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Corrosion Impact of
Cathodic Protection on
Surrounding Structures

         Robert A. Durham, PE
         D2 Tech Solutions

         Marcus O. Durham, PhD, PE
         THEWAY Corp.
Introduction

   Corrosion not new topic – since history
   Loss of material leaving a metal
   Flow through a medium
   Returns to metal at different point




                                 ANODE   CATHODE
History

   Sir Humphry Davy, 1824
   British ships copper clad corrosion
   Proposed attaching zinc
   Considered impressed current
   Batteries not perfected
Takes Many Forms

   Oxidation, rust, chemical, bacteria
   All are result of electrical current
   Treatments: chemical, coatings, electrical
   Proper impressed current can stop
   May not be practical



                              CATHODE          ZINC
                                               ANODE

                                 ELECTROLYTE
Mandatory
                   Cathodic Protection
   Underground metal pipe
    with hazardous gas or liquids
   Underground metal pipe
    within 10’ of steel reinforced concrete
   Water storage tanks
    >250,000 gallons
Fundamentals
                         Components
   Anode sacrifices metal, pos battery
   Cathode receives metal, neg battery
   Electrolyte, non-metallic medium,
    with some moisture to support
    current flow
                                            +ANODE




                                            CATHODE
                                 CHEMICAL
                                            ANODE

                                    -CATHODE
Fundamentals
                               Circuit

For corrosion to exist:
  1. Metal conductor
  2. An electrolyte
  3. A potential difference

   #1 & #2 when pipe in soil or water
   #3 caused by environment
    or differences in electrochemical
    properties
Cause & Mitigation

   Same elements that cause corrosion
    can be used to control
   Al electronegativity = 1.61
   Fe electronegativity = 1.83

   Result = electrochemical attraction
   Molecules from Al, thru electrolyte, to Fe
   Protect Fe
Cause & Mitigation

   If force Al to more negative (cathodic)
   Fe molecules through electrolyte to Al
   Al is protected
   Can create problems if CP system fails
   Current flow takes unexpected path
   Protects and destroys wrong metal
Problem

   CP is common practice on vessels, wells
    and cross-country pipelines
   CP is designed to protect pipe or vessel
   Current can take unintended path
   Can create negative results on other
    metals
   Three cases examined
Case 1
   Pipeline systems
     2 with rectifiers

     1 without, not petro

   Rectifier at major lake crossing
   Nearby soil some limestone rocks
   High soil resistivity
   Near residences
Case 1

   Problems @ residences
     Corrosion of underground lines
     Ground wires corroded

     Electric shock from water exiting faucets

   Indications of compromised ground
    system
Case 1
   Routine rectifier readings
   Complete path
     Not intended
     Through residence metal

   Investigation, break in rectifier lead
Case 1

   For corrosion to occur
    need electrical circuit
   Without direct path thru anode, will find
    alternate path thru adjacent metal
                                     RECTIFIER
                                                        STRUCTURE
                                     +      -

                                 BREAK


                             ANODE               SOIL




                                     ALTERNATE METAL PATH


                                                        CORROSION
                                                         POINT
Case 1

   Corrosion of water & sewer
       Costly & inconvenient
   More serious
     Electrical ground electrode conductor
      gone
     Propane lines damaged

   Routine maintenance may not
    catch slow trends
Case 2
   Pipeline systems
      3 with rectifiers

      1 without, not petro

   Rectifier on hill, ¾ mile from residence
   Nearby soil sandy w/ substantial sandstone
   High soil resistivity
   Very remote
      Near 1 residence with barns

      Near petroleum production
Case 2
   Pipeline systems had –1.45 V pipe to soil
   8 month period of problems
     All copper tubing in concrete floor
      replaced
     3/4” copper supply replaced twice

     Computer monitor & TV failed due to

      voltage
     Multiple motors burned out

     Fluorescent lights not ignite
Case 2
   Electrical safety
       Shock by water from shower
       Shock when touch metal of pre-engineered
        building
       Hole burned in bldg from energized ground wire
   Ground conductors
       Electrician measure 40 volts on ground wire at
        service entrance
       Utility measured 90 volts
        on ground wire at pump station
Case 2

   Problems
     Rectifier grounding electrode, 178 Ohm
     >5 times NEC allowance

     Ground rod driven only 5’

      remainder sticking up
   Utility
     Meter ground corroded in two
     Ground resistance, 48 Ohms
Case 2

   Problems pump station
     1 pump 277 V 1-phase
      w/ no ground whatsoever
     Other sites ground electrode resistance

      of 750 – 1000 Ω
   Without ground stray currents
    travel along metal
Case 2

   CP failure source of corrosion
       Plumbing and electrical
   Pump station was source of shock
   Inadequate grounding
   Need proper systems maintenance
   Other systems can complicate matters
Case 3

   Well casing
     6500 feet, 5.5” steel
     Penetrate variety of soils

     High pressure gas

     Known corrosion problems

   CP system
       Rectifier, 5 anodes
        8 Amps impressed
Case 3
   Routine
     Rectifier current read normal
     Pipe/soil readings not routine

   3 years, corrosion of pipe
   $350,000 replacement
Case 3
   Investigation
     Tank bottoms like new
     Pipeline pristine

     Casing eaten up

   Hammer union insulating flange shorted
   Current took preferential path thru line &
    tank
Electrical Bonding

   NEC requires grounding electrode
   NEC requires bonding metal to ground
   Problems
       Steel, ductile or cast iron sacrifice to
        copper
   Bond
     Pipe, well casings, tanks etc.
     Not the grounding electrode

     w/o bonding, risk of shock
Electrical Bonding
   Bonding to ground will short CP to earth
     Do not bond to CP system
     Precludes using large metal surface as

      grounding electrode
   CP has inherent personnel protection
     Drive potential ~ 1 volt negative
     Very low circuit resistance < 2Ω

   Adequate path for dissipation of
    current in a fault
   Use resistance bond for close metal
Standards

   Cases emphasize importance of proper
    C/P maintenance
   Beyond monthly current reading
   Preserve integrity of system
   DOT regulated periodic maintenance
   Become more stringent
    December 29, 2003
Standards
                                       DOT 12/29/03
Protected           a) Tests for corrosion once per year
Pipelines           b) By Dec. 29, 2003, accomplish objectives of
                       NACE RP0169-96
                    c) Inspect removed pipe; if corrosion, inspect
                       adjacent and correct
Unprotected Pipe    Electric corrosion survey every three years
Rectifier           Electrically check once every 2 months
Reverse Current     Electrically check once per year
Switch
Diodes              Electrically check once per year
Critical           Electrically check once every 2 months
Interference Bonds
Interference Bonds Electrically check once per year
Breakout Tanks      Inspect system per API RP 651
Standards
   Record keeping
       Show location of CP piping, CP facilities, anodes
       Neighboring structures bonded
       Maintain for life of pipeline
   Tests
       Tests, survey, or inspection per table
       Demonstrate adequacy
       Maintain 5 years
   Inspection of protected & critical
    interference bonds
       Life of pipeline
Standards
   49 CFR Part 192
   49 CFR Part 195
   40 CFR Part 280
   UL 1746
   NACE RP0169
   NACE RP0177
   NACE RP0193
   NACE RP0285
   NACE RP0286
   NACE RP0388
   API RP 632
   API RP 651
   STI R892
   STI R972
Installation & Maintenance

   Initial
     Imperative to isolate protected pipe
     Visual and testing

     Check resistance between protected,

      ground, other
     If not open circuit -> problem

   Electrical w/in 5 feet
       Bond per NEC
Installation & Maintenance

   Periodic current
     Show drastic changes
     Failed rectifier, broken connection

   Trend over time
     Decrease I
     Increase V

     Shows failing anode or connection
                                   8



                                   7



                                   6



                                   5



                                   4

                                           Volts
                                           Amps
                                   3



                                   2



                                   1



                                   0
                                       1    2      3   4   5   6   7   8   9
Installation & Maintenance
   Annual
     11 or 13 month cycle
     Over time will see all seasons and

      climatological conditions
   Complete periodic
     Same as initial
     Energized, so measure voltage difference

      not resistance
     Half-cell P-S, and ground bed to soil

     Rectifier
Conclusions
   Corrosion Happens
   CP sacrifices one metal to protect other
   Requires complete path
   Failure may cause unintended path
   Resultant corrosion can be costly and
    compromise safety
   New regulations in effect Dec 29, 2003

   With proper installation, maintenance and
    inspections CP can be safe and effective

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Corrosion

  • 1. Corrosion Impact of Cathodic Protection on Surrounding Structures Robert A. Durham, PE D2 Tech Solutions Marcus O. Durham, PhD, PE THEWAY Corp.
  • 2. Introduction  Corrosion not new topic – since history  Loss of material leaving a metal  Flow through a medium  Returns to metal at different point ANODE CATHODE
  • 3. History  Sir Humphry Davy, 1824  British ships copper clad corrosion  Proposed attaching zinc  Considered impressed current  Batteries not perfected
  • 4. Takes Many Forms  Oxidation, rust, chemical, bacteria  All are result of electrical current  Treatments: chemical, coatings, electrical  Proper impressed current can stop  May not be practical CATHODE ZINC ANODE ELECTROLYTE
  • 5. Mandatory Cathodic Protection  Underground metal pipe with hazardous gas or liquids  Underground metal pipe within 10’ of steel reinforced concrete  Water storage tanks >250,000 gallons
  • 6. Fundamentals Components  Anode sacrifices metal, pos battery  Cathode receives metal, neg battery  Electrolyte, non-metallic medium, with some moisture to support current flow +ANODE CATHODE CHEMICAL ANODE -CATHODE
  • 7. Fundamentals Circuit For corrosion to exist: 1. Metal conductor 2. An electrolyte 3. A potential difference  #1 & #2 when pipe in soil or water  #3 caused by environment or differences in electrochemical properties
  • 8. Cause & Mitigation  Same elements that cause corrosion can be used to control  Al electronegativity = 1.61  Fe electronegativity = 1.83  Result = electrochemical attraction  Molecules from Al, thru electrolyte, to Fe  Protect Fe
  • 9. Cause & Mitigation  If force Al to more negative (cathodic)  Fe molecules through electrolyte to Al  Al is protected  Can create problems if CP system fails  Current flow takes unexpected path  Protects and destroys wrong metal
  • 10. Problem  CP is common practice on vessels, wells and cross-country pipelines  CP is designed to protect pipe or vessel  Current can take unintended path  Can create negative results on other metals  Three cases examined
  • 11. Case 1  Pipeline systems  2 with rectifiers  1 without, not petro  Rectifier at major lake crossing  Nearby soil some limestone rocks  High soil resistivity  Near residences
  • 12. Case 1  Problems @ residences  Corrosion of underground lines  Ground wires corroded  Electric shock from water exiting faucets  Indications of compromised ground system
  • 13. Case 1  Routine rectifier readings  Complete path  Not intended  Through residence metal  Investigation, break in rectifier lead
  • 14. Case 1  For corrosion to occur need electrical circuit  Without direct path thru anode, will find alternate path thru adjacent metal RECTIFIER STRUCTURE + - BREAK ANODE SOIL ALTERNATE METAL PATH CORROSION POINT
  • 15. Case 1  Corrosion of water & sewer  Costly & inconvenient  More serious  Electrical ground electrode conductor gone  Propane lines damaged  Routine maintenance may not catch slow trends
  • 16. Case 2  Pipeline systems  3 with rectifiers  1 without, not petro  Rectifier on hill, ¾ mile from residence  Nearby soil sandy w/ substantial sandstone  High soil resistivity  Very remote  Near 1 residence with barns  Near petroleum production
  • 17. Case 2  Pipeline systems had –1.45 V pipe to soil  8 month period of problems  All copper tubing in concrete floor replaced  3/4” copper supply replaced twice  Computer monitor & TV failed due to voltage  Multiple motors burned out  Fluorescent lights not ignite
  • 18. Case 2  Electrical safety  Shock by water from shower  Shock when touch metal of pre-engineered building  Hole burned in bldg from energized ground wire  Ground conductors  Electrician measure 40 volts on ground wire at service entrance  Utility measured 90 volts on ground wire at pump station
  • 19. Case 2  Problems  Rectifier grounding electrode, 178 Ohm  >5 times NEC allowance  Ground rod driven only 5’ remainder sticking up  Utility  Meter ground corroded in two  Ground resistance, 48 Ohms
  • 20. Case 2  Problems pump station  1 pump 277 V 1-phase w/ no ground whatsoever  Other sites ground electrode resistance of 750 – 1000 Ω  Without ground stray currents travel along metal
  • 21. Case 2  CP failure source of corrosion  Plumbing and electrical  Pump station was source of shock  Inadequate grounding  Need proper systems maintenance  Other systems can complicate matters
  • 22. Case 3  Well casing  6500 feet, 5.5” steel  Penetrate variety of soils  High pressure gas  Known corrosion problems  CP system  Rectifier, 5 anodes 8 Amps impressed
  • 23. Case 3  Routine  Rectifier current read normal  Pipe/soil readings not routine  3 years, corrosion of pipe  $350,000 replacement
  • 24. Case 3  Investigation  Tank bottoms like new  Pipeline pristine  Casing eaten up  Hammer union insulating flange shorted  Current took preferential path thru line & tank
  • 25. Electrical Bonding  NEC requires grounding electrode  NEC requires bonding metal to ground  Problems  Steel, ductile or cast iron sacrifice to copper  Bond  Pipe, well casings, tanks etc.  Not the grounding electrode  w/o bonding, risk of shock
  • 26. Electrical Bonding  Bonding to ground will short CP to earth  Do not bond to CP system  Precludes using large metal surface as grounding electrode  CP has inherent personnel protection  Drive potential ~ 1 volt negative  Very low circuit resistance < 2Ω  Adequate path for dissipation of current in a fault  Use resistance bond for close metal
  • 27. Standards  Cases emphasize importance of proper C/P maintenance  Beyond monthly current reading  Preserve integrity of system  DOT regulated periodic maintenance  Become more stringent December 29, 2003
  • 28. Standards DOT 12/29/03 Protected a) Tests for corrosion once per year Pipelines b) By Dec. 29, 2003, accomplish objectives of NACE RP0169-96 c) Inspect removed pipe; if corrosion, inspect adjacent and correct Unprotected Pipe Electric corrosion survey every three years Rectifier Electrically check once every 2 months Reverse Current Electrically check once per year Switch Diodes Electrically check once per year Critical Electrically check once every 2 months Interference Bonds Interference Bonds Electrically check once per year Breakout Tanks Inspect system per API RP 651
  • 29. Standards  Record keeping  Show location of CP piping, CP facilities, anodes  Neighboring structures bonded  Maintain for life of pipeline  Tests  Tests, survey, or inspection per table  Demonstrate adequacy  Maintain 5 years  Inspection of protected & critical interference bonds  Life of pipeline
  • 30. Standards  49 CFR Part 192  49 CFR Part 195  40 CFR Part 280  UL 1746  NACE RP0169  NACE RP0177  NACE RP0193  NACE RP0285  NACE RP0286  NACE RP0388  API RP 632  API RP 651  STI R892  STI R972
  • 31.
  • 32. Installation & Maintenance  Initial  Imperative to isolate protected pipe  Visual and testing  Check resistance between protected, ground, other  If not open circuit -> problem  Electrical w/in 5 feet  Bond per NEC
  • 33. Installation & Maintenance  Periodic current  Show drastic changes  Failed rectifier, broken connection  Trend over time  Decrease I  Increase V  Shows failing anode or connection 8 7 6 5 4 Volts Amps 3 2 1 0 1 2 3 4 5 6 7 8 9
  • 34. Installation & Maintenance  Annual  11 or 13 month cycle  Over time will see all seasons and climatological conditions  Complete periodic  Same as initial  Energized, so measure voltage difference not resistance  Half-cell P-S, and ground bed to soil  Rectifier
  • 35. Conclusions  Corrosion Happens  CP sacrifices one metal to protect other  Requires complete path  Failure may cause unintended path  Resultant corrosion can be costly and compromise safety  New regulations in effect Dec 29, 2003  With proper installation, maintenance and inspections CP can be safe and effective