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The molarity of an aqueous solution of sodium hydroxide, NaOH, is determined by titration
against a 0.102 M hydrochloric acid, HCl, solution HCINaOH-NaClH20 If 30.1 mL of the base
are required to neutralize 21.7 mL of hydrochloric acid, what is the molarity of the sodium
hydroxide solution? Molarity
Solution
1.
HCl + NaOH -------> NaCl + H2O
In the above reaction equation; HCl and NaOH reacts in 1:1 ratio.
21.7 mL of 0.102 M HCl
So, moles of HCl = 0.102 M x 0.0217 L = 0.0022134 moles
Hence, the moles of NaOH will also be equal to 0.0022134 moles
Volume of NaOH = 30.1 mL = 0.0301 L
[NaOH] = 0.0022134 mol / 0.0301 L = 0.074 M
2.
HBr + Ba(OH)2 -------> BaBr2 + 2H2O
In the above reaction equation; HBr and Ba(OH)2 reacts in 2:1 ratio.
28.0 mL of 0.0471 M Ba(OH)2
So, moles of Ba(OH)2 = 0.0471 M x 0.028 L = 0.0013188 moles
Hence, the moles of HBr = (0.0013188 x 2) moles = 0.0026376 moles
Volume of HBr = 16.9 mL = 0.0169 L
[HBr] = 0.0026376 mol / 0.0169 L = 0.156 M
3.
pOH = 6.10
pH = 14 – pOH = 14 – 6.10 = 7.90
pOH = 6.10
Or, - log [OH-] = 6.10
Or,[OH-] = 10 -6.10
= 7.94 x 10^-7
pH = 7.90
Or, - log [H3O+] = 7.90
Or,[H3O+] = 10 -7.90
= 1.26 x 10^-8
4.
pH = 7.20
pOH = 14 – pH = 14 – 7.20 = 6.80
pOH = 6.80
Or, - log [OH-] = 6.80
Or,[OH-] = 10 -6.80
= 1.58 x 10^-7
pH = 7.90
Or, - log [H3O+] = 7.20
Or,[H3O+] = 10 -7.20
= 6.31 x 10^-8

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NaOH Molarity by Titration vs HCl

  • 1. The molarity of an aqueous solution of sodium hydroxide, NaOH, is determined by titration against a 0.102 M hydrochloric acid, HCl, solution HCINaOH-NaClH20 If 30.1 mL of the base are required to neutralize 21.7 mL of hydrochloric acid, what is the molarity of the sodium hydroxide solution? Molarity Solution 1. HCl + NaOH -------> NaCl + H2O In the above reaction equation; HCl and NaOH reacts in 1:1 ratio. 21.7 mL of 0.102 M HCl So, moles of HCl = 0.102 M x 0.0217 L = 0.0022134 moles Hence, the moles of NaOH will also be equal to 0.0022134 moles Volume of NaOH = 30.1 mL = 0.0301 L [NaOH] = 0.0022134 mol / 0.0301 L = 0.074 M 2. HBr + Ba(OH)2 -------> BaBr2 + 2H2O In the above reaction equation; HBr and Ba(OH)2 reacts in 2:1 ratio. 28.0 mL of 0.0471 M Ba(OH)2 So, moles of Ba(OH)2 = 0.0471 M x 0.028 L = 0.0013188 moles Hence, the moles of HBr = (0.0013188 x 2) moles = 0.0026376 moles Volume of HBr = 16.9 mL = 0.0169 L [HBr] = 0.0026376 mol / 0.0169 L = 0.156 M 3. pOH = 6.10
  • 2. pH = 14 – pOH = 14 – 6.10 = 7.90 pOH = 6.10 Or, - log [OH-] = 6.10 Or,[OH-] = 10 -6.10 = 7.94 x 10^-7 pH = 7.90 Or, - log [H3O+] = 7.90 Or,[H3O+] = 10 -7.90 = 1.26 x 10^-8 4. pH = 7.20 pOH = 14 – pH = 14 – 7.20 = 6.80 pOH = 6.80 Or, - log [OH-] = 6.80 Or,[OH-] = 10 -6.80 = 1.58 x 10^-7 pH = 7.90 Or, - log [H3O+] = 7.20 Or,[H3O+] = 10 -7.20 = 6.31 x 10^-8