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Covalent Bonding Orbitals
Hybridization and the Localized Electron Model
Localized Electron Model ,[object Object],[object Object]
Hybridization ,[object Object],[object Object],[object Object],[object Object]
Hybridization
Hybridization
sp 3  example: Methane
sp 3  example: Ammonia
sp 2  Hybridization
sp 2  Hybridization
sp 2  Hybridization ,[object Object],[object Object],[object Object]
sp 2  Hybridization
sp 2  Hybridization: Ethylene
Multiple Bonds ,[object Object],[object Object]
sp 2  Hybridization: Ethylene
sp Hybridization ,[object Object],[object Object]
sp Hybridization
sp Hybridization: CO 2
sp Hybridization: CO 2
sp Hybridization: CO 2
sp Hybridization: N 2
sp 3 d Hybridization ,[object Object],[object Object]
sp 3 d Hybridization: PCl 5 ,[object Object]
sp 3 d 2  Hybridization ,[object Object],[object Object]
Example Problem ,[object Object],sp 3 d 2
Localized Electron Summary ,[object Object],[object Object],[object Object],[object Object]
Effective Pairs and Their Spatial Arrangement
The Molecular Orbital Model
Molecular Orbital Model ,[object Object],[object Object],[object Object]
Molecular Orbitals ,[object Object],[object Object],[object Object]
MOs ,[object Object],[object Object],[object Object],[object Object]
MOs ,[object Object],[object Object]
MOs ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
MOs ,[object Object],[object Object]
MOs ,[object Object],[object Object]
Bonding and Antibonding
MOs ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
MOs ,[object Object],[object Object],[object Object]
MOs ,[object Object],[object Object],[object Object],[object Object],[object Object]
Bond Order ,[object Object],[object Object],[object Object]
Bond Order ,[object Object],[object Object],[object Object]
Bonding in Homonuclear Diatomic Molecules
Homonuclear Bonding ,[object Object],[object Object],[object Object]
Li 2  MO ,[object Object],[object Object],[object Object]
Be 2  MO ,[object Object],[object Object],[object Object]
MOs from p orbitals  ,[object Object]
MOs from p orbitals  ,[object Object]
MOs from p orbitals  ,[object Object]
B 2  Example ,[object Object],[object Object],[object Object],[object Object],[object Object]
Exceptions ,[object Object]
Paramagnetism ,[object Object],[object Object],[object Object]
Paramagnetism
Paramagnetism ,[object Object],[object Object],[object Object]
Summary  ,[object Object],[object Object],[object Object],[object Object]
 
Example Problem ,[object Object],[object Object],[object Object],[object Object],B 2   C 2   N 2 O 2   F 2 σ 2p *   σ 2p *   π 2p *   π 2p *   σ 2p   π 2p   π 2p   σ 2p   σ 2s *   σ 2s *   σ 2s   σ 2s   σ 1s *   σ 1s *   σ 1s     σ 1s    
Example Problem ,[object Object],[object Object],[object Object],B 2   C 2   N 2 O 2   F 2 σ 2p *   σ 2p *   π 2p *   π 2p *   σ 2p   π 2p   π 2p   σ 2p   σ 2s *   σ 2s *   σ 2s   σ 2s   σ 1s *   σ 1s *   σ 1s     σ 1s    
Bonding in Heteronuclear Diatomic Molecules
Heteronuclear Molecules ,[object Object]
NO example ,[object Object],[object Object]
Example Problem ,[object Object],[object Object]
Heteronuclear Diatomics ,[object Object],[object Object],[object Object],[object Object]
Combining the Localized Electron and MO models
Resonance ,[object Object],[object Object]
Resonance ,[object Object]
Resonance ,[object Object]
Resonance ,[object Object],[object Object]
NO 3 - ,[object Object]
The End
MO Worksheet B 2   C 2   N 2 O 2   F 2 σ 2p *   σ 2p *   π 2p *   π 2p *   σ 2p   π 2p   π 2p   σ 2p   σ 2s *   σ 2s *   σ 2s   σ 2s   σ 1s *   σ 1s *   σ 1s     σ 1s    

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Adv chem chapt 9

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