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Comprehensive School “M. Buonarroti“

                             Marina di Carrara

                               Secondary school

                                       Presents
                                 SCIENTIFIC WORKSHOP




Scientific project: Tiziana Perfetti

Text translated by : Maria Antonietta Caporale
LET’S DISCOVER THE CHEMICAL REACTIONS
We have a chemical reaction when we observe phenomena that testify the
disappearance of the substances used and/or the formation of new ones.

In particular :

    bubbles

    the formation and the disappearance of a solid

    spontaneous heating or cooling

    the colours changes

are evidence of chemical reactions

      The substances that give rise to the transformation are called reagents and
       the substances that are formed are called chemicals (products)

          Reagents                       Chemicals



Chemical reactions can be faster or less fast

However we may act to increase or decrease the speed of a reaction in a lot of
ways , for example using catalysts. Almost all the reactions that occur in living
organisms are activated by biological catalysts, the enzymes.
Even the stones breathe
                              ( breathe out)
                                                                           Marble
                          and hydrochloric acid




You need:



            • a plastic spoon                      •   hydrochloric acid

            •   a glass rod                        •   distilled water

            •   marble powder                      •   a beaker



       Process:

            o   With the spatula take a small amount of marble powder, add
                water and a few drops of hydrochloric acid until all the solid
                has not disappeared.

       Observations:

            What do you observe? What do you think

            happened?

            Does the acid dissolve the marble in the
same manner in which water dissolves salt and sugar?

Has a new substance formed or not?
Can it be stated that there has been a chemical reaction? Give an
    explanation




What happened?

  The effervescence observed in the test tube with the marble powder
is due to the development of another gas, the carbon dioxide. The
chemical reaction is:



hydrochloric acid + marble          calcium chloride + carbon dioxide
+ water
Accadue
                       HYDROGEN PRODUCTION
                         (be careful !)

  The use of the match requires proper precautions and the
  completion of the experiment by the teacher.

  Targets
  To recognize a very fast and effect chemical reaction.




                           You need:

     • Pieces of aluminum foil              • A match
       (for food)                           • A wood pliers
     • Hydrochloric acid                    • A glass rod
       solution (muriatic)
     • Two test tubes
     • A test tube rack
                                            • a pipette


Process:

  o Put some pieces of aluminum in a test tube
  o Add a few drops of hydrochloric acid
What do you observe?

In the test tube with aluminum effervescence is observed , the solution
becomes darker and aluminum corrodes and disappears. You must wait
a few minutes to allow reaction to develop, fragments are surrounded
by bubbles of hydrogen that keep them afloat.
   o Place above the test tube the second inverted test tube, that is
      with the opening facing downwards, to collect the hydrogen which
      is lighter than air.
   o After a few minutes move away the second test tube, always
      keeping it inverted, from that in which hydrogen is generated and
      approach the entrance to a lighted match.


What happens?

We will hear a slight explosion and, if you look carefully, you can see
a flame inside the test tube, while the blast of the explosion will turn off
the match. The effervescence observed in the test tube with the
aluminum is due to the development of a gas, the hydrogen. In the
reaction we can also see that the hydrogen reacted with the oxygen in
the air producing water vapor ( after the reaction we will find some
condensation on the inner walls of the test tube).
The chemical reaction is :

6HCI + 2AI             2      +3

( Hydrochloric acid + aluminum                aluminum chloride+
hydrogen)
Balloon
                    Let’s inflate a balloon without blowing



                             You need :

                                          • an Erlenmeyer flask

                                          • a balloon

                                          • baking soda

                                          • graduated cylinder

                • vinegar

                • a funnel

                • a teaspoon




Process:

           1.   Using a graduated cylinder pour 30ml of vinegar in the
                Erlenmeyer

                flask.

           2. Stick a balloon to the mouth of the funnel.

           3.   Put a teaspoon of baking soda in the balloon .

           4. Take off the funnel from the balloon.

           5.   Adjust the opening of the balloon around the neck of the
                flask, being careful not to fall into the baking soda.
           6. Keep the flask still, raise the balloon in such a way to allow
              the
baking soda to come into contact with the vinegar.



 Reflections



What do you observe inside the flask?

What happens to the balloon?

What conclusions do you draw?




 What happens?

After the baking soda has been dropped in vinegar, a chemical reaction
starts for which we can note the development of foam and the balloon
that is inflated. A gas called carbon dioxide develops. Since gases expand
until they occupy all the space available , the carbon dioxide inflates the
balloon. Touching it the bottle is cooled and at the end a deposit may
remain.



Baking soda + acetic acid = sodium acetate + water+ carbon dioxide



The vinegar that remains ( if it is in excess of the amount of baking soda)
is now diluted. If a white deposit remains on the bottom, it means that
the vinegar was not sufficient to react all the baking soda.
A volcano of foam
                              (be careful !)

TARGETS
To recognize an exothermic reaction and the function of a catalyst

You need:

   •    An empty glass bottle (preferably with a narrow
        neck)or a graduated cylinder
   •    1/2 cup of hydrogen peroxide at 20 volumes
   •    liquid detergent
   •    3-4 drops of food coloring
   •    Potassium iodide
   •    A funnel
   •    A large and low container



Process

   1.   Put the bottle in the centre of the container. Insert
        the funnel in the bottle and pour the peroxide.
2. Add the detergent to the peroxide in the bottle.

What happens?

   3. Add 3-4 drops of food coloring.
   4. Dissolve two teaspoons of sodium iodide in a few millimeters of
      warm water in a beaker.
   5. Quickly pour the sodium iodide in the bottle ( and move away).
   6. The students can touch the bottle to feel all the changes that
      occur.

What do you observe?

The reaction creates foam which is shot out of the bottle. After about a
minute a moving flow is formed. The bottle will feel warm to the touch
as it is an exothermic reaction.

To obtain the volcano of foam we have to use a catalyst, a substance
that accelerates the rate of the reaction and that it is found unchanged
at the end, without transformations.

How does it work?

The decomposition reaction of hydrogen peroxide into water and
oxygen is the following:

  2                  2   O+

When we pour KI in the hydrogen peroxide / liquid detergent mixture,
the volcano of foam starts. We will also recognize other phenomena
such as the release of oxygen, the production of H2O in addition to
changes in ph.

A lot of reactions of industrial importance take place with the aid of
suitable catalysts, all the reactions of biological importance take place
with the aid of enzymes, active catalysts in living organisms.
SECRET MESSAGES

                       First message



You need:

   • Lemon juice

   •   A blank sheet of paper

   •   A glass stick

   • A candle




Process:
o Take the stick and dunk it in the lemon juice

 o Write on a paper what you want or make a small drawing

 o Let the ink dry and wait till the writing disappears

 o Now let the paper pass over the flame of a candle being
   careful not to burn it.

What do you observe?



The writing reappears and it is perfectly legible




                                                    What do you
                                                    deduce?

                                               The heat makes
                                              the lemon juice
                                             react so that it
darkens and                             makes visible the writing
SECRET MESSAGES

                           Second message



You need:

   • A wad of cotton                     •   A sheet of paper
   • Very diluted tincture of            •   Lemon juice, brush
     iodine



What to do

   o Write a message on the white paper using a brush dipped in the
     lemon juice.
   o Let the writing dry till it becomes invisible.
   o Rub a wad of cotton soaked in a dilute solution of iodine on the
     sheet where it says.

What do you observe?

The writing reappears, white on a blue/purple background

What do you deduce?

The starch of the paper is combined with iodine by changing colour to
the sheet of paper which becomes blue/purple. Also the vitamin c in
lemon combines with the iodine but it forms a colourless molecule. So
the area covered by the lemon juice stands on a colored background.
Let’s change the colours


The colour change may indicate the formation of new
substances


You need:

   o   Two test tubes

   o   Two pipettes

   o   Solution of ferric chloride

   o   Solution of potassium ferrocyanide



Process:

   o   Take a few ml of solution of ferric chloride ( a yellow-
       orange colour solution) by a pipette and put it into the two
       test tubes

                          o   Add some drops of a reactive called
                              potassium ferrocyanide to the first
                              test tube

                 • What do you observe?
The second solution, light yellow, added to
                          the solution of ferric chloride determines a
                          marked change in colour : the content of the
                          test tube becomes blue ( also called Prussian
                          blue) due to the formation of a new substance
                          ( the ferric ferrocyanide)



        o Add some drops of potassium thiocyanate

            ( colourless solution) to the second test tube

     What do you observe?

  o The solution becomes dark red even if precipitate
    doesn’t form: the new formed red substance is soluble
    in water. Some chemical reactions occurred: the initial
    substances are transformed and they have given rise to
    new substances that there weren’t before, with their
    own evident characteristics ( a different coloration).

                             Rubber egg
How can an egg bounce like a ball without breaking
You need:

        o   A raw egg
        o   A glass or a glass jar
        o   Vinegar
        o   (time)

Process:
  1) Put the egg into the glass jar and cover the egg with vinegar
  2) After some hours look closely the egg. What do you observe? Do
     you see the bubbles formation around the eggshell?
  3) Let the egg into the vinegar for 24-48 hours
  4) On the second day, carefully pour the old vinegar down the drain
     and cover the egg with fresh vinegar
5) Don’t disturb the egg but pay attention to the bubbles that are
      formed on the surface of the eggshell ( or what’s left of it).
   6) Pour the vinegar and rinse thoroughly the egg with water
   7) What do you observe?

The egg looks translucent because the outer shell has disappeared! The
only thing that remains is the delicate membrane of the egg.




What happened?

The bubbles that cover the shell are carbon dioxide bubbles. Vinegar
is an acid called acetic acid. ( White vinegar is usually made up of about
5% of acetic acid and 95% of water). The egg shells are composed of
calcium carbonate. Vinegar reacts with the calcium carbonate giving
origin to a substance called calcium acetate and carbon dioxide.

The egg shell is reduced to a very thin layer and the egg is flexible. The
shelled membrane remains . The semi-impermeable membrane in
contact with the external solution begins to flow solvent ( the vinegar)
inside the egg from the outside so that the concentration of particles
inside balances the outside one. This flow of a liquid through a semi-
impermeable membrane from a less concentrated solution to a more
concentrated one is called osmosis.

The volume of the egg has visibly increased showing the effect of
osmotic pressure. If you shake the egg, the yolk can be seen splashing
around the egg white. If the egg reacts with the carbon dioxide in the
air it will harden.

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Let's play with reactions

  • 1. Comprehensive School “M. Buonarroti“ Marina di Carrara Secondary school Presents SCIENTIFIC WORKSHOP Scientific project: Tiziana Perfetti Text translated by : Maria Antonietta Caporale
  • 2. LET’S DISCOVER THE CHEMICAL REACTIONS We have a chemical reaction when we observe phenomena that testify the disappearance of the substances used and/or the formation of new ones. In particular :  bubbles  the formation and the disappearance of a solid  spontaneous heating or cooling  the colours changes are evidence of chemical reactions  The substances that give rise to the transformation are called reagents and the substances that are formed are called chemicals (products) Reagents Chemicals Chemical reactions can be faster or less fast However we may act to increase or decrease the speed of a reaction in a lot of ways , for example using catalysts. Almost all the reactions that occur in living organisms are activated by biological catalysts, the enzymes.
  • 3. Even the stones breathe ( breathe out) Marble and hydrochloric acid You need: • a plastic spoon • hydrochloric acid • a glass rod • distilled water • marble powder • a beaker Process: o With the spatula take a small amount of marble powder, add water and a few drops of hydrochloric acid until all the solid has not disappeared. Observations: What do you observe? What do you think happened? Does the acid dissolve the marble in the
  • 4. same manner in which water dissolves salt and sugar? Has a new substance formed or not?
  • 5. Can it be stated that there has been a chemical reaction? Give an explanation What happened?  The effervescence observed in the test tube with the marble powder is due to the development of another gas, the carbon dioxide. The chemical reaction is: hydrochloric acid + marble calcium chloride + carbon dioxide + water
  • 6. Accadue HYDROGEN PRODUCTION (be careful !) The use of the match requires proper precautions and the completion of the experiment by the teacher. Targets To recognize a very fast and effect chemical reaction. You need: • Pieces of aluminum foil • A match (for food) • A wood pliers • Hydrochloric acid • A glass rod solution (muriatic) • Two test tubes • A test tube rack • a pipette Process: o Put some pieces of aluminum in a test tube o Add a few drops of hydrochloric acid
  • 7. What do you observe? In the test tube with aluminum effervescence is observed , the solution becomes darker and aluminum corrodes and disappears. You must wait a few minutes to allow reaction to develop, fragments are surrounded by bubbles of hydrogen that keep them afloat. o Place above the test tube the second inverted test tube, that is with the opening facing downwards, to collect the hydrogen which is lighter than air. o After a few minutes move away the second test tube, always keeping it inverted, from that in which hydrogen is generated and approach the entrance to a lighted match. What happens? We will hear a slight explosion and, if you look carefully, you can see a flame inside the test tube, while the blast of the explosion will turn off the match. The effervescence observed in the test tube with the aluminum is due to the development of a gas, the hydrogen. In the reaction we can also see that the hydrogen reacted with the oxygen in the air producing water vapor ( after the reaction we will find some condensation on the inner walls of the test tube). The chemical reaction is : 6HCI + 2AI 2 +3 ( Hydrochloric acid + aluminum aluminum chloride+ hydrogen)
  • 8.
  • 9. Balloon Let’s inflate a balloon without blowing You need : • an Erlenmeyer flask • a balloon • baking soda • graduated cylinder • vinegar • a funnel • a teaspoon Process: 1. Using a graduated cylinder pour 30ml of vinegar in the Erlenmeyer flask. 2. Stick a balloon to the mouth of the funnel. 3. Put a teaspoon of baking soda in the balloon . 4. Take off the funnel from the balloon. 5. Adjust the opening of the balloon around the neck of the flask, being careful not to fall into the baking soda. 6. Keep the flask still, raise the balloon in such a way to allow the
  • 10. baking soda to come into contact with the vinegar. Reflections What do you observe inside the flask? What happens to the balloon? What conclusions do you draw? What happens? After the baking soda has been dropped in vinegar, a chemical reaction starts for which we can note the development of foam and the balloon that is inflated. A gas called carbon dioxide develops. Since gases expand until they occupy all the space available , the carbon dioxide inflates the balloon. Touching it the bottle is cooled and at the end a deposit may remain. Baking soda + acetic acid = sodium acetate + water+ carbon dioxide The vinegar that remains ( if it is in excess of the amount of baking soda) is now diluted. If a white deposit remains on the bottom, it means that the vinegar was not sufficient to react all the baking soda.
  • 11. A volcano of foam (be careful !) TARGETS To recognize an exothermic reaction and the function of a catalyst You need: • An empty glass bottle (preferably with a narrow neck)or a graduated cylinder • 1/2 cup of hydrogen peroxide at 20 volumes • liquid detergent • 3-4 drops of food coloring • Potassium iodide • A funnel • A large and low container Process 1. Put the bottle in the centre of the container. Insert the funnel in the bottle and pour the peroxide.
  • 12. 2. Add the detergent to the peroxide in the bottle. What happens? 3. Add 3-4 drops of food coloring. 4. Dissolve two teaspoons of sodium iodide in a few millimeters of warm water in a beaker. 5. Quickly pour the sodium iodide in the bottle ( and move away). 6. The students can touch the bottle to feel all the changes that occur. What do you observe? The reaction creates foam which is shot out of the bottle. After about a minute a moving flow is formed. The bottle will feel warm to the touch as it is an exothermic reaction. To obtain the volcano of foam we have to use a catalyst, a substance that accelerates the rate of the reaction and that it is found unchanged at the end, without transformations. How does it work? The decomposition reaction of hydrogen peroxide into water and oxygen is the following: 2 2 O+ When we pour KI in the hydrogen peroxide / liquid detergent mixture, the volcano of foam starts. We will also recognize other phenomena such as the release of oxygen, the production of H2O in addition to changes in ph. A lot of reactions of industrial importance take place with the aid of suitable catalysts, all the reactions of biological importance take place with the aid of enzymes, active catalysts in living organisms.
  • 13. SECRET MESSAGES First message You need: • Lemon juice • A blank sheet of paper • A glass stick • A candle Process:
  • 14. o Take the stick and dunk it in the lemon juice o Write on a paper what you want or make a small drawing o Let the ink dry and wait till the writing disappears o Now let the paper pass over the flame of a candle being careful not to burn it. What do you observe? The writing reappears and it is perfectly legible What do you deduce? The heat makes the lemon juice react so that it darkens and makes visible the writing
  • 15. SECRET MESSAGES Second message You need: • A wad of cotton • A sheet of paper • Very diluted tincture of • Lemon juice, brush iodine What to do o Write a message on the white paper using a brush dipped in the lemon juice. o Let the writing dry till it becomes invisible. o Rub a wad of cotton soaked in a dilute solution of iodine on the sheet where it says. What do you observe? The writing reappears, white on a blue/purple background What do you deduce? The starch of the paper is combined with iodine by changing colour to the sheet of paper which becomes blue/purple. Also the vitamin c in lemon combines with the iodine but it forms a colourless molecule. So the area covered by the lemon juice stands on a colored background.
  • 16. Let’s change the colours The colour change may indicate the formation of new substances You need: o Two test tubes o Two pipettes o Solution of ferric chloride o Solution of potassium ferrocyanide Process: o Take a few ml of solution of ferric chloride ( a yellow- orange colour solution) by a pipette and put it into the two test tubes o Add some drops of a reactive called potassium ferrocyanide to the first test tube • What do you observe?
  • 17. The second solution, light yellow, added to the solution of ferric chloride determines a marked change in colour : the content of the test tube becomes blue ( also called Prussian blue) due to the formation of a new substance ( the ferric ferrocyanide) o Add some drops of potassium thiocyanate ( colourless solution) to the second test tube What do you observe? o The solution becomes dark red even if precipitate doesn’t form: the new formed red substance is soluble in water. Some chemical reactions occurred: the initial substances are transformed and they have given rise to new substances that there weren’t before, with their own evident characteristics ( a different coloration). Rubber egg How can an egg bounce like a ball without breaking You need: o A raw egg o A glass or a glass jar o Vinegar o (time) Process: 1) Put the egg into the glass jar and cover the egg with vinegar 2) After some hours look closely the egg. What do you observe? Do you see the bubbles formation around the eggshell? 3) Let the egg into the vinegar for 24-48 hours 4) On the second day, carefully pour the old vinegar down the drain and cover the egg with fresh vinegar
  • 18. 5) Don’t disturb the egg but pay attention to the bubbles that are formed on the surface of the eggshell ( or what’s left of it). 6) Pour the vinegar and rinse thoroughly the egg with water 7) What do you observe? The egg looks translucent because the outer shell has disappeared! The only thing that remains is the delicate membrane of the egg. What happened? The bubbles that cover the shell are carbon dioxide bubbles. Vinegar is an acid called acetic acid. ( White vinegar is usually made up of about 5% of acetic acid and 95% of water). The egg shells are composed of calcium carbonate. Vinegar reacts with the calcium carbonate giving origin to a substance called calcium acetate and carbon dioxide. The egg shell is reduced to a very thin layer and the egg is flexible. The shelled membrane remains . The semi-impermeable membrane in contact with the external solution begins to flow solvent ( the vinegar) inside the egg from the outside so that the concentration of particles inside balances the outside one. This flow of a liquid through a semi- impermeable membrane from a less concentrated solution to a more concentrated one is called osmosis. The volume of the egg has visibly increased showing the effect of osmotic pressure. If you shake the egg, the yolk can be seen splashing
  • 19. around the egg white. If the egg reacts with the carbon dioxide in the air it will harden.