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Chemistry
Chapter 3 - Section 3

                Acidic and
              Basic Solutions




                         
What are some
common acids?

vinegar                   oranges
               lemons
hydrochloric            sulfuric
    acid                 acid
Properties of Acids
๏Tastes Sour
๏Conducts Electricity
  ๏The hydronium ions in an acidic solution can
   carry the electric charges in a current

๏Corrosive
  ๏They can break down certain substances. Many
   acids can corrode fabric, skin, and paper.
Properties of Acids
๏React with metals
 ๏ The solutions of some acids also react
   strongly with certain metals.
 ๏ The acid-metal reaction forms metallic
   compounds and hydrogen gas, leaving
   holes in the metal in the process.
Uses of Acids
Uses of Acids


       Acetic Acid
Uses of Acids



       Citric Acid
Uses of Acids


        Ascorbic
          Acid
Uses of Acids




 Sulfuric Acid
Uses of Acids




Acids often are used in batteries because their
         solutions conduct electricity
Uses of Acids
  Hydrochloric acid, which is known
commercially as muriatic acid, is used
in a process called pickling. Pickling is
  a process that removes impurities
     from the surfaces of metals.
Acidsin the


Environment
            Carbonic
               acid
           plays a key role in
           the formation of
              caves and of
             stalactites and
               stalagmites.
Acidsin the


Environment

            Carbonic acid is
             formed when
           carbon dioxide in
           soil is dissolved in
                   water.
Acidsin the


Environment
           When this acidic
            solution comes
            in contact with
                  calcium
            carbonate—or
            limestone rock
           —it can dissolve
              it, eventually
              carving out a
           cave in the rock.
Acids ?
Substances that RELEASE positively
 charged hydrogen ions, H+, in water.
When an acid mixes with
water, the acid dissolves,
releasing a hydrogen ion.
The hydrogen ion then
combines with a water
  molecule to form a
 hydronium ion, H30+.
Hydronium Ion ?
positively charged ion with
    the formula H3O+
Bas
      es
Properties of Bases

๏Basic solutions feel slippery.
๏Bases also taste bitter.
๏Like acids, bases are corrosive.
 Basic solutions contain ions and can
 conduct electricity.
๏Basic solutions are not as reactive with
 metals as acidic solutions are.
Where do we find
      Bases?




soaps, ammonia, cleaning products
Where do we find
       Bases?




   The hydroxide ions produced by bases can interact
strongly with certain substances, such as dirt and grease.
Where do we find
    Bases?




       chalk
Where do we find
    Bases?




       blood
Bases?
substances that can
ACCEPT hydrogen ions.
Do you remember the
definition of an acid?
Substances that
RELEASE positively
 charged hydrogen
 ions, H+, in water.
Substances that release positively
 charged hydrogen ions, H+, in water.

 Acids

                     Bases
Substances that can accept hydrogen
                 ions.
When a base dissolves in water,
some hydrogen atoms from the
water molecules are attracted to
           the base.
A hydrogen atom in the water
molecule leaves behind the
  other hydrogen atom and
        oxygen atom.
What is left of the H2O is the OH-, which
    an ion called a hydroxide ion.



                        OH      -
Most bases contain a
hydroxide ion, which is
released when the base
   dissolves in water.
For example, sodium hydroxide is a base with the
formula NaOH. When NaOH dissolves in water,
  a sodium ion and the hydroxide ion separate.
pH
pH??
a measure of how
 acidic or basic a
    solution is
pH

๏The pH scale ranges from 0 to 14.
๏Acidic solutions have pH values below 7.
๏A solution with a pH of 0 is very acidic.
๏A solution with a pH of 7 is neutral.
๏Basic solutions have pH values above 7.
pH
A change of 1 pH unit represents a tenfold
     change in the acidity of the solution.
For example, if one solution has a pH of 1
  and a second solution has a pH of 2, the
 first solution is not twice as acidic as the
    second—it is ten times more acidic.
To determine the difference in pH strength,
       use the following calculation:
                    10n,

                    where
      n = the difference between pHs.

       For example: pH3 - pH1 = 2

       102 = 100 times more acidic.
Strength of
 Acids and Bases
๏The difference between food acids and the
 acids that can burn you is that they have
 different strengths.
Strength of Acids and Bases
Hydrochloric acid separates into ions
more readily than acetic acid does
     when it dissolves in water.
The more easily a H+ ion is released,
      the stronger the acid is.
Therefore, hydrochloric acid exists in water
as separated ions. Acetic acid exists in
 water almost entirely as molecules.
More hydronium ions means a stronger-
acid solution. It would have a lower pH
      than the weak-acid solution.
The strength of a base is related to
 how easily the base accepts H+, or
 how easily a hydroxide ion is made,
  when the base dissolves in water.
Indica
         tors
Indicators??
are compounds that react
with acidic and basic solutions
and produce certain colours,
 depending on the solution’s
              pH.
Because they are different
 colors at different pHs,
 indicators can help you
  determine the pH of a
         solution.
When litmus paper is placed
in an acidic solution, it turns
red. When placed in a basic
 solution, litmus paper turns
              blue.
Neutra
      lizatio
                n
Neutralization??
the reaction of an acid with a base. It is called this
because the properties of both the acid and base
          are diminished, or neutralized.
In most cases, the
neutralization reaction
produces a water and a
          salt.
How does
neutralization occur??

 ๏Recall that every water molecule
  contains two hydrogen atoms and one
  oxygen atom.
 ๏When one hydronium ion reacts with
  one hydroxide ion, the product is two
  water molecules. This reaction occurs
  during acid-base neutralization.
How does
neutralization occur??
How does
neutralization occur??

 ๏Equal numbers of hydronium ions from
  the acidic solution and hydroxide ions
  from the basic solution react to produce
  water.
 ๏Pure water has a pH of 7, which means
  that it’s neutral.
Funny Colours
 1   2         3           4   5   6




         phenolphthalein
Funny Colours
                    1         2            3          4    5          6
                   Phenolphthalein is an indicator
pH              0−8.2                      8.2−12.0           >12.0
Conditions acidic or near-neutral           basic         strongly basic
Color          colorless                pink to fuchsia     colorless




                                    phenolphthalein
Funny Colours
        1   2   3   4   5   6




NaOH                        NaOH
Funny Colours
                    1         2        3          4    5          6
                            NaOH
               A basic solution which will be
       colourless in the presence of phenolphthalein.

pH              0−8.2                  8.2−12.0           >12.0
Conditions acidic or near-neutral       basic         strongly basic
Color          colorless            pink to fuchsia     colorless




NaOH                                                             NaOH
Funny Colours
 1   2   3   4   5     6




                 HCl
Funny Colours
                    1         2        3          4    5          6
                             HCl
              An acidic solution which will be
       colourless in the presence of phenolphthalein.

pH              0−8.2                  8.2−12.0           >12.0
Conditions acidic or near-neutral       basic         strongly basic
Color          colorless            pink to fuchsia     colorless




                                                        HCl
Funny Colours


    What made the pink colour in #2 and 4?

What made the colour disappear in test tube #5?

What could we use to take away the pink colour
              in test tube #6?

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3.3 Acids and Bases

  • 1. Chemistry Chapter 3 - Section 3 Acidic and Basic Solutions 
  • 2. What are some common acids? vinegar oranges lemons hydrochloric sulfuric acid acid
  • 3. Properties of Acids ๏Tastes Sour ๏Conducts Electricity ๏The hydronium ions in an acidic solution can carry the electric charges in a current ๏Corrosive ๏They can break down certain substances. Many acids can corrode fabric, skin, and paper.
  • 4. Properties of Acids ๏React with metals ๏ The solutions of some acids also react strongly with certain metals. ๏ The acid-metal reaction forms metallic compounds and hydrogen gas, leaving holes in the metal in the process.
  • 6. Uses of Acids Acetic Acid
  • 7. Uses of Acids Citric Acid
  • 8. Uses of Acids Ascorbic Acid
  • 9. Uses of Acids Sulfuric Acid
  • 10. Uses of Acids Acids often are used in batteries because their solutions conduct electricity
  • 11. Uses of Acids Hydrochloric acid, which is known commercially as muriatic acid, is used in a process called pickling. Pickling is a process that removes impurities from the surfaces of metals.
  • 12. Acidsin the Environment Carbonic acid plays a key role in the formation of caves and of stalactites and stalagmites.
  • 13. Acidsin the Environment Carbonic acid is formed when carbon dioxide in soil is dissolved in water.
  • 14. Acidsin the Environment When this acidic solution comes in contact with calcium carbonate—or limestone rock —it can dissolve it, eventually carving out a cave in the rock.
  • 16. Substances that RELEASE positively charged hydrogen ions, H+, in water.
  • 17. When an acid mixes with water, the acid dissolves, releasing a hydrogen ion.
  • 18. The hydrogen ion then combines with a water molecule to form a hydronium ion, H30+.
  • 20. positively charged ion with the formula H3O+
  • 21.
  • 22.
  • 23. Bas es
  • 24. Properties of Bases ๏Basic solutions feel slippery. ๏Bases also taste bitter. ๏Like acids, bases are corrosive. Basic solutions contain ions and can conduct electricity. ๏Basic solutions are not as reactive with metals as acidic solutions are.
  • 25. Where do we find Bases? soaps, ammonia, cleaning products
  • 26. Where do we find Bases? The hydroxide ions produced by bases can interact strongly with certain substances, such as dirt and grease.
  • 27. Where do we find Bases? chalk
  • 28. Where do we find Bases? blood
  • 30. substances that can ACCEPT hydrogen ions.
  • 31. Do you remember the definition of an acid?
  • 32. Substances that RELEASE positively charged hydrogen ions, H+, in water.
  • 33. Substances that release positively charged hydrogen ions, H+, in water. Acids Bases Substances that can accept hydrogen ions.
  • 34. When a base dissolves in water, some hydrogen atoms from the water molecules are attracted to the base.
  • 35. A hydrogen atom in the water molecule leaves behind the other hydrogen atom and oxygen atom.
  • 36.
  • 37. What is left of the H2O is the OH-, which an ion called a hydroxide ion. OH -
  • 38. Most bases contain a hydroxide ion, which is released when the base dissolves in water.
  • 39. For example, sodium hydroxide is a base with the formula NaOH. When NaOH dissolves in water, a sodium ion and the hydroxide ion separate.
  • 40.
  • 41. pH
  • 42. pH??
  • 43. a measure of how acidic or basic a solution is
  • 44. pH ๏The pH scale ranges from 0 to 14. ๏Acidic solutions have pH values below 7. ๏A solution with a pH of 0 is very acidic. ๏A solution with a pH of 7 is neutral. ๏Basic solutions have pH values above 7.
  • 45. pH
  • 46. A change of 1 pH unit represents a tenfold change in the acidity of the solution.
  • 47. For example, if one solution has a pH of 1 and a second solution has a pH of 2, the first solution is not twice as acidic as the second—it is ten times more acidic.
  • 48. To determine the difference in pH strength, use the following calculation: 10n, where n = the difference between pHs. For example: pH3 - pH1 = 2 102 = 100 times more acidic.
  • 49. Strength of Acids and Bases ๏The difference between food acids and the acids that can burn you is that they have different strengths.
  • 50. Strength of Acids and Bases
  • 51. Hydrochloric acid separates into ions more readily than acetic acid does when it dissolves in water. The more easily a H+ ion is released, the stronger the acid is.
  • 52. Therefore, hydrochloric acid exists in water as separated ions. Acetic acid exists in water almost entirely as molecules.
  • 53. More hydronium ions means a stronger- acid solution. It would have a lower pH than the weak-acid solution.
  • 54. The strength of a base is related to how easily the base accepts H+, or how easily a hydroxide ion is made, when the base dissolves in water.
  • 55.
  • 56. Indica tors
  • 58. are compounds that react with acidic and basic solutions and produce certain colours, depending on the solution’s pH.
  • 59. Because they are different colors at different pHs, indicators can help you determine the pH of a solution.
  • 60. When litmus paper is placed in an acidic solution, it turns red. When placed in a basic solution, litmus paper turns blue.
  • 61.
  • 62.
  • 63. Neutra lizatio n
  • 65. the reaction of an acid with a base. It is called this because the properties of both the acid and base are diminished, or neutralized.
  • 66. In most cases, the neutralization reaction produces a water and a salt.
  • 67. How does neutralization occur?? ๏Recall that every water molecule contains two hydrogen atoms and one oxygen atom. ๏When one hydronium ion reacts with one hydroxide ion, the product is two water molecules. This reaction occurs during acid-base neutralization.
  • 69. How does neutralization occur?? ๏Equal numbers of hydronium ions from the acidic solution and hydroxide ions from the basic solution react to produce water. ๏Pure water has a pH of 7, which means that it’s neutral.
  • 70.
  • 71. Funny Colours 1 2 3 4 5 6 phenolphthalein
  • 72. Funny Colours 1 2 3 4 5 6 Phenolphthalein is an indicator pH 0−8.2 8.2−12.0 >12.0 Conditions acidic or near-neutral basic strongly basic Color colorless pink to fuchsia colorless phenolphthalein
  • 73. Funny Colours 1 2 3 4 5 6 NaOH NaOH
  • 74. Funny Colours 1 2 3 4 5 6 NaOH A basic solution which will be colourless in the presence of phenolphthalein. pH 0−8.2 8.2−12.0 >12.0 Conditions acidic or near-neutral basic strongly basic Color colorless pink to fuchsia colorless NaOH NaOH
  • 75. Funny Colours 1 2 3 4 5 6 HCl
  • 76. Funny Colours 1 2 3 4 5 6 HCl An acidic solution which will be colourless in the presence of phenolphthalein. pH 0−8.2 8.2−12.0 >12.0 Conditions acidic or near-neutral basic strongly basic Color colorless pink to fuchsia colorless HCl
  • 77. Funny Colours What made the pink colour in #2 and 4? What made the colour disappear in test tube #5? What could we use to take away the pink colour in test tube #6?

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