1. AIEEE –Past papers CHEMISTRY- UNSOLVED PAPER - 2007

2. SECTION – I Single Correct Answer Type This Section contains 40multiple choice questions. Each question has four choices A), B), C) and D) out of which ONLY ONE is correct.

3. 01 Problem The energies of activation for forward and reverse reactions for A2 + B 2 2AB are 180 kJ mol−1 and 200 kJ mol −1 respectively. The presence of catalyst lowers the activation energy of both (forward and reverse) reactions by 100 kJ mol −1. The enthalpy change of the reaction (A2 + B 2 -> 2AB ) in the presence of catalyst will be (in kJ mol −1) 300 120 280 20

4. Problem 02 The cell Zn|Zn2+ (1M) ||Cu 2+1M |(CuE0cell 1.10V ), was allowed to be completely discharged at 298 K. The relative concentration of Zn2+to Cu2+ is antilog (24.08) 37.3 1037.3 9.65 ×104

5. Problem 03 The pKa of a weak acid (HA) is 4.5. The pOH of an aqueous buffered solution of HA in which 50% of the acid is ionized is 4.5 2.5 9.5 7.0

6. Problem 04 Consider the reaction, 2A +B ->Pr oducts When concentration of B alone was doubled, the half-life did not change. When the concentration of A alone was doubled, the rate increased by two times. The unit of rate constant for this reaction is L mol-1 s-1 no unit mol L-1 s-1 s-1

7. Problem 05 Identify the incorrect statement among the following d-Block elements show irregular and erratic chemical properties among themselves La and Lu have partially filled d orbitals and no other partially filled orbitals The chemistry of various lanthanoids is very similar 4f and 5f orbitals are equally shielded

8. Problem 06 Which one of the following has a square planar geometry? [CoCl 4 ]2- [FeCl 4 ] 2- [NiCl 4 ] 2- [PtCl4 ] 2-

9. Problem 07 Which of the following molecules is expected to rotate the plane of plane polarized light? a. b. c. d.

10. 08 Problem The secondary structure of a protein refers to α-helical backbone hydrophobic interactions sequence of α-amino acids fixed configuration of the polypeptide backbone

11. Problem 09 Which of the following reactions will yield 2, 2-dibromopropane? CH 3 − C ≡ CH+ 2HBr-> CH 3 CH ≡ CHBr +HBr-> CH ≡ CH+ 2HBr-> CH 3 − CH = CH2 +HBr ->

12. Problem 10 In the chemical reaction, CH3 CH2 NH2 − CHCl3 + 3KOH-> A + B + 3H2O, the compound (A) and (B) are respectively C2H5CN and 3KCl CH3CH2CONH2 and 3KCl C2H5NC and K2CO3 C2H5NC and 3KCl

13. Problem 11 The reaction of toluene with Cl2 in presence of FeCl3 gives predominantly benzoyl chloride benzyl chloride o-and p-chlorotoluene m-chlorotoluene

14. 12 Problem Presence of a nitro group in a benzene ring activates the ring towards electrophilic substitution renders the ring basic deactivates the ring towards nucleophilic substitution deactivates the ring towards electrophilic substitution

15. Problem 13 In which of the following ionization processes, the bond order has increased and the magnetic behaviour has changed? C2 ->C NO->NO O2 ->O N2->N

16. Problem 14 The actinoids exhibits more number of oxidation states in general than the lanthanoids. This is because the 5f orbitals are more buried than the 4f orbitals there is a similarity between 4f and 5f orbitals in their angular part of the wave function the actinoids are more reactive than the lanthanoids the 5f orbitals extend further from the nucleus than the 4f orbitals

17. Problem 15 Equal masses of methane and oxygen are mixed in an empty container at 25°C. The fraction of the total pressure exerted by oxygen is a. b. c. d.

18. Problem 16 A 5.25 % solution of a substance is isotonic with a 1.5% solution of urea (molar mass = 60 g mol −1 ) in the same solvent. If the densities of both the solutions are assumed to be equal to 1.0 g cm−3, molar mass of the substance will be 90.0 g mol−1 115.0 g mol −1 105.0 g mol −1 210.0 g mol −1

19. 17 Problem Assuming that water vapour is an ideal gas, the internal energy (ΔU) when 1 mol of water is vapourised at 1 bar pressure and 100°C, (Given: Molar enthalpy of vapourization of water at 1 bar and 373 K = 41 kJ mol −1 and R = 8.3 J mol −1 K −1) will be 4.100 kJ mol−1 3.7904 kJ mol −1 37.904 kJ mol −1 41. 00 kJ mol −1

20. Problem 18 In a sautrated solution of the sparingly soluble strong electrolyte AgIO3 (Molecular mass = 283) the equilibrium which sets in is AgIO3(6) Ag+(aq) + IO− 3(aq) If the solubility product constant Ksp of AgIO3 at a given temperature is 1.0 × 10−8, what is the mass of AgIO3 contained in 100 ml of its saturated solution? 28.3 × 10−2 g 2.83 × 10−3 g 1.0 × 10−7 g 1.0 × 10−4 g

21. Problem 19 A radioactive element gets spilled over the floor of a room. Its half-life period is 30 days. If the initial activity is ten times the permissible value, after how many days will it be safe to enter the room? 1000 days 300 days 10 days 100 days

22. Problem 20 Which one of the following conformation of cyclohexane is chiral? Twist boat Rigid Chair Boat

23. Problem 21 Which of the following is the correct order of decreasing SN 2 reactivity? RCH 2 X > R3CX > R 2 CHX RCH 2 X > R 2 CHX > R 3 CX R 3 CX > R 2 CHX > RCH 2 X R 2 CHX > R 3 CX > RCH 2 X

24. Problem 22 In the following sequence of reactions, the compound ‘D’ is butanal n-butyl alcohol n-propyl alcohol propanal

25. Problem 23 Which of the following sets of quantum numbers represents the highest energy of an atom? n = 3, l = 2,m = 1,s = +1/ 2 n = 3, l = 2,m = 1,s = +1/ 2 n = 4, l = 0,m = 0,s = +1/ 2 n = 3, l = 0,m = 0,s = +1/ 2

26. Problem 24 Which of the following hydrogen bonds is the strongest? O−H…….N F−H…….F O−H…….O O−H…….F

27. Problem 25 In the reaction 6 L HCl(aq) is consumed for every 3L H2(g) produced 33.6 L H2(g) is produced regardless of temperature and pressure for every mole Al that reacts 67.2 L H2(g) at STP is produced for every mole Al that reacts 11.2 H2(g) at STP is produced for every mole HCl(aq) consumed

28. Problem 26 Regular use of which of the following fertilizer increases the acidity of soil? Potassium nitrate Urea Superphosphate of lime Ammonium sulphate

29. Problem 27 Identify the correct statement regarding a spontaneous process For a spontaneous process in an isolated system, the change in entropy is positive Endothermic processes are never spontaneous Exothermic processes are always spontaneous Lowering of energy in the reaction process is the only criterion for spontaneity

30. Problem 28 Which of the following nuclear reactions will generate an isotope ? neutron particleemission positron emission α-particleemission β-particleemission

31. Problem 29 The equivalent conductances of two strong electrolytes at infinite dilution in H2O (where ions move freely through a solution) at 25°C are given below: ∧0 CH3COONa∧ 0 = 91.0 S cm2 / equiv2 ∧0 HCl= 426.2 S cm2 / equiv What additional information/quantity one needs to calculate ∧0 of an aqueous solution of acetic acid? ∧0 of NaCl ∧0 of CH3COOK ∧0 The limiting equivalent conductance of ∧0 of chloroacetic acid (C/CH2COOH)

32. Problem 30 Which one of the following is the strongest base in aqueous solution? Trimethylamine Aniline Dimethylamine Methylamine

33. Problem 31 The compound formed as a result of oxidation of ethyl benzene by KMnO4 is benzophenone acetophenone benzoic acid benzyl alcohol

34. Problem 32 The IUPAC name of is 1, 1-diethyl-2,2-dimethylpentane 4, 4-dimethyl-5, 5-diethylpentane 5, 5-diethyl-4, 4-diemthylpentane 3-ethyl-4, 4-dimethylheptane

35. Problem 33 Which of the following species exhibits the diamagnetic behaviour? O O O 2 NO

36. Problem 34 The stability of dihalides of Si, Ge, Sn and Pb increases steadily in the sequence GeX 2 « SiX 2 « SnX 2 « PbX 2 SiX2 « GeX 2 « PbX2 « SnX 2 SiX 2 « GeX 2 « SnX2 « PbX 2 PbX 2 « SnX 2 « GeX 2 « SiX 2

37. Problem 35 Identify the incorrect statement among the following Ozone reacts with SO2 to give SO3 Silicon reacts with NaOH(aq) in the presence of air to give Na2SiO3 and H2O Cl2 reacts with excess of NH3 to give N2 and HCl Br2 reacts with hot and strong NaOH solution to give NaBr, NaBrO4 and H2O

38. Problem 36 The charge/size ratio of a cation determines its polarizing power. Which one of the following sequences represents the increasing order of the polarizinig order of the polarizing power of the cationic species, K+, Ca2+, Mg2+, Be2+? Mg2+,Be2+,K+ ,Ca2+ Be2+,K + ,Ca2+,Mg2+ K + ,Ca2+,Mg2+,Be2+ Ca2+,Mg2+,Be2+,K+

39. Problem 37 The density (in g mL −1) of a 3.60 M sulphuric acid solution that is 29% H2SO4 (Molar mass = 98 g mol−1) by mass will be 1.64 1.88 1.22 1.45

40. Problem 38 The first and second dissociation constants of an acid H2A are 1.0 × 10−5 and 5.0 × 10−10 respectively. The overall dissociation constant of the acid will be 5.0 × 10−5 5.0 × 1015 5.0 × 10−15 0.0 × 105

41. Problem 39 A mixture of ethyl alcohol and propyl alcohol has a vapour pressure of 290 mm at 300 K. The vapour pressure of propyl alcohol is 200 mm. If the mole fraction of ethyl alcohol is 0.6, its vapour pressure (in mm) at the same temperature will be 350 300 700 360

42. Problem 40 In conversion of lime-stone to lime, the vales of ΔH° and ΔS° are +179.1 kJ mol−1 and 160.2 J/K respectively at 298 K and 1 bar. Assuming that ΔH° do not change with temperature, temperature above which conversion of limestone to lime will be spontaneous is 1008 K 1200 845 K 1118 K

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