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POLYMERS ,[object Object],[object Object],[object Object],[object Object],[object Object]
Polymer ,[object Object],[object Object],[object Object],[object Object]
Types of Polymers ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Thermoplastic Polymers - Thermoplastics ,[object Object],[object Object],[object Object],[object Object]
Thermosetting Polymers - Thermosets ,[object Object],[object Object],[object Object],[object Object],[object Object]
Elastomers (Rubbers) ,[object Object],[object Object],[object Object]
Market Shares ,[object Object],[object Object],[object Object],[object Object]
Examples of Polymers ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Reasons Why Polymers are Important  ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
General Properties of Polymers  ,[object Object],[object Object],[object Object],[object Object]
Limitations of Polymers ,[object Object],[object Object],[object Object],[object Object],[object Object]
Synthesis of Polymers  ,[object Object],[object Object],[object Object],[object Object]
Polyethylene ,[object Object]
Polymerization ,[object Object],[object Object],[object Object],[object Object]
Addition Polymerization ,[object Object],[object Object],[object Object]
Addition Polymerization ,[object Object]
Step Polymerization ,[object Object],[object Object],[object Object]
Step Polymerization ,[object Object]
Some Examples ,[object Object],[object Object],[object Object],[object Object]
Degree of Polymerization ,[object Object],[object Object],[object Object],[object Object],[object Object]
Molecular Weight  ,[object Object],[object Object],[object Object]
Typical Values of DP and MW MW 300,000 100,000 15,000 40,000 DP( n ) 10,000 1,500 120 200 Polymer Polyethylene Polyvinylchloride Nylon Polycarbonate
Polymer Molecular Structures ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Polymer Molecular Structures ,[object Object],[object Object],[object Object]
Effect of Branching on Properties ,[object Object],[object Object],[object Object],[object Object]
Effect of Cross-Linking on Properties ,[object Object],[object Object],[object Object],[object Object],[object Object]
Crystallinity in Polymers ,[object Object],[object Object],[object Object]
Crystalline Polymer Structure ,[object Object]
Crystallinity and Properties ,[object Object],[object Object],[object Object],[object Object],[object Object]
Low Density & High Density Polyethylene 135  C  (275  F) 115  C  (239  F) Melting temperature 700 MPa (100,000 lb/in 2 ) 140 MPa (20,000 lb/in 2 ) Modulus of elasticity 0.96 0.92 Specific gravity 92% 55% Degree of crystallinity High density Low density Polyethylene type
Some Observations About Crystallization ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Factors for Crystallization ,[object Object],[object Object],[object Object]
Thermal Behavior of Polymers ,[object Object]
Additives  ,[object Object],[object Object],[object Object]
Types of Additives by Function ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Thermoplastic Polymers (TP) ,[object Object],[object Object],[object Object],[object Object]
Mechanical Properties of Thermoplastics ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Strength vs. Temperature ,[object Object]
Physical Properties of Thermoplastics ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Commercial Thermoplastic  Products and Raw Materials ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Thermosetting Polymers (TS) ,[object Object],[object Object],[object Object],[object Object]
General Properties of Thermosets  ,[object Object],[object Object],[object Object],[object Object],[object Object]
Cross-Linking in TS Polymers ,[object Object],[object Object],[object Object],[object Object],[object Object]
Temperature‑Activated Systems ,[object Object],[object Object],[object Object],[object Object],[object Object]
Catalyst‑Activated Systems  ,[object Object],[object Object],[object Object]
Mixing‑Activated Systems ,[object Object],[object Object],[object Object]
TS vs. TP Polymers ,[object Object],[object Object],[object Object],[object Object],[object Object]
Elastomers ,[object Object],[object Object],[object Object],[object Object],[object Object]
Characteristics of Elastomers ,[object Object],[object Object],[object Object],[object Object]
Elastomer Molecules ,[object Object]
Elastic Behavior of Elastomer Molecule ,[object Object],[object Object],[object Object],[object Object]
Stiffness of Rubber ,[object Object]
Vulcanization ,[object Object],[object Object],[object Object],[object Object]
Natural Rubber (NR) ,[object Object],[object Object],[object Object],[object Object]
Vulcanized Natural Rubber ,[object Object],[object Object],[object Object],[object Object]
Natural Rubber Products ,[object Object],[object Object],[object Object],[object Object],[object Object]
Synthetic Rubbers ,[object Object],[object Object],[object Object],[object Object]
Thermoplastic Elastomers (TPE) ,[object Object],[object Object],[object Object],[object Object]
Guide to the  Processing of Polymers ,[object Object],[object Object],[object Object],[object Object],[object Object]

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Ch08

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  • 22. Typical Values of DP and MW MW 300,000 100,000 15,000 40,000 DP( n ) 10,000 1,500 120 200 Polymer Polyethylene Polyvinylchloride Nylon Polycarbonate
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  • 30. Low Density & High Density Polyethylene 135  C (275  F) 115  C (239  F) Melting temperature 700 MPa (100,000 lb/in 2 ) 140 MPa (20,000 lb/in 2 ) Modulus of elasticity 0.96 0.92 Specific gravity 92% 55% Degree of crystallinity High density Low density Polyethylene type
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