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Introduction
• Cédric Brüll (Managing Director of TWEED Cluster) - Energy Walloon Ecosystem
• Dr. Alexander Buchele (Managing Director of Energy Campus Nürnberg) - Overview of the EnCN
Delegation of the Energy Campus Nuremberg
• Prof. Dr. Arno Dentel (TH Nürnberg) – Building Technology
• Prof. Dr. Wolfgang Kcmar – Building Materials
• Dr. Andreas Distler – Organic/Printed PV
• Stefan Dürr – Hydrogen Storage
• Dr. Maximilian Göltz – Materials
Challenges for the Walloon industries
• Dr. Sébastien Borguet (Head of R&D - John Cockerill) – Hydrogen technology John Cockerill
• Dr. Marc Foguenne, (Technology and Innovation Director, AGC Glass Europe). – “ The Energy challenge :
a trigger of ambitious and innovative projects.”
Wallonia
Meets
EnCN
From Sustainable Energy Technologies
Cluster TWeeD -- 20192
Wind Solar Biomass
Hydraulic Hydrogen Batteries
Scope TWEED
To Sustainable Energy Applications
Cluster TWeeD -- 20193
Scope TWEED
What are we doing ?
Cluster TWeeD -- 20194
• Networking between industrial or commercial companies and
others actors of sustainable energy sectors.
• Reactive and proactive approaches in order to stimulate new
projects.
• Set-up technical support and management of projects.
• Promote networking by organizing specific events, general
meetings, workshops, bilateral meetings, face-to-face meetings,
visits to companies,...
• Develop synergies with other actors of sustainable energy
sectors (clusters,...).
• Local and international promotion of members.
• Carrying out industry, technical, market and economic studies
on sustainable energy sector.
• Participation in Regional/European/International projects
Scope TWEED
1. Establish an exhaustive diagnosis of the energy sectors by
identifying its strengths and weaknesses, its opportunities and
threats, its prospects, its needs or its challenges in terms of
technological innovation.
2. Carry out a mapping of Walloon and Brussels stakeholders
(companies, R&D centers, training players, etc.), whether or not
they are already involved in the sectors, who have integrable skills
in the value chain.
3. Promote Walloon skills both in Belgium and abroad, at national and
international events via an interactive website and a directory
(paper or electronic document) containing the activities of each
actor.
4. Facilitate working groups to stimulate the implementation of
projects/missions
Industry & Value chain analysis
Cluster TWeeD -- 20195
Industry & Value chain analysis
H2 example
Cluster TWeeD -- 20196
1. Eolien
2. PV
3. Biométhanisation
4. Réseau électrique
5. Electrolyseur
6. Stockage H2
7. Pile à combustible
8. Mobilité
9. Industries
10. Méthanisation
11. Cogénération
12. Réseau Gaz
13. Chauffage résidentiel
14. Méthanolisation
15. Stockage méthanol
Power to
Power
Power to
Mobility
Power to
Industry
Power to
Gas
Biogas = CH4 + Co2 + …CO2 CO2
CH4
Power to
Fuel
Power to
Heat
CH3OH
1 2
4 5
3
6 7 8 9 1
0
1
1
1
2
9
1
3
1
4
1
5
Industry & Value chain analysis
Cluster TWeeD -- 20197
1. Eolien
2. PV
3. Biométhanisation
4. Réseau électrique
5. Electrolyseur
6. Stockage H2
7. Pile à combustible
8. Mobilité
9. Industries
10. Méthanisation
11. Cogénération
12. Réseau Gaz
13. Chauffage résidentiel
14. Méthanolisation
15. Stockage méthanol
Power to
Power
Power to
Mobility
Power to
Industry
Power to
Gas
Biogas = CH4 + Co2 + …CO2 CO2
CH4
Power to
Fuel
Power to
Heat
CH3OH
1 2
4 5
3
6 7 8 9 1
0
1
1
1
2
9
1
3
1
4
1
5
Industry & Value chain analysis
H2 example
Cluster TWeeD -- 20198
R&D
R&D
Etudes &
Conception
Financement
Fabrication &
Production
Distribution
& Installation
Opérations &
Maintenance
Formation &
Certification
Education,
Promotion &
Sensibilisation
ChaînedesMétiers
Industry & Value chain analysis
H2 example
Cluster TWeeD -- 20199
Armoire
électrique
•Transformateur
•Redresseur
Electrolyseur
•Cellule
•Diaphragme /
Membrane
•Electrolyte
•Hydroxyde Sodium
/Potassium
•Membrane
polymère
•Electrode / Plaque
bipolaire
•Module de
déminéralisation
•Osmose inverse
•Système de
refroidissement
•Réservoir-séparateur
Unité de
purification
•Echangeur
•Recombineur
catalytique
•Zéolithe
•Résistance
électrique
Système de
compression
•Compresseur
•Groupe froid
•Echangeur de
refroidissement
Stockage
•Collecteur
•Tuyauterie de
transfert
•Bouteille (gaz)
•Métallique
•Composite
•Hydrure
métallique (solide)
Transport
•Gazoduc
•Camion
•Cadres
•Tubes
Station-service
•Borne de
distribution
•Pistolet
•Armoire de gestion
de la station
•Tuyauteries,
vannes,
actionneurs,
détecteurs, …
Pile à
combustible
•Cellule
•Electrolyte
•Hydroxyde de
potassium
•Membrane
polymère
•Acide
phosphorique
•Sels fondus
•Céramique
•Electrode /
Plaque bipolaire
ChaînedesTechnologies
Industry & Value chain analysis
H2 example
Cluster TWeeD -- 201910
Industry & Value chain analysis
H2 example
Cluster TWeeD -- 201911
Industry & Value chain analysis
Other sectors, Ex. solar PV
Portail Re-Wallonia
Cluster TWeeD -- 201912
Industry & Value chain analysis
ReWallonia - Players
13
> 350 belgian actors & 4.000 followers !
ReWallonia - Players
13/12/19Cluster TWEED14
http://www.rewallonia.be/cartographies/stockage/
ReWallonia - Players
15
ReWallonia - Projects
13/12/19Cluster TWEED16
Famous Walloon SG projects (2/2)
17
MeryGrid INTERESTS
This Walloon pilot project has entered the operational
phase. The aim is to test the benefits of local self-
consumption at the zoning scale, bringing together
electricity-consuming companies, renewable (solar and
hydro) production and a storage unit. The energy
management system (EMS) that manages the optimization
of the micro-network should allow a saving of 15% on the
energy bill.
INTERESTS aims the creation of an optimization tool
allowing the definition, the sizing and the management of
"integrated stations" of production, storage and
consumption (refuelling) of renewable energy (electricity /
hydrogen) at the local level. The scenarios developed must
be reproducible and economically viable.
• Nethys
• University of Liege
• CE+T Energrid
• Sirris
• SPI
• La Wallonie
• ATM-Pro
• Certech
• N-Side
• TWEED
• UCL-INMA
ReWallonia - Projects
International Strategy
Cluster TWeeD -- 201918
Collaboration/Expertise
within the Wallonia export
agency and their worldwide
network (> 100 Economic &
Trade Counselor + ALS)
joint actions &
collaborations
Partnerships/Joint Projects
between high level
Energy/Cleantech Clusters
in a EU/Worldwide scale
TWEED is the official
energy cluster in
Wallonia :
TWEED & Flux50
(Flanders) Partnership
@ Belgian level :
TWEED is a member of
International Cleantech
Cluster :
International Strategy
International Strategy
Cluster TWeeD -- 201919
Benchmark &
Establish common
knowledge
(Tools : Exchange of Best
practices,…)
Cluster Oriented
Members Oriented
Joint Cluster
Projects
(Tools: Cosme Go
International)
Main Goal : Promote
Wallonia as Smart
Energy Region
BtoB matching
(Tools: ICN Passport,…)
Joint Mission /
Target markets
(Tools : Cluster and
Awex network )
Markets/Technolog
y/Opportunity
Watch
(Tools : Cluster and
Awex network)
Crossboarder
SME
Collaborations
(Tools: Innosup)
International Strategy
Main Goal : Create
the first EU Energy
Meta Cluster
www.clustertweed.be
Cluster TWEED
Rue Natalis 2 • 4020 Liège • Belgique
Info@clustertweed.be | +32(0)4.242.47.60
www.encn.de
Funded by
THINK.
RESEARCH.
ACT.
Supported by
Introduction
“Energie Campus Nürnberg”
Dr. Alexander Buchele | 09.12.19
Page 2
www.encn.de
THINK.
RESEARCH.
ACT.
Energie Campus Nürnberg
The EnCN
Interdisciplinary Think-Tank of
established and well known
research institutions
Key competences along the
whole energy chain – from
generation to utilization
Scientific expertise from
fundamental research to
prototype development
Page 3
www.encn.de
THINK.
RESEARCH.
ACT.
Energie Campus Nürnberg
Joint Research along the Energy Chain
ENERGY MANAGEMENT TECHNOLOGIES
ENERGY MARKET DESIGN
Economy | Design
Power Electronics | Data security| ICT | Simulation
Network Electronics & Smart Grid
RENEWABLE ENERGIES
EFFICIENT ENERGY
UTILIZATION
ENERGY STORAGES
ELECTRIC GRIDS Industrial Drives
Building Insulation
Building Technology
Combined Heat & Power
Photovoltaics
Solar Thermal Energy
Chemical & Thermal
TRANSPORT &
STORAGE
GENERATION UTILIZATION
Page 4
www.encn.de
THINK.
RESEARCH.
ACT.
Energie Campus Nürnberg
Mission
We aspire to work together with our partners from science, industry and
politics to help shape and promote the energy transition process.
Interdisciplinary and cross-institutional research at
highest scientific level
Visible center of energy research
with diverse scientific and practical offers
Utilization of the innovation potential for
Technology transfer and start-up activities
Page 5
www.encn.de
THINK.
RESEARCH.
ACT.
ORGANISATION
INFRASTRUCTURE
TECHNOLOGY TRANSFER
FINANCIAL FIGURES
Energie Campus Nürnberg
EnCN in Numbers
53
7
As of 2018
15
Page 6
www.encn.de
THINK.
RESEARCH.
ACT.
www.encn.de
Page 7
Central Office
Energie Campus Nürnberg
Fon: +49 (0)911 / 56 854 9120
Fax: +49 (0)911 / 56 854 9121
info@encn.de
Dr. Alexander Buchele
Fürther Str. 250, „Auf AEG“
Building 16, 2nd floor, room 16.2.12
90429 Nuremberg
Germany
Funded by Supported by
Thank you
Building – Energieeffiziente Systeme der Gebäudetechnik (Energy Efficient Building Systems) (Nuremberg Tech)
Gunnar Harhausen
Technische Hochschule Nürnberg | Nuremberg Tech
Energy and load flexible
buildings and production
facilities
Research Group
EnCN Effizienz
Energy Efficient Building Systems
Building – Energieeffiziente Systeme der Gebäudetechnik (Energy Efficient Building Systems) (Nuremberg Tech)
Equipment and Integration
• Research group EnCN Building - Energy Efficient Buildung Systems –
Prof. Dr. Arno Dentel
• with labs and offices at Energie Campus Nürnberg
• Research group at the Institute for Energy and Buildings (ieg) –
Prof. Dr. Wolfram Stephan
• Lab-Building with test benches for CHP, HP, climate chamber, …
• Embedded in the Faculty Mechanical Engineering and Building Services Engineering
at THN (Nuremberg Tech)
Seite 2
Building – Energieeffiziente Systeme der Gebäudetechnik (Energy Efficient Building Systems) (Nuremberg Tech)
Research Focus Building Services Engineering
Seite 3
Energy und load flexible buildings
Increase of the
energy efficiency
through system
integration
Simulation and
emulation models
Building automation
and management
Monitoring und
optimization of
buildings
• Decentralized
generator systems
• Heat pump systems
• Integral planning
methodes
• Hardware-in-the-Loop
• Systems for fault
dedection
• MPC in building
technologies
• Scientific monitoring
of demonstration
buildings
Building – Energieeffiziente Systeme der Gebäudetechnik (Energy Efficient Building Systems) (Nuremberg Tech)
Technische Hochschule Nürnberg Georg Simon Ohm
www.th-nuernberg.de
Seite 4
• 14 partners from 6 EU countries
(Finland, France, Germany, Portugal,
Spain, Great Britain)
• Overall project goal:
• Develop, demonstrate and
evaluate storage based energy
supply of buildings and
communities
• 3 demonstrators to present the
results This project has received funding
from the European Union's Horizon
research and innovation programme
under grant agreement no. 645963.
SENSIBLE Project
Building – Energieeffiziente Systeme der Gebäudetechnik (Energy Efficient Building Systems) (Nuremberg Tech)
Technische Hochschule Nürnberg Georg Simon Ohm
www.th-nuernberg.de
Seite 5
SENSIBLE Project
13 use cases:
Community Meadows / Nottingham
(UK)
Energy management and market
interaction of buildings with PV and
storage
Non-urban Microgrid in Évora
(PT)
Microgrid with PV, battery storage
container and a Home Energy System
Commercial Building in Nuremberg
(DE)
Energy management for multimodal
energy storage for commercial building.
PV, CHP, HP, building mass as storage,
buffer storage.
Building – Energieeffiziente Systeme der Gebäudetechnik (Energy Efficient Building Systems) (Nuremberg Tech)
Technische Hochschule Nürnberg Georg Simon Ohm
www.th-nuernberg.de
Seite 6
SENSIBLE Project
Coupling of local generator and storage devices with an online BEMS and a market platform
Building – Energieeffiziente Systeme der Gebäudetechnik (Energy Efficient Building Systems) (Nuremberg Tech)
Technische Hochschule Nürnberg Georg Simon Ohm
www.th-nuernberg.de
Seite 7
Herzo Base Project
The building(s) :
Terraced houses, 8 dwellings, 150 m² each Specific values
Heating and cooling power
• max. heat load: 22.7 kW
≈ 20 W/m²
Heating and cooling energy
• Heating energy: 23.4 kWh/m²a
• DHW: 18.5 kWh/m²a
PV Production
• PV: 86 MWh/a
• Peak: 98 kWp
Building – Energieeffiziente Systeme der Gebäudetechnik (Energy Efficient Building Systems) (Nuremberg Tech)
Technische Hochschule Nürnberg Georg Simon Ohm
www.th-nuernberg.de
Seite 8
Herzo Base Project
• 2 geothermal heat pumps
• 7 boreholes with free cooling
• 8 decentralized DHW heat pumps
• Thermal storage cascade
• Battery (common use)
• Control strategies
Advantages:
• Shift of electrical load peaks
• DHW hygiene and temperature
• Use of PV surplus
Energy Concept - Plant with common technical room
borehole
heat
exchanger
DHW
booster
DHW
storage
technical center
electric
storage
PV
collector
thermal storage
cascade
modulating
heat pumps
system
control
control
heat
pumps
domestic
electricity
Building – Energieeffiziente Systeme der Gebäudetechnik (Energy Efficient Building Systems) (Nuremberg Tech)
Geotabs Project
Seite 9
GEOTABS focus: Optimized control for GEO-HP + TABS in office buildings
heating and cooling loads in the administration building
• even balance in the ground
heating: high temperature level of the heat source (ground) and low exergy systems
(TABS - Thermally Activated Building Systems)
• high HP performance
cooling: high temperature level of the load transfer (TABS)
⇒ passive cooling
Building – Energieeffiziente Systeme der Gebäudetechnik (Energy Efficient Building Systems) (Nuremberg Tech)
Thank you for your attention!
Technische Hochschule Nürnberg Georg Simon Ohm
EnCN Building – Energy Efficient Building Systems
Prof. Dr.-Ing. Arno Dentel | Dipl.-Phys. Gunnar Harhausen
e-mail: arno.dentel@th-nuernberg.de | gunnar.harhausen@th-nuernberg.de
phone: +49 911/5880-3121 | +49 911/5880-3146
fax: +49 911/5880-7120 | +49 911/5880-7120
EnCN „Auf AEG“:
Fürther Straße 250
90429 Nürnberg
K:Standort Keßlerplatz am ieg:
Keßlerplatz 12
90489 Nürnberg
Seite 10
Workshop “Wallonia meets Energy Campus Nuremberg”,
Ottignies-Louvain-la-Neuve, Belgien, 09.-10.12.2019
“Highly heat insulating building materials”
Prof. Dr. Wolfgang Krcmar, Department of materials engineering
University of Applied Sciences Nuremberg
Fields of activities
• Highly heat-insulating building materials
• Bricks, mortar, thin-layer mortar, plaster
• Archive-concrete, prefabricated components
• Geopolymers
• Insulating materials (Nanofibers + Aerogels)
• Construction of energy-efficient buildings
• Energy-efficient building facades
• Recycling of building materials
• Heat-insulating coatings
• Easy-to-clean-effect on building materials
• FEM-simulations (heat- & noise insulation)
• Different laboratory testings
• Building-projects
Work group of Prof. Dr. Krcmar - Energy efficient building materials
Cooperation between the University of Applied Sciences Nuremberg with partners
in the Energie Campus Nuremberg – Joint research along the energy chain
Improvement of the thermal insulation: 35 %
Properties of CALOSTAT
• Diffusion coefficient µ = 6
• Hydrophobe; no water-absorption
• Minerally; incombustible
• Thermal conductivity l10, dr. = 0,019 W/(m*K)
Nanostructure
CALOSTAT-
brick
lequiv. = 0,041
Perlite-
brick
lequiv. = 0,07
CALOSTAT
Perlite-brick
lequiv. = 0,071
CALOSTAT-brick
lequiv. = 0,046
Brick-envelope
lequiv. = 0,345
Improvement: 41 %
Example 1: Herzo Base energy-storage buildings: Application of the
highly insulating material „CALOSTAT“ (silica fume SiO2) in wall-bricks
Example 1: Herzo Base energy-storage buildings
Energetic standard KfW 40 Plus
End of November 2016Plan of the architect
March 2017
Groundbreaking 14.07.2016
Roofing Ceremony 02.12.2016 Rear View Energy Storage Houses
Nov. 2017
Improvement
22,5 %
Ø Lowering the thermal radiation in the building material by 79 %
Ø Lowering the equivalent thermal conductivity by max. 30 %
Ø Optimization of the thermal insulation of the solo brick by max. 30 %
Ø Saving of primary energy for heating and cooling buildings
Ø Reduction of CO2-emissions for heating and cooling buildings
Improvement
28,4 %
Example 2: Optimization of the thermal insulation of building materials
by reduction of the thermal radiation
12 Brick types
Beschichtete Ziegelproben
Example 2: Optimization of the thermal insulation of building materials
by reduction of the thermal radiation
e without C. e with C. λeq, without C. λeq, with C. Reduction
[-] [-] [W/mK] [W/mK] [%]
1 0,96 0,25 0,11 0,09 21,60
2 0,96 0,36 0,14 0,13 9,00
3 0,95 0,30 0,11 0,10 6,79
4 0,96 0,19 0,12 0,10 16,26
5 0,95 0,28 0,16 0,14 13,71
6 0,94 0,27 0,13 0,09 27,54
7 0,94 0,27 0,20 0,15 25,03
8 0,96 0,31 0,17 0,11 33,30
9 0,95 0,30 0,15 0,11 23,90
10 0,96 0,31 0,17 0,15 14,38
11 0,96 0,36 0,14 0,13 9,13
12 0,95 0,31 0,15 0,11 24,85
Brick Type
Example 3: SiO2 – aerogel foam as insulation material
§ Thermal conductivity of silica aerogel zero samples : 0,023 W/mK
§ Thermal conductivity of fiber-modified silica aerogels : 0,021 W/mK
§ Distinctive hydrophobicity:
contact angle with "sessile
drop" method > 145°.
Modified silica aerogelAerogel zero sample Filling of wall building materials
Example 4: Development of high thermal insulation bricks with sound
insulation properties by means of FEM simulation and rapid prototyping
3D-printing of PLA based brick prototypes
„HV“ hole pattern
left: Original hole
pattern
right: Sound
insulation optimisation
Ø 400 % increase in absorbed sound
level without any loss of thermal
insulation
Ø Universally applicable to any hole
pattern
Ø Even minor changes of the hole
pattern have a big impact
Ø Production implementation is
possible
Brick with HV hole pattern,
365 mm
Zero sample:
λeq : 0,132 W/mk
Sound adsorption Rw: 44 dB
Brick with „sound-stop“ modification
λeq : 0,131 W/mk
Sound adsorption Rw: 50 dB
Example 5: New building and insulating materials from geopolymers
compressive strength
ß = 2 N/mm²
l10,tr. = 0,06 W/(m*K)
0,5 (Al2O3 · 2 SiO2) + 2 Na+ + 2 OH-
+ 2,5 H2O → 2 Na+ + (HO)3SiO-
+ [Al(OH)4]-
compressive strength
ß = < 120 N/mm²
1. High strength geopolymers
2. Foamed Geopolymers
Unfilled Foamed Geopolymer
Example 6: Improvement of thermal insulation of thin-bed mortar and
base plaster
Thin-bed mortar with fumed silica :
Ø Reduction of thermal conductivity by almost
29,0 %
Ø Compliance with the specified compressive
strength class M 10
Base plaster with pyrogenic silica :
Ø Reduction of thermal conductivity by
almost 29,0 %
Ø Simultaneous 49% increase in
compressive strength
Dimensions:
Ø Max. ground clearance
between base level
and the additive head
of 8 m
Ø Provides the ability to
erect decend 2-storey
buildings.
Example 7: Print houses – Additive manufacturing of buildings with the
mobile 3 D-printer ACR
Example 7: Additive Construction Robot (ACR)
Swiveling printer
arm on trolley
Transport
Installation, loading kinematics
Ø Project duration: 4 years
Ø Estimated costs: 2.1 Mio €, only for the German part
Ø Idea generator and designer
Ø 2 Research partners in Germany
R & D of highly insulating binder, highly strength binder,
composite materials (glass, carbon reinforced plastics,
demolition waste, mineral waste, geopolymers
Ø We have industrial partners in:
Germany, Switzerland, Austria
Ø We are looking for further potential partners
from other EU countries !
Ø Call: ICT-46-2020 „ROBOTICS“: 41 Mio. €
Ø Call: ICT-47-2020 „ROBOTICS“: 2-3 Mio. €
Searching for partners for the realisation of a EU - research project, e.g:
Ø R & D with energy-efficient building- and insulation materials
Ø R & D with Recycling-materials
Ø Construction of highly insulated, energy-efficient houses
Ø Construction of an energy-efficient building complex
Ø Construction of an energy self-sufficient settlement
My Goals for this workshop
Contact address:
Energie Campus Nürnberg
Prof. Dr. Wolfgang Krcmar
Fürther Strasse 250 („auf AEG“)
D – 90429 Nürnberg
Tel.: +49 911 / 5880 3110
Fax: +49 911 / 5880 7110
wolfgang.krcmar@th-nuernberg.de
www.encn.de
Thank you for your attention !
© Bayerisches Zentrum für Angewandte Energieforschung e. V.
Alle Rechte vorbehalten, auch bezüglich jeder Verfügung, Verwertung, Reproduktion, Bearbeitung und Weitergabe sowie für den Fall von Schutzrechtanmeldungen.
ZAE Bayern – Solar Factory of the Future
Dr. Andreas Distler
9.12.2019
© ZAE Bayern 2
ZAE Bayern – Mission & Vision
Since 1992:
Research & Development
Education
Application
Consulting & Information
In all fields of energy research.
Our goal:
Realization of a CO2-neutral energy supply
by means of a synergetic use of renewable
energy sources and efficient technologies.
SFF
Research Along
the Value Chain
Technology Pipeline:
University
(Basic Science)
SFF
Industry
(Application)
Organic / Printed Photovoltaics
Technology:
• Low-light and diffuse light performance
• Shadowing tolerance
• Positive temperature dependency
Design:
• Transparency
• Color
• Freedom of shape
Integration:
• Thin
• Lightweight
• Flexible
3
The Magic Square of PV
Efficiency
CostLifetime
0%
20%
40%
60%
80%
100%
120%
140%
NormalizedEfficiency
Gen1, Lowell Rooftop
Gen 2, Lowell rooftop
Gen2, South Florida
Design
Solar Factory of the Future –
Cost Reduction by R2R Processing
The Concept
P3HT:PCBM PV2000:PCBM P3HT:O-IDTBR
Roll to Roll printing
Roll to Sheet laminationRoll to Roll Bus Bar lamination
 450 cm²
 20 cell in series
 Semi transparent
 encapsulatedRoll to Roll laser patterning
High-throughput OPV Manufacturing
Equipment at the
“Solar Factory of the Future” (SFF)
High volume
Combination of Silver Nanowire Electrodes
and Laser Patterning  Semi-transparency
- high geometric fill factor (>95%)
- semitransparent
- no visibly obstructing electrodes
and interconnects
Inkjet Printed Solar Cells
 now also on 3D-surfaces by means of a 5-axis robot
© Bayerisches Zentrum für Angewandte Energieforschung e. V.
Alle Rechte vorbehalten, auch bezüglich jeder Verfügung, Verwertung, Reproduktion, Bearbeitung und Weitergabe sowie für den Fall von Schutzrechtanmeldungen.
 30% / 35% higher than the previous world records!
The Solar Factory of the Future Sets
New World Records for OPV Modules
© Bayerisches Zentrum für Angewandte Energieforschung e. V.
Alle Rechte vorbehalten, auch bezüglich jeder Verfügung, Verwertung, Reproduktion, Bearbeitung und Weitergabe sowie für den Fall von Schutzrechtanmeldungen.
Nuremberg, October 2019
PCE = 12.6%
on 26 cm²
PCE = 11.7%
on 204 cm²
Energy Harvesting and Lifetime Studies
© Bayerisches Zentrum für Angewandte Energieforschung e. V.
Alle Rechte vorbehalten, auch bezüglich jeder Verfügung, Verwertung, Reproduktion, Bearbeitung und Weitergabe sowie für den Fall von Schutzrechtanmeldungen.
0 100 200 300
0.0
0.5
1.0
NormalizedPCE
Time (h)
Sun test
Damp heat
Feasibility Studies
© Bayerisches Zentrum für Angewandte Energieforschung e. V.
Alle Rechte vorbehalten, auch bezüglich jeder Verfügung, Verwertung, Reproduktion, Bearbeitung und Weitergabe sowie für den Fall von Schutzrechtanmeldungen.
Feasibility Studies
© Bayerisches Zentrum für Angewandte Energieforschung e. V.
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Prototyping
© Bayerisches Zentrum für Angewandte Energieforschung e. V.
Alle Rechte vorbehalten, auch bezüglich jeder Verfügung, Verwertung, Reproduktion, Bearbeitung und Weitergabe sowie für den Fall von Schutzrechtanmeldungen.
Future Projects and Collaborations?
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Alle Rechte vorbehalten, auch bezüglich jeder Verfügung, Verwertung, Reproduktion, Bearbeitung und Weitergabe sowie für den Fall von Schutzrechtanmeldungen.
SFF Core Competencies:
 Manufacturing of printed electronic devices (especially photovoltaics,
OPV/Perovskite) on a large scale (roll-to-roll)
 Developing printed high-performance barriers
 Device characterization and inspection
 Lifetime studies & PV monitoring
 Prototyping & Application
Fields of Interest / Potential Future Collaborations:
 Anything related to photovoltaics or printed electronics
 Direct coupling of printed PV modules with other electrical
components (sensors, transmitters, capacitors, batteries, …)
or various energy storage technologies
 Functionalization of any surface (also 3D objects)
 Printable high-barriers
Thank you very much for your kind attention
Dr. Andreas Distler
ZAE – Solar Factory of the Future
© Bayerisches Zentrum für Angewandte Energieforschung e. V.
Alle Rechte vorbehalten, auch bezüglich jeder Verfügung, Verwertung, Reproduktion, Bearbeitung und Weitergabe sowie für den Fall von Schutzrechtanmeldungen.
www.encn.de
Gefördert durch Unterstützt durch
Liquid Organic Hydrogen Carriers
…taking Hydrogen everywhere
Stefan Dürr, M.Sc.
Seite 2
www.encn.de
Why is hydrogen seen as the fuel of the future?
In future, hydrogen is supposed to be used for smoothing electricity
feed-in from renewable energies. But it is not only a buffer in times
of high demand or supply, it is also able to connect different
branches of industry or even society: power, industry, heat,
chemical production and mobility can all be fuelled by hydrogen.
Seite 3
www.encn.de
And where’s the problem now?
[1] https://www.engineeringtoolbox.com/docs/documents/1419/Hydrogen%20phase%20diagram.jpg
[2] Foto: © Gerhard-Hofmann, Agentur-Zukunft
[3] Claus Ableiter – own work, CC BY-SA 4.0, https://commons.wikimedia.org/w/index.php?curid=3541402
[1]
[2]
[3]
Critical point:
pc = 13.30 bara
Tc = 33.18 K
Seite 4
www.encn.de
Hydrogen transport made easy
- The LOHC-technology
[1] S. Dürr (2015), Untersuchung der Hydrierung von Dibenzyltoluol mit H2/CH4-Gasgemischen, Masterarbeit, Lst. F. Chemische
Reaktionstechnik
[2] https://www.hafen-hamburg.de/images/image_cache/images/800x533/fotos/schiffe/9365623.jpg
[3] http://www.unitank.de/eng/images/emleben-luftbild.jpg
[4] http://www.bahnbilder.de/1024/1116-149-mit-einem-gueterzug-629234.jpg
[5] https://t4.ftcdn.net/jpg/00/54/28/77/240_F_54287709_IxzEErROnx0cOwu5hTjCY2mQcnpQlWzt.jpg
[1]
[5]
[4]
[3]
[2]
Seite 5
www.encn.de
Hydrogen transport made easy
- The LOHC-technology
High hydrogen capacity
• 6.2 wt% (56 gH2/L)
• 1.75 kWhLHV/kgH18-DBT = 7.43 MJLHV/kgH18-DBT
• 1.58 kWhLHV/LH18-DBT = 6.72 MJLHV/LH18-DBT
Non-toxic, no dangerous good in terms of
transportation regulations (no „UN-Nr.“)
Non-flammable
No hydrogen release without catalyst present
Extensively used as a heat-transfer agent
• High level of experience
• World-scale production capacities
• Cheap market-price
2,6-Dibenzyltoluene
(as an example, the actual
fluid is a mixture of multiple
isomers)
Seite 6
www.encn.de
Hydrogen transport made easy
- The LOHC-technology
Compressed
H2
LOHC
Total weight 250 kg 50 kg
Total volume 150 L 50 L
Comparison: Storage of 3 kg hydrogen via
compressed H2 (300 bar) or LOHC
2170 kgH2
400 - 950 kgH2
(300 bara)
Seite 7
www.encn.de
Hydrogen transport made easy
- The LOHC-technology
[1] S. Dürr (2015), Untersuchung der Hydrierung von Dibenzyltoluol mit H2/CH4-Gasgemischen, Masterarbeit, Lst. F. Chemische
Reaktionstechnik
[2] https://www.hafen-hamburg.de/images/image_cache/images/800x533/fotos/schiffe/9365623.jpg
[3] http://www.unitank.de/eng/images/emleben-luftbild.jpg
[4] http://www.bahnbilder.de/1024/1116-149-mit-einem-gueterzug-629234.jpg
[5] https://t4.ftcdn.net/jpg/00/54/28/77/240_F_54287709_IxzEErROnx0cOwu5hTjCY2mQcnpQlWzt.jpg
[1]
[5]
[4]
[3]
[2]
p = 10 – 50 bara
T ≥ 160 °C
ΔHR= - 65.4 kJ/molH2
Ru, Pt on alumina / carbon
p = 1 - 5 bara
T ≥ 280 °C
ΔHR= 65.4 kJ/molH2
Pt on alumina
Seite 8
www.encn.de
General aspects of LOHC research
Nanoscale:
Optimizing the
active catalytic site
Mesoscale:
Optimizing mass
transfer at the catalyst
pellet level
Operando spectroscopies,
microscopies, on-line
monitoring
Reactor scale:
Optimizing mass
and heat transfer
Storage unit scale:
Optimizing heat
integration aspects
Theory & simulation:
DFT, CFD, mass & heat
balances
Preuster, Papp, Wasserscheid, Accounts of
Chemical Research, 2017, 50(1), 74-85.
General: Design and test other LOHC systems
Seite 9
www.encn.de
Current research topics of CRT @ EnCN
• Heat integration
• Dynamic behavior
• Overall efficiency
• Long-term stability of
LOHC- and catalytic
system
• Compact reactor systems
• on-vehicle gas separation
• Fuel cell systems
• Transfer Hydrogenation
• Membrane Development
• Electrode Development
• Lower dehydrogenation
temperature
• New catalytic systems
• Pt-efficiency
• Hydrogen quality
• Cost reduction
• Performance density
Dynamic local storage Mobility solutions Hydrogen supply
Seite 10
www.encn.de
Partners
A joint project of Fraunhofer IISB, Fraunhofer
IIS and Friedrich-Alexander-University
Erlangen-Nürnberg
Seite 11
www.encn.de
On-site storage scenarios:
• Highly dynamic
behaviour
• Heat storage possible
• Efficient peak shaving
• Flow-battery-like setup
enables taylor-made
solutions
• High capacity
• High hydrogen
output
X
Further developments – the oneReactor
Seite 12
www.encn.de
Further developments – the oneReactor
On-site storage scenarios:
• Highly dynamic
behaviour
• Heat storage possible
• Efficient peak shaving
• Flow-battery-like setup
enables taylor-made
solutions
• High capacity
• High hydrogen
output
Seite 13
www.encn.de
Further developments – the oneReactor
In cooperation with
A joint project of Fraunhofer IISB, Fraunhofer IIS and
Friedrich-Alexander-University Erlangen-Nürnberg
Seite 14
www.encn.de
Further developments – direct LOHC fuel cell
Is it possible to skip the
release-step?
• No gaseous hydrogen
• Less equipment needed
• Directly fuel mobile
applications
Is it possible to build
Dibenzyltoluene Fuel Cells?
• Mass transfer issues
• Low power densities
• No suitable equipment
Seite 15
www.encn.de
Further developments – direct LOHC fuel cell
Catalytic hydrogen transfer to other
molecules is feasible
• Surface reaction, thus no
gaseous hydrogen
• Thermoneutral reaction vs.
Highly endothermic
dehydrogenation
• Direct fuel cells using smaller
organic molecules do exist
Catalytic Hydrogenation
Exothermic
@ 160 – 300 °C
Catalytic Transfer
Hydrogenation
Nearly thermoneutral
@ 150 – 230 °C
ΔHR = - 65 kJ/molH2
Direct Isopropanol Fuel Cell
(PEM)
Exothermic
@ 80 - 90 °C
Seite 16
www.encn.de
Further developments – direct LOHC fuel cell
New process design for
heavy-duty mobile
applications
Seite 17
www.encn.de
Further developments – direct LOHC fuel cell
Isopropanol Oxygen
WaterAcetone
Flow Field
Gas Diffusion Layer
Catalyst (electrochemical)
Proton Exchange Membrane
Copper Foil
Hydrogen Membrane
Catalyst (Isopropanol oxidation)
Direct Methanol Fuel Cell –
Baltic Fuel Cells
Current research (CRT / HI-ErN):
• Catalyst and catalyst support materials for Isopropanol oxidation
• Hydrogen membrane Materials
Seite 18
www.encn.de
Further developments – direct LOHC fuel cell
LOHC as alternative fuel especially suitable for
heavy duty applications (long range, high power)
• Ships
• Trains
Project in Bavaria since 2019 (2019-2023)
• LOHC-powered local transport train
• On-board hydrogen release and power
recovery in a fuel cell
• Development of a „LOHC-Powerpack“ that can
supply energy to a diesel-electric-train
• Thus old local transport trains can still be used
• Also focus on new technologies e.g. Direct
LOHC fuel cell
Seite 19
www.encn.de
Further developments – the oneReactor
Development of a highly flexible catalyst system
• Modification of a Pt catalyst through doping with Nitrogen and Sulfur to block the
most active centers and facilitate desorption of reaction products
Seite 20
www.encn.de
And where’s the problem now?
How much hydrogen can this
truck carry?
350 kg
Fuel tank size Toyota Mirai
5 kg
Which means…
à only 70 fuelling processes
[1] Foto: © Gerhard-Hofmann, Agentur-Zukunft
[2] Von Mirai.PNG: Maskrosenderivative work: Mariordo - Diese Datei wurde von diesem Werk abgeleitet: Mirai.PNG:, CC BY-SA
4.0, https://commons.wikimedia.org/w/index.php?curid=36965785
[1]
[2]
Seite 21
www.encn.de
[1] https://t4.ftcdn.net/jpg/00/54/28/77/240_F_54287709_IxzEErROnx0cOwu5hTjCY2mQcnpQlWzt.jpg
[2] Von Mirai.PNG: Maskrosenderivative work: Mariordo - Diese Datei wurde von diesem Werk abgeleitet: Mirai.PNG:, CC BY-SA
4.0, https://commons.wikimedia.org/w/index.php?curid=36965785
[1] How much hydrogen can this
truck carry?
2170 kg
Fuel tank size Toyota Mirai
5 kg
Which means…
à 434 fuelling processes
[2]
Hydrogen transport made easy
- The LOHC-technology
Introduction
-
HFCVD-Diamond Coatings
Maximilian Göltz, Stefan Rosiwal, Carolin Körner
Chair of Materials Science and Engineering for Metals (WTM)
Department of Materials Science
Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU)
09.12.2019Maximilian Göltz, Chair for Metals: HFCVD-Diamond Coatings
Department Materials Science
• Largest in Germany
• 9 chairs
• 18 professors, 270 staff
• 600 students
Chair of Materials Science and Engineering for Metals (WTM)
• 5 research groups – 50 staff members:
• Additive Manufacturing
• Modelling and Simulation
• Lightweight Materials
• High Temperature Alloys
• Ultra-hard Coatings
Associated institutes
2
Department and Chair WTM
Part of the department – WTM in second floor
09.12.2019Maximilian Göltz, Chair for Metals: HFCVD-Diamond Coatings
Fields of Activity
• Process technology
• Alloy development
• Characterisation
Equipment
• Electron-beam machines (Ni, Cu)
• Laser-beam machines (Ti)
Applications
• “Impossible structures”
• Catalyst support
• Single crystal turbine blades
• Meta-structures
3
Additive Manufacturing
Chemical reactors with integrated catalyst support and cooling
5 cm
Microstructure of additively produced copper
09.12.2019Maximilian Göltz, Chair for Metals: HFCVD-Diamond Coatings
Fields of Activity
• Process technology
• Alloy development
• Tool certification
Equipment
• SAMPLE, ThermoCalc, CALPHAD,
DICTRA, cellular automata, Flow-3D
Applications
• Alloy development
• process strategies
• Microstructure predictions
• Lightweight Al-foams
4
Modelling and Simulation
Meltpool at SEBM process in the particle bedMetal foam simulation
Simulation of additive manufacturing process
09.12.2019Maximilian Göltz, Chair for Metals: HFCVD-Diamond Coatings
Fields of Activity
• Cold chamber casting
• Foam casting
• Alloy development
Equipment
• Frech DAK 450-54
• Impeller and dosing robot
Applications
• High pressure die-casting
• Cellular structures
• Reinforced alloys
• Prediction of local properties
5
Lightweight Materials
Sample of integral foam die-casting of aluminumMetal foam simulation
Aluminum die-casting machine by Frech
09.12.2019Maximilian Göltz, Chair for Metals: HFCVD-Diamond Coatings
Fields of Activity
• Single crystal solidification
• Metal powder injection molding
• Alloy development – Ni-base superalloys
Equipment
• Two Investment casting units
• Vacuum Arc furnace
Applications
• Alloy development
• process strategies
• Microstructure predictions
6
High Temperature Alloys
Metal powder for injection molding
Nickel-base superalloy casting plant for 10kg samples
09.12.2019Maximilian Göltz, Chair for Metals: HFCVD-Diamond Coatings
Fields of Activity
• Process development diamond CVD
• Interlayer development - TiN
• Diamond against mechanical wear
• Boron-doped diamond (BDD) electrodes
Equipment
• MW-,HF- and HW- CVD machines
• Sputter machine
Applications
• Slip seals
• Water disinfection and cleaning
• Medical treatment
• Alumium die-casting
7
Ultra-Hard Coatings - Diamond
HFCVD process with glowing filaments and sampleMicrobiological results of water disinfection with BDD
HFCVD-machines for diamond coating
0 min 15 min 60 min
09.12.2019Maximilian Göltz, Chair for Metals: HFCVD-Diamond Coatings 8
Diamond – Electrochemical Water Treatment
Electrochemical treatment of landfill leachate by BDD: The organic parts are destroyed by OH-radicals, anorganic is deposited cathodically
t=0.0 t=1h t=2h anode cathode
Electrochemical window of diamond vs Pt
OH-radicals
Background
• BDD shows large potential window of 3.5 V
• formation of OH-radicals at anode
• disinfection and destruction of organic
• deposition of metals on cathode
Application
• Landfill leachate
• 3rd stage in sewage plant – multi resistancies
• Oil- and fracking water
• ballast water of big ships
09.12.2019Maximilian Göltz, Chair for Metals: HFCVD-Diamond Coatings 9
Diamond – Electrochemical Medical Treatment
Application of BDD coated tools or implant to disinfect inflammations by electrochemical treatment
Background
• Inflammation of implants
• 10% of all implants affected
• Dental infections
Application
• Coating of implants and medical tools
• Degradation of cell membranes
• In-vitro tests successful
1 µm
before after BDD
Candida
Dubliniensis
2 cm
diamond coated wire
with anodic potential
Degradation of Candida D. cell after BDD treatment
09.12.2019Maximilian Göltz, Chair for Metals: HFCVD-Diamond Coatings
Background
• Aluminum shows a non-wetting behaviour on diamond
• “Non-stick” – coating against liquid metal
• Standard materials are etched and eroded by melt
• Lifetime and surface quality greatly enhanced
Application
• Die-casting tools
• Cold-working of aluminum
• Welding of Aluminum
10
Diamond – Aluminum Die-Casting Tools
Non-wetting of Al on WC and diamond – this is used for die-cast tools to enhance life time and surface quality. For steel an interlayer is needed.
1 mm 1 mm
Al on WC
Al on
diamond
Steel
TiN
diamond
09.12.2019Maximilian Göltz, Chair for Metals: HFCVD-Diamond Coatings
Thank You
Please do not hesitate to aks!
11
09.12.2019Maximilian Göltz, Chair for Metals: HFCVD-Diamond Coatings
• diamond on steel has a high industrial impact, thin coatings already applied:
• aluminum die-casting
• welding
• tribological application
• against mechanical wear thick coatings are neccessary
12
Motivation
Thin diamond coating on steel tools are applied in industry. [Rosiwal2017]
10 cm
09.12.2019Maximilian Göltz, Chair for Metals: HFCVD-Diamond Coatings
• diamond on steel has a high industrial impact, thin coatings already applied:
• aluminum die-casting
• welding
• tribological application
• against mechanical wear thick coatings are neccessary
𝜎𝑡ℎ𝑒𝑟𝑚𝑎𝑙 =
𝐸 𝑑𝑖𝑎𝑚𝑜𝑛𝑑
1 − 𝜈
𝑇 𝑎𝑚𝑏𝑖𝑒𝑛𝑡
𝑇 𝑐𝑜𝑎𝑡𝑖𝑛𝑔
𝛼 𝑠𝑡𝑒𝑒𝑙 − 𝛼 𝑑𝑖𝑎𝑚𝑜𝑛𝑑 𝑑𝑇
𝜎𝑡ℎ𝑒𝑟𝑚𝑎𝑙 - thermal stresses
𝐸 𝑑𝑖𝑎𝑚𝑜𝑛𝑑 - Youngs modulus of diamond
𝜈 - Poisson ratio
𝑇𝑐𝑜𝑎𝑡𝑖𝑛𝑔 - coating temperature
𝑇𝑎𝑚𝑏𝑖𝑒𝑛𝑡 - room temperature
𝛼 𝑠𝑡𝑒𝑒𝑙 - thermal expansion coefficient of steel
𝛼 𝑑𝑖𝑎𝑚𝑜𝑛𝑑 - thermal expansion coefficient
• differences in thermal expansion cause thermal stresses
• typical values around -7 GPa
13
Motivation
Delamination of a thick diamond coating
from a TiNB coated steel sample.
09.12.2019Maximilian Göltz, Chair for Metals: HFCVD-Diamond Coatings
Substrate: Steel X46Cr13 (1.4034)
Surface Pretreatment
• particle blasting
• allow for mechanical adherence
Interlayer
• titanium nitride
• hot-wall CVD at 1030 °C
Diamond Coating
• seeding before coating
• hot-filament CVD at ~900°C
• steel hardening by Helium-quenching
14
Standard Coating Process
Aluminum die-casting tools at different process steps with surface micrographs.
5 cm
09.12.2019Maximilian Göltz, Chair for Metals: HFCVD-Diamond Coatings
CVD Diamant auf Stahl – Zwischenschicht
SURMETAL Heißwand CVD Beschichtungsanlage - Standort Fürth
• Reaktanten: H2, N2, TiCl4, BCl3, CH4, TaCl5
• Beschichtungstemperatur: Bis zu 1030°C
• Druck: 80 - 800 mbar
• Max. Bauteilgröße: D x l = 200 mm x 800 mm
 Titannitrid (bordotiert)
09.12.2019Maximilian Göltz, Chair for Metals: HFCVD-Diamond Coatings
TiNB-Zwischenschicht als Diffusionsbarriere
Bordotiertes Titannitrid erfüllt die Anforderungen
J.C. Bareiβ et al.: CVD diamond coating of steel on a CVD-TiBN interlayer, Surface & Coatings Technology 201: 718–
723, 2006.
Interdiffusionszone zwischen dem Stahlsubstrat und der Diamantschicht
verhindert die Fe3C Bildung
• Gute Anbindung an das Stahlsubstrat
• Abscheidung bei über 1000°C gewährleistet die thermische Stabilität im
Diamantprozess
09.12.2019Maximilian Göltz, Chair for Metals: HFCVD-Diamond Coatings
Phase I Phase II Phase III
unused tops severed Plateaus form
17
Run-in behaviour
[Schiegerl 19]
Titannitride layer
Steel
Diamond layer
09.12.2019Maximilian Göltz, Chair for Metals: HFCVD-Diamond Coatings 18
Running behaviour
[Schiegerl 19]
sandblast titannitrit diamond
0
5
10
15
20
25
30
35
40
45
50 in front of graphite plate
in front of graphite plate
free hanging
free hanging
flatnessinµm
~8
%
~5
%
~8
%
Unbalanced wear
 Real load is much higher
John Cockerill
Hydrogen Solutions
▪︎ 1
Dr. Sebastien J. Borguet
R&D Manager
Meeting with Energy Campus Nuremberg
December 9, 2019
John Cockerill, a 200-year-old engineering group fully
committed to provide solutions for energy transition
▪︎ 2
Concentrated Solar Power Wind turbine maintenance
Micro-grids and batteries Electrolytic hydrogen
… and for energy efficiency
▪︎ 3
Reheating furnace
Thermal and surface treatment
Heat recovery steam generators
Water and air/gas treatment
A group with a global presence
A private, independent Group
Bernard Serin
Chairman of the Board
since 2002
Turnover: 1 297 M€
Operating results: 86.1 M€
Global workforce: 5 566
Safety performance: LF = 3.08
LS = 0.15
(data for FY 2018)
STEAM
METHANE
REFORMING
OIL
CRACKING
COAL GASIFICATION
INDUSTRY BY-PRODUCT
WATER
ELECTROLYSIS
Hydrogen in a nutshell
6
Hydrogen is the most present element in the
universe, at the basis of life on earth
Hydrogen is the lightest and smallest atom – one
electron and one proton
Hydrogen does not exist naturally – only combined
in molecules like water
In the form of dihydrogen H2 , it is an energy vector
that allows storage over long periods
Hydrogen allows sector coupling between power
generation, mobility, heating and industry
FOSSIL
SOURCES
~10KG
CO2 FOR
1KG H2
H2 industrials uses by sector (68 Mtons/year)
Chemical industries: 63%
Refining: 30%
Metal: 6%
Other industries: 1%
Share of H2 generation
Alkaline water electrolysis 101
7
Main advantages
Proven, simple, mature and reliable
Long lifetime (> 90 000 hours)
No precious materials  less expansive
Large capacity stacks (up to 5+MW)
Working pressure up to 30 bars
Main drawbacks
Lower power density at stack level
Large volume of corrosive electrolyte
Longer cold start-up time
Higher minimum turndown at stack level (20-40%)
ANODE
CATHODE
MEMBRANE
ELECTROLYTE
H2O2
+ -
DC ELECTRICITY
H+OH-
water + power  oxygen + hydrogen + heat
John Cockerill: a proven experience in water electrolysers
8
More than 1000 references around the world
Customers in industries as various as
/ chemicals
/ glassmaking
/ silicon (PV panel manufacturer)
/ steelmaking
/ power plants
Brand new workshop with an annual production
capacity of 350+MW located in Suzhou (Shanghai
area)
John Cockerill in the H2 Value Chain
9
DEMISTER
STACK
H2O2
TRANSFORMER
RECTIFIER
UNIT (TRU)
PURIFICATION
UNIT
DRYER
STORAGE
COMPRESSORS
ELECTROLYZING
UNIT
SMART MICRO GRID WITH BATTERIES
EMS
ELECTROLYTE LYE
TANK
COMPRESSOR
& STORAGE
OPTIMISED DISTRIBUTION
UNIT
INDUSTRIAL
PROCESSES
TO GAS GRID - BLENDING
SAFETY STORAGE – 200BAR
TO INDUSTRY – 200BAR
MOBILE DISPENSER
700 BAR
350 BAR
H2
O2
Evolution of the unit capacity of our electrolysers
to meet increasing demand of decarbonised H2
10
60 Nm³/h 200 Nm³/h 375 Nm³/h 600 Nm³/h 1000 Nm³/h 1500 Nm³/h
1992 1994 2005 2009 2015 2018
Turning to 100+MW units to address large industry needs
11Source : EU 2018, JRC Technical Reports
OIL REFINERY
• Average refining capacity of
10,4MT oil per year
• Requires 50 ktons H2
• 340MW electrolyser
• EU : 24 GW
• World - 98 Mbbl/day : 142
GW
STEELMAKING PLANT
• 3MWh of electrolysis for 1
ton of steel
• Average production plant
of 4MT/year
• 1,2GW of electrolysis
• European production of
168MT : 51GW
• Global steel production of
1700MT: 515 GW
AMMONIA PLANT
• Average plant capacity of
800kT per year requires
144k tons H2
• ~8TWh of electrolysis per
year
• 0,9-1 GW electrolyser
• EU production of ~20MT
per year: 25 GW
• World production of 180-
200MT per year: 225-
250GW
Introducing the world’s largest single-stack alkaline
electrolyser: 1 500 Nm3/h (7.5 MW)
12
TDQ-1500/1.6
H2 output (Nm³/h) 1,500
O2 output (Nm³/h) 750
System pressure (bar) 16
H2 purity (%) 99.9
O2 purity (%) 99
Stack dimension (mm) 7160 x 2014 x
2086
DC current (A) 16400
DC voltage (V) 440
DC consumption (kWh/Nm³) ≤ 4.6
John Cockerill to supply Hydrogen to 85 Fuel Cell
Buses at the Beijing Olympics 2022
13
2.5 tons H2 / day
Overview of our latest large-scale installations
in operation
14
Capacity (Nm3/h) Power (MW)
1 x 500 2.5
3 x 300 4.5
5 x 250 6.25
2 x 1000 10
4 x 600 12
6 x 500 15
Skid-mounted purification units up to 3000 Nm3/h
to produce 99.999 %vol H2
15
HIGH HYDROGEN PURITY (UP TO 99.999%)
3-step process
- O2 removal with Pd catalyst
- H2O removal with chilled water
- Final H2 drying with self-regenerating
molecular sieve
SEP 19 16
HaYrport : a multi-modal refueling station at Liege Airport
COMPRESSORS
AIRPORT HEAT
NETWORK
HaYrport: schematic design
17
ELECTROLYZING UNIT
HEAT
SOLAR PV
GRID
WATER
BACK-UP
H2O2
H2
H2
H2
H2
H2
H2
INDUSTRIES
A I R S I D E
L A N D S I D E
PRODUCTION DISTRIBUTION
Sizing and optimizing the design of H2 refuelling stations
with our in-house software
18
refuelling
 fast
 compliant to SAE refueling protocol
 high state of charge
station optimization
 reduced capex
 reduced opex
Sebastien Borguet
Sebastien.borguet@johncockerill.com
John Cockerill (Headquarters)
Avenue Greiner 1
4100 Seraing
Belgium
T. +32 4 330 2444
F. +32 4 330 2582
welcome@johncockerill.com
johncockerill.com
John Cockerill
Hydrogen Solutions
▪︎ 19
DR IR MARC FOGUENNE
VP TECHNOLOGY AND INNOVATION,
BUILDING AND INDUSTRIAL DIVISION
DECEMBER 09, 2019
THE ENERGY CHALLENGE : A TRIGGER OF
AMBITIOUS AND INNOVATIVE PROJECTS
Confidential
AGC: Business Overview
2
Building & Industrial
Glass
48%
of sales
Electronics 16%
of sales
Chemicals 31%
of sales
(*) Ceramic / Other : 5%
N°1 glass producer Leading positions
• External glass
• Decorative glass
• Glass for high tech applications
• Original Equipment Manufacturer (OEM)
• Automotive Replacement Glass (ARG)
• Display
• (LCD and PDP glass substrates)
• Electronic materials
• Fluorochemicals & specialty chemicals
• Chlor-alkali & urethane
• Life science
Automotive
Glass
&
AGC Glass Europe Confidential
AGC Glass Europe at a glance
• 2 business segments:
− Glass for Buildings & Industry
− Glass for automotive Automotive
• R&D center and Headquarters in Belgium
• 1 car out of 4 glazed by AGC
• Nearly 1 building out of 4 with AGC coated glass
• 16,080 people in Europe
• € 2.5 bn sales (2018)
3
4
• Gosselies : 279 people
ü 176 Researchers/ University degrees – 97 employees – 6 blue collars
ü 19 different nationalities at Gosselies
• Lauenförde (GE) : 35 people
• 2 Technology transfer offices (Aniche, France – Mol, Belgium)
VISION : Glass creates emotions by connecting people to their environment
AGC Glass Europe Confidential
AGC TECHNOLOGY & INNOVATION VISION
5
/ Combination & Hybridation
/ Creativity
/ Conversion Rate
/ Expertise
/ Speed
/ Value creation
Sustain & Grow
https://www.agc-glass.eu/en/innovation
Innovation
AGC Glass Europe Confidential 6
DEVELOPPING OUR STRONG PILARS
COATING– DECO - FRG
INDUSTRIAL– WINDOW
Supported by Digitalization
SustainGrow
SUPPORTING STRONG FOUNDATION
PLANT SUPPORT / CRP
SMART FACTORIES
FLEXIBLE & GREEN TECH.
Supported by INDUSTRY 4.0
Innov
SMART CITIES
SUSTAINIBILITY / INTERACTIVITY /
CONNECTIVITY /MOBILITY
NEW TECHNOLOGIES
HOLLOW CATHODE
ION IMPLANTATION
PTW
27%
24%
49%
AGC Glass Europe Innovation strategy
Confidential 7
Total CO2balance for the glass industry
1
12
q Many glass products have a positive
impact on the CO2 emission during their
use because they contribute to energy
saving
§ Insulating & solar control glass units
§ Solar applications
o Photovoltaic panels
o Mirrors
o Greenhouses
§ Automotive glazing
§ Chilled display cabinets/Freezers
§ Availability of daylight vs artificial
lighting
q Direct CO2 emitted from fossil
fuel used
q CO2 emitted from electricity
consumption
q All other indirect sources of
emissions upstream &
downstream (raw material
production, transportation,
waste, products end of life, etc.)
q Actions
§ continuous efforts and
development
§ implement best practices
§ reduce specific
consumption
§ improve melting technology
Results : 0.61 T CO2/T Glass
-> 0.47 T/T= -23%
Manufacturing
processes
products
Energy
production
Confidential
Next generation of Factories
8
AGC Glass Europe Confidential 9
FINEO – Vacuum insulating glazing
ü 2 single glass panes separated by a vacuum space of 0.1mm and micro-spacers
ü Dedicated to renovation and new buildings
ü Produced in AGC Lodelinsart
Belgian Environment & Energy Awards 2019
Confidential
Introducing natural light on-demand
10
HALIO OFFERS THE ULTIMATE IN COMFORT W/O COMPROMISING ON PERFORMANCE & AESTHETIC
from Clear… to Dark… and In-
Between…
Seamlessly
Transition
< 3
minutes
FUTURE-PROOF SYSTEM THROUGH ITS CLOUD CONNECTION
0.1%
light
transmission
Unlimited
intermediate
tint levels
Confidential
66%
light
transmission
Confidential 11
Confidential
Decarbonizing electricity grid
12
ENERGY
GENERATION
DISTRIBUTED RENEWABLES CENTRALIZED RENEWABLES
Glass solutions for ZEB: Building Integrated PV
o BIPV for zero emission and positive energy building
o Future solutions to improve aesthetic and financials
o Toward invisible and transparent BIPV
Solar Mirrors for CSP
o Potential in some areas
o Storage advantage
o Cost challenge
Confidential 13
Active facades
SOLAR CELLS
14
PEOPLE SAY THINGS
ARE IMPOSSIBLE
Because they
donʼt
DARE TO TRY
Confidential 15
Source : LeSoir.be
AGC BRINGS
CONCRETE ANSWERS
TO
SOCIETAL CHALLENGES.

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Wallonia Meets Energy Campus Nürnberg | LLN - 09 décembre 2019

  • 1.
  • 2. Introduction • Cédric Brüll (Managing Director of TWEED Cluster) - Energy Walloon Ecosystem • Dr. Alexander Buchele (Managing Director of Energy Campus Nürnberg) - Overview of the EnCN Delegation of the Energy Campus Nuremberg • Prof. Dr. Arno Dentel (TH Nürnberg) – Building Technology • Prof. Dr. Wolfgang Kcmar – Building Materials • Dr. Andreas Distler – Organic/Printed PV • Stefan Dürr – Hydrogen Storage • Dr. Maximilian Göltz – Materials Challenges for the Walloon industries • Dr. Sébastien Borguet (Head of R&D - John Cockerill) – Hydrogen technology John Cockerill • Dr. Marc Foguenne, (Technology and Innovation Director, AGC Glass Europe). – “ The Energy challenge : a trigger of ambitious and innovative projects.”
  • 4. From Sustainable Energy Technologies Cluster TWeeD -- 20192 Wind Solar Biomass Hydraulic Hydrogen Batteries Scope TWEED
  • 5. To Sustainable Energy Applications Cluster TWeeD -- 20193 Scope TWEED
  • 6. What are we doing ? Cluster TWeeD -- 20194 • Networking between industrial or commercial companies and others actors of sustainable energy sectors. • Reactive and proactive approaches in order to stimulate new projects. • Set-up technical support and management of projects. • Promote networking by organizing specific events, general meetings, workshops, bilateral meetings, face-to-face meetings, visits to companies,... • Develop synergies with other actors of sustainable energy sectors (clusters,...). • Local and international promotion of members. • Carrying out industry, technical, market and economic studies on sustainable energy sector. • Participation in Regional/European/International projects Scope TWEED
  • 7. 1. Establish an exhaustive diagnosis of the energy sectors by identifying its strengths and weaknesses, its opportunities and threats, its prospects, its needs or its challenges in terms of technological innovation. 2. Carry out a mapping of Walloon and Brussels stakeholders (companies, R&D centers, training players, etc.), whether or not they are already involved in the sectors, who have integrable skills in the value chain. 3. Promote Walloon skills both in Belgium and abroad, at national and international events via an interactive website and a directory (paper or electronic document) containing the activities of each actor. 4. Facilitate working groups to stimulate the implementation of projects/missions Industry & Value chain analysis Cluster TWeeD -- 20195 Industry & Value chain analysis
  • 8. H2 example Cluster TWeeD -- 20196 1. Eolien 2. PV 3. Biométhanisation 4. Réseau électrique 5. Electrolyseur 6. Stockage H2 7. Pile à combustible 8. Mobilité 9. Industries 10. Méthanisation 11. Cogénération 12. Réseau Gaz 13. Chauffage résidentiel 14. Méthanolisation 15. Stockage méthanol Power to Power Power to Mobility Power to Industry Power to Gas Biogas = CH4 + Co2 + …CO2 CO2 CH4 Power to Fuel Power to Heat CH3OH 1 2 4 5 3 6 7 8 9 1 0 1 1 1 2 9 1 3 1 4 1 5 Industry & Value chain analysis
  • 9. Cluster TWeeD -- 20197 1. Eolien 2. PV 3. Biométhanisation 4. Réseau électrique 5. Electrolyseur 6. Stockage H2 7. Pile à combustible 8. Mobilité 9. Industries 10. Méthanisation 11. Cogénération 12. Réseau Gaz 13. Chauffage résidentiel 14. Méthanolisation 15. Stockage méthanol Power to Power Power to Mobility Power to Industry Power to Gas Biogas = CH4 + Co2 + …CO2 CO2 CH4 Power to Fuel Power to Heat CH3OH 1 2 4 5 3 6 7 8 9 1 0 1 1 1 2 9 1 3 1 4 1 5 Industry & Value chain analysis H2 example
  • 10. Cluster TWeeD -- 20198 R&D R&D Etudes & Conception Financement Fabrication & Production Distribution & Installation Opérations & Maintenance Formation & Certification Education, Promotion & Sensibilisation ChaînedesMétiers Industry & Value chain analysis H2 example
  • 11. Cluster TWeeD -- 20199 Armoire électrique •Transformateur •Redresseur Electrolyseur •Cellule •Diaphragme / Membrane •Electrolyte •Hydroxyde Sodium /Potassium •Membrane polymère •Electrode / Plaque bipolaire •Module de déminéralisation •Osmose inverse •Système de refroidissement •Réservoir-séparateur Unité de purification •Echangeur •Recombineur catalytique •Zéolithe •Résistance électrique Système de compression •Compresseur •Groupe froid •Echangeur de refroidissement Stockage •Collecteur •Tuyauterie de transfert •Bouteille (gaz) •Métallique •Composite •Hydrure métallique (solide) Transport •Gazoduc •Camion •Cadres •Tubes Station-service •Borne de distribution •Pistolet •Armoire de gestion de la station •Tuyauteries, vannes, actionneurs, détecteurs, … Pile à combustible •Cellule •Electrolyte •Hydroxyde de potassium •Membrane polymère •Acide phosphorique •Sels fondus •Céramique •Electrode / Plaque bipolaire ChaînedesTechnologies Industry & Value chain analysis H2 example
  • 12. Cluster TWeeD -- 201910 Industry & Value chain analysis H2 example
  • 13. Cluster TWeeD -- 201911 Industry & Value chain analysis Other sectors, Ex. solar PV
  • 14. Portail Re-Wallonia Cluster TWeeD -- 201912 Industry & Value chain analysis
  • 15. ReWallonia - Players 13 > 350 belgian actors & 4.000 followers !
  • 16. ReWallonia - Players 13/12/19Cluster TWEED14 http://www.rewallonia.be/cartographies/stockage/
  • 19. Famous Walloon SG projects (2/2) 17 MeryGrid INTERESTS This Walloon pilot project has entered the operational phase. The aim is to test the benefits of local self- consumption at the zoning scale, bringing together electricity-consuming companies, renewable (solar and hydro) production and a storage unit. The energy management system (EMS) that manages the optimization of the micro-network should allow a saving of 15% on the energy bill. INTERESTS aims the creation of an optimization tool allowing the definition, the sizing and the management of "integrated stations" of production, storage and consumption (refuelling) of renewable energy (electricity / hydrogen) at the local level. The scenarios developed must be reproducible and economically viable. • Nethys • University of Liege • CE+T Energrid • Sirris • SPI • La Wallonie • ATM-Pro • Certech • N-Side • TWEED • UCL-INMA ReWallonia - Projects
  • 20. International Strategy Cluster TWeeD -- 201918 Collaboration/Expertise within the Wallonia export agency and their worldwide network (> 100 Economic & Trade Counselor + ALS) joint actions & collaborations Partnerships/Joint Projects between high level Energy/Cleantech Clusters in a EU/Worldwide scale TWEED is the official energy cluster in Wallonia : TWEED & Flux50 (Flanders) Partnership @ Belgian level : TWEED is a member of International Cleantech Cluster : International Strategy
  • 21. International Strategy Cluster TWeeD -- 201919 Benchmark & Establish common knowledge (Tools : Exchange of Best practices,…) Cluster Oriented Members Oriented Joint Cluster Projects (Tools: Cosme Go International) Main Goal : Promote Wallonia as Smart Energy Region BtoB matching (Tools: ICN Passport,…) Joint Mission / Target markets (Tools : Cluster and Awex network ) Markets/Technolog y/Opportunity Watch (Tools : Cluster and Awex network) Crossboarder SME Collaborations (Tools: Innosup) International Strategy Main Goal : Create the first EU Energy Meta Cluster
  • 22. www.clustertweed.be Cluster TWEED Rue Natalis 2 • 4020 Liège • Belgique Info@clustertweed.be | +32(0)4.242.47.60
  • 23. www.encn.de Funded by THINK. RESEARCH. ACT. Supported by Introduction “Energie Campus Nürnberg” Dr. Alexander Buchele | 09.12.19
  • 24. Page 2 www.encn.de THINK. RESEARCH. ACT. Energie Campus Nürnberg The EnCN Interdisciplinary Think-Tank of established and well known research institutions Key competences along the whole energy chain – from generation to utilization Scientific expertise from fundamental research to prototype development
  • 25. Page 3 www.encn.de THINK. RESEARCH. ACT. Energie Campus Nürnberg Joint Research along the Energy Chain ENERGY MANAGEMENT TECHNOLOGIES ENERGY MARKET DESIGN Economy | Design Power Electronics | Data security| ICT | Simulation Network Electronics & Smart Grid RENEWABLE ENERGIES EFFICIENT ENERGY UTILIZATION ENERGY STORAGES ELECTRIC GRIDS Industrial Drives Building Insulation Building Technology Combined Heat & Power Photovoltaics Solar Thermal Energy Chemical & Thermal TRANSPORT & STORAGE GENERATION UTILIZATION
  • 26. Page 4 www.encn.de THINK. RESEARCH. ACT. Energie Campus Nürnberg Mission We aspire to work together with our partners from science, industry and politics to help shape and promote the energy transition process. Interdisciplinary and cross-institutional research at highest scientific level Visible center of energy research with diverse scientific and practical offers Utilization of the innovation potential for Technology transfer and start-up activities
  • 27. Page 5 www.encn.de THINK. RESEARCH. ACT. ORGANISATION INFRASTRUCTURE TECHNOLOGY TRANSFER FINANCIAL FIGURES Energie Campus Nürnberg EnCN in Numbers 53 7 As of 2018 15
  • 30. Central Office Energie Campus Nürnberg Fon: +49 (0)911 / 56 854 9120 Fax: +49 (0)911 / 56 854 9121 info@encn.de Dr. Alexander Buchele Fürther Str. 250, „Auf AEG“ Building 16, 2nd floor, room 16.2.12 90429 Nuremberg Germany Funded by Supported by Thank you
  • 31. Building – Energieeffiziente Systeme der Gebäudetechnik (Energy Efficient Building Systems) (Nuremberg Tech) Gunnar Harhausen Technische Hochschule Nürnberg | Nuremberg Tech Energy and load flexible buildings and production facilities Research Group EnCN Effizienz Energy Efficient Building Systems
  • 32. Building – Energieeffiziente Systeme der Gebäudetechnik (Energy Efficient Building Systems) (Nuremberg Tech) Equipment and Integration • Research group EnCN Building - Energy Efficient Buildung Systems – Prof. Dr. Arno Dentel • with labs and offices at Energie Campus Nürnberg • Research group at the Institute for Energy and Buildings (ieg) – Prof. Dr. Wolfram Stephan • Lab-Building with test benches for CHP, HP, climate chamber, … • Embedded in the Faculty Mechanical Engineering and Building Services Engineering at THN (Nuremberg Tech) Seite 2
  • 33. Building – Energieeffiziente Systeme der Gebäudetechnik (Energy Efficient Building Systems) (Nuremberg Tech) Research Focus Building Services Engineering Seite 3 Energy und load flexible buildings Increase of the energy efficiency through system integration Simulation and emulation models Building automation and management Monitoring und optimization of buildings • Decentralized generator systems • Heat pump systems • Integral planning methodes • Hardware-in-the-Loop • Systems for fault dedection • MPC in building technologies • Scientific monitoring of demonstration buildings
  • 34. Building – Energieeffiziente Systeme der Gebäudetechnik (Energy Efficient Building Systems) (Nuremberg Tech) Technische Hochschule Nürnberg Georg Simon Ohm www.th-nuernberg.de Seite 4 • 14 partners from 6 EU countries (Finland, France, Germany, Portugal, Spain, Great Britain) • Overall project goal: • Develop, demonstrate and evaluate storage based energy supply of buildings and communities • 3 demonstrators to present the results This project has received funding from the European Union's Horizon research and innovation programme under grant agreement no. 645963. SENSIBLE Project
  • 35. Building – Energieeffiziente Systeme der Gebäudetechnik (Energy Efficient Building Systems) (Nuremberg Tech) Technische Hochschule Nürnberg Georg Simon Ohm www.th-nuernberg.de Seite 5 SENSIBLE Project 13 use cases: Community Meadows / Nottingham (UK) Energy management and market interaction of buildings with PV and storage Non-urban Microgrid in Évora (PT) Microgrid with PV, battery storage container and a Home Energy System Commercial Building in Nuremberg (DE) Energy management for multimodal energy storage for commercial building. PV, CHP, HP, building mass as storage, buffer storage.
  • 36. Building – Energieeffiziente Systeme der Gebäudetechnik (Energy Efficient Building Systems) (Nuremberg Tech) Technische Hochschule Nürnberg Georg Simon Ohm www.th-nuernberg.de Seite 6 SENSIBLE Project Coupling of local generator and storage devices with an online BEMS and a market platform
  • 37. Building – Energieeffiziente Systeme der Gebäudetechnik (Energy Efficient Building Systems) (Nuremberg Tech) Technische Hochschule Nürnberg Georg Simon Ohm www.th-nuernberg.de Seite 7 Herzo Base Project The building(s) : Terraced houses, 8 dwellings, 150 m² each Specific values Heating and cooling power • max. heat load: 22.7 kW ≈ 20 W/m² Heating and cooling energy • Heating energy: 23.4 kWh/m²a • DHW: 18.5 kWh/m²a PV Production • PV: 86 MWh/a • Peak: 98 kWp
  • 38. Building – Energieeffiziente Systeme der Gebäudetechnik (Energy Efficient Building Systems) (Nuremberg Tech) Technische Hochschule Nürnberg Georg Simon Ohm www.th-nuernberg.de Seite 8 Herzo Base Project • 2 geothermal heat pumps • 7 boreholes with free cooling • 8 decentralized DHW heat pumps • Thermal storage cascade • Battery (common use) • Control strategies Advantages: • Shift of electrical load peaks • DHW hygiene and temperature • Use of PV surplus Energy Concept - Plant with common technical room borehole heat exchanger DHW booster DHW storage technical center electric storage PV collector thermal storage cascade modulating heat pumps system control control heat pumps domestic electricity
  • 39. Building – Energieeffiziente Systeme der Gebäudetechnik (Energy Efficient Building Systems) (Nuremberg Tech) Geotabs Project Seite 9 GEOTABS focus: Optimized control for GEO-HP + TABS in office buildings heating and cooling loads in the administration building • even balance in the ground heating: high temperature level of the heat source (ground) and low exergy systems (TABS - Thermally Activated Building Systems) • high HP performance cooling: high temperature level of the load transfer (TABS) ⇒ passive cooling
  • 40. Building – Energieeffiziente Systeme der Gebäudetechnik (Energy Efficient Building Systems) (Nuremberg Tech) Thank you for your attention! Technische Hochschule Nürnberg Georg Simon Ohm EnCN Building – Energy Efficient Building Systems Prof. Dr.-Ing. Arno Dentel | Dipl.-Phys. Gunnar Harhausen e-mail: arno.dentel@th-nuernberg.de | gunnar.harhausen@th-nuernberg.de phone: +49 911/5880-3121 | +49 911/5880-3146 fax: +49 911/5880-7120 | +49 911/5880-7120 EnCN „Auf AEG“: Fürther Straße 250 90429 Nürnberg K:Standort Keßlerplatz am ieg: Keßlerplatz 12 90489 Nürnberg Seite 10
  • 41. Workshop “Wallonia meets Energy Campus Nuremberg”, Ottignies-Louvain-la-Neuve, Belgien, 09.-10.12.2019 “Highly heat insulating building materials” Prof. Dr. Wolfgang Krcmar, Department of materials engineering University of Applied Sciences Nuremberg
  • 42. Fields of activities • Highly heat-insulating building materials • Bricks, mortar, thin-layer mortar, plaster • Archive-concrete, prefabricated components • Geopolymers • Insulating materials (Nanofibers + Aerogels) • Construction of energy-efficient buildings • Energy-efficient building facades • Recycling of building materials • Heat-insulating coatings • Easy-to-clean-effect on building materials • FEM-simulations (heat- & noise insulation) • Different laboratory testings • Building-projects Work group of Prof. Dr. Krcmar - Energy efficient building materials
  • 43. Cooperation between the University of Applied Sciences Nuremberg with partners in the Energie Campus Nuremberg – Joint research along the energy chain
  • 44. Improvement of the thermal insulation: 35 % Properties of CALOSTAT • Diffusion coefficient µ = 6 • Hydrophobe; no water-absorption • Minerally; incombustible • Thermal conductivity l10, dr. = 0,019 W/(m*K) Nanostructure CALOSTAT- brick lequiv. = 0,041 Perlite- brick lequiv. = 0,07 CALOSTAT Perlite-brick lequiv. = 0,071 CALOSTAT-brick lequiv. = 0,046 Brick-envelope lequiv. = 0,345 Improvement: 41 % Example 1: Herzo Base energy-storage buildings: Application of the highly insulating material „CALOSTAT“ (silica fume SiO2) in wall-bricks
  • 45. Example 1: Herzo Base energy-storage buildings Energetic standard KfW 40 Plus End of November 2016Plan of the architect March 2017 Groundbreaking 14.07.2016 Roofing Ceremony 02.12.2016 Rear View Energy Storage Houses Nov. 2017
  • 46. Improvement 22,5 % Ø Lowering the thermal radiation in the building material by 79 % Ø Lowering the equivalent thermal conductivity by max. 30 % Ø Optimization of the thermal insulation of the solo brick by max. 30 % Ø Saving of primary energy for heating and cooling buildings Ø Reduction of CO2-emissions for heating and cooling buildings Improvement 28,4 % Example 2: Optimization of the thermal insulation of building materials by reduction of the thermal radiation
  • 47. 12 Brick types Beschichtete Ziegelproben Example 2: Optimization of the thermal insulation of building materials by reduction of the thermal radiation e without C. e with C. λeq, without C. λeq, with C. Reduction [-] [-] [W/mK] [W/mK] [%] 1 0,96 0,25 0,11 0,09 21,60 2 0,96 0,36 0,14 0,13 9,00 3 0,95 0,30 0,11 0,10 6,79 4 0,96 0,19 0,12 0,10 16,26 5 0,95 0,28 0,16 0,14 13,71 6 0,94 0,27 0,13 0,09 27,54 7 0,94 0,27 0,20 0,15 25,03 8 0,96 0,31 0,17 0,11 33,30 9 0,95 0,30 0,15 0,11 23,90 10 0,96 0,31 0,17 0,15 14,38 11 0,96 0,36 0,14 0,13 9,13 12 0,95 0,31 0,15 0,11 24,85 Brick Type
  • 48. Example 3: SiO2 – aerogel foam as insulation material § Thermal conductivity of silica aerogel zero samples : 0,023 W/mK § Thermal conductivity of fiber-modified silica aerogels : 0,021 W/mK § Distinctive hydrophobicity: contact angle with "sessile drop" method > 145°. Modified silica aerogelAerogel zero sample Filling of wall building materials
  • 49. Example 4: Development of high thermal insulation bricks with sound insulation properties by means of FEM simulation and rapid prototyping 3D-printing of PLA based brick prototypes „HV“ hole pattern left: Original hole pattern right: Sound insulation optimisation Ø 400 % increase in absorbed sound level without any loss of thermal insulation Ø Universally applicable to any hole pattern Ø Even minor changes of the hole pattern have a big impact Ø Production implementation is possible Brick with HV hole pattern, 365 mm Zero sample: λeq : 0,132 W/mk Sound adsorption Rw: 44 dB Brick with „sound-stop“ modification λeq : 0,131 W/mk Sound adsorption Rw: 50 dB
  • 50. Example 5: New building and insulating materials from geopolymers compressive strength ß = 2 N/mm² l10,tr. = 0,06 W/(m*K) 0,5 (Al2O3 · 2 SiO2) + 2 Na+ + 2 OH- + 2,5 H2O → 2 Na+ + (HO)3SiO- + [Al(OH)4]- compressive strength ß = < 120 N/mm² 1. High strength geopolymers 2. Foamed Geopolymers Unfilled Foamed Geopolymer
  • 51. Example 6: Improvement of thermal insulation of thin-bed mortar and base plaster Thin-bed mortar with fumed silica : Ø Reduction of thermal conductivity by almost 29,0 % Ø Compliance with the specified compressive strength class M 10 Base plaster with pyrogenic silica : Ø Reduction of thermal conductivity by almost 29,0 % Ø Simultaneous 49% increase in compressive strength
  • 52. Dimensions: Ø Max. ground clearance between base level and the additive head of 8 m Ø Provides the ability to erect decend 2-storey buildings. Example 7: Print houses – Additive manufacturing of buildings with the mobile 3 D-printer ACR
  • 53. Example 7: Additive Construction Robot (ACR) Swiveling printer arm on trolley Transport Installation, loading kinematics Ø Project duration: 4 years Ø Estimated costs: 2.1 Mio €, only for the German part Ø Idea generator and designer Ø 2 Research partners in Germany R & D of highly insulating binder, highly strength binder, composite materials (glass, carbon reinforced plastics, demolition waste, mineral waste, geopolymers Ø We have industrial partners in: Germany, Switzerland, Austria Ø We are looking for further potential partners from other EU countries ! Ø Call: ICT-46-2020 „ROBOTICS“: 41 Mio. € Ø Call: ICT-47-2020 „ROBOTICS“: 2-3 Mio. €
  • 54. Searching for partners for the realisation of a EU - research project, e.g: Ø R & D with energy-efficient building- and insulation materials Ø R & D with Recycling-materials Ø Construction of highly insulated, energy-efficient houses Ø Construction of an energy-efficient building complex Ø Construction of an energy self-sufficient settlement My Goals for this workshop
  • 55. Contact address: Energie Campus Nürnberg Prof. Dr. Wolfgang Krcmar Fürther Strasse 250 („auf AEG“) D – 90429 Nürnberg Tel.: +49 911 / 5880 3110 Fax: +49 911 / 5880 7110 wolfgang.krcmar@th-nuernberg.de www.encn.de Thank you for your attention !
  • 56. © Bayerisches Zentrum für Angewandte Energieforschung e. V. Alle Rechte vorbehalten, auch bezüglich jeder Verfügung, Verwertung, Reproduktion, Bearbeitung und Weitergabe sowie für den Fall von Schutzrechtanmeldungen. ZAE Bayern – Solar Factory of the Future Dr. Andreas Distler 9.12.2019
  • 57. © ZAE Bayern 2 ZAE Bayern – Mission & Vision Since 1992: Research & Development Education Application Consulting & Information In all fields of energy research. Our goal: Realization of a CO2-neutral energy supply by means of a synergetic use of renewable energy sources and efficient technologies. SFF Research Along the Value Chain Technology Pipeline: University (Basic Science) SFF Industry (Application)
  • 58. Organic / Printed Photovoltaics Technology: • Low-light and diffuse light performance • Shadowing tolerance • Positive temperature dependency Design: • Transparency • Color • Freedom of shape Integration: • Thin • Lightweight • Flexible 3
  • 59. The Magic Square of PV Efficiency CostLifetime 0% 20% 40% 60% 80% 100% 120% 140% NormalizedEfficiency Gen1, Lowell Rooftop Gen 2, Lowell rooftop Gen2, South Florida Design
  • 60. Solar Factory of the Future – Cost Reduction by R2R Processing The Concept
  • 61. P3HT:PCBM PV2000:PCBM P3HT:O-IDTBR Roll to Roll printing Roll to Sheet laminationRoll to Roll Bus Bar lamination  450 cm²  20 cell in series  Semi transparent  encapsulatedRoll to Roll laser patterning High-throughput OPV Manufacturing Equipment at the “Solar Factory of the Future” (SFF) High volume
  • 62. Combination of Silver Nanowire Electrodes and Laser Patterning  Semi-transparency - high geometric fill factor (>95%) - semitransparent - no visibly obstructing electrodes and interconnects
  • 63. Inkjet Printed Solar Cells  now also on 3D-surfaces by means of a 5-axis robot © Bayerisches Zentrum für Angewandte Energieforschung e. V. Alle Rechte vorbehalten, auch bezüglich jeder Verfügung, Verwertung, Reproduktion, Bearbeitung und Weitergabe sowie für den Fall von Schutzrechtanmeldungen.
  • 64.  30% / 35% higher than the previous world records! The Solar Factory of the Future Sets New World Records for OPV Modules © Bayerisches Zentrum für Angewandte Energieforschung e. V. Alle Rechte vorbehalten, auch bezüglich jeder Verfügung, Verwertung, Reproduktion, Bearbeitung und Weitergabe sowie für den Fall von Schutzrechtanmeldungen. Nuremberg, October 2019 PCE = 12.6% on 26 cm² PCE = 11.7% on 204 cm²
  • 65. Energy Harvesting and Lifetime Studies © Bayerisches Zentrum für Angewandte Energieforschung e. V. Alle Rechte vorbehalten, auch bezüglich jeder Verfügung, Verwertung, Reproduktion, Bearbeitung und Weitergabe sowie für den Fall von Schutzrechtanmeldungen. 0 100 200 300 0.0 0.5 1.0 NormalizedPCE Time (h) Sun test Damp heat
  • 66. Feasibility Studies © Bayerisches Zentrum für Angewandte Energieforschung e. V. Alle Rechte vorbehalten, auch bezüglich jeder Verfügung, Verwertung, Reproduktion, Bearbeitung und Weitergabe sowie für den Fall von Schutzrechtanmeldungen.
  • 67. Feasibility Studies © Bayerisches Zentrum für Angewandte Energieforschung e. V. Alle Rechte vorbehalten, auch bezüglich jeder Verfügung, Verwertung, Reproduktion, Bearbeitung und Weitergabe sowie für den Fall von Schutzrechtanmeldungen.
  • 68. Prototyping © Bayerisches Zentrum für Angewandte Energieforschung e. V. Alle Rechte vorbehalten, auch bezüglich jeder Verfügung, Verwertung, Reproduktion, Bearbeitung und Weitergabe sowie für den Fall von Schutzrechtanmeldungen.
  • 69. Future Projects and Collaborations? © Bayerisches Zentrum für Angewandte Energieforschung e. V. Alle Rechte vorbehalten, auch bezüglich jeder Verfügung, Verwertung, Reproduktion, Bearbeitung und Weitergabe sowie für den Fall von Schutzrechtanmeldungen. SFF Core Competencies:  Manufacturing of printed electronic devices (especially photovoltaics, OPV/Perovskite) on a large scale (roll-to-roll)  Developing printed high-performance barriers  Device characterization and inspection  Lifetime studies & PV monitoring  Prototyping & Application Fields of Interest / Potential Future Collaborations:  Anything related to photovoltaics or printed electronics  Direct coupling of printed PV modules with other electrical components (sensors, transmitters, capacitors, batteries, …) or various energy storage technologies  Functionalization of any surface (also 3D objects)  Printable high-barriers
  • 70. Thank you very much for your kind attention Dr. Andreas Distler ZAE – Solar Factory of the Future © Bayerisches Zentrum für Angewandte Energieforschung e. V. Alle Rechte vorbehalten, auch bezüglich jeder Verfügung, Verwertung, Reproduktion, Bearbeitung und Weitergabe sowie für den Fall von Schutzrechtanmeldungen.
  • 71. www.encn.de Gefördert durch Unterstützt durch Liquid Organic Hydrogen Carriers …taking Hydrogen everywhere Stefan Dürr, M.Sc.
  • 72. Seite 2 www.encn.de Why is hydrogen seen as the fuel of the future? In future, hydrogen is supposed to be used for smoothing electricity feed-in from renewable energies. But it is not only a buffer in times of high demand or supply, it is also able to connect different branches of industry or even society: power, industry, heat, chemical production and mobility can all be fuelled by hydrogen.
  • 73. Seite 3 www.encn.de And where’s the problem now? [1] https://www.engineeringtoolbox.com/docs/documents/1419/Hydrogen%20phase%20diagram.jpg [2] Foto: © Gerhard-Hofmann, Agentur-Zukunft [3] Claus Ableiter – own work, CC BY-SA 4.0, https://commons.wikimedia.org/w/index.php?curid=3541402 [1] [2] [3] Critical point: pc = 13.30 bara Tc = 33.18 K
  • 74. Seite 4 www.encn.de Hydrogen transport made easy - The LOHC-technology [1] S. Dürr (2015), Untersuchung der Hydrierung von Dibenzyltoluol mit H2/CH4-Gasgemischen, Masterarbeit, Lst. F. Chemische Reaktionstechnik [2] https://www.hafen-hamburg.de/images/image_cache/images/800x533/fotos/schiffe/9365623.jpg [3] http://www.unitank.de/eng/images/emleben-luftbild.jpg [4] http://www.bahnbilder.de/1024/1116-149-mit-einem-gueterzug-629234.jpg [5] https://t4.ftcdn.net/jpg/00/54/28/77/240_F_54287709_IxzEErROnx0cOwu5hTjCY2mQcnpQlWzt.jpg [1] [5] [4] [3] [2]
  • 75. Seite 5 www.encn.de Hydrogen transport made easy - The LOHC-technology High hydrogen capacity • 6.2 wt% (56 gH2/L) • 1.75 kWhLHV/kgH18-DBT = 7.43 MJLHV/kgH18-DBT • 1.58 kWhLHV/LH18-DBT = 6.72 MJLHV/LH18-DBT Non-toxic, no dangerous good in terms of transportation regulations (no „UN-Nr.“) Non-flammable No hydrogen release without catalyst present Extensively used as a heat-transfer agent • High level of experience • World-scale production capacities • Cheap market-price 2,6-Dibenzyltoluene (as an example, the actual fluid is a mixture of multiple isomers)
  • 76. Seite 6 www.encn.de Hydrogen transport made easy - The LOHC-technology Compressed H2 LOHC Total weight 250 kg 50 kg Total volume 150 L 50 L Comparison: Storage of 3 kg hydrogen via compressed H2 (300 bar) or LOHC 2170 kgH2 400 - 950 kgH2 (300 bara)
  • 77. Seite 7 www.encn.de Hydrogen transport made easy - The LOHC-technology [1] S. Dürr (2015), Untersuchung der Hydrierung von Dibenzyltoluol mit H2/CH4-Gasgemischen, Masterarbeit, Lst. F. Chemische Reaktionstechnik [2] https://www.hafen-hamburg.de/images/image_cache/images/800x533/fotos/schiffe/9365623.jpg [3] http://www.unitank.de/eng/images/emleben-luftbild.jpg [4] http://www.bahnbilder.de/1024/1116-149-mit-einem-gueterzug-629234.jpg [5] https://t4.ftcdn.net/jpg/00/54/28/77/240_F_54287709_IxzEErROnx0cOwu5hTjCY2mQcnpQlWzt.jpg [1] [5] [4] [3] [2] p = 10 – 50 bara T ≥ 160 °C ΔHR= - 65.4 kJ/molH2 Ru, Pt on alumina / carbon p = 1 - 5 bara T ≥ 280 °C ΔHR= 65.4 kJ/molH2 Pt on alumina
  • 78. Seite 8 www.encn.de General aspects of LOHC research Nanoscale: Optimizing the active catalytic site Mesoscale: Optimizing mass transfer at the catalyst pellet level Operando spectroscopies, microscopies, on-line monitoring Reactor scale: Optimizing mass and heat transfer Storage unit scale: Optimizing heat integration aspects Theory & simulation: DFT, CFD, mass & heat balances Preuster, Papp, Wasserscheid, Accounts of Chemical Research, 2017, 50(1), 74-85. General: Design and test other LOHC systems
  • 79. Seite 9 www.encn.de Current research topics of CRT @ EnCN • Heat integration • Dynamic behavior • Overall efficiency • Long-term stability of LOHC- and catalytic system • Compact reactor systems • on-vehicle gas separation • Fuel cell systems • Transfer Hydrogenation • Membrane Development • Electrode Development • Lower dehydrogenation temperature • New catalytic systems • Pt-efficiency • Hydrogen quality • Cost reduction • Performance density Dynamic local storage Mobility solutions Hydrogen supply
  • 80. Seite 10 www.encn.de Partners A joint project of Fraunhofer IISB, Fraunhofer IIS and Friedrich-Alexander-University Erlangen-Nürnberg
  • 81. Seite 11 www.encn.de On-site storage scenarios: • Highly dynamic behaviour • Heat storage possible • Efficient peak shaving • Flow-battery-like setup enables taylor-made solutions • High capacity • High hydrogen output X Further developments – the oneReactor
  • 82. Seite 12 www.encn.de Further developments – the oneReactor On-site storage scenarios: • Highly dynamic behaviour • Heat storage possible • Efficient peak shaving • Flow-battery-like setup enables taylor-made solutions • High capacity • High hydrogen output
  • 83. Seite 13 www.encn.de Further developments – the oneReactor In cooperation with A joint project of Fraunhofer IISB, Fraunhofer IIS and Friedrich-Alexander-University Erlangen-Nürnberg
  • 84. Seite 14 www.encn.de Further developments – direct LOHC fuel cell Is it possible to skip the release-step? • No gaseous hydrogen • Less equipment needed • Directly fuel mobile applications Is it possible to build Dibenzyltoluene Fuel Cells? • Mass transfer issues • Low power densities • No suitable equipment
  • 85. Seite 15 www.encn.de Further developments – direct LOHC fuel cell Catalytic hydrogen transfer to other molecules is feasible • Surface reaction, thus no gaseous hydrogen • Thermoneutral reaction vs. Highly endothermic dehydrogenation • Direct fuel cells using smaller organic molecules do exist Catalytic Hydrogenation Exothermic @ 160 – 300 °C Catalytic Transfer Hydrogenation Nearly thermoneutral @ 150 – 230 °C ΔHR = - 65 kJ/molH2 Direct Isopropanol Fuel Cell (PEM) Exothermic @ 80 - 90 °C
  • 86. Seite 16 www.encn.de Further developments – direct LOHC fuel cell New process design for heavy-duty mobile applications
  • 87. Seite 17 www.encn.de Further developments – direct LOHC fuel cell Isopropanol Oxygen WaterAcetone Flow Field Gas Diffusion Layer Catalyst (electrochemical) Proton Exchange Membrane Copper Foil Hydrogen Membrane Catalyst (Isopropanol oxidation) Direct Methanol Fuel Cell – Baltic Fuel Cells Current research (CRT / HI-ErN): • Catalyst and catalyst support materials for Isopropanol oxidation • Hydrogen membrane Materials
  • 88. Seite 18 www.encn.de Further developments – direct LOHC fuel cell LOHC as alternative fuel especially suitable for heavy duty applications (long range, high power) • Ships • Trains Project in Bavaria since 2019 (2019-2023) • LOHC-powered local transport train • On-board hydrogen release and power recovery in a fuel cell • Development of a „LOHC-Powerpack“ that can supply energy to a diesel-electric-train • Thus old local transport trains can still be used • Also focus on new technologies e.g. Direct LOHC fuel cell
  • 89. Seite 19 www.encn.de Further developments – the oneReactor Development of a highly flexible catalyst system • Modification of a Pt catalyst through doping with Nitrogen and Sulfur to block the most active centers and facilitate desorption of reaction products
  • 90. Seite 20 www.encn.de And where’s the problem now? How much hydrogen can this truck carry? 350 kg Fuel tank size Toyota Mirai 5 kg Which means… à only 70 fuelling processes [1] Foto: © Gerhard-Hofmann, Agentur-Zukunft [2] Von Mirai.PNG: Maskrosenderivative work: Mariordo - Diese Datei wurde von diesem Werk abgeleitet: Mirai.PNG:, CC BY-SA 4.0, https://commons.wikimedia.org/w/index.php?curid=36965785 [1] [2]
  • 91. Seite 21 www.encn.de [1] https://t4.ftcdn.net/jpg/00/54/28/77/240_F_54287709_IxzEErROnx0cOwu5hTjCY2mQcnpQlWzt.jpg [2] Von Mirai.PNG: Maskrosenderivative work: Mariordo - Diese Datei wurde von diesem Werk abgeleitet: Mirai.PNG:, CC BY-SA 4.0, https://commons.wikimedia.org/w/index.php?curid=36965785 [1] How much hydrogen can this truck carry? 2170 kg Fuel tank size Toyota Mirai 5 kg Which means… à 434 fuelling processes [2] Hydrogen transport made easy - The LOHC-technology
  • 92. Introduction - HFCVD-Diamond Coatings Maximilian Göltz, Stefan Rosiwal, Carolin Körner Chair of Materials Science and Engineering for Metals (WTM) Department of Materials Science Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU)
  • 93. 09.12.2019Maximilian Göltz, Chair for Metals: HFCVD-Diamond Coatings Department Materials Science • Largest in Germany • 9 chairs • 18 professors, 270 staff • 600 students Chair of Materials Science and Engineering for Metals (WTM) • 5 research groups – 50 staff members: • Additive Manufacturing • Modelling and Simulation • Lightweight Materials • High Temperature Alloys • Ultra-hard Coatings Associated institutes 2 Department and Chair WTM Part of the department – WTM in second floor
  • 94. 09.12.2019Maximilian Göltz, Chair for Metals: HFCVD-Diamond Coatings Fields of Activity • Process technology • Alloy development • Characterisation Equipment • Electron-beam machines (Ni, Cu) • Laser-beam machines (Ti) Applications • “Impossible structures” • Catalyst support • Single crystal turbine blades • Meta-structures 3 Additive Manufacturing Chemical reactors with integrated catalyst support and cooling 5 cm Microstructure of additively produced copper
  • 95. 09.12.2019Maximilian Göltz, Chair for Metals: HFCVD-Diamond Coatings Fields of Activity • Process technology • Alloy development • Tool certification Equipment • SAMPLE, ThermoCalc, CALPHAD, DICTRA, cellular automata, Flow-3D Applications • Alloy development • process strategies • Microstructure predictions • Lightweight Al-foams 4 Modelling and Simulation Meltpool at SEBM process in the particle bedMetal foam simulation Simulation of additive manufacturing process
  • 96. 09.12.2019Maximilian Göltz, Chair for Metals: HFCVD-Diamond Coatings Fields of Activity • Cold chamber casting • Foam casting • Alloy development Equipment • Frech DAK 450-54 • Impeller and dosing robot Applications • High pressure die-casting • Cellular structures • Reinforced alloys • Prediction of local properties 5 Lightweight Materials Sample of integral foam die-casting of aluminumMetal foam simulation Aluminum die-casting machine by Frech
  • 97. 09.12.2019Maximilian Göltz, Chair for Metals: HFCVD-Diamond Coatings Fields of Activity • Single crystal solidification • Metal powder injection molding • Alloy development – Ni-base superalloys Equipment • Two Investment casting units • Vacuum Arc furnace Applications • Alloy development • process strategies • Microstructure predictions 6 High Temperature Alloys Metal powder for injection molding Nickel-base superalloy casting plant for 10kg samples
  • 98. 09.12.2019Maximilian Göltz, Chair for Metals: HFCVD-Diamond Coatings Fields of Activity • Process development diamond CVD • Interlayer development - TiN • Diamond against mechanical wear • Boron-doped diamond (BDD) electrodes Equipment • MW-,HF- and HW- CVD machines • Sputter machine Applications • Slip seals • Water disinfection and cleaning • Medical treatment • Alumium die-casting 7 Ultra-Hard Coatings - Diamond HFCVD process with glowing filaments and sampleMicrobiological results of water disinfection with BDD HFCVD-machines for diamond coating 0 min 15 min 60 min
  • 99. 09.12.2019Maximilian Göltz, Chair for Metals: HFCVD-Diamond Coatings 8 Diamond – Electrochemical Water Treatment Electrochemical treatment of landfill leachate by BDD: The organic parts are destroyed by OH-radicals, anorganic is deposited cathodically t=0.0 t=1h t=2h anode cathode Electrochemical window of diamond vs Pt OH-radicals Background • BDD shows large potential window of 3.5 V • formation of OH-radicals at anode • disinfection and destruction of organic • deposition of metals on cathode Application • Landfill leachate • 3rd stage in sewage plant – multi resistancies • Oil- and fracking water • ballast water of big ships
  • 100. 09.12.2019Maximilian Göltz, Chair for Metals: HFCVD-Diamond Coatings 9 Diamond – Electrochemical Medical Treatment Application of BDD coated tools or implant to disinfect inflammations by electrochemical treatment Background • Inflammation of implants • 10% of all implants affected • Dental infections Application • Coating of implants and medical tools • Degradation of cell membranes • In-vitro tests successful 1 µm before after BDD Candida Dubliniensis 2 cm diamond coated wire with anodic potential Degradation of Candida D. cell after BDD treatment
  • 101. 09.12.2019Maximilian Göltz, Chair for Metals: HFCVD-Diamond Coatings Background • Aluminum shows a non-wetting behaviour on diamond • “Non-stick” – coating against liquid metal • Standard materials are etched and eroded by melt • Lifetime and surface quality greatly enhanced Application • Die-casting tools • Cold-working of aluminum • Welding of Aluminum 10 Diamond – Aluminum Die-Casting Tools Non-wetting of Al on WC and diamond – this is used for die-cast tools to enhance life time and surface quality. For steel an interlayer is needed. 1 mm 1 mm Al on WC Al on diamond Steel TiN diamond
  • 102. 09.12.2019Maximilian Göltz, Chair for Metals: HFCVD-Diamond Coatings Thank You Please do not hesitate to aks! 11
  • 103. 09.12.2019Maximilian Göltz, Chair for Metals: HFCVD-Diamond Coatings • diamond on steel has a high industrial impact, thin coatings already applied: • aluminum die-casting • welding • tribological application • against mechanical wear thick coatings are neccessary 12 Motivation Thin diamond coating on steel tools are applied in industry. [Rosiwal2017] 10 cm
  • 104. 09.12.2019Maximilian Göltz, Chair for Metals: HFCVD-Diamond Coatings • diamond on steel has a high industrial impact, thin coatings already applied: • aluminum die-casting • welding • tribological application • against mechanical wear thick coatings are neccessary 𝜎𝑡ℎ𝑒𝑟𝑚𝑎𝑙 = 𝐸 𝑑𝑖𝑎𝑚𝑜𝑛𝑑 1 − 𝜈 𝑇 𝑎𝑚𝑏𝑖𝑒𝑛𝑡 𝑇 𝑐𝑜𝑎𝑡𝑖𝑛𝑔 𝛼 𝑠𝑡𝑒𝑒𝑙 − 𝛼 𝑑𝑖𝑎𝑚𝑜𝑛𝑑 𝑑𝑇 𝜎𝑡ℎ𝑒𝑟𝑚𝑎𝑙 - thermal stresses 𝐸 𝑑𝑖𝑎𝑚𝑜𝑛𝑑 - Youngs modulus of diamond 𝜈 - Poisson ratio 𝑇𝑐𝑜𝑎𝑡𝑖𝑛𝑔 - coating temperature 𝑇𝑎𝑚𝑏𝑖𝑒𝑛𝑡 - room temperature 𝛼 𝑠𝑡𝑒𝑒𝑙 - thermal expansion coefficient of steel 𝛼 𝑑𝑖𝑎𝑚𝑜𝑛𝑑 - thermal expansion coefficient • differences in thermal expansion cause thermal stresses • typical values around -7 GPa 13 Motivation Delamination of a thick diamond coating from a TiNB coated steel sample.
  • 105. 09.12.2019Maximilian Göltz, Chair for Metals: HFCVD-Diamond Coatings Substrate: Steel X46Cr13 (1.4034) Surface Pretreatment • particle blasting • allow for mechanical adherence Interlayer • titanium nitride • hot-wall CVD at 1030 °C Diamond Coating • seeding before coating • hot-filament CVD at ~900°C • steel hardening by Helium-quenching 14 Standard Coating Process Aluminum die-casting tools at different process steps with surface micrographs. 5 cm
  • 106. 09.12.2019Maximilian Göltz, Chair for Metals: HFCVD-Diamond Coatings CVD Diamant auf Stahl – Zwischenschicht SURMETAL Heißwand CVD Beschichtungsanlage - Standort Fürth • Reaktanten: H2, N2, TiCl4, BCl3, CH4, TaCl5 • Beschichtungstemperatur: Bis zu 1030°C • Druck: 80 - 800 mbar • Max. Bauteilgröße: D x l = 200 mm x 800 mm  Titannitrid (bordotiert)
  • 107. 09.12.2019Maximilian Göltz, Chair for Metals: HFCVD-Diamond Coatings TiNB-Zwischenschicht als Diffusionsbarriere Bordotiertes Titannitrid erfüllt die Anforderungen J.C. Bareiβ et al.: CVD diamond coating of steel on a CVD-TiBN interlayer, Surface & Coatings Technology 201: 718– 723, 2006. Interdiffusionszone zwischen dem Stahlsubstrat und der Diamantschicht verhindert die Fe3C Bildung • Gute Anbindung an das Stahlsubstrat • Abscheidung bei über 1000°C gewährleistet die thermische Stabilität im Diamantprozess
  • 108. 09.12.2019Maximilian Göltz, Chair for Metals: HFCVD-Diamond Coatings Phase I Phase II Phase III unused tops severed Plateaus form 17 Run-in behaviour [Schiegerl 19] Titannitride layer Steel Diamond layer
  • 109. 09.12.2019Maximilian Göltz, Chair for Metals: HFCVD-Diamond Coatings 18 Running behaviour [Schiegerl 19] sandblast titannitrit diamond 0 5 10 15 20 25 30 35 40 45 50 in front of graphite plate in front of graphite plate free hanging free hanging flatnessinµm ~8 % ~5 % ~8 % Unbalanced wear  Real load is much higher
  • 110. John Cockerill Hydrogen Solutions ▪︎ 1 Dr. Sebastien J. Borguet R&D Manager Meeting with Energy Campus Nuremberg December 9, 2019
  • 111. John Cockerill, a 200-year-old engineering group fully committed to provide solutions for energy transition ▪︎ 2 Concentrated Solar Power Wind turbine maintenance Micro-grids and batteries Electrolytic hydrogen
  • 112. … and for energy efficiency ▪︎ 3 Reheating furnace Thermal and surface treatment Heat recovery steam generators Water and air/gas treatment
  • 113. A group with a global presence
  • 114. A private, independent Group Bernard Serin Chairman of the Board since 2002 Turnover: 1 297 M€ Operating results: 86.1 M€ Global workforce: 5 566 Safety performance: LF = 3.08 LS = 0.15 (data for FY 2018)
  • 115. STEAM METHANE REFORMING OIL CRACKING COAL GASIFICATION INDUSTRY BY-PRODUCT WATER ELECTROLYSIS Hydrogen in a nutshell 6 Hydrogen is the most present element in the universe, at the basis of life on earth Hydrogen is the lightest and smallest atom – one electron and one proton Hydrogen does not exist naturally – only combined in molecules like water In the form of dihydrogen H2 , it is an energy vector that allows storage over long periods Hydrogen allows sector coupling between power generation, mobility, heating and industry FOSSIL SOURCES ~10KG CO2 FOR 1KG H2 H2 industrials uses by sector (68 Mtons/year) Chemical industries: 63% Refining: 30% Metal: 6% Other industries: 1% Share of H2 generation
  • 116. Alkaline water electrolysis 101 7 Main advantages Proven, simple, mature and reliable Long lifetime (> 90 000 hours) No precious materials  less expansive Large capacity stacks (up to 5+MW) Working pressure up to 30 bars Main drawbacks Lower power density at stack level Large volume of corrosive electrolyte Longer cold start-up time Higher minimum turndown at stack level (20-40%) ANODE CATHODE MEMBRANE ELECTROLYTE H2O2 + - DC ELECTRICITY H+OH- water + power  oxygen + hydrogen + heat
  • 117. John Cockerill: a proven experience in water electrolysers 8 More than 1000 references around the world Customers in industries as various as / chemicals / glassmaking / silicon (PV panel manufacturer) / steelmaking / power plants Brand new workshop with an annual production capacity of 350+MW located in Suzhou (Shanghai area)
  • 118. John Cockerill in the H2 Value Chain 9 DEMISTER STACK H2O2 TRANSFORMER RECTIFIER UNIT (TRU) PURIFICATION UNIT DRYER STORAGE COMPRESSORS ELECTROLYZING UNIT SMART MICRO GRID WITH BATTERIES EMS ELECTROLYTE LYE TANK COMPRESSOR & STORAGE OPTIMISED DISTRIBUTION UNIT INDUSTRIAL PROCESSES TO GAS GRID - BLENDING SAFETY STORAGE – 200BAR TO INDUSTRY – 200BAR MOBILE DISPENSER 700 BAR 350 BAR H2 O2
  • 119. Evolution of the unit capacity of our electrolysers to meet increasing demand of decarbonised H2 10 60 Nm³/h 200 Nm³/h 375 Nm³/h 600 Nm³/h 1000 Nm³/h 1500 Nm³/h 1992 1994 2005 2009 2015 2018
  • 120. Turning to 100+MW units to address large industry needs 11Source : EU 2018, JRC Technical Reports OIL REFINERY • Average refining capacity of 10,4MT oil per year • Requires 50 ktons H2 • 340MW electrolyser • EU : 24 GW • World - 98 Mbbl/day : 142 GW STEELMAKING PLANT • 3MWh of electrolysis for 1 ton of steel • Average production plant of 4MT/year • 1,2GW of electrolysis • European production of 168MT : 51GW • Global steel production of 1700MT: 515 GW AMMONIA PLANT • Average plant capacity of 800kT per year requires 144k tons H2 • ~8TWh of electrolysis per year • 0,9-1 GW electrolyser • EU production of ~20MT per year: 25 GW • World production of 180- 200MT per year: 225- 250GW
  • 121. Introducing the world’s largest single-stack alkaline electrolyser: 1 500 Nm3/h (7.5 MW) 12 TDQ-1500/1.6 H2 output (Nm³/h) 1,500 O2 output (Nm³/h) 750 System pressure (bar) 16 H2 purity (%) 99.9 O2 purity (%) 99 Stack dimension (mm) 7160 x 2014 x 2086 DC current (A) 16400 DC voltage (V) 440 DC consumption (kWh/Nm³) ≤ 4.6
  • 122. John Cockerill to supply Hydrogen to 85 Fuel Cell Buses at the Beijing Olympics 2022 13 2.5 tons H2 / day
  • 123. Overview of our latest large-scale installations in operation 14 Capacity (Nm3/h) Power (MW) 1 x 500 2.5 3 x 300 4.5 5 x 250 6.25 2 x 1000 10 4 x 600 12 6 x 500 15
  • 124. Skid-mounted purification units up to 3000 Nm3/h to produce 99.999 %vol H2 15 HIGH HYDROGEN PURITY (UP TO 99.999%) 3-step process - O2 removal with Pd catalyst - H2O removal with chilled water - Final H2 drying with self-regenerating molecular sieve
  • 125. SEP 19 16 HaYrport : a multi-modal refueling station at Liege Airport
  • 126. COMPRESSORS AIRPORT HEAT NETWORK HaYrport: schematic design 17 ELECTROLYZING UNIT HEAT SOLAR PV GRID WATER BACK-UP H2O2 H2 H2 H2 H2 H2 H2 INDUSTRIES A I R S I D E L A N D S I D E PRODUCTION DISTRIBUTION
  • 127. Sizing and optimizing the design of H2 refuelling stations with our in-house software 18 refuelling  fast  compliant to SAE refueling protocol  high state of charge station optimization  reduced capex  reduced opex
  • 128. Sebastien Borguet Sebastien.borguet@johncockerill.com John Cockerill (Headquarters) Avenue Greiner 1 4100 Seraing Belgium T. +32 4 330 2444 F. +32 4 330 2582 welcome@johncockerill.com johncockerill.com John Cockerill Hydrogen Solutions ▪︎ 19
  • 129. DR IR MARC FOGUENNE VP TECHNOLOGY AND INNOVATION, BUILDING AND INDUSTRIAL DIVISION DECEMBER 09, 2019 THE ENERGY CHALLENGE : A TRIGGER OF AMBITIOUS AND INNOVATIVE PROJECTS
  • 130. Confidential AGC: Business Overview 2 Building & Industrial Glass 48% of sales Electronics 16% of sales Chemicals 31% of sales (*) Ceramic / Other : 5% N°1 glass producer Leading positions • External glass • Decorative glass • Glass for high tech applications • Original Equipment Manufacturer (OEM) • Automotive Replacement Glass (ARG) • Display • (LCD and PDP glass substrates) • Electronic materials • Fluorochemicals & specialty chemicals • Chlor-alkali & urethane • Life science Automotive Glass &
  • 131. AGC Glass Europe Confidential AGC Glass Europe at a glance • 2 business segments: − Glass for Buildings & Industry − Glass for automotive Automotive • R&D center and Headquarters in Belgium • 1 car out of 4 glazed by AGC • Nearly 1 building out of 4 with AGC coated glass • 16,080 people in Europe • € 2.5 bn sales (2018) 3
  • 132. 4 • Gosselies : 279 people ü 176 Researchers/ University degrees – 97 employees – 6 blue collars ü 19 different nationalities at Gosselies • Lauenförde (GE) : 35 people • 2 Technology transfer offices (Aniche, France – Mol, Belgium) VISION : Glass creates emotions by connecting people to their environment
  • 133. AGC Glass Europe Confidential AGC TECHNOLOGY & INNOVATION VISION 5 / Combination & Hybridation / Creativity / Conversion Rate / Expertise / Speed / Value creation Sustain & Grow https://www.agc-glass.eu/en/innovation Innovation
  • 134. AGC Glass Europe Confidential 6 DEVELOPPING OUR STRONG PILARS COATING– DECO - FRG INDUSTRIAL– WINDOW Supported by Digitalization SustainGrow SUPPORTING STRONG FOUNDATION PLANT SUPPORT / CRP SMART FACTORIES FLEXIBLE & GREEN TECH. Supported by INDUSTRY 4.0 Innov SMART CITIES SUSTAINIBILITY / INTERACTIVITY / CONNECTIVITY /MOBILITY NEW TECHNOLOGIES HOLLOW CATHODE ION IMPLANTATION PTW 27% 24% 49% AGC Glass Europe Innovation strategy
  • 135. Confidential 7 Total CO2balance for the glass industry 1 12 q Many glass products have a positive impact on the CO2 emission during their use because they contribute to energy saving § Insulating & solar control glass units § Solar applications o Photovoltaic panels o Mirrors o Greenhouses § Automotive glazing § Chilled display cabinets/Freezers § Availability of daylight vs artificial lighting q Direct CO2 emitted from fossil fuel used q CO2 emitted from electricity consumption q All other indirect sources of emissions upstream & downstream (raw material production, transportation, waste, products end of life, etc.) q Actions § continuous efforts and development § implement best practices § reduce specific consumption § improve melting technology Results : 0.61 T CO2/T Glass -> 0.47 T/T= -23% Manufacturing processes products Energy production
  • 137. AGC Glass Europe Confidential 9 FINEO – Vacuum insulating glazing ü 2 single glass panes separated by a vacuum space of 0.1mm and micro-spacers ü Dedicated to renovation and new buildings ü Produced in AGC Lodelinsart Belgian Environment & Energy Awards 2019
  • 138. Confidential Introducing natural light on-demand 10 HALIO OFFERS THE ULTIMATE IN COMFORT W/O COMPROMISING ON PERFORMANCE & AESTHETIC from Clear… to Dark… and In- Between… Seamlessly Transition < 3 minutes FUTURE-PROOF SYSTEM THROUGH ITS CLOUD CONNECTION 0.1% light transmission Unlimited intermediate tint levels Confidential 66% light transmission
  • 140. Confidential Decarbonizing electricity grid 12 ENERGY GENERATION DISTRIBUTED RENEWABLES CENTRALIZED RENEWABLES Glass solutions for ZEB: Building Integrated PV o BIPV for zero emission and positive energy building o Future solutions to improve aesthetic and financials o Toward invisible and transparent BIPV Solar Mirrors for CSP o Potential in some areas o Storage advantage o Cost challenge
  • 142. 14 PEOPLE SAY THINGS ARE IMPOSSIBLE Because they donʼt DARE TO TRY
  • 143. Confidential 15 Source : LeSoir.be AGC BRINGS CONCRETE ANSWERS TO SOCIETAL CHALLENGES.