compressibility.  The most common oxidation states of osmium element include +2, +3, +4, and +8. It can be dissolved by fused alkalies, especially if an oxidizing agent such as sodium chlorate is present. Osmium will react at 200° C with air or oxygen to form OsO4. Osmium has high reflectivity in the ultraviolet range of the electromagnetic spectrum.
  • 5. Chemical properties of Osmium  AppearanceBlue - Gray or Blue-Black Metal  Atomic Number - 76  Atomic Weight - 190.23 g/mol  Boiling Point - 5012 °C  CAS Number - 7440-04-2  Density - 22.59  Melting Point - 3033 °C  Find here Complete osmium chemical properties
  • 6. Facts about iridium element  Iridium is a very hard, brittle, silvery-white transition metal of the platinum family. It is the only metal to maintain good mechanical properties in air at temperatures above 1600 °C.  The most important iridium compounds in use are the salts and acids it forms with chlorine, though iridium also forms a number of organometallic compounds used in industrial catalysis, and in research.  Iridium metal is employed when high corrosion resistance at high temperatures is needed, as in high-performance spark plugs, crucibles for recrystallization of semiconductors at high temperatures, and electrodes for the production of chlorine in the chloralkali process.  Iridium radioisotopes are used in some radioisotope thermoelectric generators.
  • 7. Facts about iridium element Cont…  Iridium forms compounds in oxidation states between −3 and +9. Iridium has two naturally occurring, stable isotopes, 191Ir and 193Ir, with natural abundances of 37.3% and 62.7%, respectively.  Iridium is one of the nine least abundant stable elements in Earth's crust, having an average mass fraction of 0.001 ppm in crustal rock. Iridium is obtained commercially as a by-product from nickel and copper mining and processing.
  • 8. Chemical properties of Iridium  Appearance - Silver-White Metallic Solid  Atomic Number – 77  Atomic Weight - 192.217 g/mol  Boiling Point - 4428 °C  CAS Number - 7439-88-5  Melting Point - 2466 °C  Find here complete Iridium chemical properties
  • 9. References  http://www.worldofchemicals.com/462/chemistry-articles/ smithson-tennant-discoverer-of-iridium-osmium- elements.html  Iridium Chemical suppliers  Osmium chemical suppliers  osmium chemical properties  Iridium chemical properties