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Biodiesel 101

    By: Luke Closs
        @lukec

vancouverbiodiesel.org
    @vanbiodiesel
What is Biodiesel?
• Renewable fuel for Diesel Engines

• Derived from natural oils

• Meets ASTM D 6751 specification




                                      2
What is Biodiesel?
• Biodiesel can be mixed with Petro-diesel in any
  ratio.
  – B50 is 50% Biodiesel, 50% Petrodiesel
  – B100 is 100% Biodiesel


• Biodiesel can be used in most Diesel engines
  with little or no modification


                                            3
Rudolf Diesel
• Design the Diesel
  engine to run on
  peanut fuel
• Farmers can be
  more independent




                               4
Rudolf Diesel
• “The use of vegetable oils for engine fuels may
  seem insignificant today. But such oils may
  become in the course of time as important as
  petroleum and the coal tar products of the present
  time” - 1912




                                              5
Biodiesel Performance
• Pretty much the same as Petrodiesel
• Highest BTU content of any alternative fuel
• High lubricity
  – protects, extends engine life
  – Low sulfur diesel has a very low lubricity, requires an
    additive. Biodiesel solves this.
• Fuel consumption, horsepower, torque, similar to
  petrodiesel.

                                                    6
Biodiesel Toxicity
•   Very high flash point (260°F vs 125°F for diesel)
•   Safest fuel to use, handle, store
•   Biodegrades four times faster than petrodiesel
•   Will not harm fish
•   Less toxic than table salt




                                               7
B5 Today
• BC Provincial government mandated that diesel
  fuel must contain at least a 5% biodiesel content
  – Even a B2 blend greatly improves lubricity




                                                 8
What is Biodiesel Not?
• Biodiesel is not Ethanol!
  – Ethanol is made from fermenting the whole corn
    kernel to ethanol
  – Ethanol is intended only for gasoline engines
  – “Drink the best and burn the rest”




                                                9
What is Biodiesel Not?
• Biodiesel is not raw vegetable oil
• Veggie Oil can also be used as a fuel, often called
  WVO - Waste Veggie Oil
• WVO can be burned in Diesel engines, but
  requires modifications to the fuel system.




                                              10
Brief Diversion: WVO
• How do waste veggie oil systems work?
• SVO - Straight Veggie Oil
  – Fuel system is modified to pre-heat fuel before it gets
    to the engine
• Dual Fuel Systems
  – Start up engine on petro/bio-diesel, let it get warm
  – Switch fuel system over to WVO
  – Switch back to purge system at end of trip

                                                    11
Biodiesel & Clean Air
• Biodiesel exhaust is safer to breathe
• Less offensive exhaust
    – smells more like french fries
•   Reduces cancer-causing compounds by 80-90%
•   Reduces particulate matter in exhaust
•   Lowers net carbon in biosphere
•   Soy B100 reduces lifecycle CO2 by 78%


                                          12
Biodiesel & Energy Balance
• Highest energy balance of any fuel
  – 3.2 units of energy gained per one unit of fossil fuel
    to produce
• Petroleum diesel production creates negative
  energy balance
  – 0.88 unit of energy per one unit of fossil fuel
• One gallon of biodiesel could conserve four
  gallons of petroleum diesel!

                                                      13
Making Biodiesel
• Raw Materials:
  – Oil or Fat
  – Alcohol
  – Catalyst
• Mechanically combine
• Yields: Biodiesel and Glycerin



                                    14
Raw Materials - Fats
•   Soybean            • Animal Tallow
•   Corn               • Used Cooking Oils
•   Canola             • Camellia
•   Cottonseed
•   Sunflower          • Algae?
•   Lards



                                     15
Raw Materials - Other
• Alcohol
  – Methanol
  – Ethanol
• Catalyst
  – Sodium hydroxide
  – Potassium hydroxide




                                     16
Biodiesel Reaction
• In the presence of a catalyst, combining:
• 100 lbs of oil + 10 lbs of Methanol/Ethanol
  – yields:
• 100 lbs of Biodiesel + 10 lbs of Glycerin
  – (Assuming reaction is pushed to 100%)




                                                17
Homebrew
• You can do this at home!
• In a blender:
   – Waste veggie oil
   – Methanol
   – Lie
• Mix!
• Let sit


                               18
Quality
•   Need to remove all the free glycerin
•   Need to remove all the lie
•   Need to remove all the methanol
•   Need to remove any water in the oil

• You do not want these in your engine.



                                           19
Improving Quality
• Oil can be heated to remove water
  – Especially for WVO
• After the mechanical combination with the
  catalyst, the biodiesel can be “washed” to remove
  the catalyst, alcohols & glycerin.




                                            20
Homebrew
• You can produce high quality biodiesel at home
  with a small scale reactor
  – It’s a decent amount of work
  – Professional fuel testing is very expensive, so it’s
    hard to say exactly the quality
  – Burn it yourself, but questionable to homebrew for
    other people



                                                   21
Biodiesel in the Pacific Northwest
• Consumer locations:
  –   Vancouver Biodiesel Co-op (more later)
  –   B5 at the pump (meh)
  –   Duncan (Vancouver Island)
  –   Bellingham
  –   I5 Corridor




                                               22
Biodiesel in the Pacific Northwest
• Producers / Distributors:
  –   Consolidated Biofuels - Delta, BC
  –   Cowichan Biodiesel Co-op - Duncan, BC
  –   Whole Energy - Washington State
  –   Cascadia Biofuels - Washington




                                              23
Biodiesel and Taxes
• Prior to July 2010, Biodiesel was exempt from
  the Motor Fuels Tax (26¢/Litre)
• BC’s carbon tax was introduced. Biodiesel gets
  another 6.39¢/L
• Biodiesel is suddenly no longer price competitive




                                            24
Biodiesel Incentives
• In the USA, a “blenders credit” is given for
  blending Biodiesel with Diesel of 1¢/gal for each
  % of biodiesel.
• B99 yields a 99¢/gal credit
• As a result, almost all BC produced biodiesel
  goes to the US - $1 profit right there.
  – It often comes back into Canada after



                                             25
BC’s B5 Mandate
• BC Mandated B5 in all diesel sold
• All this biodiesel comes up from the US, often
  very far away
• Done by the big oil companies
• Tradeoff: more bio litres vs supporting local bio




                                              26
Burning Bio in your Car
• Old diesels pretty much love it.
• Those japanese vans you see around?
  – They love biodiesel
• B20 and lower is a drop-in replacement for diesel
• Take cold weather precautions
•



                                            27
Burning Bio - Some maintenance
• Biodiesel has a solvent effect
• Cleans out buildup from petro-diesel
• Fuel filters can clog up from the petro-diesel crud
  – Change fuel filter after 6 months of biodiesel use
• Biodiesel can eat rubber fuel lines, gaskets
  – Replace them with synthetic lines (Viton)
  – Only applies to vehicles older than mid nineties


                                                   28
Burning Bio - Rich Blends
• B100 issues to be aware of:
  –   Cold flow issues (gelling)
  –   Rubber hoses, gaskets
  –   Cleaning effect is more immediate
  –   Fuel filter clogging is the most common problem
       • Keep a spare, if possible




                                                  29
B20 vs Diesel
• Same issues you’d expect, except:
  – Less lubricity problems
  – Fuel filter problems due to diesel crud or bad
    biodiesel
  – Less black smoke from the exhaust!




                                                     30
Biodiesel & Your Warranty
• Usually warranties are the biggest impediment to
  burning biodiesel in new cars
  – All major OEMs support at least B5 & lower
    provided they meat ASTM D 6751
  – Increasingly support for B20 is seen
  – Play it safe or know what you’re doing!




                                                 31
Sounds great, where do I get some?




                              32
VBC: 360 Industrial Ave
Google's Eye View of our Co-op
Co-op Chair (Dave) at our Pump
In the beginning …

• VBC was started in 2003
• Robb Miller & Recycling Alternative
• Homebrew Biodiesel from WVO
• 50L drum
• Honour system - pen, paper & a
  binder
In the beginning … Problems!

Growing pains
• Tank runs dry

• Losing $$
In the beginning … Infrastructure!

• RA purchases:
  o 4000L tank, cardlock, old pump

• RA admin staff process payments

• City likes it, but uncomfortable, unsure
  o RA: Install Concrete pad, berm, drain
  o City: ☺
VBC … Today

• BC's biggest biofuel co-op:
  o 200+ members
  o Only source of B100 in Greater
    Vancouver Area
  o 4000L tank, 24/7 cardlock
  o ~2000-6000L sold per month
VBC … Challenges
• Technical
   o Cold winters are cold
   o High taxes are high
   o Manual processes are manual

• Social
  o Maintaining an engaged Board of Directors
  o Engaging our membership
VBC … Projects
VBC: Automated Billing

• Created by Luke & Recycling Alternative

• Web based tool for Co-op Admin

• Interfaces with cardlock in realtime

• Tracks all members, all purchases
VBC: Automated Billing

• Transactions sent to CC processor

• Email receipt / invoice sent to member

• Bad accounts are frozen
VBC: Automated Billing

• Benefits
  o Lower costs (Less admin time)
  o Detailed usage tracking
  o More scalable
     Could add more pumps
  o More professional
VBC: Future
• Expansion: More pumps in Lower Mainland?
  BC?
  o Made possible by automated system
  o Cardlock + Fuel Tank + Trailer + GPS + Cell
    Modem + Solar Panel = Portable Biodiesel
    Fuel Network!

• Engagement:
  o More active Board of Directors
  o More engaged membership
VBC: Future
• Collaboration with other BC Co-ops
  o BC Biodiesel Network?
  o Co-op "roaming" capability?

• Integrating WVO Collection capabilities?
   o Goal: Local fuel, lower costs
Biodiesel and Organizational
         Structures




                           47
Co-ops are great
• “Sharing” vs “Buying”
  – Less strict guidelines when you are sharing
• Ideally less overhead because no profit taking
• Operational costs are often cheaper for non-
  profits and co-op organizations




                                                  48
Co-ops are great, but …
• 80/20 rule - (95/5?)
  – 95% of the work is done by 5% of the people
  – no profit incentive means easy to burnout people
• Hard to be successful alone as a co-op
• Most people just want to buy fuel, they don’t
  want to make it.



                                                  49
Vancouver Biodiesel Co-op
• Today just a legal structure co-op, advocacy
  group
• Operations is all done by a benevolent company
  – Recycling Alternative
     • They run their diesel vehicle fleet on biodiesel
  – They organize the fuel purchases, resupply, billing
• VBC couldn’t operate today without RA


                                                          50
Cowichan / Duncan
•   Started out as a members co-op
•   Members picked up oil, made fuel, shared it.
•   People join to get cheap fuel, don’t want to work-
•   Makers get tired, aren’t compensated
•   Time for a change




                                               51
Cowichan Biodiesel Co-op
• smellbetter.org
• Buys biodiesel, has a 4000L tank, cardlock,
  pump
• Sells pre-paid cards to members
• Operationally light, but still supported by other
  orgs …



                                               52
Cowichan Grease Corporation
• (Not the real name)
• For-profit entity that does the dirty work of
  collecting grease, filtering it, preparing it for
  biodiesel
• Sells grease to …




                                                 53
Cowichan Energy Alternatives
• Registered non-profit
• Got a great deal with local municipality on a
  building for a biodiesel processor
• Buys oil from the grease puller corp
• Sells biodiesel to the co-op




                                             54
Using the best of each organization
• Co-operative
    – Sharing a resource, annual fees, low overhead
• Non-profit
    – Can get free things from gov / corporations
• For-profit
    – For the hard work, yield profit
    – Hopefully we don’t burn out, it can be sustainable
•

                                                      55
Thank You!

       Twitter: @lukec
 info@vancouverbiodiesel.org
http://vancouverbiodiesel.org
Sources
• http://www.slideshare.net/educationprojects/
  biodiesel-101
• http://www.slideshare.net/biodieselautomotive/
  technical-overview-of-biodiesel
• http://smellbetter.org
•



                                            57

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Biodiesel & organizations

  • 1. Biodiesel 101 By: Luke Closs @lukec vancouverbiodiesel.org @vanbiodiesel
  • 2. What is Biodiesel? • Renewable fuel for Diesel Engines • Derived from natural oils • Meets ASTM D 6751 specification 2
  • 3. What is Biodiesel? • Biodiesel can be mixed with Petro-diesel in any ratio. – B50 is 50% Biodiesel, 50% Petrodiesel – B100 is 100% Biodiesel • Biodiesel can be used in most Diesel engines with little or no modification 3
  • 4. Rudolf Diesel • Design the Diesel engine to run on peanut fuel • Farmers can be more independent 4
  • 5. Rudolf Diesel • “The use of vegetable oils for engine fuels may seem insignificant today. But such oils may become in the course of time as important as petroleum and the coal tar products of the present time” - 1912 5
  • 6. Biodiesel Performance • Pretty much the same as Petrodiesel • Highest BTU content of any alternative fuel • High lubricity – protects, extends engine life – Low sulfur diesel has a very low lubricity, requires an additive. Biodiesel solves this. • Fuel consumption, horsepower, torque, similar to petrodiesel. 6
  • 7. Biodiesel Toxicity • Very high flash point (260°F vs 125°F for diesel) • Safest fuel to use, handle, store • Biodegrades four times faster than petrodiesel • Will not harm fish • Less toxic than table salt 7
  • 8. B5 Today • BC Provincial government mandated that diesel fuel must contain at least a 5% biodiesel content – Even a B2 blend greatly improves lubricity 8
  • 9. What is Biodiesel Not? • Biodiesel is not Ethanol! – Ethanol is made from fermenting the whole corn kernel to ethanol – Ethanol is intended only for gasoline engines – “Drink the best and burn the rest” 9
  • 10. What is Biodiesel Not? • Biodiesel is not raw vegetable oil • Veggie Oil can also be used as a fuel, often called WVO - Waste Veggie Oil • WVO can be burned in Diesel engines, but requires modifications to the fuel system. 10
  • 11. Brief Diversion: WVO • How do waste veggie oil systems work? • SVO - Straight Veggie Oil – Fuel system is modified to pre-heat fuel before it gets to the engine • Dual Fuel Systems – Start up engine on petro/bio-diesel, let it get warm – Switch fuel system over to WVO – Switch back to purge system at end of trip 11
  • 12. Biodiesel & Clean Air • Biodiesel exhaust is safer to breathe • Less offensive exhaust – smells more like french fries • Reduces cancer-causing compounds by 80-90% • Reduces particulate matter in exhaust • Lowers net carbon in biosphere • Soy B100 reduces lifecycle CO2 by 78% 12
  • 13. Biodiesel & Energy Balance • Highest energy balance of any fuel – 3.2 units of energy gained per one unit of fossil fuel to produce • Petroleum diesel production creates negative energy balance – 0.88 unit of energy per one unit of fossil fuel • One gallon of biodiesel could conserve four gallons of petroleum diesel! 13
  • 14. Making Biodiesel • Raw Materials: – Oil or Fat – Alcohol – Catalyst • Mechanically combine • Yields: Biodiesel and Glycerin 14
  • 15. Raw Materials - Fats • Soybean • Animal Tallow • Corn • Used Cooking Oils • Canola • Camellia • Cottonseed • Sunflower • Algae? • Lards 15
  • 16. Raw Materials - Other • Alcohol – Methanol – Ethanol • Catalyst – Sodium hydroxide – Potassium hydroxide 16
  • 17. Biodiesel Reaction • In the presence of a catalyst, combining: • 100 lbs of oil + 10 lbs of Methanol/Ethanol – yields: • 100 lbs of Biodiesel + 10 lbs of Glycerin – (Assuming reaction is pushed to 100%) 17
  • 18. Homebrew • You can do this at home! • In a blender: – Waste veggie oil – Methanol – Lie • Mix! • Let sit 18
  • 19. Quality • Need to remove all the free glycerin • Need to remove all the lie • Need to remove all the methanol • Need to remove any water in the oil • You do not want these in your engine. 19
  • 20. Improving Quality • Oil can be heated to remove water – Especially for WVO • After the mechanical combination with the catalyst, the biodiesel can be “washed” to remove the catalyst, alcohols & glycerin. 20
  • 21. Homebrew • You can produce high quality biodiesel at home with a small scale reactor – It’s a decent amount of work – Professional fuel testing is very expensive, so it’s hard to say exactly the quality – Burn it yourself, but questionable to homebrew for other people 21
  • 22. Biodiesel in the Pacific Northwest • Consumer locations: – Vancouver Biodiesel Co-op (more later) – B5 at the pump (meh) – Duncan (Vancouver Island) – Bellingham – I5 Corridor 22
  • 23. Biodiesel in the Pacific Northwest • Producers / Distributors: – Consolidated Biofuels - Delta, BC – Cowichan Biodiesel Co-op - Duncan, BC – Whole Energy - Washington State – Cascadia Biofuels - Washington 23
  • 24. Biodiesel and Taxes • Prior to July 2010, Biodiesel was exempt from the Motor Fuels Tax (26¢/Litre) • BC’s carbon tax was introduced. Biodiesel gets another 6.39¢/L • Biodiesel is suddenly no longer price competitive 24
  • 25. Biodiesel Incentives • In the USA, a “blenders credit” is given for blending Biodiesel with Diesel of 1¢/gal for each % of biodiesel. • B99 yields a 99¢/gal credit • As a result, almost all BC produced biodiesel goes to the US - $1 profit right there. – It often comes back into Canada after 25
  • 26. BC’s B5 Mandate • BC Mandated B5 in all diesel sold • All this biodiesel comes up from the US, often very far away • Done by the big oil companies • Tradeoff: more bio litres vs supporting local bio 26
  • 27. Burning Bio in your Car • Old diesels pretty much love it. • Those japanese vans you see around? – They love biodiesel • B20 and lower is a drop-in replacement for diesel • Take cold weather precautions • 27
  • 28. Burning Bio - Some maintenance • Biodiesel has a solvent effect • Cleans out buildup from petro-diesel • Fuel filters can clog up from the petro-diesel crud – Change fuel filter after 6 months of biodiesel use • Biodiesel can eat rubber fuel lines, gaskets – Replace them with synthetic lines (Viton) – Only applies to vehicles older than mid nineties 28
  • 29. Burning Bio - Rich Blends • B100 issues to be aware of: – Cold flow issues (gelling) – Rubber hoses, gaskets – Cleaning effect is more immediate – Fuel filter clogging is the most common problem • Keep a spare, if possible 29
  • 30. B20 vs Diesel • Same issues you’d expect, except: – Less lubricity problems – Fuel filter problems due to diesel crud or bad biodiesel – Less black smoke from the exhaust! 30
  • 31. Biodiesel & Your Warranty • Usually warranties are the biggest impediment to burning biodiesel in new cars – All major OEMs support at least B5 & lower provided they meat ASTM D 6751 – Increasingly support for B20 is seen – Play it safe or know what you’re doing! 31
  • 32. Sounds great, where do I get some? 32
  • 34. Google's Eye View of our Co-op
  • 35. Co-op Chair (Dave) at our Pump
  • 36. In the beginning … • VBC was started in 2003 • Robb Miller & Recycling Alternative • Homebrew Biodiesel from WVO • 50L drum • Honour system - pen, paper & a binder
  • 37. In the beginning … Problems! Growing pains • Tank runs dry • Losing $$
  • 38. In the beginning … Infrastructure! • RA purchases: o 4000L tank, cardlock, old pump • RA admin staff process payments • City likes it, but uncomfortable, unsure o RA: Install Concrete pad, berm, drain o City: ☺
  • 39. VBC … Today • BC's biggest biofuel co-op: o 200+ members o Only source of B100 in Greater Vancouver Area o 4000L tank, 24/7 cardlock o ~2000-6000L sold per month
  • 40. VBC … Challenges • Technical o Cold winters are cold o High taxes are high o Manual processes are manual • Social o Maintaining an engaged Board of Directors o Engaging our membership
  • 42. VBC: Automated Billing • Created by Luke & Recycling Alternative • Web based tool for Co-op Admin • Interfaces with cardlock in realtime • Tracks all members, all purchases
  • 43. VBC: Automated Billing • Transactions sent to CC processor • Email receipt / invoice sent to member • Bad accounts are frozen
  • 44. VBC: Automated Billing • Benefits o Lower costs (Less admin time) o Detailed usage tracking o More scalable Could add more pumps o More professional
  • 45. VBC: Future • Expansion: More pumps in Lower Mainland? BC? o Made possible by automated system o Cardlock + Fuel Tank + Trailer + GPS + Cell Modem + Solar Panel = Portable Biodiesel Fuel Network! • Engagement: o More active Board of Directors o More engaged membership
  • 46. VBC: Future • Collaboration with other BC Co-ops o BC Biodiesel Network? o Co-op "roaming" capability? • Integrating WVO Collection capabilities? o Goal: Local fuel, lower costs
  • 48. Co-ops are great • “Sharing” vs “Buying” – Less strict guidelines when you are sharing • Ideally less overhead because no profit taking • Operational costs are often cheaper for non- profits and co-op organizations 48
  • 49. Co-ops are great, but … • 80/20 rule - (95/5?) – 95% of the work is done by 5% of the people – no profit incentive means easy to burnout people • Hard to be successful alone as a co-op • Most people just want to buy fuel, they don’t want to make it. 49
  • 50. Vancouver Biodiesel Co-op • Today just a legal structure co-op, advocacy group • Operations is all done by a benevolent company – Recycling Alternative • They run their diesel vehicle fleet on biodiesel – They organize the fuel purchases, resupply, billing • VBC couldn’t operate today without RA 50
  • 51. Cowichan / Duncan • Started out as a members co-op • Members picked up oil, made fuel, shared it. • People join to get cheap fuel, don’t want to work- • Makers get tired, aren’t compensated • Time for a change 51
  • 52. Cowichan Biodiesel Co-op • smellbetter.org • Buys biodiesel, has a 4000L tank, cardlock, pump • Sells pre-paid cards to members • Operationally light, but still supported by other orgs … 52
  • 53. Cowichan Grease Corporation • (Not the real name) • For-profit entity that does the dirty work of collecting grease, filtering it, preparing it for biodiesel • Sells grease to … 53
  • 54. Cowichan Energy Alternatives • Registered non-profit • Got a great deal with local municipality on a building for a biodiesel processor • Buys oil from the grease puller corp • Sells biodiesel to the co-op 54
  • 55. Using the best of each organization • Co-operative – Sharing a resource, annual fees, low overhead • Non-profit – Can get free things from gov / corporations • For-profit – For the hard work, yield profit – Hopefully we don’t burn out, it can be sustainable • 55
  • 56. Thank You! Twitter: @lukec info@vancouverbiodiesel.org http://vancouverbiodiesel.org
  • 57. Sources • http://www.slideshare.net/educationprojects/ biodiesel-101 • http://www.slideshare.net/biodieselautomotive/ technical-overview-of-biodiesel • http://smellbetter.org • 57

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