Manufacturing of Synthetic Resins with Formulae & Processes

Manufacturing of
Synthetic Resins with
Formulae & Processes
(allyl resins, alkyd resins, electro
deposition primers, zinc rich coatings,
alginate, carboxymethyl cellulose,
carrageenan, guar gum, polyethylene glycol,
alginate, polyvinyl pyrrolidone, silicones
resins)

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Introduction
Synthetic resin is typically manufactured using a
chemical polymerization process. This process then
results in the creation of polymers that are more stable
and homogeneous than naturally occurring resin. Since
they are more stable and are cheaper, various forms of
synthetic resin are used in a variety of products such as
plastics, paints, varnishes, and textiles. There are various
kinds of synthetic resins; silicones resins, polyvinyl
pyrrolidone, gum arabic, epoxy resins, guar gum,
carrageenan, carboxymethyl cellulose, etc. Resins are
polymeric compound which are available in nature and
are also manufactured by synthetic routes. Some resins
are also manufactured by partial modification of natural
precursor polymer by chemical.

Silicones are unique among the commercially important
polymers both in chemistry and in variety of industrial
applications. Silicones can be applied as high
temperature insulating varnishes, impregnates to be
used with glass, asbestos, mica products and
encapsulating agents for electrical components. Water
borne dispersions or emulsions, for example emulsions
of vinyl or acrylic copolymers are popular in decorative
coatings. The applications of synthetic resins are seen
in some important industries like paint industry,
adhesive industry, the textile industry, paper, paint,
agricultural industry, petroleum industry etc. As it can
be seen that there is an enormous scope of application
of resins hence it is one of the major field to venture.

Some of the fundamentals of the book are
electrodepositable pigmented coating compositions
based on alkyd resins, phosphorus containing allyl
resins, vapour permeation cure technology,
characterization of water soluble anodic
electrodepositive pigmented coating compositions,
protection of concrete substrates, zinc rich coatings,
electro deposition primers, developments in
thermosetting powder coatings, application of powder
coatings, polyethylene glycol, petroleum recovery and
processing, industries using polyethylene glycols,
silicones resins, preparation & formulation of silicone
resin based coatings, pigments and dyes etc. Resin is a
thermosetting synthetic polymer having properties such
as adhesive strength, luster, and hardness.

Epoxy resins are available in the form of liquid as well
as high viscosity solid. Epoxy resins are segmented on
the basis of applications such as follow-paints &
coatings, electrical & electronics, wind energy,
construction, and composites.
During 2009–2013, consumption of epoxy resins for
coatings increased at an average annual rate of 8.3%
and for electrical and electronics applications at 6.8%.
Epoxy resins for composite applications increased at an
average rate of 8.1% per year
In 2013, the largest end use for epoxy resins was
coating applications, which accounted for 43% of total
consumption, followed by electrical and electronics
applications, at 35%. The resin market accounted for
USD 7.54 Billion in 2015 and is expected to reach USD
11.22 Billion by 2021, growing at a CAGR

of around 6.9% between 2016 and 2021.In INDIA,
epoxy resins consumption will grow at an average
annual rate of 4.9% for 2013–2018.
Epoxy resin consumption for composites in the United
States is forecast to grow at an average annual rate of
nearly 10% during 2013–2018. Synthetic Resins are
used by lot of industries. Yet, little emphasis has been
placed on the comparative value on functionality of
polymeric material as a class. These resins have been
classified in separate categories, usually in terms of
their Chemistry, sources or end uses. The present
book contains formulae, processes and other valuable
details for various synthetic resins. This is very useful
book for those concerned with development,
consultants, research scholars, new entrepreneurs
existing units, institutional libraries etc.

Table of Contents
1. PHOSPHORUS CONTAINING ALLYL RESINS
Properties of Monomers
Polymerization
Applications
2 . ELECTRODEPOSITABLE PIGMENTED COATING
COMPOSITIONS BASED ON ALKYD RESINS
Introduction
Experimental
Materials
Synthesis of water soluble alkyd resin from phthalic
anhydride and maleic anhydride (A1).

Synthesis of water soluble alkyd resin from
phthalic
anhydride and trimellitic anhydride (A2).
phthalic
anhydride and maleopimaric acid (A3).
maleopimaric
acid (A4).
Synthesis of water soluble methylated
melamine
formaldehyde resin.
Preparation of water soluble anodic
electrodepositive
pigmented coating compositions.

Testing and evaluation of anodic electrodepositive pigmented
coating compositions
Results and Discussions
Solvent (MTO) Resistance
Protection Against Corrosion
3. VAPOUR PERMEATION CURE TECHNOLOGY
Introduction
Vapour Permeation Cure (VPC)
Primary Advantages of VPC Coating
Disadvantages
Limitations
Vapour Injection Cure (VIC) Process
Chemical Composition
Reaction and Mechanism

Advantages of VIC
Conclusion
4. PROTECTION OF CONCRETE SUBSTRATES
Differences Between Concrete and Metallic Substrates
Constructions Influence
Coatings Used on Concrete
Organic coatings Thin film
Modified Epoxies
Furans
Chlorinated Rubbers
Waterborne Coatings
Vinyl Esters
Other Coatings

Organic Coatings Thick Film
Elastomeric Coatings
Polyurethane Coatings
Synthetic Rubber (Elastomers)
Resin Rich System
Polymer Concretes
Plastic Liners
Brick or Tile and Mortar Systems
Machinery Setting Grouts
Inorganic Coatings
New Versus Aged or Deteriorated Substrates
Quality Assurance
Conclusion
5. ZINC RICH COATINGS
Inhibitive Primers

Organic Zinc Rich Coatings
Inorganic Zinc Rich Coatings
Surface Preparation
White Metal Blasting
Galvanising
Galvanising and Zinc Rich Coating Comparison
Beach Front Exposure
Tidal Exposure
5% Salt Spray Test
Inorganic Zinc Rich Coating Advantages and Limitations
Application of Inorganic Zinc Rich Coatings
Cost Aspects
6. ELECTRO DEPOSITION PRIMERS
Electrodeposition Primers
Mechanism of Electrodeposition
Electro osmosis

Advantages of Electrodeposition
Types of Electrodeposition Primers
Shift to Cathodic E.D. Primer
Cathodic Electrodeposition Paint
Comparison of AED and CED
Properties of Dry Film
Latest Development in C.E.D.
Comparative Features of Different Types of CED
Plant Design and Process Control
Trends in Top Coats
Up gradation of Appearance & Performance of Top
Coats
Solid Colors
Metallic Colors
Developments in Top Coat Application
Developments in Thermosetting Powder Coatings

Powder Manufacture
Types of Powder
Powder Coatings Method of Application
Electrostatic Spray Corona Charging
Faraday Cage
Back Ionization
Electrostatic Spray Tribo Charging
Advantages of Powder Coatings
Dis Advantages of Powder
Economic Advantages of Powder Coatings
Application of Powder Coatings
General Metal Coatings
Industrial Machinery
Conclusion

7. WATERBORNE DISPERSIONS
Formulating Principles
Pigments
Additives
Binders
Acrylics/Vinyls/Vinyl Acrylic Emulsions
Polyurethane Dispersions
Cross Linking
Epoxy Dispersions
Miscellaneous Systems
Conclusion
8. ALGINATE
Chemical Structure
Chemical Derivatives
Manufacture

Physical Properties
Powdered Alginates
Solution Properties
Rheological Properties
Commercial Uses
Food Applications
Industrial Applications
Formulations
Stabilizing Frozen Foods
Fruit pie Filling
Frozen Gel
Frozen Fruit
Cream Sauce
Barbecue Sauce
Frozen Shortcake Berry Filling

Frozen Gel
Frozen Fruit
Cream Sauce
Barbecue Sauce
Frozen Shortcake Berry Filling
Tomato Sauce (Pizza and Spaghetti)
Macaroni and Cheese
Chopsuey
Food Gels
Dessert Gel
Cold Water Gel
Cold Milk Gel
Instant Chiffon Pie Filling
Instant Cheese Cake Mix
Instant Limitation Bakery Jelly
Banana Gel Base

Meringue Powder with Dried Egg Whites
Dessert Souffles
Vanilla Souffle
Chocolate Souffle
Lemon Souffle
Dressings
Fabricated fruit
Pie fillings
Cooked Fillings
Cold mix Fillings
Industrial Applications
Corrugating Adhesives
Single Starch System
Two Starch System
Fiber Reactive dyes

Pad Dyeing
Laboratory Techniques
Viscosity Measurement
Moisture Determination
Powder Color Determination
Alginates in Mixtures (Detection)
Alginates in Mixtures (Determination)
Spectrophotometric
9. CARBOXYMETHYL CELLULOSE
Chemical Nature
Physical Properties
Equilibrium Moisture Content
Molecular Weights
Solubility
Film Properties

Manufacture
Biological Properties
Toxicological Properties
Six month Oral Toxicity
One year Studies
Chronic Oral Toxicity
Reproduction
Gastrointestinal Absorption
Clinical Study
Skin Irritation and Sensitization
Getting Information
Rheology
Storage and Handling
Packaging
In Plant Handling
Bulk Handling

Bag Handling and Storage
Shipping
Applications
Detergents
Petroleum
Paper
Textiles
BOD and Desizing Wastes
Coatings
Cosmetics and Pharmaceuticals
Miscellaneous Applications
Specialties
Future Developments
World Production

10. CARRAGEENAN
Chemical Nature
Structure
Molecular Weight
Reactivities
Physical Properties
Appearance
Particle Size
Density
Solubility's
Manufacture
Biological/Toxicological Properties
Gastrointestinal Ulceration
Teratogenicity
Carcinogenicity

Gelation
Milk Gels
Additives/Extenders
Handling
Applications
By Result
By End Product
By Industry
By Process
Application Procedures
Dispersion
Stability
Specialties
Future Developments
Commercial Uses: Compounding and
Formulating

Milk Applications
Uses in Dry Mixes
Uses in Manufactured Products
Water Applications
Uses in Dry Mixes
Uses in Manufactured Products
Nonfood Applications
Pharmaceuticals and Toilet Goods
Other Applications
Commercial Uses: Processing Aids
Beverage Clarification
Abrasive Suspensions
Ceramic Glazes and Core Washes
Industries Using Carrageenans
Food
Dairy

Dairy Substitutes
Packaged Desserts
Other Food Uses
Pharmaceuticals and Toilet Goods
Metal Fabrication
Ceramics
Coatings
Agriculture
Household Products
Formulations
Chocolate Milk
Canned Water Dessert Gel
Air Treatment Gel
Toothpaste
Milk Puddings
Creamy Type (Cold Set)

Cooked Custard Type (Dessert and pie
filling)
Cooked Custard or Flan
Antacid Gel
Water Viscosity Measurement
Water Gel Strength Measurement
Milk Gel Strength measurement
11. GUAR GUM
Manufacture
Seed Structure
Purification
Grades
Chemical and Physical Properties
Structure
Solubility in Water

Rheology
Viscosity
Shear Response
Handling
Dry Storage
Solution Preparation
Applications
Oil and Gas
Explosives
Textile
Food
Ice Cream
Canned Pet Food
Cheese
Sauces and Salad Dressings
Paper

Mining
Commercial Applications: Compounding and Formulating
Food
Explosives
Oil and Gas
Textile
Carpets
Paper
Kraft Papers
Kraft Liner board
Recycled Liner board
Corrugating Medium
Boxboard
Offset News Stock
White Papers

Mining
Industries Using Guar Gum
Oil and Gas
Explosives
Food
Paper
Textile
Mining
Formulations
12. GUM ARABIC
Chemical Nature
Physical Properties
Manufacture
Biological/Toxicological
Properties

Additives/ Extenders
Additives
Extenders
Handling
Applications
Emulsification
Colloid Stabilization
Encapsulation
Suspension
Compatibility
Commercial Uses
Food Applications
Confectioneries
Dairy Products

Bakery Products
Flavor Fixation
Flavor Emulsification
Beverages
Pharmaceuticals
Suspending Agent
Demulcent Agent
Emulsification
Antiseptic Preparations
Miscellaneous Applications
Medicines
Cosmetics
Adhesives
Paints
Inks

Record Ink
Soluble Inks
Watercolor Inks
Quick Drying Inks
Fabric and Laundry Marking Inks
Pigmented Inks
Emulsion or Typographic Inks
Hectographic Inks
Electrically Conductive Inks
Lithography
Textiles
Miscellaneous Uses
Industries Using Gum Arabic
Food Industry
Pharmaceutical Industry

Other Industries
Formulations
Confectioneries
Dietetic or Sugarless Candies
Marshmallows
Food Emulsions
Pickle Oil Emulsion
Pickle Juice
Beverages
Stabilized Fruit Drink
Dry Mix Imitation Orange Drink
Beverage Stabilizers
Nut Coating
Inks
Gloss Finish Inks

Wood Grain Inks
30% Viscosity Method
Insoluble Residue
Sediment and Color
Peroxidase Content
13. HYDROXY ETHYL CELLULOSE
Chemical Nature
Stability
Physical Properties
Solubility in water
Solubility in Organic Solvents
Dissolving Methods
Viscosity Properties
Compatibilities

Manufacture
Rheological Properties of Solutions
Additives/Extenders
Handling
Applications
Specialties
Future Developments
Commercial Uses: Compounding and Formulating
Protective Colloid in Latex
Thickener for Latex Compositions
Latex Paints
Color Coats for Paper
Textile Binders and Adhesives

Building Specialties
Cosmetics and Pharmaceuticals
Paper Sizes and Coatings
Carpet and Textile Dye Pastes
Special Applications
Crude Oil Drilling and Recovery
Electroplating and Electrowinning
Miscellaneous Binders
Other Specialty Uses
Industries Using Hydroxyethylcellulose
Adhesives
Agricultural Products
Building Products
Cosmetics
Oil and Gas Extraction

Paints and Coatings
Paper and Allied Products
Synthetic Resins
Textile Mill Products
Formulations
Copolymer Latex
Latex Interior Flat Wall Paint
Textile Printing
Oil Well Work over Fluid
Roll on Antiperspirant
Liquid Shampoo
14. HYDROXY PROPYL CELLULOSE
Chemical Nature
Stability
Chemical
Stability

Biological Stability
Insolubilization
Physical Properties
Moisture Content
Solutions
Rheology
Organic Solutions
Hot Melts and Waxes
Compatibility
Film Properties
Thermo plasticity
Manufacture
Additives
Preservatives
Defoamers

Plasticizers
Handling
Applications
Water Temperature
Compatibility with Salts
Molding Powder Preparation
Specialties
Industries Using Hydroxypropyl Cellulose
Formulations
Cosmetics
Antiperspirant (Roll On)
Hair Grooming Aid
Shampoo (Gel)

Paint Removers
Nonflammable Solvent Type Remover
Acid Type Remover
Pharmaceuticals
Thermoplastics
Injection Molding Formulation (Unfilled)
15. POLYETHYLENE GLYCOL
Chemical Nature
Physical Properties
Viscosity
Solubility in Water
Solubility in Organic Solvents
Solvency and Compatibility
Hygroscopicity

Surface Tension
Volatility
Thermal Stability
Manufacture
Handling
Applications
Functions
End Products
Industries
Processes
Additives/Extenders
Specialties
Future Developments

Chemical Intermediates
Adhesives
Agricultural Formulations
Cellophane Film Humectants
Cosmetics and Toiletries
Detergents and Cleaners
Inks
Paints and Coatings
Pharmaceutical Products
Rubber Compounds
Miscellaneous Products
Cork Products
Food Products
Lubricants and Hydraulic Fluids
Paper Products

Photographic Developers
Sponges
Wood swelling agent
Commercial Uses: for Processing Aids
Ceramics
Dialysis Operations
Electroplating
Heat Transfer Baths
Leather Treatment
Metal Working Operations
Paper Products
Petroleum Recovery and Processing
Plastic Compounding
Rubber Products
Textile Products
Wood Products

Industries Using Polyethylene Glycols
Adhesives
Agricultural Products
Ceramics Products
Chemical Specialties
Electronic and Electrowinning
Food Products
Inks and Printing
Leather Processing
Lubricants and Hydraulic Fluids
Medical Sundries
Metal Fabricating
Packaging Materials
Paints and Coatings
Paper Products

Petroleum Recovery and Processing
Pharmaceuticals
Photographic Products
Plastics Products
Rubber and Elastomers
Textile Products
Wood Processing
Formulations
Fatty Acid Esters
Water Dispersible Alkyd Resin for Paints
Suppository Bases
Ointment Bases
Cosmetic Cream
Hand Lotion
Brushless Shaving Cream

Cream Rouge (Vanishing)
Perfume Stick
Clay Starch Paper Coating
Metal Working Lubricant
Ball point Pen Ink
Identification of PEGs
Determination of PEGs in Other Materials
16. ALGINATE POLY ETHYLENE OXIDE
Chemical Nature
Narrow Molecular Weight Distribution Grades
Hydrogels
Thermoplastic Compound
Hydrodynamic Drag Reduction Slurry

Oxidative Degradation
Association Complexes
Physical Properties
Bulk Properties
Manufacture
Toxicological Studies
Biodegradability
Rheological properties
Viscosity
Additives/Extenders
Applications
Application procedures
Boiling Water Dispersion
Nonsolvent Dispersion

Commercial Uses: Compounding and
Formulating
Adhesives
Water Soluble Paper Adhesives
Adhesives from Association Complexes
Industrial Supplies
Thickened Cleaning Solutions
Construction Products
Paving Composition
Water Soluble Purge Dam
Paints and Paint Removers
Latex Paints
Spatter Finish
Thickener for Paint and Varnish Remover
Pharmaceuticals
Dispersant for Calamine Lotion

Rubbing Alcohol
Printing Products
Microencapsulated Inks
Lithographic Press Dampening Fluid
Soap, Detergents, and Personal Care Products
Detergents
Toothpastes
Denture Fixative
Shaving Stick
Ophthalmic Solution
Absorbent Pads
Water Soluble Films
Seed Tape
Water Soluble Packaging

Binder
Ceramics
Battery Electrodes
Fluorescent Lamps
Soil Stabilization
Other Binder Applications
Coatings and Sizes
Tablet Coatings
Glass Fiber Size
Dispersant
Vinyl Polymerization
Glass Fiber Reinforced Concrete
Flocculation
Clays
Coal
Silica

Filier Retention Drainage Aid (Paper Making)
Hydrodynamic Drag Reduction
Fire fighting Additive
Fluid jet Cutting
Additive to Prevent Sewer Surcharges
Other Drag Reduction Applications
Thermoplastics Manufacture
Textile Antistat
Fugitive Textile Weft
Thickening / Rheology Control
Antimist Additive
Drift Control Additive
Oil Recovery Fluids
Water Retention
Asbestos Cement Extrusion Aid
Soil Amendment

Industries Using Poly (Ethylene Oxide)
Formulations
Aluminum and Metal Cleaner
Calamine Lotion
Denture Fixative, Powder
Detergent Bars
Detergent Liquid
Lithographic Press Dampening Fluid
Microencapsulation
Paint and Varnish Remover
Thickened Acetic Acid
Thickened Hydrochloric Acid (Muriatric Acid)
Thickened Sulfuric Acid
Rubber Lubricant (for Mounting of Tires)
Toothpastes

17. POLYVINYLPYRROLIDONE
General Information
Chemical Nature
Physical Properties
Manufacture
Intrinsic Viscosity
General
Acute Toxicology
National Cancer Institute
Sub acute and Chronic
PVP Films
Compatibilities
Future Developments
Applications of PVP

Pharmacy
Medicine
Beverages
Textiles
Paper
Adhesives
Detergents and Soaps
Polymers and Polymerization
Agricultural
Photography and Lithography
18. SILICONES RESINS
Chlorosilanes
Commercial Production of
Monomeric Intermediates

Silicone Fluids
Manufacture
Properties and Uses
Thermal Stability
Rheological Characteristics
Surface Activity
Lubricating Properties
Electrical Properties
Other Characteristics
Identification
Silicone Elastomers
Manufacture of Base Polymers
Fillers
Processing
Vulcanization
Properties and Uses

High and Low Temperature Applications
Electrical Applications
Molding and Mold Release Applications
Thermal Insulation and Ablative Applications
Construction Products
Medical Applications
Convenience Uses and Miscellaneous Applications
Silicone Resins
Manufacture
Cure
Properties and Uses
Greases and Compounds
Surfactants
Primers and Adhesion Promoters
Preparation & Formulation of Silicone Resin Based Coatings
Cure Catalyst Driers

Pigments and Dyes
Thinners
Formulations
Application Guides
Surface Preparation
Priming
Applying the Coating
Curing
Surfactants and Specialties
Methods of Manufacture
Properties
Emulsions

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o Ayurvedic And Herbal Medicines, Herbal Cosmetics
o Alcoholic And Non Alcoholic Beverages, Drinks
o Adhesives, Industrial Adhesive, Sealants, Glues, Gum & Resin
o Activated Carbon & Activated Charcoal
o Aluminium And Aluminium Extrusion Profiles & Sections,
o Bio-fertilizers And Biotechnology
o Breakfast Snacks And Cereal Food
o Bicycle Tyres & Tubes, Bicycle Parts, Bicycle Assembling

Sectors We Cover Cont…
o Bamboo And Cane Based Projects
o Building Materials And Construction Projects
o Biodegradable & Bioplastic Based Projects
o Chemicals (Organic And Inorganic)
o Confectionery, Bakery/Baking And Other Food
o Cereal Processing
o Coconut And Coconut Based Products
o Cold Storage For Fruits & Vegetables
o Coal & Coal Byproduct

o Copper & Copper Based Projects
o Dairy/Milk Processing
o Disinfectants, Pesticides, Insecticides, Mosquito Repellents,
o Electrical, Electronic And Computer based Projects
o Essential Oils, Oils & Fats And Allied
o Engineering Goods
o Fibre Glass & Float Glass
o Fast Moving Consumer Goods
o Food, Bakery, Agro Processing

o Fruits & Vegetables Processing
o Ferro Alloys Based Projects
o Fertilizers & Biofertilizers
o Ginger & Ginger Based Projects
o Herbs And Medicinal Cultivation And Jatropha (Biofuel)
o Hotel & Hospitability Projects
o Hospital Based Projects
o Herbal Based Projects
o Inks, Stationery And Export Industries

o Infrastructure Projects
o Jute & Jute Based Products
o Leather And Leather Based Projects
o Leisure & Entertainment Based Projects
o Livestock Farming Of Birds & Animals
o Minerals And Minerals
o Maize Processing(Wet Milling) & Maize Based Projects
o Medical Plastics, Disposables Plastic Syringe, Blood Bags
o Organic Farming, Neem Products Etc.

o Paints, Pigments, Varnish & Lacquer
o Paper And Paper Board, Paper Recycling Projects
o Printing Inks
o Packaging Based Projects
o Perfumes, Cosmetics And Flavours
o Power Generation Based Projects & Renewable Energy Based Projects
o Pharmaceuticals And Drugs
o Plantations, Farming And Cultivations
o Plastic Film, Plastic Waste And Plastic Compounds
o Plastic, PVC, PET, HDPE, LDPE Etc.

o Potato And Potato Based Projects
o Printing And Packaging
o Real Estate, Leisure And Hospitality
o Rubber And Rubber Products
o Soaps And Detergents
o Stationary Products
o Spices And Snacks Food
o Steel & Steel Products
o Textile Auxiliary And Chemicals

o Township & Residential Complex
o Textiles And Readymade Garments
o Waste Management & Recycling
o Wood & Wood Products
o Water Industry(Packaged Drinking Water & Mineral
Water)
o Wire & Cable

Contact us
106-E, Kamla Nagar, Opp. Spark Mall,
New Delhi-110007, India.
Email: npcs.ei@gmail.com , info@entrepreneurindia.co
Tel: +91-11-23843955, 23845654, 23845886, 8800733955
Mobile: +91-9811043595
Fax: +91-11-2385886
Website : www.entrepreneurindia.co , www.niir.org
Take a look at NIIR PROJECT CONSULTANCY SERVICES on
#StreetView

www.niir.org
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Manufacturing of Synthetic Resins with Formulae & Processes

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