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HYDROGEN 
A FUEL FOR TODAY AND TOMORROW 
SHAILESH MISHRA 
GAURAV PANDEY 
MANISH TRIPATHI 
MANISH KUMAR SINGH 
DEEPAK KUMAR SINGH 
MENTOR: DR. D.K. BHALLA
HISTORY 
The first references to hydrogen fuel cells appeared in 1838. In a letter dated October 
1838 but published in the December 1838 edition of The London and Edinburgh 
Philosophical Magazine and Journal of Science, Welsh physicist and barrister 
WILLIAM GROOVE wrote about the development of his first crude fuel cells. He used 
a combination of sheet iron, copper and porcelain plates, and a solution of sulphate of 
copper and dilute acid. In a letter to the same publication written in December 1838 but 
published in June 1839, German physicist Christian Friedrich Schönbein discussed 
the first crude fuel cell that he had invented. His letter discussed current generated 
from hydrogen and oxygen dissolved in water. Grove later sketched his design, in 
1842, in the same journal. The fuel cell he made used similar materials to 
today's phosphoric-acid fuel cell
•What is Hydrogen? 
• Element 1 on the Periodic Table - 1 proton, 1 electron 
• Diatomic molecule (H2) - 2 protons, 2 electrons 
• Highest energy content of common fuels on a WEIGHT basis 
• Lowest energy content of common fuels on a VOLUME basis 
• Elemental hydrogen is abundant on earth, but usually bound to carbon or 
oxygen 
• Abundant throughout the universe (stars are primarily hydrogen)
•DIFFERENT HYDROGEN STRUCTURE
What is a hydrogen fuel cell? 
•Hydrogen fuel cells (HFCs) are a type of 
electrochemical cell. 
•HFCs generate electricity by reduction 
and oxidation reactions within the cell. 
•They use three main components, a 
fuel, an oxidant and an electrolyte. 
•HFCs operate like batteries, although 
they require external fuel. 
•HFCs are a thermodynamically open 
system. 
•HFCs use hydrogen as a fuel, oxygen as 
an oxidant, a proton exchange 
membrane as an electrolyte, and emit 
only water as waste.
How do they work? 
•Fuel (H2) is first transported to 
the anode of the cell 
•Fuel undergoes the anode 
reaction 
•Anode reaction splits the fuel 
into H+ (a proton) and e- 
•Protons pass through the 
electrolyte to the cathode 
•Electrons can not pass through 
the electrolyte, and must travel 
through an external circuit which 
creates a usable electric current 
•Protons and electrons reach the 
cathode, and undergo the 
cathode reaction
•How a Hydrogen Fuel Cell 
Works
Chemistry behind the technology 
Oxidation 
At the anode of the cell, a 
catalyst (platinum powder) 
is used to separate the 
proton from the electron in 
the hydrogen fuel. 
Anode half-reaction: 
2H2 
 4H+ + 4e- 
Eo = 0.00V 
Reduction 
At the cathode of the cell, a 
second catalyst (nickel) is used to 
recombine the protons, 
electrons, and oxygen atoms to 
form water. 
Cathode half- reaction: 
4H+ + O2 + 4e-  2H2O 
Eo = 0.68V 
In electrochemistry, the Eo 
cell value (energy) of a fuel cell is equal to the Eo of 
the cathode half-reaction minus the Eo of the anode half-reaction. For a 
hydrogen fuel cell, the two half reactions are shown above. So to calculate the 
energy of one fuel cell, we need to subtract the anode energy from the 
cathode energy. For a HFC, the Eo 
cell = 0.68V – 0.00V which equals 0.68V
In this project 
we will produce 
electricity using 
hydrogen fuel. 
It helps to run 
hydrogen 
powered 
bicycle 
By wikipedia
Uses of hydrogen fuel cells 
There are many different uses of fuel cells being utilized right now. Some of these 
uses are… 
•Power sources for vehicles such as cars, trucks, buses and even boats and submarines 
•Power sources for spacecraft, remote weather stations and military technology 
•Batteries for electronics such as laptops and smart phones 
•Sources for uninterruptable power supplies.
Problems regarding hydrogen fuel cells 
•Lack of hydrogen infrastructure 
•Need for refueling stations 
•Lack of consumer distribution system 
•Cost of hydrogen fuel cells 
•2009 Department of Energy estimated $61/kw 
•Honda FCX Clarity costs about half a million dollars to make 
•Carbon cost of producing hydrogen 
•Problems with HFC cars 
•Short range (~260 miles) 
•Warm up time (~5 minutes)
Other Ways to Liberate Hydrogen From Water 
• Steam Electrolysis 
• Split water with heat, pressure, and electricity 
• Thermochemical 
• Split water with chemicals and heat 
• Photoelectrochemical 
• Split water using sunlight directly, or using chemicals 
and heat 
• Biological 
• Split water using organisms
Bush Administration’s Hydrogen 
Commitment 
• 500 metric tons of carbon 
saved each year by 2040 
• Reduce demand for 
oil by 11 million 
barrels per day by 
2040 
• Child born in 2003 to 
drive a hydrogen car at age 16
Why Hydrogen? 
It’s abundant, clean, efficient, and can be derived 
from diverse domestic resources. 
HIGH EFFICIENCY 
& RELIABILITY 
ZERO/NEAR ZERO 
EMISSIONS 
Transportation 
. 
Distributed 
Generation 
Biomass 
Hydro 
Wind 
Solar 
Geothermal 
Nuclear 
Oil 
Coal 
Natural 
Gas 
With Carbon Sequestration
•Hydrogen Storage 
• High-pressure storage tanks. Hydrogen 
gas can be compressed and stored in 
storage tanks at high pressure, but these 
tanks must be very strong. 
• Liquid hydrogen. Hydrogen can be stored 
as a liquid. In this form, more hydrogen 
can be stored per volume, but it must be 
kept at very cold temperature (about - 
253° C).
Fuel leak simulation 
Hydrogen on left 
Gasoline on right 
Equivalent energy 
release 
•Hydrogen Safety 
Hydrogen Gasoline 
Three 
Second 
seconds 
One minute
•Flexibility Of Use 
Transportation 
Desired range can be achieved with on-board hydrogen 
storage (unlike Battery Electric Vehicle) 
Can be used in internal combustion engines 
Trains, automobiles, buses, and ships 
Buildings 
Combined heat, power, and fuel 
Reliable energy services for critical applications 
Grid independence 
Industrial Sector 
Already plays an important role as a chemical 
Opportunities for additional revenue streams
•So– why hydrogen? 
• Energy security 
• Diverse domestic sources 
• Flexibility of system 
• Economic security 
• International leadership in technical 
• development and deployment 
• Price stability 
• Environmental security 
• Potential to meet GHG targets 
• Urban air quality improvements 
• Reduction in air pollutants
Why India Should Think About 
Hydrogen 
As estimation of use of crude oil state that the fossil 
fuel will extinct till 2100 A.D. 
At present , In a setback for the government’s 
grand plan to cut down the current account deficit 
(CAD), through containing the outflow of dollars and 
saving around $8.47 billion on crude oil imports from 
Iran, the Persian Gulf country has turned down India’s 
request for accepting full rupee payment for oil 
imports.
Conclusion 
• Hydrogen fuel cells will dramatically 
change our cars, homes and businesses 
are powered and heated, and it both 
positively and negatively change places 
like the Middle East and third world 
countries. They will also clean up the 
world’s air.
Any 
query ?????
Thank you

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Hydrogen fuel cell

  • 1. HYDROGEN A FUEL FOR TODAY AND TOMORROW SHAILESH MISHRA GAURAV PANDEY MANISH TRIPATHI MANISH KUMAR SINGH DEEPAK KUMAR SINGH MENTOR: DR. D.K. BHALLA
  • 2. HISTORY The first references to hydrogen fuel cells appeared in 1838. In a letter dated October 1838 but published in the December 1838 edition of The London and Edinburgh Philosophical Magazine and Journal of Science, Welsh physicist and barrister WILLIAM GROOVE wrote about the development of his first crude fuel cells. He used a combination of sheet iron, copper and porcelain plates, and a solution of sulphate of copper and dilute acid. In a letter to the same publication written in December 1838 but published in June 1839, German physicist Christian Friedrich Schönbein discussed the first crude fuel cell that he had invented. His letter discussed current generated from hydrogen and oxygen dissolved in water. Grove later sketched his design, in 1842, in the same journal. The fuel cell he made used similar materials to today's phosphoric-acid fuel cell
  • 3. •What is Hydrogen? • Element 1 on the Periodic Table - 1 proton, 1 electron • Diatomic molecule (H2) - 2 protons, 2 electrons • Highest energy content of common fuels on a WEIGHT basis • Lowest energy content of common fuels on a VOLUME basis • Elemental hydrogen is abundant on earth, but usually bound to carbon or oxygen • Abundant throughout the universe (stars are primarily hydrogen)
  • 5. What is a hydrogen fuel cell? •Hydrogen fuel cells (HFCs) are a type of electrochemical cell. •HFCs generate electricity by reduction and oxidation reactions within the cell. •They use three main components, a fuel, an oxidant and an electrolyte. •HFCs operate like batteries, although they require external fuel. •HFCs are a thermodynamically open system. •HFCs use hydrogen as a fuel, oxygen as an oxidant, a proton exchange membrane as an electrolyte, and emit only water as waste.
  • 6. How do they work? •Fuel (H2) is first transported to the anode of the cell •Fuel undergoes the anode reaction •Anode reaction splits the fuel into H+ (a proton) and e- •Protons pass through the electrolyte to the cathode •Electrons can not pass through the electrolyte, and must travel through an external circuit which creates a usable electric current •Protons and electrons reach the cathode, and undergo the cathode reaction
  • 7. •How a Hydrogen Fuel Cell Works
  • 8. Chemistry behind the technology Oxidation At the anode of the cell, a catalyst (platinum powder) is used to separate the proton from the electron in the hydrogen fuel. Anode half-reaction: 2H2  4H+ + 4e- Eo = 0.00V Reduction At the cathode of the cell, a second catalyst (nickel) is used to recombine the protons, electrons, and oxygen atoms to form water. Cathode half- reaction: 4H+ + O2 + 4e-  2H2O Eo = 0.68V In electrochemistry, the Eo cell value (energy) of a fuel cell is equal to the Eo of the cathode half-reaction minus the Eo of the anode half-reaction. For a hydrogen fuel cell, the two half reactions are shown above. So to calculate the energy of one fuel cell, we need to subtract the anode energy from the cathode energy. For a HFC, the Eo cell = 0.68V – 0.00V which equals 0.68V
  • 9. In this project we will produce electricity using hydrogen fuel. It helps to run hydrogen powered bicycle By wikipedia
  • 10. Uses of hydrogen fuel cells There are many different uses of fuel cells being utilized right now. Some of these uses are… •Power sources for vehicles such as cars, trucks, buses and even boats and submarines •Power sources for spacecraft, remote weather stations and military technology •Batteries for electronics such as laptops and smart phones •Sources for uninterruptable power supplies.
  • 11. Problems regarding hydrogen fuel cells •Lack of hydrogen infrastructure •Need for refueling stations •Lack of consumer distribution system •Cost of hydrogen fuel cells •2009 Department of Energy estimated $61/kw •Honda FCX Clarity costs about half a million dollars to make •Carbon cost of producing hydrogen •Problems with HFC cars •Short range (~260 miles) •Warm up time (~5 minutes)
  • 12. Other Ways to Liberate Hydrogen From Water • Steam Electrolysis • Split water with heat, pressure, and electricity • Thermochemical • Split water with chemicals and heat • Photoelectrochemical • Split water using sunlight directly, or using chemicals and heat • Biological • Split water using organisms
  • 13. Bush Administration’s Hydrogen Commitment • 500 metric tons of carbon saved each year by 2040 • Reduce demand for oil by 11 million barrels per day by 2040 • Child born in 2003 to drive a hydrogen car at age 16
  • 14. Why Hydrogen? It’s abundant, clean, efficient, and can be derived from diverse domestic resources. HIGH EFFICIENCY & RELIABILITY ZERO/NEAR ZERO EMISSIONS Transportation . Distributed Generation Biomass Hydro Wind Solar Geothermal Nuclear Oil Coal Natural Gas With Carbon Sequestration
  • 15. •Hydrogen Storage • High-pressure storage tanks. Hydrogen gas can be compressed and stored in storage tanks at high pressure, but these tanks must be very strong. • Liquid hydrogen. Hydrogen can be stored as a liquid. In this form, more hydrogen can be stored per volume, but it must be kept at very cold temperature (about - 253° C).
  • 16. Fuel leak simulation Hydrogen on left Gasoline on right Equivalent energy release •Hydrogen Safety Hydrogen Gasoline Three Second seconds One minute
  • 17. •Flexibility Of Use Transportation Desired range can be achieved with on-board hydrogen storage (unlike Battery Electric Vehicle) Can be used in internal combustion engines Trains, automobiles, buses, and ships Buildings Combined heat, power, and fuel Reliable energy services for critical applications Grid independence Industrial Sector Already plays an important role as a chemical Opportunities for additional revenue streams
  • 18. •So– why hydrogen? • Energy security • Diverse domestic sources • Flexibility of system • Economic security • International leadership in technical • development and deployment • Price stability • Environmental security • Potential to meet GHG targets • Urban air quality improvements • Reduction in air pollutants
  • 19.
  • 20. Why India Should Think About Hydrogen As estimation of use of crude oil state that the fossil fuel will extinct till 2100 A.D. At present , In a setback for the government’s grand plan to cut down the current account deficit (CAD), through containing the outflow of dollars and saving around $8.47 billion on crude oil imports from Iran, the Persian Gulf country has turned down India’s request for accepting full rupee payment for oil imports.
  • 21. Conclusion • Hydrogen fuel cells will dramatically change our cars, homes and businesses are powered and heated, and it both positively and negatively change places like the Middle East and third world countries. They will also clean up the world’s air.