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CONCEPT PRESENTATION
 IONIC AND COVALENT
   BONDING (SCH3U)




   Presenter: Iris Lo
   Instructors: Janine Extavour & Marty Zatzman, OISE/UT
Overview

   Curriculum Expectations
   Common Misconceptions
   Curriculum Placement
   4 Day Lesson Sequence
   Applications
   Teacher Resources
Curriculum Expectations

Sp e c ific Ex p e c ta tio ns :
 B2.1 – Use appropriate terminology related to chemical trends and
   chemical bonding, including, but not limited to: atomic radius,
   effective nuclear charge, electronegativity, ionization energy and
   electron affinity.
 B2.4 – Draw Lewis structures to represent the bonds in ionic and
   molecular compounds.
 B2.5 - Predict the nature of a bond (e.g., non-polar covalent, etc.)
   using electronegativity values of atoms.
 B2.6 - Build molecular models, and write structure formulae, for
   molecular compounds containing single and multiple bonds and for
   ionic crystalline structures.
 B3.4 – Explain the differences between the formulation of ionic
   bonds and the formation of covalent bonds.
 B3.5 – Compare and contrast the physical properties of ionic and
   molecular compounds.
Bonding Analogy
   Welcome to the Dr. Phil Show!

   Today we will be counseling 3 divorced
    couples
       Lisa Simpson and Milhouse
       Buzz Lightyear and Jessie
       Ken and Barbie
   Let’s have a look at how they interact to
    determine what is ‘bonding’ them together
    before we begin!
Couple #1
   Milhouse is still very
    attracted to Lisa while she
    feels no attraction.
   Milhouse has taken sole
    custody of their child,
    Nelson, a factor that keeps
    them bonded together.

   Which bond does this
    couple represent (ionic,
    polar covalent or non-polar
    covalent)?
Couple #2
   Buzz Lightyear is more attracted
    to Jessie than she is to him.
   Although this attraction is
    unequal, they Do still share a love
    for one another.
   They have joint custody of their
    son, Buzz Jr, with Buzz Jr.
    spending time primarily with his
    father.

   Which bond does this couple
    represent (ionic, polar covalent or
    non-polar covalent)?
Couple #3
   This couple has equal
    attraction to each other
   They maintain their bond
    by having shared custody
    of their son, Ben.
   Ben spends an equal
    amount of time with both
    parents.

   Which bond does this
    couple represent (ionic,
    polar covalent or non-
    polar covalent)?
Common Student
Misconception #1
  “Since both involve charges, the attraction
  between polar covalent molecules is the same as
  the attraction between ions in an ionic compound”

Solutions:
     Emphasize that charges across polar covalent bonds
      are only p a rtia l charges
     Use the Dr. Phil bonding analogy
Common Student
Misconception #2
 “The Lewis structure of covalent compounds
 gives the shape of the molecule.”

Solutions:
     Reinforce that Lewis structure only shows atom
      linkage
     Have students build molecular models
      (modification: use gumdrops and toothpicks)
Common Student
Misconception #3
  “When predicting bond type using electronegativity,
  there is a sharp divide between ionic and covalent
  bonds.”

Solutions:
     Emphasize that the spectrum of electronegativity difference
      values is smooth
     Reinforce using a model of a bonding continuum and a table
      organizer showing percent ionic/covalent character for various
      ∆EN values
Common Student
Misconception #4
   “The modern view of the atom is one in
    which the electrons circle the nucleus in fixed
    orbits, like the planets orbiting the sun.”

Solutions:
       Make students aware that the models they are using
        is simplified
           Chemists describe electrons in terms of energy and
            probability of finding electrons within a region of space
       Use videos to help students visually
         Covalent Bonding Video
         Ionic Bonding Video
Curriculum Placement of the
Unit
Matter, Chemical Trends and Chemical Bonding
  unit:
 Matter, Chemical Trends and Chemical bonding

  unit is placed as the1st unit of the course
       Covers underlying basis of all other units
       Natural progression from grade 9 and 10 Chemistry

   Chemical Reactions suggested to be the 2nd unit
       Natural progression from grade 10 Chemistry
       Natural progression from Unit 1 - writing chemical
        formulas and naming of compounds needed for
        writing chemical equations, predicting chemical
        reaction products, etc.)
Concept Placement Within the
Unit
   Placed after periodic trends and before writing chemical formulas and
    naming compounds

   Suggested order of the chemical bonding section:

    1) Review:
       Bo hr m o d e l o f the a to m , io n fo rm a tio n, p ro p e rtie s o f io nic a nd m o le c ula r
       c o m p o und s

    2) Introduce key underlying concepts:
       O c te t rule , Le wis s truc ture s

    3) Introduce bonding overview:
       To give students some context

    4) Intramolecular bonds: Ionic and covalent bonding

    5) Intermolecular and Metallic Bonding
Bonding Overview
4 Day Lesson Sequence
   Day 1: Review & Classifying Chemical Compounds

       PowerPoint presentation:
          Bohr model of the atom
          Drawing Lewis structures
          Properties of ionic and covalent compounds.

       Demo:
          Test and compare the conductivity of salt solution and sugar solution
          Safety: Use low-voltage conductivity apparatus

       Group Activity: Bond With a Classmate
            Students act as positive and negative ions and form bonds with their peers. Introductory activity
        for day 2.

       Assessment:
            Informal question and answer (diagnostic)
           Lewis structure and Properties of Ionic/Covalent Compounds worksheet
           Predict, Observe, Explain Activity
Bond With a Classmate Activity: Your
Thoughts?
   In your table groups, discuss:
    a) Pros/cons of this activity?
    b) Ways to modify this activity for:
         -Different grade levels
         -Different streams (i.e. academic, applied, etc.)
Day 2: Introduction to Bonding
   PowerPoint presentation:
         Octet rule
         Electronegativity (including its periodic trend)
         Bonding continuum/characteristics of ionic, polar covalent, covalent
    bonds
 
   Video Clip on Bonding/Electronegativity

   Role-Play:

         Use the analogy of 3 couples going through relationship counseling
    to   represent ionic, polar covalent and covalent bonding.
 
   Assessment:
         Informal question and answer
         Determine Bond Type Using Electronegativity worksheet
         Observation & feedback
Day 3: Ionic and Covalent
    Bonding
   Ionic Bonding
        PowerPoint presentation/Chalk and Talk:
             Formation of ions,
             Transferring single /multiple electrons & bonding involving > 2 ions (shown using Lewis structures/structural
         formulas),
             Properties of ionic compounds.

       Demo: Poker chips used to simulate ionic bonding.

       Video Clip: Ionic Bonding

   Covalent Bonding
       PowerPoint presentation (continuation):
            Single and multiple covalent bonding (shown using Lewis structures/structural formulas)
            Coordinate covalent bonds
            Exceeding the octet rule
            Properties of covalent compounds
            Compare/contrast ionic and covalent compounds.

       Demo: Poker chips used to simulate covalent bonding.

       Video Clip: Covalent Bonding
Day 3 (Cont’d)
   Assessment:
     Informal question and answer
     Drawing Lewis and Structural Diagrams of Ionic
     and Covalent Compounds worksheet
Day 4: Polar Covalent Bonding
   PowerPoint presentation:
           Polar covalent bonding (shown using Lewis structures and structural
    formulas)
           Polar/non-polar molecules, partial charges, and overall polarity
           Summary of all 3 bonds

   Demo:
             Place a charged ebonite rod next to water and then hexane. Water
    (polar) is          attracted to the rod, hexane is not (non-polar)

            Safety: Hexane is a flammable liquid – do not place near open flames.
                    Do not directly smell it. Use in well-ventilated area.

   Class discussion: Applications and societal implications.
 
   Lab: Gumdrop Molecular Models
           Build molecular models and draw the Lewis diagram, structural
    formulas and      predicted shape of molecule for ionic and covalent
    compounds (Cherkas e t a l. , 2002).

            Safety: Students must not eat the candy if they are working with it in
                    the lab.
Day 4 (Cont’d)
   Assessment and Evaluation:
        Informal question and answer (assessment)
              Polar Covalent Bonding worksheet
    (assessment)
        Predict, Observe, Explain Activity
    (assessment) Learning skills rubric
    (assessment)
       Lab worksheet (evaluation)
Concept Applications
1 ) I ns a nd the Hum a n Bo d y
    o
       Humans depend on ions for their survival they
        are essential for maintaining good health


2 ) Ca rbo n Dio x id e in So ft Drinks : ACo va le nt
    Co m p o und
       CO2 is somewhat soluble in water, especially at
        high pressures which is why soft drinks are
        bottled under pressure (Mustoe e t a l. , 2001).
       When you open a bottle of pop, some of the CO2
        comes out of solution due to its low solubility
        (Mustoe e t a l. , 2001).


3 ) A p lic a tio n o f Wa te r Po la rity : M ro wa ve
     p                                        ic
    O ve ns
       Water is a polar molecule that is a good
        absorber of microwaves (Rayner-Canham, e t
        a l. , 2002).
       The energy is converted into heat to warm up
        food (Rayner-Canham, e t a l. , 2002).
Resources
1) Nelson and McGraw-Hill Ryerson Chemistry 11
   Teacher’s Resource
        Both provide:
         background info
         teaching suggestions (activities, tips/safety precautions for
          conducting labs, effective ways to approach the topic)
         answers to lab/textbook questions
         common misconceptions and solutions

        Prefer McGraw-Hill Ryerson Teacher’s Resource
         more detailed, includes strategies to support diverse student
          needs (ex. ESL students, etc.)
Resources (cont’d)
2) Chemistry Games: J. Hand’s class website
   Provides   pre-made review games

3) Chalkbored: J. Schneider’s class website
   Provides
           PowerPoint presentations, handouts, labs,
   worksheets for grade 11 and 12

4) Chemistry Demonstrations: T. Sperring’s website
   Provides many quick Chemistry demos
   Materials, procedure and what should be observed are
    included
References
1) Cherkas, A., Freure, C., George, T., Ivanco, J., Kisway, L., Plavetic, S.J., Stewart, J., and G. Wisnicki. (2002). M G ra w-Hill Ry e rs o n
                                                                                                                       c
        Che m is try 1 1 Te a c he r’s            Re s o urc e . Toronto: Mc-Graw-Hill Ryerson.


2) Hand, J. (2010). Che m is try G a m e s . Retrieved July 9, 2010, from <http://www.mansfieldct.org/schools/mms/staff/hand/chemgames.htm>


3) Jenkins, F., van Kessel, H., Davies, L., Lantz, O., Thomas, P., and D. Tompkins. (2002). N ls o n Che m is try 1 1 . Toronto: Nelson
                                                                                             e
                  Thomson Learning.


4) Jenkins, F., van Kessel, H., Davies, L., Sanader, M., Tompkins, D., Lantz, O., and S. Haberer. (2002). N ls o n Che m is try 1 1
                                                                                                           e
                  Te a c he r’s Re s o urc e . Toronto: Nelson Thomson Learning.


5) Mustoe, F., Jansen, M., Doram, T., Ivanco, J., Clancy, C., and A. Ghazariansteja. (2001). M G ra w-Hill Ry e rs o n Che m is try
                                                                                              c
                  1 1 . Toronto: McGraw-Hill Ryerson Limited.


6) Rayner-Canham, G., Damju, S., and U. Goering-Boone. (2002). A d is o n We s le y Che m is try 1 1 . Toronto: Addison Wesley.
                                                                d


7) Schneider, J. (2009). Cha lkbo re d : Che m is try 1 1 . Retrieved July 9, 2010, from <http://www.chalkbored.com/lessons/chemistry-11.htm>


8) Sperring, T. (2000). Che m is try De m o ns tra tio ns . Retrieved July 9, 2010, from
                  <http://webcache.googleusercontent.com/search?q=cache:vRVGMG9e6HcJ:alex.edfac.usyd.edu.au/methods/scien
                  ce/Chemistry%2520Demonstrations+water,+ebonite+rod,+hexane&cd=1&hl=en&ct=clnk&gl=ca>

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Concept presentation on chemical bonding (iris lo)

  • 1. CONCEPT PRESENTATION IONIC AND COVALENT BONDING (SCH3U) Presenter: Iris Lo Instructors: Janine Extavour & Marty Zatzman, OISE/UT
  • 2. Overview  Curriculum Expectations  Common Misconceptions  Curriculum Placement  4 Day Lesson Sequence  Applications  Teacher Resources
  • 3. Curriculum Expectations Sp e c ific Ex p e c ta tio ns :  B2.1 – Use appropriate terminology related to chemical trends and chemical bonding, including, but not limited to: atomic radius, effective nuclear charge, electronegativity, ionization energy and electron affinity.  B2.4 – Draw Lewis structures to represent the bonds in ionic and molecular compounds.  B2.5 - Predict the nature of a bond (e.g., non-polar covalent, etc.) using electronegativity values of atoms.  B2.6 - Build molecular models, and write structure formulae, for molecular compounds containing single and multiple bonds and for ionic crystalline structures.  B3.4 – Explain the differences between the formulation of ionic bonds and the formation of covalent bonds.  B3.5 – Compare and contrast the physical properties of ionic and molecular compounds.
  • 4. Bonding Analogy  Welcome to the Dr. Phil Show!  Today we will be counseling 3 divorced couples  Lisa Simpson and Milhouse  Buzz Lightyear and Jessie  Ken and Barbie  Let’s have a look at how they interact to determine what is ‘bonding’ them together before we begin!
  • 5. Couple #1  Milhouse is still very attracted to Lisa while she feels no attraction.  Milhouse has taken sole custody of their child, Nelson, a factor that keeps them bonded together.  Which bond does this couple represent (ionic, polar covalent or non-polar covalent)?
  • 6. Couple #2  Buzz Lightyear is more attracted to Jessie than she is to him.  Although this attraction is unequal, they Do still share a love for one another.  They have joint custody of their son, Buzz Jr, with Buzz Jr. spending time primarily with his father.  Which bond does this couple represent (ionic, polar covalent or non-polar covalent)?
  • 7. Couple #3  This couple has equal attraction to each other  They maintain their bond by having shared custody of their son, Ben.  Ben spends an equal amount of time with both parents.  Which bond does this couple represent (ionic, polar covalent or non- polar covalent)?
  • 8. Common Student Misconception #1 “Since both involve charges, the attraction between polar covalent molecules is the same as the attraction between ions in an ionic compound” Solutions:  Emphasize that charges across polar covalent bonds are only p a rtia l charges  Use the Dr. Phil bonding analogy
  • 9. Common Student Misconception #2 “The Lewis structure of covalent compounds gives the shape of the molecule.” Solutions:  Reinforce that Lewis structure only shows atom linkage  Have students build molecular models (modification: use gumdrops and toothpicks)
  • 10. Common Student Misconception #3 “When predicting bond type using electronegativity, there is a sharp divide between ionic and covalent bonds.” Solutions:  Emphasize that the spectrum of electronegativity difference values is smooth  Reinforce using a model of a bonding continuum and a table organizer showing percent ionic/covalent character for various ∆EN values
  • 11. Common Student Misconception #4  “The modern view of the atom is one in which the electrons circle the nucleus in fixed orbits, like the planets orbiting the sun.” Solutions:  Make students aware that the models they are using is simplified  Chemists describe electrons in terms of energy and probability of finding electrons within a region of space  Use videos to help students visually  Covalent Bonding Video  Ionic Bonding Video
  • 12. Curriculum Placement of the Unit Matter, Chemical Trends and Chemical Bonding unit:  Matter, Chemical Trends and Chemical bonding unit is placed as the1st unit of the course  Covers underlying basis of all other units  Natural progression from grade 9 and 10 Chemistry  Chemical Reactions suggested to be the 2nd unit  Natural progression from grade 10 Chemistry  Natural progression from Unit 1 - writing chemical formulas and naming of compounds needed for writing chemical equations, predicting chemical reaction products, etc.)
  • 13. Concept Placement Within the Unit  Placed after periodic trends and before writing chemical formulas and naming compounds  Suggested order of the chemical bonding section: 1) Review: Bo hr m o d e l o f the a to m , io n fo rm a tio n, p ro p e rtie s o f io nic a nd m o le c ula r c o m p o und s 2) Introduce key underlying concepts: O c te t rule , Le wis s truc ture s 3) Introduce bonding overview: To give students some context 4) Intramolecular bonds: Ionic and covalent bonding 5) Intermolecular and Metallic Bonding
  • 15. 4 Day Lesson Sequence  Day 1: Review & Classifying Chemical Compounds  PowerPoint presentation: Bohr model of the atom Drawing Lewis structures Properties of ionic and covalent compounds.  Demo: Test and compare the conductivity of salt solution and sugar solution Safety: Use low-voltage conductivity apparatus  Group Activity: Bond With a Classmate Students act as positive and negative ions and form bonds with their peers. Introductory activity for day 2.  Assessment: Informal question and answer (diagnostic) Lewis structure and Properties of Ionic/Covalent Compounds worksheet Predict, Observe, Explain Activity
  • 16. Bond With a Classmate Activity: Your Thoughts?  In your table groups, discuss: a) Pros/cons of this activity? b) Ways to modify this activity for: -Different grade levels -Different streams (i.e. academic, applied, etc.)
  • 17. Day 2: Introduction to Bonding  PowerPoint presentation: Octet rule Electronegativity (including its periodic trend) Bonding continuum/characteristics of ionic, polar covalent, covalent bonds    Video Clip on Bonding/Electronegativity  Role-Play: Use the analogy of 3 couples going through relationship counseling to represent ionic, polar covalent and covalent bonding.    Assessment: Informal question and answer Determine Bond Type Using Electronegativity worksheet Observation & feedback
  • 18. Day 3: Ionic and Covalent Bonding  Ionic Bonding  PowerPoint presentation/Chalk and Talk: Formation of ions, Transferring single /multiple electrons & bonding involving > 2 ions (shown using Lewis structures/structural formulas), Properties of ionic compounds.  Demo: Poker chips used to simulate ionic bonding.  Video Clip: Ionic Bonding  Covalent Bonding  PowerPoint presentation (continuation): Single and multiple covalent bonding (shown using Lewis structures/structural formulas) Coordinate covalent bonds Exceeding the octet rule Properties of covalent compounds Compare/contrast ionic and covalent compounds.  Demo: Poker chips used to simulate covalent bonding.  Video Clip: Covalent Bonding
  • 19. Day 3 (Cont’d)  Assessment: Informal question and answer Drawing Lewis and Structural Diagrams of Ionic and Covalent Compounds worksheet
  • 20. Day 4: Polar Covalent Bonding  PowerPoint presentation: Polar covalent bonding (shown using Lewis structures and structural formulas) Polar/non-polar molecules, partial charges, and overall polarity Summary of all 3 bonds  Demo: Place a charged ebonite rod next to water and then hexane. Water (polar) is attracted to the rod, hexane is not (non-polar) Safety: Hexane is a flammable liquid – do not place near open flames. Do not directly smell it. Use in well-ventilated area.  Class discussion: Applications and societal implications.    Lab: Gumdrop Molecular Models Build molecular models and draw the Lewis diagram, structural formulas and predicted shape of molecule for ionic and covalent compounds (Cherkas e t a l. , 2002). Safety: Students must not eat the candy if they are working with it in the lab.
  • 21. Day 4 (Cont’d)  Assessment and Evaluation: Informal question and answer (assessment) Polar Covalent Bonding worksheet (assessment) Predict, Observe, Explain Activity (assessment) Learning skills rubric (assessment) Lab worksheet (evaluation)
  • 22. Concept Applications 1 ) I ns a nd the Hum a n Bo d y o  Humans depend on ions for their survival they are essential for maintaining good health 2 ) Ca rbo n Dio x id e in So ft Drinks : ACo va le nt Co m p o und  CO2 is somewhat soluble in water, especially at high pressures which is why soft drinks are bottled under pressure (Mustoe e t a l. , 2001).  When you open a bottle of pop, some of the CO2 comes out of solution due to its low solubility (Mustoe e t a l. , 2001). 3 ) A p lic a tio n o f Wa te r Po la rity : M ro wa ve p ic O ve ns  Water is a polar molecule that is a good absorber of microwaves (Rayner-Canham, e t a l. , 2002).  The energy is converted into heat to warm up food (Rayner-Canham, e t a l. , 2002).
  • 23. Resources 1) Nelson and McGraw-Hill Ryerson Chemistry 11 Teacher’s Resource  Both provide:  background info  teaching suggestions (activities, tips/safety precautions for conducting labs, effective ways to approach the topic)  answers to lab/textbook questions  common misconceptions and solutions  Prefer McGraw-Hill Ryerson Teacher’s Resource  more detailed, includes strategies to support diverse student needs (ex. ESL students, etc.)
  • 24. Resources (cont’d) 2) Chemistry Games: J. Hand’s class website  Provides pre-made review games 3) Chalkbored: J. Schneider’s class website  Provides PowerPoint presentations, handouts, labs, worksheets for grade 11 and 12 4) Chemistry Demonstrations: T. Sperring’s website  Provides many quick Chemistry demos  Materials, procedure and what should be observed are included
  • 25. References 1) Cherkas, A., Freure, C., George, T., Ivanco, J., Kisway, L., Plavetic, S.J., Stewart, J., and G. Wisnicki. (2002). M G ra w-Hill Ry e rs o n c Che m is try 1 1 Te a c he r’s Re s o urc e . Toronto: Mc-Graw-Hill Ryerson. 2) Hand, J. (2010). Che m is try G a m e s . Retrieved July 9, 2010, from <http://www.mansfieldct.org/schools/mms/staff/hand/chemgames.htm> 3) Jenkins, F., van Kessel, H., Davies, L., Lantz, O., Thomas, P., and D. Tompkins. (2002). N ls o n Che m is try 1 1 . Toronto: Nelson e Thomson Learning. 4) Jenkins, F., van Kessel, H., Davies, L., Sanader, M., Tompkins, D., Lantz, O., and S. Haberer. (2002). N ls o n Che m is try 1 1 e Te a c he r’s Re s o urc e . Toronto: Nelson Thomson Learning. 5) Mustoe, F., Jansen, M., Doram, T., Ivanco, J., Clancy, C., and A. Ghazariansteja. (2001). M G ra w-Hill Ry e rs o n Che m is try c 1 1 . Toronto: McGraw-Hill Ryerson Limited. 6) Rayner-Canham, G., Damju, S., and U. Goering-Boone. (2002). A d is o n We s le y Che m is try 1 1 . Toronto: Addison Wesley. d 7) Schneider, J. (2009). Cha lkbo re d : Che m is try 1 1 . Retrieved July 9, 2010, from <http://www.chalkbored.com/lessons/chemistry-11.htm> 8) Sperring, T. (2000). Che m is try De m o ns tra tio ns . Retrieved July 9, 2010, from <http://webcache.googleusercontent.com/search?q=cache:vRVGMG9e6HcJ:alex.edfac.usyd.edu.au/methods/scien ce/Chemistry%2520Demonstrations+water,+ebonite+rod,+hexane&cd=1&hl=en&ct=clnk&gl=ca>