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Energy and Metabolism

Muhammad Fahad Ansari 12IEEM14
The Energy of Life
• The living cell generates thousands of different
  reactions
• Metabolism
  – Is the totality of an organism’s chemical reactions
  – Arises from interactions between molecules
• An organism’s metabolism transforms matter
  and energy, subject to the laws of
  thermodynamics
•
                 Metabolic Pathways
   Biochemical pathways are the organizational units of metabolism
• Metabolism is the total of all chemical reactions carried out by an organism
• A metabolic pathway has many steps that begin with a specific molecule and
  end with a product, each catalyzed by a specific enzyme
• Reactions that join small molecules together to form larger, more complex
  molecules are called anabolic.
• Reactions that break large molecules down into smaller subunits are called
  catabolic.




                   Enzyme 1         Enzyme 2         Enzyme 3
          A                     B                C                  D
                   Reaction 1       Reaction 2       Reaction 3
        Starting                                                  Product
        molecule
Metabolic Pathway
• A sequence of chemical reactions, where the product of one
  reaction serves as a substrate for the next, is called a metabolic
  pathway or biochemical pathway
• Most metabolic pathways take place in specific regions of the
  cell.
Bioenergetics

• Bioenergetics is the study of how organisms
  manage their energy resources via metabolic
  pathways
• Catabolic pathways release energy by breaking
  down complex molecules into simpler
  compounds
• Anabolic pathways consume energy to build
  complex molecules from simpler ones
Energy
• Energy is the capacity to do work or ability to
  cause change. Any change in the universe
  requires energy. Energy comes in 2 forms:
  – Potential energy is stored energy. No change is
    currently taking place
  – Kinetic energy is currently causing change. This
    always involves some type of motion.
Forms of Energy
• Kinetic energy is the energy           On the platform, a diver
                                         has more potential energy.
                                                                              Diving converts potential
                                                                              energy to kinetic energy.

  associated with motion
• Potential energy
   – Is stored in the location of
     matter
   – Includes chemical energy
     stored in molecular
     structure
• Energy can be converted
  from one form to another
                                    Climbing up converts kinetic      In the water, a diver has
                                    energy of muscle movement          less potential energy.

                                    to potential energy.
Laws of Energy Transformation
• Thermodynamics is the study of energy
  changes.
• Two fundamental laws govern all energy
  changes in the universe. These 2 laws are
  simply called the first and second laws of
  thermodynamics:
The First Law of Thermodynamics
• According to the first law of thermodynamics
   – Energy cannot be created or destroyed
   – Energy can be transferred and transformed



                                                 Chemical
                                                 energy




                For example, the chemical (potential) energy
                in food will be converted to the kinetic
                energy of the cheetah’s movement
Second Law of Thermodynamics
•   The disorder (entropy) in the universe is continuously increasing.
     – Energy transformations proceed spontaneously to convert matter from a more
        ordered, less stable form, to a less ordered, more stable form
     – Spontaneous changes that do not require outside energy increase the entropy, or
        disorder, of the universe
     – For a process to occur without energy input, it must increase the entropy of the
        universe
Second Law some of the energy dissipates into the
– During each conversion,
                          of Thermodynamics
    environment as heat.
–   During every energy transfer or transformation, some energy is unusable,
    often lost as heat
–   Heat is defined as the measure of the random motion of molecules
–   Living cells unavoidably convert organized forms of energy to heat
–   According to the second law of thermodynamics, every energy transfer or
    transformation increases the entropy (disorder) of the universe



                                                              Heat             co2
                                                                                 +
                                                                                  H2O




               For example, disorder is added to the cheetah’ssurroundings in the form of heat and
               the small molecules that are the by-products of metabolism.
Biological Order and Disorder
• Cells create ordered structures from less ordered
  materials
• Organisms also replace ordered forms of matter
  and energy with less ordered forms
• The evolution of more complex organisms does not
  violate the second law of thermodynamics
• Entropy (disorder) may decrease in an organism,
  but the universe’s total entropy increases
Biological Order and Disorder
• Living systems
  – Increase the entropy of the universe
  – Use energy to maintain order
  – A living system’s free energy is energy that can do
    work under cellular conditions
  – Organisms live at the expense of free energy
                            50µm
Free Energy
• Free energy is the portion of a system’s energy that is able to
  perform work when temperature and pressure is uniform
  throughout the system, as in a living cell
• Free energy also refers to the amount of energy actually
  available to break and subsequently form other chemical
  bonds
• Gibbs’ free energy (G) – in a cell, the amount of energy
  contained in a molecule’s chemical bonds (T&P constant)
       • Change in free energy - ΔG
           – Endergonic - any reaction that requires an input of
             energy
           – Exergonic - any reaction that releases free energy
Exergonic reactions
• Reactants have more free energy than the products
• Involve a net release of energy and/or an increase in entropy
• Occur spontaneously (without a net input of energy)


                         Reactants



                                                                           Amount of
                                                                           energy
                                                                           released
           Free energy




                                                                           (∆G <0)
                                                 Energy
                                                                Products




                                     Progress of the reaction

          (a) Exergonic reaction: energy released
Endergonic Reactions
• Reactants have less free energy than the products
• Involve a net input of energy and/or a decrease in
  entropy
• Do not occur spontaneously
                                                                Products




                                                                           Amount of
                                                                           energy
          Free energy




                                                                           released
                                                                           (∆G>0)
                                            Energy
                         Reactants




                                     Progress of the reaction

        (b) Endergonic reaction: energy required
Energy released Energy supplied



                                                            Product

                                                                    Energy
                                                                    must be
                                                                    supplied.

                                       Reactant                                                Reactant           Energy is
                                                                                                                  released.


                                                                                                              Product
                                       Endergonic                                                 Exergonic


Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or display.
Understanding Heat Transfer,
Conduction, Convection and
        Radiation
Heat Transfer
• Heat always moves from a warmer place to a
  cooler place.
• Hot objects in a cooler room will cool to room
  temperature.
• Cold objects in a warmer room will heat up to
  room temperature.
Question
• If a cup of coffee and a red popsickle were left
  on the table in this room what would happen
  to them? Why?
• The cup of coffee will cool until it reaches
  room temperature. The popsickle will melt
  and then the liquid will warm to room
  temperature.
Heat Transfer Methods
• Heat transfers in three ways:
  –Conduction
  –Convection
  –Radiation
Conduction
  When you heat a metal strip at one end, the heat
  travels to the other end.




  As you heat the metal, the particles vibrate, these
  vibrations make the adjacent particles vibrate, and so on
  and so on, the vibrations are passed along the metal and
  so is the heat. We call this? Conduction
Metals are different


  The outer e______ of metal atoms
              lectrons
  drift, and are free to move.

                                             When the metal is heated, this
                                             ‘sea of electrons’ gain k_____
                                             energy and transfer it
                                                                    inetic
                                             throughout the metal.




               Insulators, such as w___ and p____, do not have this ‘sea of
                                           ood          lastic
               electrons’ which is why they do not conduct heat as well as
               metals.
Why does metal feel colder than wood, if they
are both at the same temperature?

   Metal is a conductor, wood is an insulator. Metal
   conducts the heat away from your hands. Wood
   does not conduct the heat away from your hands as
   well as the metal, so the wood feels warmer than
   the metal.
Convection
  What happens to the particles in a liquid or a
  gas when you heat them?


                      The particles spread out and
                          become less dense.




                           This effects afluid movement.
                                 What is or gas.
                                  A liquid fluid?
Fluid movement


                 Cooler, more d____, fluids
                               ense
                 sink through w_____, less
                               armer
                 dense fluids.

                 In effect, warmer liquids and gases r___
                 up.      ise


                 Cooler liquids and gases s___.   ink
Water movement

              Cools at the   Convection
                surface
                              current



  Cooler                                  Hot water
water sinks                                 rises
Why is it windy at the seaside?
Cold air sinks


    Where is the                  Freezer
       freezer                  compartment
    compartment
   put in a fridge?
                             It is warmer at
                             the bottom, so
                             this warmer air
   It is put at the top,
                               rises and a
     because cool air
                               convection
   sinks, so it cools the
                            current is set up.
      food on the way
           down.
The third method of heat transfer

 How does heat energy get
 from the Sun to the Earth?    There are no particles between
                               the Sun and the Earth so it
                               CANNOT travel by conduction or
                               by convection.




                                RADIATION
                        ?
Radiation

              Radiation travels in straight lines
                          True/False
            Radiation can travel through a vacuum
                          True/False
            Radiation requires particles to travel
                          True/False
            Radiation travels at the speed of light
                          True/False
Emission experiment
   Four containers were filled with warm water. Which
   container would have the warmest water after ten minutes?

                Dull metal                  Shiny black




  Shiny metal                Dull black

       shiny metal
 The __________ container would be the warmest after ten
 minutes because its shiny surface reflects heat radiation back
                                                      _______
                                         dull black
 into the container so less is lost. The ________ container
                                                    emitting
 would be the coolest because it is the best at _______ heat
 radiation.
Absorption experiment
Four containers were placed equidistant from a heater. Which
container would have the warmest water after ten minutes?

                 Dull metal                 Shiny black




  Shiny metal                 Dull black


          dull black
  The __________ container would be the warmest after ten
                                            radiation
  minutes because its surface absorbs heat _______ the best.
       shiny metal
  The _________ container would be the coolest because it is
                     absorbing
  the poorest at __________ heat radiation.
Convection questions

    Why does hot air rise and cold air sink?

    Cool air is more dense than warm air, so the cool air ‘falls
    through’ the warm air.




    Why are boilers placed beneath hot water
    tanks in people’s homes?
    Hot water rises.
    So when the boiler heats the water, and the hot water rises, the water tank
    is filled with hot water.
Radiation questions


  Why are houses painted white in hot countries?
  White reflects heat radiation and keeps the house cooler.




  Why are shiny foil blankets wrapped around marathon runners at the end of a
  race?


  The shiny metal reflects the heat radiation from the runner back in, this stops
  the runner getting cold.
1.  Which of the following is not a
method of heat transfer?

 A.   Radiation
 B.   Insulation
 C.   Conduction
 D.   Convection
2. In which of the following are
the particles closest together?

 A.   Solid
 B.   Liquid
 C.   Gas
 D.   Fluid
3. How does heat energy reach
the Earth from the Sun?

 A.   Radiation
 B.   Conduction
 C.   Convection
 D.   Insulation
4. Which is the best surface for
reflecting heat radiation?

 A.   Shiny white
 B.   Dull white
 C.   Shiny black
 D.   Dull black
5. Which is the best surface for
absorbing heat radiation?

 A.   Shiny white
 B.   Dull white
 C.   Shiny black
 D.   Dull black

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Energy and metabolism conduction,convection,radiation by Muhammad Fahad Ansari 12IEEM14

  • 1. Energy and Metabolism Muhammad Fahad Ansari 12IEEM14
  • 2. The Energy of Life • The living cell generates thousands of different reactions • Metabolism – Is the totality of an organism’s chemical reactions – Arises from interactions between molecules • An organism’s metabolism transforms matter and energy, subject to the laws of thermodynamics
  • 3. Metabolic Pathways Biochemical pathways are the organizational units of metabolism • Metabolism is the total of all chemical reactions carried out by an organism • A metabolic pathway has many steps that begin with a specific molecule and end with a product, each catalyzed by a specific enzyme • Reactions that join small molecules together to form larger, more complex molecules are called anabolic. • Reactions that break large molecules down into smaller subunits are called catabolic. Enzyme 1 Enzyme 2 Enzyme 3 A B C D Reaction 1 Reaction 2 Reaction 3 Starting Product molecule
  • 4. Metabolic Pathway • A sequence of chemical reactions, where the product of one reaction serves as a substrate for the next, is called a metabolic pathway or biochemical pathway • Most metabolic pathways take place in specific regions of the cell.
  • 5. Bioenergetics • Bioenergetics is the study of how organisms manage their energy resources via metabolic pathways • Catabolic pathways release energy by breaking down complex molecules into simpler compounds • Anabolic pathways consume energy to build complex molecules from simpler ones
  • 6. Energy • Energy is the capacity to do work or ability to cause change. Any change in the universe requires energy. Energy comes in 2 forms: – Potential energy is stored energy. No change is currently taking place – Kinetic energy is currently causing change. This always involves some type of motion.
  • 7. Forms of Energy • Kinetic energy is the energy On the platform, a diver has more potential energy. Diving converts potential energy to kinetic energy. associated with motion • Potential energy – Is stored in the location of matter – Includes chemical energy stored in molecular structure • Energy can be converted from one form to another Climbing up converts kinetic In the water, a diver has energy of muscle movement less potential energy. to potential energy.
  • 8. Laws of Energy Transformation • Thermodynamics is the study of energy changes. • Two fundamental laws govern all energy changes in the universe. These 2 laws are simply called the first and second laws of thermodynamics:
  • 9. The First Law of Thermodynamics • According to the first law of thermodynamics – Energy cannot be created or destroyed – Energy can be transferred and transformed Chemical energy For example, the chemical (potential) energy in food will be converted to the kinetic energy of the cheetah’s movement
  • 10. Second Law of Thermodynamics • The disorder (entropy) in the universe is continuously increasing. – Energy transformations proceed spontaneously to convert matter from a more ordered, less stable form, to a less ordered, more stable form – Spontaneous changes that do not require outside energy increase the entropy, or disorder, of the universe – For a process to occur without energy input, it must increase the entropy of the universe
  • 11. Second Law some of the energy dissipates into the – During each conversion, of Thermodynamics environment as heat. – During every energy transfer or transformation, some energy is unusable, often lost as heat – Heat is defined as the measure of the random motion of molecules – Living cells unavoidably convert organized forms of energy to heat – According to the second law of thermodynamics, every energy transfer or transformation increases the entropy (disorder) of the universe Heat co2 + H2O For example, disorder is added to the cheetah’ssurroundings in the form of heat and the small molecules that are the by-products of metabolism.
  • 12. Biological Order and Disorder • Cells create ordered structures from less ordered materials • Organisms also replace ordered forms of matter and energy with less ordered forms • The evolution of more complex organisms does not violate the second law of thermodynamics • Entropy (disorder) may decrease in an organism, but the universe’s total entropy increases
  • 13. Biological Order and Disorder • Living systems – Increase the entropy of the universe – Use energy to maintain order – A living system’s free energy is energy that can do work under cellular conditions – Organisms live at the expense of free energy 50µm
  • 14. Free Energy • Free energy is the portion of a system’s energy that is able to perform work when temperature and pressure is uniform throughout the system, as in a living cell • Free energy also refers to the amount of energy actually available to break and subsequently form other chemical bonds • Gibbs’ free energy (G) – in a cell, the amount of energy contained in a molecule’s chemical bonds (T&P constant) • Change in free energy - ΔG – Endergonic - any reaction that requires an input of energy – Exergonic - any reaction that releases free energy
  • 15. Exergonic reactions • Reactants have more free energy than the products • Involve a net release of energy and/or an increase in entropy • Occur spontaneously (without a net input of energy) Reactants Amount of energy released Free energy (∆G <0) Energy Products Progress of the reaction (a) Exergonic reaction: energy released
  • 16. Endergonic Reactions • Reactants have less free energy than the products • Involve a net input of energy and/or a decrease in entropy • Do not occur spontaneously Products Amount of energy Free energy released (∆G>0) Energy Reactants Progress of the reaction (b) Endergonic reaction: energy required
  • 17. Energy released Energy supplied Product Energy must be supplied. Reactant Reactant Energy is released. Product Endergonic Exergonic Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or display.
  • 18. Understanding Heat Transfer, Conduction, Convection and Radiation
  • 19. Heat Transfer • Heat always moves from a warmer place to a cooler place. • Hot objects in a cooler room will cool to room temperature. • Cold objects in a warmer room will heat up to room temperature.
  • 20. Question • If a cup of coffee and a red popsickle were left on the table in this room what would happen to them? Why? • The cup of coffee will cool until it reaches room temperature. The popsickle will melt and then the liquid will warm to room temperature.
  • 21. Heat Transfer Methods • Heat transfers in three ways: –Conduction –Convection –Radiation
  • 22. Conduction When you heat a metal strip at one end, the heat travels to the other end. As you heat the metal, the particles vibrate, these vibrations make the adjacent particles vibrate, and so on and so on, the vibrations are passed along the metal and so is the heat. We call this? Conduction
  • 23. Metals are different The outer e______ of metal atoms lectrons drift, and are free to move. When the metal is heated, this ‘sea of electrons’ gain k_____ energy and transfer it inetic throughout the metal. Insulators, such as w___ and p____, do not have this ‘sea of ood lastic electrons’ which is why they do not conduct heat as well as metals.
  • 24. Why does metal feel colder than wood, if they are both at the same temperature? Metal is a conductor, wood is an insulator. Metal conducts the heat away from your hands. Wood does not conduct the heat away from your hands as well as the metal, so the wood feels warmer than the metal.
  • 25. Convection What happens to the particles in a liquid or a gas when you heat them? The particles spread out and become less dense. This effects afluid movement. What is or gas. A liquid fluid?
  • 26. Fluid movement Cooler, more d____, fluids ense sink through w_____, less armer dense fluids. In effect, warmer liquids and gases r___ up. ise Cooler liquids and gases s___. ink
  • 27. Water movement Cools at the Convection surface current Cooler Hot water water sinks rises
  • 28. Why is it windy at the seaside?
  • 29. Cold air sinks Where is the Freezer freezer compartment compartment put in a fridge? It is warmer at the bottom, so this warmer air It is put at the top, rises and a because cool air convection sinks, so it cools the current is set up. food on the way down.
  • 30. The third method of heat transfer How does heat energy get from the Sun to the Earth? There are no particles between the Sun and the Earth so it CANNOT travel by conduction or by convection. RADIATION ?
  • 31. Radiation Radiation travels in straight lines True/False Radiation can travel through a vacuum True/False Radiation requires particles to travel True/False Radiation travels at the speed of light True/False
  • 32. Emission experiment Four containers were filled with warm water. Which container would have the warmest water after ten minutes? Dull metal Shiny black Shiny metal Dull black shiny metal The __________ container would be the warmest after ten minutes because its shiny surface reflects heat radiation back _______ dull black into the container so less is lost. The ________ container emitting would be the coolest because it is the best at _______ heat radiation.
  • 33. Absorption experiment Four containers were placed equidistant from a heater. Which container would have the warmest water after ten minutes? Dull metal Shiny black Shiny metal Dull black dull black The __________ container would be the warmest after ten radiation minutes because its surface absorbs heat _______ the best. shiny metal The _________ container would be the coolest because it is absorbing the poorest at __________ heat radiation.
  • 34. Convection questions Why does hot air rise and cold air sink? Cool air is more dense than warm air, so the cool air ‘falls through’ the warm air. Why are boilers placed beneath hot water tanks in people’s homes? Hot water rises. So when the boiler heats the water, and the hot water rises, the water tank is filled with hot water.
  • 35. Radiation questions Why are houses painted white in hot countries? White reflects heat radiation and keeps the house cooler. Why are shiny foil blankets wrapped around marathon runners at the end of a race? The shiny metal reflects the heat radiation from the runner back in, this stops the runner getting cold.
  • 36. 1. Which of the following is not a method of heat transfer? A. Radiation B. Insulation C. Conduction D. Convection
  • 37. 2. In which of the following are the particles closest together? A. Solid B. Liquid C. Gas D. Fluid
  • 38. 3. How does heat energy reach the Earth from the Sun? A. Radiation B. Conduction C. Convection D. Insulation
  • 39. 4. Which is the best surface for reflecting heat radiation? A. Shiny white B. Dull white C. Shiny black D. Dull black
  • 40. 5. Which is the best surface for absorbing heat radiation? A. Shiny white B. Dull white C. Shiny black D. Dull black