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International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 04 Issue: 11 | Nov -2017 www.irjet.net p-ISSN: 2395-0072
© 2017, IRJET | Impact Factor value: 6.171 | ISO 9001:2008 Certified Journal | Page 1148
Partial Replacement of Cement by Fly ash in Concrete Mix Design
Jagdish Virupakshi Patil1
M.Tech in Project and Construction Management, MIT ADT University, Pune, Maharashtra, India.
-----------------------------------------------------------------------------***----------------------------------------------------------------------------
Abstract - Concrete is the most important engineering
material in construction industry because of its inherent
strength properties. However, the addition of some other
materials may change the properties of concrete. With
increase in trend towards the wider use of concrete for pre-
stressed concrete and high rise buildings there is a growing
demand of concrete with higher compressive strength. The
mineral admixtures with pozzolanic properties such as flyash
(FA), silica fume (SF), ground blast-furnace slag (GGBS) and
metakaolin (MK) are commonly used as a partial substitution
of Portland cement during construction. Theseadmixturesare
often added to modify the physical and chemical properties of
cementitious mixes. In comparison to ordinary Portland
cement, the collection of flyash as a by-product requires less
energy and it produces less the main objectiveofthesepaperis
to see the difference between strengthandworkabilityofplain
concrete and concrete mix by using fly ash
Key Words- Fly-ash, Ordinary Portland Cement, Mix
Design, Workability.
1. INTRODUCTION
Fly ash is comprised of the non-combustible
mineral portion of coal. When coal is consumed in the
power plant, it is first ground to the fineness of powder.
Blown into the power plants boiler, the carbon is consumed,
leaving molten particles rich in silica alumina and calcium.
These particles solidify as microscopic, glassy spheres that
are collected from the power plants exhaust before they can
fly away- hence the products name fly ash. There are two
basic types of fly ash: Class F and Class C. According to ASTM
C618, fly ash belongs to Class F if (SiO2+Al2O3+Fe2O3) >
70% and belongs to Class C if 70% > (SiO2+Al2O3+Fe2O3) >
50%. Both these fly ashes undergo pozzolanic reaction with
lime (Calcium hydroxide) created by hydration of cement
and water to form calcium silicate hydrate like cement. In
addition, some Class C fly ashes may possess enough lime to
be self-cementing in addition to the pozzolanic reaction with
lime from cement hydration.
Through pozzolanic activity, fly ash combines with
free lime to produce the same cementitious compounds
formed by the hydration of Portland cement. Due to this
series of chemical reaction, rate of strength gain for fly ash
concrete is relatively slower at early ages of curing. During
the last few years, some cement companies have started
using fly ash in manufacturing cement, which is known as
“Pozzolana Portland Cement,” but the overall percentage
utilization remains very low and most of the fly ash is
dumped at landfills.
Fly ash is a fine, glass-like powder recovered from
gases created by coal-fired electric powergeneration.Power
plants produce millions of tons of fly ash annually, which is
usually dumped in landfills. Fly ash is an inexpensive
replacement for Portland cement used in concrete, while it
actually improves strength, and ease of pumping of the
concrete. Fly ash is also used as an ingredient in brick, block,
paving, and structural fills.
2. FLY ASH
2.1 CLASSIFICATION OF FLY-ASH
There are two basic types of fly ash: Class F and Class C.
Both types react in concrete insimilarways.BothClassFand
Class C fly ashes undergo a “pozzolanic reaction” with the
lime (calcium hydroxide) createdbythehydration(chemical
reaction) of cement and water, to create the same binder
(calcium silicate hydrate) as cement. In addition, some Class
C fly ashes may possess enough lime to be self-cementing, in
addition to the pozzolanic reaction with lime from cement
hydration.
2.2 PROPERTIES OF FLY-ASH
The fly ash or pulverized fuel is the residue, which is
collected by the mechanical dust collector or electrostatic
precipitator from the fuel gases of thermal power plants.
Composition of fly ash varies with the typeoffuel burnt,load
on the boiler and the type of separator. Like Portland
cement, fly ash contains oxides of calcium, aluminum and
silicon, but the amount of calcium oxide is considerably less.
The carbon contents should be as low as possible, whereas
the silica content should be as high as possible. Fly ash
obtained from electrostatic precipitator (ESP) may have a
specific surface of about 350 to 500 m2/kg. I.e.finerthanthe
Portland cement. Properties of fly ash in concrete are not
directly related to the chemistry of fly ash. Some properties
of fly ash are known by two parameters, these are fly ash
mineralogy and fly ash practical size.
2.3 ADVANTAGES OF FLY-ASH
The advantages of fly ash concrete over the
corresponding plain cement concrete are:
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 04 Issue: 11 | Nov -2017 www.irjet.net p-ISSN: 2395-0072
© 2017, IRJET | Impact Factor value: 6.171 | ISO 9001:2008 Certified Journal | Page 1149
 Improved workability
 Lower heat of hydration
 The increase in creep with fly ash content up to
15% is negligible
 Increases the modulusofelasticityofconcrete when
concretes of the same strength with and without fly
ash are compared
 Superior resistance to freezing and thawing
 Improved sulphate resistance
 Lower water and air permeability
 Lower leaching of lime liberated during hydratedof
cement
 Reduced alkali-aggregate reactions
 Greater resistance to attack of aggressive water
2.4 EFECT OF USING FLY-ASH IN FRESH & HARDENED
CONCRETE
 Use of right quality fly ash, results in reduction of
water demand for desired slump.
 With the reduction of unit water content, bleeding
and drying shrinkage will also be reduced.
 Since fly ash is not highly reactive, the heat of
hydration can be reduced through replacement of
part of the cement with fly ash.
 Fly ash, when used in concrete, contributes to the
strength of concrete due to its pozzolanic reactivity.
 The pozzolanic reaction also contributes to making
the texture of concrete dense, resulting in decrease
of water permeability & gas permeability.
 It should be noted thatsince pozzolanic reactioncan
only proceed in the presence of water, fly ash
concrete should be cured for longer time.
 Dams will derive full benefits of attaining improved
long term strength and water tightness.
3. MIX DESIGN
A mix is to be designed for characteristic strength of 50
N/mm2 at 28 days having target strength of 62 N/mm2 at 28
days. 30% of fly ash is to be included by weight of
cementitious material. Maximum w/c ratioorw/c +f.a.ratio
= 0.4,
Minimum cement concrete or cement + f.a. content = 400
kg/m3. Slump: Collapsible.
Fly ash or pulverized fuel ash (PFA) is a finely divided
powder thrown out as a waste material atthe thermal power
plants using pulverized coal for raising steam in the boilers.
In the building industry, the use of fly asha partreplacement
of cement in mortar and concrete attheconstructionsitehas
been made all over the world including India and is well
known.
A. Grade of Material:
 Cement: OPC, 53 grade, specific gravity = 3.15
 Fine aggregate: From river of Zone II Specific gravity =
2.6
 Coarse aggregate: Crushed 20 mm graded, Specific
gravity = 2.6
 Fly ash: As per I.S.: 3812, Specific gravity = 2.25
B. Workability:
 Water content reduction for fly ash concrete: 5%
 Increase in cementitious material: 12%
C. Designed plain concrete of above strength and
workability:
 Water (free) = 150 kg/m3
 OP Cement = 425 kg/m3
 Fine aggregate = 769 kg/m3
 Coarse aggregate = 1062 kg/m3
 Add mixture (Basf Rheoplus)= 4.3 kg/m3 (1% of
cement)
 Total = Sum of all of the above = 2410 kg/m3 (air = 1%)
D. Fly ash concrete of above strength and workability:
Table 1. Quantities of Materials used for Fly Ash
Concrete
Material Weight
(Kg/m3)
Volume
(m3)
Total Cementitious
Materials
476
OPC 333 0.1057
Fly Ash 143 0.0636
Water (free) 142.5 0.1425
Admixture 4.76 0.0045
Air (1%) 0.0100
Total 0.3263
Aggregate 1-0.3263 0.6737
Coarse Aggregate 1062 0.4085
Fine Aggregate 690 0.2652
Total 2375 1
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 04 Issue: 11 | Nov -2017 www.irjet.net p-ISSN: 2395-0072
© 2017, IRJET | Impact Factor value: 6.171 | ISO 9001:2008 Certified Journal | Page 1150
4 METHOD OF FLY ASH CONCRETE MIXING
For obtaining the best result the fly ash concrete should
be prepared by the following mixing method:
 About 3/4th quantity of the mixing water should be
taken in the concrete mixer. Weighted amount of
the required quantity of fly ash then added to it and
mixed for 30 sec. To the slurry of fly ash so
obtained, weighted quantities of coarse aggregate,
fine aggregate, cement and remaining quantity of
the mixing water be added and mixed for 90 sec.
However, if this is not convenient normal mixing method
may be adopted i.e.
 Weighted quantities of coarse aggregate, fine
aggregate cement and flyashshouldbeputtogether
in the concrete mixer and mixed dry for 30 sec. The
required quantity of the mixing water then added
and the mixing continued for 90 sec. TheAdmixture
should be added just before discharge of the mix
from mixer.
5 CONCLUSION
It may be noticed that, for the fly ash concrete the total
cementitious material is greater but the OPC content is
smaller, the fine aggregate content is reduced but the coarse
aggregate content is deliberately the same, the water is
reduced and the density is reduced because of the lower
density of fly ash compared with cement
A Comparison (kg/m3)
Table 2. Comparison between Plain Concrete & Fly Ash
Concrete Quantities
Materials Plain Concrete Fly ash Concrete
Water (free) 150 142.5
OP Cement 425 333
Fly ash — 143
Fine aggregate 769 690
Coarse aggregate 1062 1062
Admixture 4.300 4.76
Total 2410 2375
Saving in cement 425-333 = 92 kg/m3
REFERENCES
1] Ajay Verma, “Effect of Micro Silica on The Strength of
Concrete with Ordinary Portland Cement”, ResearchJournal
of Engineering Sciences, Vol. 1(3), 1-4, Sept. (2012) pp. 55-
75
2] .Alaa M. Rashad,” Effect of Silica Fume and Slag on
Compressive Strength and Abrasion Resistance of HVFA
Concrete”, International Journal of Concrete Structuresand
Materials Vol.8, No.1, pp.69–81
3] K Ganesh Babu and V. Sree Rama Kumar, “Efficiency of
GGBS in Concrete”, Cement and Concrete Research, Vol. 30,
2000, 1031- 1036.
4] D Dilip Kumar Singha Roy and AmitavaSil , “the effect of
Partial Replacement of Cement by Silica Fume on Hardened
Concrete” The Indian concrete Journal, September 2004, pp.
57-60.

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Partial Replacement of Cement by Fly ash in Concrete Mix Design

  • 1. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 04 Issue: 11 | Nov -2017 www.irjet.net p-ISSN: 2395-0072 © 2017, IRJET | Impact Factor value: 6.171 | ISO 9001:2008 Certified Journal | Page 1148 Partial Replacement of Cement by Fly ash in Concrete Mix Design Jagdish Virupakshi Patil1 M.Tech in Project and Construction Management, MIT ADT University, Pune, Maharashtra, India. -----------------------------------------------------------------------------***---------------------------------------------------------------------------- Abstract - Concrete is the most important engineering material in construction industry because of its inherent strength properties. However, the addition of some other materials may change the properties of concrete. With increase in trend towards the wider use of concrete for pre- stressed concrete and high rise buildings there is a growing demand of concrete with higher compressive strength. The mineral admixtures with pozzolanic properties such as flyash (FA), silica fume (SF), ground blast-furnace slag (GGBS) and metakaolin (MK) are commonly used as a partial substitution of Portland cement during construction. Theseadmixturesare often added to modify the physical and chemical properties of cementitious mixes. In comparison to ordinary Portland cement, the collection of flyash as a by-product requires less energy and it produces less the main objectiveofthesepaperis to see the difference between strengthandworkabilityofplain concrete and concrete mix by using fly ash Key Words- Fly-ash, Ordinary Portland Cement, Mix Design, Workability. 1. INTRODUCTION Fly ash is comprised of the non-combustible mineral portion of coal. When coal is consumed in the power plant, it is first ground to the fineness of powder. Blown into the power plants boiler, the carbon is consumed, leaving molten particles rich in silica alumina and calcium. These particles solidify as microscopic, glassy spheres that are collected from the power plants exhaust before they can fly away- hence the products name fly ash. There are two basic types of fly ash: Class F and Class C. According to ASTM C618, fly ash belongs to Class F if (SiO2+Al2O3+Fe2O3) > 70% and belongs to Class C if 70% > (SiO2+Al2O3+Fe2O3) > 50%. Both these fly ashes undergo pozzolanic reaction with lime (Calcium hydroxide) created by hydration of cement and water to form calcium silicate hydrate like cement. In addition, some Class C fly ashes may possess enough lime to be self-cementing in addition to the pozzolanic reaction with lime from cement hydration. Through pozzolanic activity, fly ash combines with free lime to produce the same cementitious compounds formed by the hydration of Portland cement. Due to this series of chemical reaction, rate of strength gain for fly ash concrete is relatively slower at early ages of curing. During the last few years, some cement companies have started using fly ash in manufacturing cement, which is known as “Pozzolana Portland Cement,” but the overall percentage utilization remains very low and most of the fly ash is dumped at landfills. Fly ash is a fine, glass-like powder recovered from gases created by coal-fired electric powergeneration.Power plants produce millions of tons of fly ash annually, which is usually dumped in landfills. Fly ash is an inexpensive replacement for Portland cement used in concrete, while it actually improves strength, and ease of pumping of the concrete. Fly ash is also used as an ingredient in brick, block, paving, and structural fills. 2. FLY ASH 2.1 CLASSIFICATION OF FLY-ASH There are two basic types of fly ash: Class F and Class C. Both types react in concrete insimilarways.BothClassFand Class C fly ashes undergo a “pozzolanic reaction” with the lime (calcium hydroxide) createdbythehydration(chemical reaction) of cement and water, to create the same binder (calcium silicate hydrate) as cement. In addition, some Class C fly ashes may possess enough lime to be self-cementing, in addition to the pozzolanic reaction with lime from cement hydration. 2.2 PROPERTIES OF FLY-ASH The fly ash or pulverized fuel is the residue, which is collected by the mechanical dust collector or electrostatic precipitator from the fuel gases of thermal power plants. Composition of fly ash varies with the typeoffuel burnt,load on the boiler and the type of separator. Like Portland cement, fly ash contains oxides of calcium, aluminum and silicon, but the amount of calcium oxide is considerably less. The carbon contents should be as low as possible, whereas the silica content should be as high as possible. Fly ash obtained from electrostatic precipitator (ESP) may have a specific surface of about 350 to 500 m2/kg. I.e.finerthanthe Portland cement. Properties of fly ash in concrete are not directly related to the chemistry of fly ash. Some properties of fly ash are known by two parameters, these are fly ash mineralogy and fly ash practical size. 2.3 ADVANTAGES OF FLY-ASH The advantages of fly ash concrete over the corresponding plain cement concrete are:
  • 2. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 04 Issue: 11 | Nov -2017 www.irjet.net p-ISSN: 2395-0072 © 2017, IRJET | Impact Factor value: 6.171 | ISO 9001:2008 Certified Journal | Page 1149  Improved workability  Lower heat of hydration  The increase in creep with fly ash content up to 15% is negligible  Increases the modulusofelasticityofconcrete when concretes of the same strength with and without fly ash are compared  Superior resistance to freezing and thawing  Improved sulphate resistance  Lower water and air permeability  Lower leaching of lime liberated during hydratedof cement  Reduced alkali-aggregate reactions  Greater resistance to attack of aggressive water 2.4 EFECT OF USING FLY-ASH IN FRESH & HARDENED CONCRETE  Use of right quality fly ash, results in reduction of water demand for desired slump.  With the reduction of unit water content, bleeding and drying shrinkage will also be reduced.  Since fly ash is not highly reactive, the heat of hydration can be reduced through replacement of part of the cement with fly ash.  Fly ash, when used in concrete, contributes to the strength of concrete due to its pozzolanic reactivity.  The pozzolanic reaction also contributes to making the texture of concrete dense, resulting in decrease of water permeability & gas permeability.  It should be noted thatsince pozzolanic reactioncan only proceed in the presence of water, fly ash concrete should be cured for longer time.  Dams will derive full benefits of attaining improved long term strength and water tightness. 3. MIX DESIGN A mix is to be designed for characteristic strength of 50 N/mm2 at 28 days having target strength of 62 N/mm2 at 28 days. 30% of fly ash is to be included by weight of cementitious material. Maximum w/c ratioorw/c +f.a.ratio = 0.4, Minimum cement concrete or cement + f.a. content = 400 kg/m3. Slump: Collapsible. Fly ash or pulverized fuel ash (PFA) is a finely divided powder thrown out as a waste material atthe thermal power plants using pulverized coal for raising steam in the boilers. In the building industry, the use of fly asha partreplacement of cement in mortar and concrete attheconstructionsitehas been made all over the world including India and is well known. A. Grade of Material:  Cement: OPC, 53 grade, specific gravity = 3.15  Fine aggregate: From river of Zone II Specific gravity = 2.6  Coarse aggregate: Crushed 20 mm graded, Specific gravity = 2.6  Fly ash: As per I.S.: 3812, Specific gravity = 2.25 B. Workability:  Water content reduction for fly ash concrete: 5%  Increase in cementitious material: 12% C. Designed plain concrete of above strength and workability:  Water (free) = 150 kg/m3  OP Cement = 425 kg/m3  Fine aggregate = 769 kg/m3  Coarse aggregate = 1062 kg/m3  Add mixture (Basf Rheoplus)= 4.3 kg/m3 (1% of cement)  Total = Sum of all of the above = 2410 kg/m3 (air = 1%) D. Fly ash concrete of above strength and workability: Table 1. Quantities of Materials used for Fly Ash Concrete Material Weight (Kg/m3) Volume (m3) Total Cementitious Materials 476 OPC 333 0.1057 Fly Ash 143 0.0636 Water (free) 142.5 0.1425 Admixture 4.76 0.0045 Air (1%) 0.0100 Total 0.3263 Aggregate 1-0.3263 0.6737 Coarse Aggregate 1062 0.4085 Fine Aggregate 690 0.2652 Total 2375 1
  • 3. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 04 Issue: 11 | Nov -2017 www.irjet.net p-ISSN: 2395-0072 © 2017, IRJET | Impact Factor value: 6.171 | ISO 9001:2008 Certified Journal | Page 1150 4 METHOD OF FLY ASH CONCRETE MIXING For obtaining the best result the fly ash concrete should be prepared by the following mixing method:  About 3/4th quantity of the mixing water should be taken in the concrete mixer. Weighted amount of the required quantity of fly ash then added to it and mixed for 30 sec. To the slurry of fly ash so obtained, weighted quantities of coarse aggregate, fine aggregate, cement and remaining quantity of the mixing water be added and mixed for 90 sec. However, if this is not convenient normal mixing method may be adopted i.e.  Weighted quantities of coarse aggregate, fine aggregate cement and flyashshouldbeputtogether in the concrete mixer and mixed dry for 30 sec. The required quantity of the mixing water then added and the mixing continued for 90 sec. TheAdmixture should be added just before discharge of the mix from mixer. 5 CONCLUSION It may be noticed that, for the fly ash concrete the total cementitious material is greater but the OPC content is smaller, the fine aggregate content is reduced but the coarse aggregate content is deliberately the same, the water is reduced and the density is reduced because of the lower density of fly ash compared with cement A Comparison (kg/m3) Table 2. Comparison between Plain Concrete & Fly Ash Concrete Quantities Materials Plain Concrete Fly ash Concrete Water (free) 150 142.5 OP Cement 425 333 Fly ash — 143 Fine aggregate 769 690 Coarse aggregate 1062 1062 Admixture 4.300 4.76 Total 2410 2375 Saving in cement 425-333 = 92 kg/m3 REFERENCES 1] Ajay Verma, “Effect of Micro Silica on The Strength of Concrete with Ordinary Portland Cement”, ResearchJournal of Engineering Sciences, Vol. 1(3), 1-4, Sept. (2012) pp. 55- 75 2] .Alaa M. Rashad,” Effect of Silica Fume and Slag on Compressive Strength and Abrasion Resistance of HVFA Concrete”, International Journal of Concrete Structuresand Materials Vol.8, No.1, pp.69–81 3] K Ganesh Babu and V. Sree Rama Kumar, “Efficiency of GGBS in Concrete”, Cement and Concrete Research, Vol. 30, 2000, 1031- 1036. 4] D Dilip Kumar Singha Roy and AmitavaSil , “the effect of Partial Replacement of Cement by Silica Fume on Hardened Concrete” The Indian concrete Journal, September 2004, pp. 57-60.