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The chemoselectivity
The selectivity
• Thisquestion arises from presence of more than one
functional group.
The chemoselectivity
• It is matter of reactivity ….
The chemoselectivity
• Which is more reactive ??
The chemoselectivity
The chemoselectivity
The chemoselectivity
Dianions
• Last formed , react first ????




                    16


         25
Protecting groups
Protecting groups
Protecting groups
Protecting groups
Oxidizing agents




• Oxidation of primary alcohols
Oxidizing agents
• Oxidation   of primary alcohols
                                    • Dess – Martin oxidation




                                • Swern oxidation
Oxidizing agents
• Oxidation of secondary alcohols to acids

• Cr (VI) and Mn (VII) still the preferred agents.
Think bout it ?
Think about it ?

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The chemoselectivity