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Gfs chemicals organic capabilities 2010

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Liza Tallon
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ISO 9001:2008 Certified U.S. Based Manufacturing Since 1928
www.GFSChemicals.com Leaders in Small Molecule Building Blocks Shipping/Receiving Columbus, OH Manufacturing Complex
Why Source from GFS? ,[object Object],[object Object],[object Object],[object Object],[object Object],www.GFSChemicals.com Leaders in Small Molecule Building Blocks
Equipment Capabilities and Scale (Organic Division) ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],www.GFSChemicals.com Leaders in Small Molecule Building Blocks ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Equipment Capabilities and Scale (Organic Division) ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],www.GFSChemicals.com Leaders in Small Molecule Building Blocks ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Core Organic Technologies ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],www.GFSChemicals.com Leaders in Small Molecule Building Blocks
[object Object],[object Object],Liquid Ammonia www.GFSChemicals.com Leaders in Small Molecule Building Blocks NH 3
Liquid Ammonia ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],www.GFSChemicals.com Leaders in Small Molecule Building Blocks NH 3
Acetylene Reactions ,[object Object],[object Object],www.GFSChemicals.com Leaders in Small Molecule Building Blocks HC CH
Alkyne Chemistry ,[object Object],[object Object],[object Object],[object Object],www.GFSChemicals.com Leaders in Small Molecule Building Blocks RC CH
Alkyne Chemistry ,[object Object],[object Object],www.GFSChemicals.com Leaders in Small Molecule Building Blocks RC CH
Alkyne Chemistry www.GFSChemicals.com Leaders in Small Molecule Building Blocks RC CH Benzofurans Indoles Isocoumarins Isoquinolines Pyrimidines Furopyridines
Organometallics (Mg, Li, Na) ,[object Object],[object Object],[object Object],www.GFSChemicals.com Leaders in Small Molecule Building Blocks RMgX RLi
Organometallics (Mg, Li, Na) ,[object Object],[object Object],[object Object],[object Object],www.GFSChemicals.com Leaders in Small Molecule Building Blocks RMgX RLi
Halogen Chemistry (Cl, Br, I) ,[object Object],[object Object],[object Object],[object Object],[object Object],www.GFSChemicals.com Leaders in Small Molecule Building Blocks Cl, Br, I
Heteroaromatic Chemistry ,[object Object],[object Object],[object Object],[object Object],[object Object],www.GFSChemicals.com Leaders in Small Molecule Building Blocks Pyridines Phenylenediamines Acetylenes
Core Organic Synthetic Methods Performed at GFS ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],www.GFSChemicals.com Leaders in Small Molecule Building Blocks
Reagents Handled Routinely at GFS in > 100 kg Quantities ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],www.GFSChemicals.com Leaders in Small Molecule Building Blocks

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Gfs chemicals organic capabilities 2010

Notas del editor

  1. Many reactions are Palladium or Copper catalyzed.
  2. Many reactions are Palladium or Copper catalyzed.
  3. Terminal Alkynes, Internal Alkynes, Alkynols, Amines (Ammonia to bromo alkane)
  4. Alkylate across diphenylmethane (diphenylalkanes), Birch reductions, trans-olefins (Cis done through palladium catalysis), alkylation of nitriles
  5. Terminal alkynes – Bromoalkane & Na/Li acetylide, Terminal alkynes & ethylene oxide (3-yn-1-ol), Na/Li acetylide & Bromochloroalkane, Acetylene & epichlorohydrin to make 2-en-4-yn-1-ols, dibromoalkane & acetylene SLA gives alpha-omega diynes.
  6. Aldehydes(Triethylorthoformate), Ketones(from amide), Esters(chloroformate coupling, alcohols (ethlyene oxide for 3-yn-1-ols)
  7. Symmetric and asymmetric diynes. Alkynyl grignards (displacement of alkane with acetylene), organometallic diyn (lithium) for further addition
  8. Scores of heterocycles can be made using acetylenes. See detailed technical acetylenic presentation for more info.
  9. Alkyl lithium and alkyl Magnesium halides. Chain lengthening of alkanes. Addition to aryl ring, alkynyl grignards for addition, Blocked alcohol addition
  10. Dimethylformamide + alkyl lithium or Alkyl MgX (adds across carbonyl, hydrolysis splits out dimethylamine) or Triethylorthoformate + alkyl lithium or Alkyl MgX – displace two ethyl group through reaction and hydrolysis, paraformaldehyde and addition across carbonyl by alkyl lithium or grignard, michael addition for ene one (unsaturated ketone), substituded phenyl addition
  11. Aldehydes, Ketones, Esters, alcohols (ethlyene oxide for 3-yn-1-ols)
  12. Many reactions are Palladium or Copper catalyzed.