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Carbohydrates and lipids




                           Jorge Melo
   High specific heat capacity.




                                   High latent heat.
Hydrolysis   Condensation
   List the features of carbohydrates.
   Using diagrams to explain the structure of a
    simple carbohydrate.
   Explain how complex carbohydrates are
    formed from simple carbohydrates.
   List the differences between triglycerides and
    phospholipids.
   Describe the structure of lipids.
   Explain how the structure of lipids affects their
    properties.
   Carbohydrates
   Disaccharides
   Polysaccharides
   Lipids
   Triglycerides
   Phospholipids
   Cholesterol
   Most important source of energy

   Store energy

   Make structure

   Elimination of waste materials and
    toxins

   Sources: dairy products, fruits and sugar
    (simple) starches are found in grains or
    cereals such as rice, barley, oat,
    buckwheat, millet and rye, and in some
    root vegetables including parsnips and
    potatoes (more complex).
   Carbon    Hydrate

   Carbon and water

   3 atoms

   C
   O
   H
   Three types of
    carbohydrates
       Monosaccharides
        (simple sugars)
       Disaccharides
        (double sugars
        (form from two
        monosaccharides)
       Polysaccharides
        (polymer chain –
        hundreds of
        monosaccharides)
   Carbohydrates are made up of sugar
    molecules, the general formula for sugar is
    CnH2nOn.

   A carbohydrate that is a single sugar molecule is a
    monosaccharide. Examples include
    glucose, fructose, and galactose.

   As sugars monosaccharides are all sweet.

   Glucose is an example of a Hexose, and has two
    forms alpha and beta.
   The name of monosaccharides varies with the
         number of C atoms

3C      Trioses

5C      Pentoses

6C      Hexoses
   Main energy source
    for most living
    organisms

   Photosynthesis
    product

   Structural isomers

   α 1-4 linkages: starch
    (amylose and
    amylopectin) easy to
    break down by
    enzymes

   β 1-4 linkages: linear
    microfibrils of
    cellulose difficult to
    break down
   Fructose
        Very sweet sugar




   Galactose
        Found on milk


                            Galactose
   Made by joining two
    monosaccharides.


   Two α glucose molecules form
    maltose.

   condensation reaction.

   glycosidic bond (covalent)

   Because the link is between
    carbon 1 and 4, it’s an α 1-4
    glycosidic bond.

   Disaccharides are also sweet.
   Sucrose: the sugar you put in your tea




   lactose: milk sugar
   Using the diagram on the previous slide work
    out the formula for maltose.

   C12H22O11
   What name is given to the carbohydrate in which n
    is
     6
     5
     3



   State 2 different functions of the carbohydrates
   Simple carbohydrates are combined to form
    disaccharides, what else is produced?
   Maltose is broken down
    by the enzyme maltase.



   This is a hydrolysis
    reaction.
   Linking together thousands of α glucose molecules
    produces amylose found in starch.

   Amylose molecules coil to form long spirals held
    in place by hydrogen bonds, making it compact.

   Starch is insoluble and metabolically inactive
    making it perfect for storing in plant cells.

   It is not sweet.
   Animals do not store amylose, instead they use
    glycogen which is similar but contains 1-6
    glycosidic bonds forming side branches.
   Glycogen is broken down by the enzyme
    glycogen phosphorylase which is activated by
    insulin.
   Cellulose is similar to amylose but it is made of
    β-glucose, the β 1-4 bonds do not cause it to coil
    instead it is straight.

   As a result the molecules do not form hydrogen
    bonds within the same strand but with their
    neighbours forming bundles called fibrils which
    in turn for larger bundles called fibres all held by
    hydrogen bonds.

   This makes cellulose extremely strong, and there
    are very few animals with enzymes to break β 1-
    4 bonds.
   Fats and oils
       Room temp. fats are solids, oils are
        liquid
   Made of:
     C
     O
     H

   Higher proportion of H

   Insoluble in H2O
   Simplest example of
    a lipid

   3 fatty acids attached
    to a glycerol
    molecule
   The carboxyl group at the end
    of the fatty acid reacts with the
    hydroxyl group on the glycerol.

   Forming an ester bond,
    (involves covalent bonds).

   This is a condensation reaction

   Ester bond
   Insoluble in H2O – no
    charge

   Hydrophobic

   Saturated (where each of
    the carbons in the fatty
    acid are attached to two
    hydrogen atoms.)

   Unsaturated (double
    bonds)
   Like a triglyceride but one
    of the fatty acid chain
    replaced by a phosphate
    group

   Different properties

   Head hydrophobic
   Tail hydrophilic

   Blue: Fatty acid
   Pink: Glycerol
   Yellow phosphate group
   Basic form
    of the cell
    membrane
   Cholesterol is very
    different from other
    lipids, some don’t class
    it as a lipid at all.

   This basic structure is
    shared with all steroids
    that are made from it,
    many of which are
    hormones.
   List the features of carbohydrates.
   Using diagrams explain the structure of a
    simple carbohydrate.
   Explain how complex carbohydrates are
    formed from simple carbohydrates.
   List the differences between triglycerides and
    phospholipids.
   Describe the structure of lipids.
   Explain how the structure of lipids affects their
    properties.

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Carbs Lipids Structures Properties

  • 2.
  • 3. High specific heat capacity. High latent heat.
  • 4.
  • 5. Hydrolysis Condensation
  • 6.
  • 7.
  • 8.
  • 9.
  • 10. List the features of carbohydrates.  Using diagrams to explain the structure of a simple carbohydrate.  Explain how complex carbohydrates are formed from simple carbohydrates.  List the differences between triglycerides and phospholipids.  Describe the structure of lipids.  Explain how the structure of lipids affects their properties.
  • 11. Carbohydrates  Disaccharides  Polysaccharides  Lipids  Triglycerides  Phospholipids  Cholesterol
  • 12. Most important source of energy  Store energy  Make structure  Elimination of waste materials and toxins  Sources: dairy products, fruits and sugar (simple) starches are found in grains or cereals such as rice, barley, oat, buckwheat, millet and rye, and in some root vegetables including parsnips and potatoes (more complex).
  • 13. Carbon Hydrate  Carbon and water  3 atoms  C  O  H
  • 14. Three types of carbohydrates  Monosaccharides (simple sugars)  Disaccharides (double sugars (form from two monosaccharides)  Polysaccharides (polymer chain – hundreds of monosaccharides)
  • 15. Carbohydrates are made up of sugar molecules, the general formula for sugar is CnH2nOn.  A carbohydrate that is a single sugar molecule is a monosaccharide. Examples include glucose, fructose, and galactose.  As sugars monosaccharides are all sweet.  Glucose is an example of a Hexose, and has two forms alpha and beta.
  • 16. The name of monosaccharides varies with the number of C atoms 3C  Trioses 5C  Pentoses 6C  Hexoses
  • 17. Main energy source for most living organisms  Photosynthesis product  Structural isomers  α 1-4 linkages: starch (amylose and amylopectin) easy to break down by enzymes  β 1-4 linkages: linear microfibrils of cellulose difficult to break down
  • 18. Fructose  Very sweet sugar  Galactose  Found on milk Galactose
  • 19. Made by joining two monosaccharides.  Two α glucose molecules form maltose.  condensation reaction.  glycosidic bond (covalent)  Because the link is between carbon 1 and 4, it’s an α 1-4 glycosidic bond.  Disaccharides are also sweet.
  • 20. Sucrose: the sugar you put in your tea  lactose: milk sugar
  • 21. Using the diagram on the previous slide work out the formula for maltose.  C12H22O11
  • 22. What name is given to the carbohydrate in which n is  6  5  3  State 2 different functions of the carbohydrates  Simple carbohydrates are combined to form disaccharides, what else is produced?
  • 23. Maltose is broken down by the enzyme maltase.  This is a hydrolysis reaction.
  • 24.
  • 25. Linking together thousands of α glucose molecules produces amylose found in starch.  Amylose molecules coil to form long spirals held in place by hydrogen bonds, making it compact.  Starch is insoluble and metabolically inactive making it perfect for storing in plant cells.  It is not sweet.
  • 26. Animals do not store amylose, instead they use glycogen which is similar but contains 1-6 glycosidic bonds forming side branches.  Glycogen is broken down by the enzyme glycogen phosphorylase which is activated by insulin.
  • 27.
  • 28.
  • 29. Cellulose is similar to amylose but it is made of β-glucose, the β 1-4 bonds do not cause it to coil instead it is straight.  As a result the molecules do not form hydrogen bonds within the same strand but with their neighbours forming bundles called fibrils which in turn for larger bundles called fibres all held by hydrogen bonds.  This makes cellulose extremely strong, and there are very few animals with enzymes to break β 1- 4 bonds.
  • 30.
  • 31. Fats and oils  Room temp. fats are solids, oils are liquid  Made of:  C  O  H  Higher proportion of H  Insoluble in H2O
  • 32. Simplest example of a lipid  3 fatty acids attached to a glycerol molecule
  • 33. The carboxyl group at the end of the fatty acid reacts with the hydroxyl group on the glycerol.  Forming an ester bond, (involves covalent bonds).  This is a condensation reaction  Ester bond
  • 34. Insoluble in H2O – no charge  Hydrophobic  Saturated (where each of the carbons in the fatty acid are attached to two hydrogen atoms.)  Unsaturated (double bonds)
  • 35.
  • 36. Like a triglyceride but one of the fatty acid chain replaced by a phosphate group  Different properties  Head hydrophobic  Tail hydrophilic  Blue: Fatty acid  Pink: Glycerol  Yellow phosphate group
  • 37. Basic form of the cell membrane
  • 38. Cholesterol is very different from other lipids, some don’t class it as a lipid at all.  This basic structure is shared with all steroids that are made from it, many of which are hormones.
  • 39.
  • 40.
  • 41. List the features of carbohydrates.  Using diagrams explain the structure of a simple carbohydrate.  Explain how complex carbohydrates are formed from simple carbohydrates.  List the differences between triglycerides and phospholipids.  Describe the structure of lipids.  Explain how the structure of lipids affects their properties.