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Mg 2+ O 2- KMnO 4
Redox reactions   are a chemical reactions involving simultaneously (serentak)  oxidation and reduction processes  ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
PbO –  oxidising agent  (experiences reduction Mg –  reducing agent  ( experiences  oxidation) Mg  +  PbO  MgO  +  Pb  Gain of oxygen ----  oxidation Loss of oxygen ----  reduction
Cl 2  –  oxidising agent  ( undergoes reduction ) --- chlorine  oxidises  hydrogen sulphide to sulphur  H 2 S –  reducing agent   ( undergoes oxidation)   --- hydrogen sulphide  reduces  chlorine to hydrogen chloride  Redox reaction  H 2  S  +  Cl 2   2HCl  +  S Loss of hydrogen ---  oxidation Gain of hydrogen ---  reduction
[object Object],[object Object],[object Object],Chlorine   –  oxidising agent  Sodium – reducing agent  ,[object Object],[object Object],2Na(s)  +  Cl 2  (g)  2NaCl(s) Na  Na +   +  e (  loss of electron) Cl 2   +  2e -   2Cl -   ( gain of electron) Oxidation  Process  Reduction  Process
 
Solution :  ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],O.N Reducing agent --- iron (II) chloride  Oxidising agent  --- chlorine gas C  :  Change in Oxidation Number ( O.N )  2FeCl 2   +  Cl 2   2FeCl 3   Oxidation number  decreases  (0  -> -1)  Oxidation number  increases ( +2  -> +3) reduction oxidation +2 +3 -1 0 -1
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],The charge of chlorate Oxidation number of S
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Make sure that you  add  the electron on the side of the  half equation  that has the  bigger oxidation number
[object Object],[object Object],[object Object],Fe 2+   Fe 3+ Cl - Cl 2 Br - I - Br 2 Green  solution Brown  solution  Yellow solution  Colourless solution  MnO 4  - Purple  solution  Cr 2 O 7   2- Cu 2+ Orange  solution  Blue  solution  Cr 3+   I 2 Example : Half equation  : Fe 2+   Fe 3+   +  e -   --------  (1)  X 2  Br 2   +  2e -   2Br  -   --------  (2) Ionic equation  : 2Fe  2+   +  Br 2   2Fe 3+   +  2Br - Combined
A .  Redox Reaction  ( The combustion of Magnesium in oxygen) ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],combined  Reactants
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Combined   B.  The change of iron(II) ions to iron(III) ions  (  Fe 2+   Fe 3+ )
C  :  The change of iron(III) ion,  Fe 3+   to iron(II) ion ,  Fe 2+   ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],combined
D : The  Displacement  (penyesaran) of Metal from its Salt Solution  ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],K, Na , Ca , Mg , Al , Zn , Fe , Sn , Pb , H , Cu , Hg , Ag , Au Most  electropositive Least  electropositive
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Zn  loses  electrons & is  oxidised  to Zn 2+ Cu 2+   receives  electrons  & is  reduced  to Cu
E :  Displacement  of Halogens from Halide  Solutions  ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Solution   Reactivity decreases, higher act as a oxidising agent
Example Chlorine water react with sodium bromide solution  ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Confirmatory Test for the Bromine, Chlorine and Iodine  ,[object Object],Solution Colour in water Colour in CCl 4 Concentrated  Dilute  Iodine  Brown Yellow  Purple  Bromine Brown Yellow  Brown Chlorine  Light greenish yellow  Colourless  Colourless
F :  Transfer of Electrons at a Distance   ,[object Object],[object Object],[object Object],[object Object],The  electrons  that are  released   from  reducing agent  (negative electrode) will flow out through outer circuit to the  oxidising agent  ( positive electrode)  reduction oxd
Example : The Reaction Between Bromine Water and Iron(II) Sulphate solution  ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],Reduction   Oxidation  (Positive terminal) (Negative terminal)
Test Yourself  ,[object Object],[object Object],[object Object]
 
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Solution :
Redox Reaction in a simple voltaic cells ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],0 +2 +2 0 Oxidation  Reduction
 
G .  Corrosion of Metals ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Metal corrosion
RUSTING OF IRON ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Stage 1 corrosion
[object Object],[object Object],O 2  in the air   Stage 4 ,[object Object],[object Object],Stage 3 ,[object Object],[object Object],[object Object],Stage 2 Iron rusting
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Example  :  Electrochemical Corrosion of Metals More  easily  corroded Difficult  to be corroded Tendency for corrosion increases
Example  :  The effect of rusting when iron comes into contact with other metals    ( Mg, Cu , Zn , Sn) Hypothesis  :  Iron is protected  from rusting when it comes in contact with more    electropositive metals, but rusts when it contact with less electropositive metals .  ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],B A rusting
PREVENTION THE  RUSTING OF IRON Coating  a layer of  metal such as Al or  Sn on food tins Applying paint,oil or grease  on surface such as engine Wrapping  the iron with  a layer of plastic  . Ex: hangers Applying a coat  of Al  such as car bumpers  or water pipes Iron sheet used as house roofs Are  galvanised with  a layer of zinc Iron is  alloyed  with other  metals such as chromium  or nickel  to produce stainless steel Huge iron construction structure such  as bridges  protected  from corrosion by  using  sacrificial metals(logam korban) such as Mg & Zn
Reactivity Series (R.S)  of Metals  A : Metals with Oxygen  ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
K Na Ca Mg Al C Zn Fe Sn Pb Cu  Ag Au  Reactivity decreases Example : The reaction between Lead(II) oxide with Carbon Observation   :  burn brightly  :  produces a grey solids  Inference   : Carbon is more reactive than Lead  Equation  :  PbO  +  C  Pb  + CO 2 If carbon is  more reactive  than metal X , a flame or glows(baraan)  can be seen . If carbon is  less reactive  than metal Y  ,the flame or glows will  not be seen  when carbon react with metal oxide  Y is heated . The position of Carbon in the R. S.
 
PREPARED BY PN ZAINAB BINTI AYUB 22 JULY 2008

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Oxidation & reduction

  • 1. Mg 2+ O 2- KMnO 4
  • 2.
  • 3. PbO – oxidising agent (experiences reduction Mg – reducing agent ( experiences oxidation) Mg + PbO MgO + Pb Gain of oxygen ---- oxidation Loss of oxygen ---- reduction
  • 4. Cl 2 – oxidising agent ( undergoes reduction ) --- chlorine oxidises hydrogen sulphide to sulphur H 2 S – reducing agent ( undergoes oxidation) --- hydrogen sulphide reduces chlorine to hydrogen chloride Redox reaction H 2 S + Cl 2 2HCl + S Loss of hydrogen --- oxidation Gain of hydrogen --- reduction
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  • 35.
  • 36. PREVENTION THE RUSTING OF IRON Coating a layer of metal such as Al or Sn on food tins Applying paint,oil or grease on surface such as engine Wrapping the iron with a layer of plastic . Ex: hangers Applying a coat of Al such as car bumpers or water pipes Iron sheet used as house roofs Are galvanised with a layer of zinc Iron is alloyed with other metals such as chromium or nickel to produce stainless steel Huge iron construction structure such as bridges protected from corrosion by using sacrificial metals(logam korban) such as Mg & Zn
  • 37.
  • 38. K Na Ca Mg Al C Zn Fe Sn Pb Cu Ag Au Reactivity decreases Example : The reaction between Lead(II) oxide with Carbon Observation : burn brightly : produces a grey solids Inference : Carbon is more reactive than Lead Equation : PbO + C Pb + CO 2 If carbon is more reactive than metal X , a flame or glows(baraan) can be seen . If carbon is less reactive than metal Y ,the flame or glows will not be seen when carbon react with metal oxide Y is heated . The position of Carbon in the R. S.
  • 39.  
  • 40. PREPARED BY PN ZAINAB BINTI AYUB 22 JULY 2008