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U N I D O C L E A N E R P R O D U C T I O N T O O L K I T
UNITED NATIONS INDUSTRIAL DEVELOPMENT ORGANIZATION
1
Introduction
into Cleaner Production
Main directorym
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Textbook 1 - CP Basics
1- Background Material
1 Textbook
1.1 Introduction
Aims and goals of the Cleaner Production brochure
„Cleaner production and waste minimization“
After working with the present brochure you will be able to tell the
difference between cause and effect of waste problems,
Aims and goals
• recognize the economic benefits of waste minimization,
• categorize waste and emissions in your company,
• identify the factors influencing waste and emission minimization,
• use the worksheets to find systematic solutions for your problems.
To ensure this, you should read more about the following:
• Definitions (waste, emissions, ...)
Procedure
• Traditional waste management versus a more holistic approach
• Interrelations between raw material, production process and
waste/emissions
• Factors influencing the generation of waste (where to start from)
Data collection as a basis for waste minimization
Defining categories for waste and emissions together with strategies to
minimize them
You should now take two or three hours to study this introduction and
subsequently think about the effects and consequences this may have on
your company. Data collection - as an essential basis for comprehensive
information on emissions and waste in your firm - can be very time
consuming. On the other hand, there is the possibility, especially in bigger
companies, to obtain the data immediately from the computer system.
Authors:
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1.2 What is CLEANER PRODUCTION?
CLEANER PRODUCTION is defined as the continuous application of an
integrated preventive environmental strategy to processes, products and
services to increase the overall efficiency and to reduce risks to humans
and environment.
What does
CLEANER
PRODUCTION
mean?
• In production processes, Cleaner Production addresses the saving of
raw materials and energy, the elimination of toxic raw materials and the
reduction in the quantities and toxicity of wastes and emissions.
• In product development and design, Cleaner Production addresses the
reduction of negative impacts throughout the life cycle of the product:
from raw material extraction to ultimate disposal.
• In services, Cleaner Production addresses the incorporation of
environmental considerations into the design and delivery of services.
As mentioned before Cleaner Production is the continuous application of a
preventive strategy and methodology.
In this context it is quite important to say that it is you who knows your
own company best and that this expert know-how is essential. Therefore
Cleaner Production will only be successful if you do your best to support
and promote it. External knowledge can and shall only help you to find
solutions. From this point of view Cleaner Production is above all a
stimulation of new ideas through an external view.
Help for self-help
in the company
A Cleaner Production project follows a certain methodology and consists of
the following elements:
Slides 1 - CP Basics
Elements of a CP-Project
! mass flow
! energy flow
! costs and safety
!Data Collection
!Reflection:
Where and why do we generate waste?
!Option generation
!Feasibiltiy
!Implementation
!Controlling, continuation,
EMS
Data collection – mass flow, energy flow, costs and safety
This is one of the basic and most important and often also quite
time consuming steps: the proper description of the status quo. The
better the actual procedures and data are known the better the
implementation of the right CP options is.
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Reflection: where and why do we generate waste
After the collection of data, the data are analysed and reflected
according to the principles of Cleaner Production.
Option generation
Starting from the analysis CP options are generated. New, creative
and/or already well-known ones will come up, aiming at a reduction
at the source by good house keeping, product or process
modification, organizational changes, internal or external recycling.
Feasibility analysis
For selected options a feasibility study will analyse the economical,
technical and ecological feasibility.
Implementation
In this step CP options are implemented. Either after proceeding the
steps 1 to 4, but very often options are directly implemented
without the detailed feasibility analysis – when advantages and
feasibility are obvious – or even without the option generation – as
data collection and data reflection already makes obvious CP
options visible.
Controlling and continuation
Probably the most important and challenging aspect is the setting
up of a systematic way for successful, on-going improvement. Here
environmental controlling is needed, the setting up of new goals
and targets and the continuous implementation.
Company analyses as used in a Cleaner Production project/programme may
be used for five different kinds of evaluations:
Evaluation of the company analyses For use by
Regular report, ecological controlling ⇒ Management
Waste management plan ⇒ Authorities, company
Analysis of ecological/economical weak
points
⇒ Personnel / management
Environmental management system
(ISO 14001)
⇒ Business partners /
customers
Environmental report ⇒ Public
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1.3 What is waste and what are emissions?
According to the Waste Management Act, waste is defined as
mobile objects which the owner wants to dispose of or has
already disposed of, or which should be gathered and treated as
waste in the interest of the public.
This definition does not seem to be very useful for your purpose in the
sense of industrial waste management and waste minimization.
Waste and emissions are - mostly very expensively acquired - raw and
process materials that have not been transformed into marketable products
or into raw materials to be used as inputs into another production process.
They include all solid, liquid and gaseous materials which are emitted into
the air, water or soil as well as noise and waste heat. The production
process also comprises activities one often tends to forget, such as
maintenance, servicing, cleaning as well as the office area.
Minimizing waste
and emissions
means...
to increase the
ecological
efficiency of your
company ...
Therefore minimizing waste and emissions also means increasing the
degree of utilization of the materials and energy used for production
(increasing the ecological efficiency) until, and this is the ideal case, a 100
percent utilization guarantees a waste and emission free procedure.
Thus, for the company, waste minimization is not only an environmental
goal but more so, and primarily, a commercially orientated program to
increase the degree of utilization of materials.
to benefit from
commercial
advantages ...
This situation can also be illustrated by the fact that even though the
treatment and disposal of waste and emissions is very expensive, the costs
due to the loss of raw materials (which are wasted in the proper sense of
the word) are normally much higher.
to save costs of
raw materials
Use the worksheets in this brochure to verify this fact and also for your
own company!
Example: Applying a repair coat on a car can be a very material intensive
process. Using a conventional, solvent-containing varnish with a non-
volatile matter content of about 60%, combined with an uneconomic
spraying application from a beaker pistol which is unadequately handled
and badly regulated by the painter, the application of 1 kg of varnish on
the material consumes a quantity of about 10 kg of raw material.
Opting for a varnish with a higher non-volatile matter content together with
the use of a HVLP-spraying pistol, a metering pump during application and
an improved cleaning system for the spraying pistol - the best available
technology, that is - brings the consumption of raw material necessary for
the application of the same paint film down to a bit more than 2 kg (see
below). On the basis of disposal costs of about 1,- €/kg and a material cost
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of 15,- €/kg considerable amounts can be saved, which can be deducted
from the investment costs.
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1.4 Cleaner Production versus End of Pipe?
Up to now, conventional environmental technologies have mostly worked
on the treatment of existing waste and emissions (examples: air filter
technology, waste water treatment, treatment of sludge, waste incineration
etc.). As this approach takes up things at the end of the production
process, it is also referred to as end-of-pipe technology. It is essentially
characterized by additional expenses for the company and a shifting of
problems (examples: production of sewage sludge through waste water
treatment, production of gypsum from flue gas, etc.)
Environmental
protection should
mean more than
shifting problems
Cleaner
production
means
integrating
environmental
objectives into
the production
process
Cleaner production aims to integrate environmental objectives into the
production process in order to reduce waste and emissions in terms of
quantity and toxicity and thus to reduce costs. Compared to the disposal by
external services or to end-of-pipe technologies, it presents several
advantages:
• Cleaner production in the sense of reducing the quantity of materials
and energy used essentially presents a potential for economic solutions.
• Due to an intensive exploration of the production process, the
minimization of waste and emissions generally induces an innovation
process within the company.
• Responsibility can be assumed for the production process as a whole;
risks in the field of environmental liabilities and of waste disposal can
be minimized.
• Waste and emission minimization is a step towards a more sustained
economic development.
While conventional waste management asks:
What can we do with existing waste and emissions?
Cleaner Production, production integrated environmental protection asks:
Where do our waste and emissions come from?
Why have they turned into waste at all?
From the symptom
to the source
Therefore, the essential difference lies in the fact that cleaner production
does not simply treat the symptom but that it tries to get down to the
source of the problem.
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Example: In the water treatment unit of a copper manufacturer mud
containing metal is produced, which should be marketed because of
increasing disposal costs. Marketing turns out to be quite difficult due to
the fact that the mud contains too much iron.
Further investigation reveals that the iron is added only later in
considerable amounts. It is introduced into the waste water treatment unit
in the form of iron chloride (as a typical flocculent). Thus the company
realizes that its problem is not so much a mud problem but rather a waste
water problem.
A further analysis of the principal waste water sources has shown that at
two points of the production process an enourmous quantity of
electrolytical copper in solution is consumed and consequently ends up in
the waste water. The mud or waste water problem has finally turned out to
be a process problem. Relatively simple measures on both organisational
and technological levels finally helped to considerably reduce the
consumption of raw materials at these two points thus leading to a 50%
reduction of the mud produced.
A further characteristic of cleaner production is the idea of regarding the
company as an entity. This means that raw materials, energy, products,
solid waste as well as emissions into the water and the air are closely
intertwined via the production process - notwithstanding the fact that the
areas of water, air and soil are legally independent.
The following table illustrates once again the difference between end-of-
pipe technologies and cleaner production in the sense of production
integrated environmental protection.
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End of pipe technology Cleaner production
how can we treat existing waste and
emissions?
where do waste and emissions come from?
... stands for re-action ... stands for action
... generally leads to additional costs ... can help to reduce costs
waste and emissions are limited through
filters and treatment units
end-of-pipe solutions
repair technology
storage of emissions
waste and emission prevention at the source
avoids potentially toxic processes and
materials
environmental protection comes in after
products and processes have been
developed
environmental protection comes in as an
integral part of product design and
process engineering
environmental problems are solved from a
technological point of view
environmental problems are tackled at all
levels / in all fields
environmental protection is a matter for
competent experts
environmental protection is everybody´s
business
... is bought from outside ... is an innovation developed within the
company
... increases material and energy
consumption
... reduces material and energy consumption
increased complexity and risks reduced risks and increased transparency
environmental protection comes down to
fulfilling legal prescriptions
environmental protection as a permanent
challenge
... is the result of a production paradigm
dating from a time when environmental
problems were not as yet known
...is an approach intending to create
production techniques for a more
sustained development
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A further differentiation of terms like clean technologies, cleaner
production, sustainable technology, production integrated environmental
protection etc. cannot be dealt with in detail in this brochure. However,
they correspond to the principle of integrated environmental protection as
discussed above.
In addition to the above mentioned arguments in favour of cleaner
production, other advantages are as follows:
• avoiding increased costs due to waste treatment
• less susceptible to bottlenecks (disposal space, export licences,
incineration capacities etc.)
• less problems due to liabilities
• better image
• less protests from neighbouring owners
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1.5 Which factors are at the origin of waste and
emissions?
When asked about the factors influencing the generation of waste and
emissions, you will probably first think of the technology used in the
company. Certainly, technology does play an important role in this context.
But this should not lead to the conclusion that only technological measures
can help to realize efficient and clean production. There is a multitude of
various other fields to be taken into account. The main factors at the origin
of waste and emissions are the following:
The
environmental
situation does
not solely depend
on the
technology used
• Personnel
• Technologies
• Raw materials
• Products
• Capital
• Know-how / process
• Suppliers / business partners
On the basis of these factors, various levels and strategies aiming towards
cleaner production and waste minimization are possible. For details please
refer to the following illustration.
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The experience from the past as well as the evaluation of different projects
shows the following:
The major goal is to find measures to tackle the problem at the source
(level 1). These include modifications of both the production process and
the product itself.
Priority has to be
given to
measures
tackling the
problem at the
source...
• Product modifications can lead to a highly improved ecological
situation in terms of production, utilization and disposal of the product.
They may lead to the substitution of the product by another, to
increased longevity by using different materials or changing the product
design. In this context, the term of ”ecological design“ has gained in
importance in recent years. However, many companies are very
reluctant to modify their products.
• Process modifications can help to greatly reduce waste and
emissions. By process, one understands the entire production process
within the company which comprises a whole set of measures:
Good housekeeping of raw and process materials, including changes
on the organisational level: in most cases these are economically
the most interesting measures and can be very easily put into
practice. They may include personnel training and motivation,
changes regarding the operation of equipment, handling
instructions for materials and containers etc.
Substitution of raw and process materials: raw and process
materials which are toxic or otherwise difficult to recycle can often
be substituted by less harmful ones thus helping to reduce waste
and emission volumes.
Technological modifications: these may range from simple
reconstruction activities to comprehensive changes of the
production process. Also included are many energy saving
measures.
...only then
should you
consider...
Internal recycling
...
Waste products that cannot be avoided with the help of the above
described measures should be re-integrated into the production process of
your company (internal recycling, level 2). This may mean
• recycling back into the original production process,
• recycling of products to be used as inputs into another production
process,
• further exploitation for a different, minor purpose (downcycling) or
• recovery and partial use of a residual substance.
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Only then should you opt for measures to recycle waste and emissions
outside the company (level 3). This may happen in the form of external
recycling or of a re-integration into the biogenic cycle (e.g. compost). The
recovery of valuable materials and their re-integration into the economic
cycle - such as paper, scrap, glass, compost materials - is a less widely
recognised method of integrated environmental protection through waste
minimization. This is essentially due to the fact that this approach does not
help to further reduce the amount of materials used in the company.
...or external
recycling
As a rule, one can say that the closer to the root of the problem and the
smaller the cycles, the more efficient the measures will be.
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1.6 Data collection: the basis for cleaner production
In order to be able to detect the appropriate measures for a cleaner
production, it is in most cases essential to use an up-to-date database. For
this purpose you should establish an overview of the major material flows
within your firm.
Data represent
the basis of your
planning
Before collecting data you should be able to answer the following
questions:
• Which data do I need?
• Where do I get them from?
• Which information sources exist in my company?
First of all, you might want to determine for which areas of your company
data should be collected. On this basis you can define the data you will
need. Ideally, you should consider the company as a whole, however, it
might be useful to leave out certain areas.
Examples of typical areas:
ENERGY
CARRIER
EMISSIONS
material
EMISSIONS
energetic
PRODUCTSMATERIALS
ENERGY
Administration
Process A
Process Z
Energy plant
Mainten. / Service
OUTPUTINPUT
How to
determine the
limits of your
energy balance
By defining the areas to be worked upon you determine the limits of your
energy balance. The principle of conservation of mass and energy states
that any material entering an observed scope of balance also has to leave
it: it is either stored there or transformed into another material.
Mass and energy
are constant
This means that everything you may wish to dispose of as waste once
could be found in your shopping basket.
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Within an industrial production orientated company, all materials and
energy resources can be monitored at three points:
• at the point of entry into the scope of balance - i.e. at the moment they
are bought
• at the point of leaving the scope of balance - i.e. the product in the
form of emissions, waste, waste heat
• at the point of use - on the machine, at the production unit
On the basis of the above principles of conservation, the same quantities
should be detected at all three points. However, that is all mere theory. In
reality, you will see that these principles can be verified only in very rare
cases.
And here arises another question:
Do the collected data correspond to reality?
In most cases, one tends to underestimate the importance of this question.
There have actually been severe problems due to unverified data. As an
example, the data stored in accounting (purchasing department) do not
always have to correspond to the quantities that were consumed in reality.
Different working documents available from various information sources
can be of equally different quality:
How to collect
and verify data
For materials entering the scope of balance:
documents for accounting and costing,
delivery notes,
documents from suppliers on product formulas,
internal book keeping of packaging,
...
For materials leaving the scope of balance:
product lists and product formulas,
internal documents on waste and emissions, delivery notes,
invoices of disposal firms,
documents from the waste water association,
...
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In-site use:
allocation to cost centres
measurements carried out on machines and installations
information of personnel on working time and shift changing intervals
lists of parts
product formulas
machine specifications
model identifications
...
As it appears, information can never be complete at any of those points.
For example, take the materials entering the balance space: data on
containers are only very rarely available. Very often, the designation of a
product (e.g. detergent) does not suggest in any way its chemical
composition. For goods leaving the balance space, information on volatile
matters is missing in most cases (evaporated solvents, waste heat) as well
as information on product formulas.
After collecting all data, you should be able to answer the following
questions:
What should you
know after
having collected
the data? • How much raw and process material, how much energy do we use?
• How much waste and emissions are produced?
• From which part/s of the process do they come from?
• Which waste products are hazardous/have to be controlled and why?
• Which portion of the raw or process material becomes waste?
• Which portion of the raw or process material is lost in the form of
volatile emissions?
• What are the costs incurred due to waste disposal and the loss of raw
materials?
However:
It's a long way to Tipperary and may be you are only at the beginning.
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1.7 How to classify waste after its origin?
Waste and emissions can originate from different raw materials for
different reasons. By establishing a list of possible origins, waste and
emissions can be classified accordingly. The table on the following page
contains 11 categories. For each category, various strategies can be
applied to avoid or minimize waste or emissions. The avoiding strategies
described below may serve as an example of which type of measure could
be taken for a certain type of waste.
Main categories of waste and typical solutions
C* CATEGORY OF WASTE EXAMPLES TYPICAL SOLUTIONS
A Raw materials, not used plate scraps, paper blanks,
varnish residues, dyeing
agents in waste water from
textile producers
changes in technology,
automation, thoughtful use,
personnel training, use of
different raw materials,
improved stock-keeping, ...
B Impurities / secondary
substances from raw
materials
ash from combustibles, oil
and grease on metal plates,
skins and seeds in fruit
processing
use of different raw
materials, search for further
exploitation possibilities
C Undesired by-products gypsum from flue gas
precipitation, mud from
waste water treatment
re-utilisation as a new
product, technological
improvement, process
changes
D Used auxiliary materials oils, solvents, paintbrushes,
catalysts
internal recycling, cleaning
and maintenance, checking of
dosage
E Substances produced at
start-up or shut-down
non-commercial products,
only partly filled containers
improved operations
scheduling, personnel
training, improved
technology, larger production
batches, internal recycling
F Misproduced batches, refuse non-commercial products improved technology,
personnel training,
automation, quality
assurance
G Residues and materials from
maintenance
filter cloths, lubricant oils,
cleaning rags
improved serviceable life,
different raw materials,
outsourcing, maintenance
H Materials from handling,
storage, sampling, analysis,
residues from the lab or from
container cleaning, spoiled or
check logistics, outsourcing
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C* CATEGORY OF WASTE EXAMPLES TYPICAL SOLUTIONS
transport damaged goods
I Losses due to evaporation loss of solvents due to open
containers, evaporation
during varnishing/cleaning
etc.
personnel training, thoughtful
use, different raw materials
J Materials from disturbances
and leakages
oil fixing agents, impurities in
raw materials or products
due to inexpert handling, loss
of heat (leakage)
quality assurance, improved
maintenance, automation,
training
K Packaging material cardboard, foil, pallets, ... purchasing directives,
returnable packs, recycling
1.8 How to proceed systematically to minimize waste and
emissions
In order to work systematically on the minimization and avoidance of waste
and emissions, you should know about the most important mass flows in
your company. In this case the term „important“ may have several
meanings:
Which mass flows
within the
company are
particularly
important? • important in terms of legal regulations
• important in terms of large quantities
• important in terms of high costs
• important in terms of toxicity, ecological effects
As a working period you might want to choose a calendar year. For the
worksheets, please refer to the annex.
Worksheet 1: The most important products/services
Here you should enter the main products / services you produce. Even if
the unit does not correspond to the quantity produced, it may be useful to
try to calculate the quantity in kg - as far as possible - (e.g. through
conversion).
What do you
produce?
Worksheet 2: The most important wastes and emissions
This worksheet refers to the main wastes and emissions occurring in your
company. Here you should not forget about waste water and waste air.
The categories refer to the above mentioned identification initials. In
addition to the quantities produced, there are also questions on specific
purchasing and disposal costs - please indicate in money unit per quantitiy
Waste water and
waste air must
also be taken into
account
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unit. The total expense in money units is then calculated from the specific
cost multiplied with the quantity.
Worksheet 3 and 4: The most important raw and process
materials
Here you should indicate the main raw and process materials used in your
company. Besides the quantity, specific and total costs as well as their
purpose of use are of great interest. Please also try to determine the
portion of any raw material used for production. Depending on the
material, this may vary from 0 to 100%. If there are no exact documents
or measuring data available try to give a reliable estimation. Please do not
forget water and air, two elements that are often overlooked in this
context.
Which portion of
the raw and
process material
is used for
production?
As soon as you have collected the main data, you may start to define
measures to minimize or even totally avoid waste and emissions as well as
solutions for other problem zones. The systematic overview of the main
approaches (partly illustrated by simple examples) may help you to do so.
Use the worksheet and tick the measures in the table that you consider
useful for your own purpose.
Which materials
used in your
company are
particularly
dangerous?
Tip: Use worksheets 4 as a brainstorming aid and tick everything you
consider useful for your work. Try to get away from the beaten track of
ideas and strategies you may have developed within your company. In the
heading line of the worksheets, please indicate the waste and emissions
from worksheet 2 as well as other problem zones you might think of (e.g.
because of raw materials used).
How to define
measures to
minimize them
Example: It is possible to avoid waste by using other detergents. Those
do not appear on worksheet 2 or are subsumed under the term of „waste
water“. In this case the raw material „detergent“ should appear on the
worksheets as a „problem zone“.
In many cases measures to avoid or minimize waste and emissions cannot
be clearly assigned to one or more columns. However, this is not a great
problem for your further work.
In the following you will find possible measures for minimizing waste and
emissions. Some of them have already been put into practice and are
mentioned as an example to illustrate this. Here it is also possible to
allocate one example to several categories. As an example, technological
modifications can be accompanied by a change of raw materials and
personnel training.
Possibilities of
avoiding waste
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Product modification
Product modification can be an important approach, albeit sometimes hard
to realize. The most widely accepted argument against changing a product
are customer preferences. Product modification may include:
• Substitution of a product
Examples: instead of offering a certain quantity of energy, an energy
supplier offers the insulation of buildings; solar cells instead of
batteries for pocket calculators; energy saving light bulbs.
• Increased longevity
Examples: accumulators instead of batteries; increased product
longevity through improved corrosion protection.
• Changing materials
Example: aerosol substitutes in refrigerating agents.
• Modification of the product design
Examples: special furniture design to minimize cuttings; module design
allows easier access for repair purposes.
• Use of recycled materials
Examples: leather fibre scraps as filling material in leather production;
granulated recycled plastic for the production of bumpers.
• Avoiding critical components
Example: asbestos as heat insulator in irons.
• Improved possibilities of returning products
Examples: the electronic part of the energy saving bulb is kept, only
the tube is changed; module systems ensure easier disassembly and
return of products.
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Substitution/change of raw and process materials
There is a whole range of possibilities available of substituting or changing
raw or process materials which are dealt with in a special worksheet. It
includes the following measures:
• Substituting organic solvents by aqueous agents
• Examples: hydrosoluble varnishes, waterbased alkaline cleansing
agents for metal degreasing.
• Substituting halogenated solvents
Examples: substitution of aerosols in cleansing units, in the production
of insulating materials and cooling units; halogen free hydrocarbon
solvents in dry cleaning instead of perchloroethylene (per).
• Substituting petrochemical with biochemical products
Examples: cleansing agents on a soya or rape basis; natural dyeing
substances instead of dyeing agents on a petrochemical basis;
lubricants on biological bases.
• Choose materials with less impurities
Examples: fuels containing less sulphur (natural gas instead of coal);
minerals containing less hazardous substances; use of clearly
separated corrugated board in the packaging industry; use of de-
ionized water to prepare process solutions.
• Use of residues as raw materials
Example: use of fibre mucilage from chemical pulp production for the
brick industry, products from recycled materials (glass, paper, ...).
• Use of biodegradable materials
Examples: biodegradable washing active substances.
• Reducing the number of components
Examples: less plastic in car manufacture; use of standardized screws
for assembly of do-it-yourself furniture.
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• Use of alternative energy carrier
Example: natural gas or renewable sources of energy (solar energy,
water power, biomass) instead of coal or oil.
• Use of heavy metal-free substances
Example: heavy metal-free substances in paints and varnishes
(especially lead and cadmium).
• In general: use of less toxic materials
Examples: cyanide-free galvanizing; chromating on the basis of chrome
(III) rather than of chrome (VI).
Technological modifications
A wide selection of measures can be applied at the technology end of the
process. They can range from relatively simple reconstructions to time and
energy consuming changes of the production process. Quite often these
measures have to be combined with improved housekeeping and the use of
modified raw materials. The multitude of possibilities available has led us to
prepare a special worksheet for this area. It comprises the following items:
• Substituting thermo-chemical processes through mechanical
alternatives
Examples: cleaning of surfaces with brushes or supersonic methods
rather than with acid or alkaline solutions; engraving instead of
chemical etching.
• Use of countercurrent rather than single-cascade techniques
Examples: countercurrent cascades in washing processes;
countercurrent method in drying units; heat integration in processes
with different temperatures; stripping of product carriers in two steps.
• Separate management of waste and waste water streams
Examples: the separate management of waste water streams permits
the electrolytic recovery of metals; separate waste collection facilitates
both internal and external recycling.
22
Main Menu Teachers notesTeachers' notes
Textbook 1 - CP Basics
• Improved process conditions
Examples: varying pressure and temperature helps to increase the
production yield; use of appropriate catalyzers.
• Increasing energy efficiency, use of waste heat
To increase the energy efficiency, several measures can be pointed
out.
Example: insulation of the heat source and/or of the point of
consumption
Reducing loss through distribution
Example: insulation of pipes
Heat recovery
Example: preheating of the air with hot oven flue gas; use of flash
vapours
Capacity management
Example: stopping certain units at peak times, such as air
extraction fans, etc.
Co-generation of heat and electricity
Example: combined heat and power plants for the co-generation of
heat, electrical power and possibly refrigerating.
Turning off lighting and heating outside working hours
Example: ... e.g. with movement detectors
Energy-efficient machinery with speed control
Example: for feed pumps, ventilation, flue gas fans etc.
23
Main Menu Teachers notesTeachers' notes
Textbook 1 - CP Basics
• Closing of equipment (air)
Example: metal protection of CHC cleaning installations (required by the
CHC regulations).
• Recovery and re-use of materials (water)
Example: by changing the water tubing the rinsing water of an acid
pickling bath can be re-used to rinse the preceding alkaline degreasing
bath; directing the rinsing water circuit through an ion exchanger.
• Improved life time of chemicals / materials
Examples: treatment of cooling lubricant emulsions with ultrafine
filtration, pH and bacteria regulation; use of high performance fine oil
filters in car maintenance.
• Reducing the drag in of impurities
Examples: covering of process baths; careful cleaning of storage areas.
Good housekeeping and operation
As mentioned above, this group of measures allows one of the most
efficient approaches featuring low investment cost in most cases while at
the same time showing a great saving potential. Besides the thoughtful use
of raw and process materials, it also includes all types of organisational
measures.
• Good housekeeping and operation: the following measures can
be taken in this field.
Changing the dosage / concentration
Examples: reducing the temperature of a degreasing bath;
changing the pH values of solutions; checking if the concentration
of chemicals recommended by the producer can be reduced
(reduction of the often very high security buffers); introduction of
a rinsing water regulation.
24
Main Menu Teachers notesTeachers' notes
Textbook 1 - CP Basics
Increasing the use of process capacities
Examples: filling the drying unit to the full; creating buffer
capacities to be able to operate continuously working machinery at
full capacity (by avoiding unnecessary losses of partial capacities);
turning off momentarily unnecessary equipment and machinery.
Reorganisation of cleaning and maintenance intervals
Examples: less cleaning stages in batch yoghurt production;
monitoring of oil-changes with regard to time intervals, working
hours and quality assurance.
Avoiding loss due to evaporation and leakage
Examples: emptying barrels with handpumps when securely
sealed.
Improved purchasing, storage and delivery
Examples: refusing leaking barrels; refusing unnecessary varnish
samples; internal transport in closed circuits (tubes).
Retracing the material flow
Example: a waterbalance shows that main consumption and
leakage is within the company, which allows one to detect
possibilities of saving water.
• Improved waste logistics
• Improving waste logistics/waste separation may present the
following advantages:
Facilitates closed circuits
Facilitates recovery and re-utilisation
Minimizes quantities of hazardous substances
Minimizes disposal costs
25
Main Menu Teachers notesTeachers' notes
Textbook 1 - CP Basics
Minimizes cleaning expenses
Examples: newly designed waste collection areas („waste islands“)
in assorted colours; separate waste collection in the workplace.
• Improved information
Developing awareness
Training
Operating instructions aiming to minimize waste
Transparent costs
Adding consumption, loss and emission features to the existing
documentation
Defining responsibilities
Coupling with controlling
Examples: personnel education; information through a „green
corner“; nominating people to be in charge of matters concerning
environment and waste in each department; collecting ideas;
setting up teams in charge of environmental matters;
computerizing the use of materials.
• Standardization/automation
• Examples: taking racks out of a galvanic bath, usually done by
hand, can be automized in order to avoid loss through
dripping; predefining cleaning intervals; predefining colours
and tools.
• Improved purchasing
Examples: reducing the huge number of different detergents to three
brands.
26
Main Menu Teachers notesTeachers' notes
Textbook 1 - CP Basics
Closing internal loops
Closing internal circuits requires another set of measures among which are:
• Re-utilisation: renewed utilization of a material or product for
the same purpose as before
Examples: recovery of solvents used for the same purpose, returnable
packs; washing cleaning rags; electrolytic or chemical recycling of
caustic chemical solutions.
• Further utilization: utilization of a material or product for a
different purpose
Examples: use of the solvent acetone for cleaning purposes only; use
of varnish residues for paintspraying invisible parts (e.g. for
undersealing).
• Downcycling: further exploitation of a material for another
purpose, generally of minor quality
Example: plastic or paper residues as fillings for packaging.
• Recovery: partial use of a residual substance
Example: recovery of silver from photochemicals.
27
Main Menu Teachers notesTeachers' notes
Textbook 1 - CP Basics
External recycling
The above general classification of internal recycling is equally valid for
external recycling. For the reasons we explained above it is generally
preferable to create closed circuits within your own company. In this
context it is also important to know whether you are dealing with real
recycling or with downcycling, which in principle does not solve the disposal
problem, as it is only postponed to a later date.
Examples: aluminium; glass; recovery of metal from waste water; but
also the use of plastic in noise protection walls and for park benches.
Furthermore we can distinguish between:
• the renewed use of whole structures
Examples: containers as containers, pallets as pallets
• the use of different materials
Examples: waste paper, scrap as a raw material for production
• the use of the energy contained
Example: pallets as firing material
In addition to recycling in the proper sense of the word, external recycling
may also include the re-integration of waste into biogenic circuits.
Example: composting of labels from the cleaning process of milk and beer
bottles
Modification of the work flow/omission of a process
sequence
In some areas the - often justified - question arises whether it is possible to
change the work flow by omitting a certain sequence of the production
process and thus avoiding the generation of waste right from the
beginning.
Examples: no intermediate greasing of metal plates; no chromating of
metal parts which are going to be treated with an anticorrosive coating
anyway, no priming ; no unnecessary drying procedures.
28
Main Menu Teachers notesTeachers' notes
Textbook 1 - CP Basics
Returnable packs
In packaging there is a wide range of approaches to minimize waste which
comprise the above discussed groups of measures.
Examples: use of 1000 l returnable skeleton containers rather than 70 l
throw-away packs; use of compostable packaging and/or filling materials
(on the basis of pulp/paper or vegetable amylum); cloths for furniture
transport; packing units in the right size (neither too big nor too small);
complete emptying of packs.
After having received some ideas on how to minimize and avoid waste and
having identified a few approaches and concepts for your own firm, it is
now time to formulate them for yourself and carry out a first simple
evaluation using the enclosed worksheet. The evaluation (a simple three-
scale rating) should give an insight into the value and the projected
potential for improvement of each single measure taken in your company.
A more exact evaluation of the quantities and costs reduced as well as of
the feasibility of these measures will only be possible after a more detailed
input-output study and/or after a precise analysis of the material flow have
been carried out. For details please refer to volume 4 of this series of
brochures.
In the annex you will find an overview of a number of copy originals on
waste minimization which might be of great help for you for further
argumentation.
29
Main Menu Teachers notesTeachers' notes

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Unido tool kit 1-textbook

  • 1. U N I D O C L E A N E R P R O D U C T I O N T O O L K I T UNITED NATIONS INDUSTRIAL DEVELOPMENT ORGANIZATION 1 Introduction into Cleaner Production Main directorym 1
  • 2. Textbook 1 - CP Basics 1- Background Material 1 Textbook 1.1 Introduction Aims and goals of the Cleaner Production brochure „Cleaner production and waste minimization“ After working with the present brochure you will be able to tell the difference between cause and effect of waste problems, Aims and goals • recognize the economic benefits of waste minimization, • categorize waste and emissions in your company, • identify the factors influencing waste and emission minimization, • use the worksheets to find systematic solutions for your problems. To ensure this, you should read more about the following: • Definitions (waste, emissions, ...) Procedure • Traditional waste management versus a more holistic approach • Interrelations between raw material, production process and waste/emissions • Factors influencing the generation of waste (where to start from) Data collection as a basis for waste minimization Defining categories for waste and emissions together with strategies to minimize them You should now take two or three hours to study this introduction and subsequently think about the effects and consequences this may have on your company. Data collection - as an essential basis for comprehensive information on emissions and waste in your firm - can be very time consuming. On the other hand, there is the possibility, especially in bigger companies, to obtain the data immediately from the computer system. Authors: 2 Main Menu Teachers' notes
  • 3. Textbook 1 - CP Basics 1.2 What is CLEANER PRODUCTION? CLEANER PRODUCTION is defined as the continuous application of an integrated preventive environmental strategy to processes, products and services to increase the overall efficiency and to reduce risks to humans and environment. What does CLEANER PRODUCTION mean? • In production processes, Cleaner Production addresses the saving of raw materials and energy, the elimination of toxic raw materials and the reduction in the quantities and toxicity of wastes and emissions. • In product development and design, Cleaner Production addresses the reduction of negative impacts throughout the life cycle of the product: from raw material extraction to ultimate disposal. • In services, Cleaner Production addresses the incorporation of environmental considerations into the design and delivery of services. As mentioned before Cleaner Production is the continuous application of a preventive strategy and methodology. In this context it is quite important to say that it is you who knows your own company best and that this expert know-how is essential. Therefore Cleaner Production will only be successful if you do your best to support and promote it. External knowledge can and shall only help you to find solutions. From this point of view Cleaner Production is above all a stimulation of new ideas through an external view. Help for self-help in the company A Cleaner Production project follows a certain methodology and consists of the following elements: Slides 1 - CP Basics Elements of a CP-Project ! mass flow ! energy flow ! costs and safety !Data Collection !Reflection: Where and why do we generate waste? !Option generation !Feasibiltiy !Implementation !Controlling, continuation, EMS Data collection – mass flow, energy flow, costs and safety This is one of the basic and most important and often also quite time consuming steps: the proper description of the status quo. The better the actual procedures and data are known the better the implementation of the right CP options is. 3 Main Menu Teachers notesTeachers' notes
  • 4. Textbook 1 - CP Basics Reflection: where and why do we generate waste After the collection of data, the data are analysed and reflected according to the principles of Cleaner Production. Option generation Starting from the analysis CP options are generated. New, creative and/or already well-known ones will come up, aiming at a reduction at the source by good house keeping, product or process modification, organizational changes, internal or external recycling. Feasibility analysis For selected options a feasibility study will analyse the economical, technical and ecological feasibility. Implementation In this step CP options are implemented. Either after proceeding the steps 1 to 4, but very often options are directly implemented without the detailed feasibility analysis – when advantages and feasibility are obvious – or even without the option generation – as data collection and data reflection already makes obvious CP options visible. Controlling and continuation Probably the most important and challenging aspect is the setting up of a systematic way for successful, on-going improvement. Here environmental controlling is needed, the setting up of new goals and targets and the continuous implementation. Company analyses as used in a Cleaner Production project/programme may be used for five different kinds of evaluations: Evaluation of the company analyses For use by Regular report, ecological controlling ⇒ Management Waste management plan ⇒ Authorities, company Analysis of ecological/economical weak points ⇒ Personnel / management Environmental management system (ISO 14001) ⇒ Business partners / customers Environmental report ⇒ Public 4 Main Menu Teachers notesTeachers' notes
  • 5. Textbook 1 - CP Basics 1.3 What is waste and what are emissions? According to the Waste Management Act, waste is defined as mobile objects which the owner wants to dispose of or has already disposed of, or which should be gathered and treated as waste in the interest of the public. This definition does not seem to be very useful for your purpose in the sense of industrial waste management and waste minimization. Waste and emissions are - mostly very expensively acquired - raw and process materials that have not been transformed into marketable products or into raw materials to be used as inputs into another production process. They include all solid, liquid and gaseous materials which are emitted into the air, water or soil as well as noise and waste heat. The production process also comprises activities one often tends to forget, such as maintenance, servicing, cleaning as well as the office area. Minimizing waste and emissions means... to increase the ecological efficiency of your company ... Therefore minimizing waste and emissions also means increasing the degree of utilization of the materials and energy used for production (increasing the ecological efficiency) until, and this is the ideal case, a 100 percent utilization guarantees a waste and emission free procedure. Thus, for the company, waste minimization is not only an environmental goal but more so, and primarily, a commercially orientated program to increase the degree of utilization of materials. to benefit from commercial advantages ... This situation can also be illustrated by the fact that even though the treatment and disposal of waste and emissions is very expensive, the costs due to the loss of raw materials (which are wasted in the proper sense of the word) are normally much higher. to save costs of raw materials Use the worksheets in this brochure to verify this fact and also for your own company! Example: Applying a repair coat on a car can be a very material intensive process. Using a conventional, solvent-containing varnish with a non- volatile matter content of about 60%, combined with an uneconomic spraying application from a beaker pistol which is unadequately handled and badly regulated by the painter, the application of 1 kg of varnish on the material consumes a quantity of about 10 kg of raw material. Opting for a varnish with a higher non-volatile matter content together with the use of a HVLP-spraying pistol, a metering pump during application and an improved cleaning system for the spraying pistol - the best available technology, that is - brings the consumption of raw material necessary for the application of the same paint film down to a bit more than 2 kg (see below). On the basis of disposal costs of about 1,- €/kg and a material cost 5 Main Menu Teachers notesTeachers' notes
  • 6. Textbook 1 - CP Basics of 15,- €/kg considerable amounts can be saved, which can be deducted from the investment costs. 6 Main Menu Teachers notesTeachers' notes
  • 7. Textbook 1 - CP Basics 1.4 Cleaner Production versus End of Pipe? Up to now, conventional environmental technologies have mostly worked on the treatment of existing waste and emissions (examples: air filter technology, waste water treatment, treatment of sludge, waste incineration etc.). As this approach takes up things at the end of the production process, it is also referred to as end-of-pipe technology. It is essentially characterized by additional expenses for the company and a shifting of problems (examples: production of sewage sludge through waste water treatment, production of gypsum from flue gas, etc.) Environmental protection should mean more than shifting problems Cleaner production means integrating environmental objectives into the production process Cleaner production aims to integrate environmental objectives into the production process in order to reduce waste and emissions in terms of quantity and toxicity and thus to reduce costs. Compared to the disposal by external services or to end-of-pipe technologies, it presents several advantages: • Cleaner production in the sense of reducing the quantity of materials and energy used essentially presents a potential for economic solutions. • Due to an intensive exploration of the production process, the minimization of waste and emissions generally induces an innovation process within the company. • Responsibility can be assumed for the production process as a whole; risks in the field of environmental liabilities and of waste disposal can be minimized. • Waste and emission minimization is a step towards a more sustained economic development. While conventional waste management asks: What can we do with existing waste and emissions? Cleaner Production, production integrated environmental protection asks: Where do our waste and emissions come from? Why have they turned into waste at all? From the symptom to the source Therefore, the essential difference lies in the fact that cleaner production does not simply treat the symptom but that it tries to get down to the source of the problem. 7 Main Menu Teachers notesTeachers' notes
  • 8. Textbook 1 - CP Basics Example: In the water treatment unit of a copper manufacturer mud containing metal is produced, which should be marketed because of increasing disposal costs. Marketing turns out to be quite difficult due to the fact that the mud contains too much iron. Further investigation reveals that the iron is added only later in considerable amounts. It is introduced into the waste water treatment unit in the form of iron chloride (as a typical flocculent). Thus the company realizes that its problem is not so much a mud problem but rather a waste water problem. A further analysis of the principal waste water sources has shown that at two points of the production process an enourmous quantity of electrolytical copper in solution is consumed and consequently ends up in the waste water. The mud or waste water problem has finally turned out to be a process problem. Relatively simple measures on both organisational and technological levels finally helped to considerably reduce the consumption of raw materials at these two points thus leading to a 50% reduction of the mud produced. A further characteristic of cleaner production is the idea of regarding the company as an entity. This means that raw materials, energy, products, solid waste as well as emissions into the water and the air are closely intertwined via the production process - notwithstanding the fact that the areas of water, air and soil are legally independent. The following table illustrates once again the difference between end-of- pipe technologies and cleaner production in the sense of production integrated environmental protection. 8 Main Menu Teachers notesTeachers' notes
  • 9. Textbook 1 - CP Basics End of pipe technology Cleaner production how can we treat existing waste and emissions? where do waste and emissions come from? ... stands for re-action ... stands for action ... generally leads to additional costs ... can help to reduce costs waste and emissions are limited through filters and treatment units end-of-pipe solutions repair technology storage of emissions waste and emission prevention at the source avoids potentially toxic processes and materials environmental protection comes in after products and processes have been developed environmental protection comes in as an integral part of product design and process engineering environmental problems are solved from a technological point of view environmental problems are tackled at all levels / in all fields environmental protection is a matter for competent experts environmental protection is everybody´s business ... is bought from outside ... is an innovation developed within the company ... increases material and energy consumption ... reduces material and energy consumption increased complexity and risks reduced risks and increased transparency environmental protection comes down to fulfilling legal prescriptions environmental protection as a permanent challenge ... is the result of a production paradigm dating from a time when environmental problems were not as yet known ...is an approach intending to create production techniques for a more sustained development 9 Main Menu Teachers notesTeachers' notes
  • 10. Textbook 1 - CP Basics A further differentiation of terms like clean technologies, cleaner production, sustainable technology, production integrated environmental protection etc. cannot be dealt with in detail in this brochure. However, they correspond to the principle of integrated environmental protection as discussed above. In addition to the above mentioned arguments in favour of cleaner production, other advantages are as follows: • avoiding increased costs due to waste treatment • less susceptible to bottlenecks (disposal space, export licences, incineration capacities etc.) • less problems due to liabilities • better image • less protests from neighbouring owners 10 Main Menu Teachers notesTeachers' notes
  • 11. Textbook 1 - CP Basics 1.5 Which factors are at the origin of waste and emissions? When asked about the factors influencing the generation of waste and emissions, you will probably first think of the technology used in the company. Certainly, technology does play an important role in this context. But this should not lead to the conclusion that only technological measures can help to realize efficient and clean production. There is a multitude of various other fields to be taken into account. The main factors at the origin of waste and emissions are the following: The environmental situation does not solely depend on the technology used • Personnel • Technologies • Raw materials • Products • Capital • Know-how / process • Suppliers / business partners On the basis of these factors, various levels and strategies aiming towards cleaner production and waste minimization are possible. For details please refer to the following illustration. 11 Main Menu Teachers notesTeachers' notes
  • 12. Textbook 1 - CP Basics The experience from the past as well as the evaluation of different projects shows the following: The major goal is to find measures to tackle the problem at the source (level 1). These include modifications of both the production process and the product itself. Priority has to be given to measures tackling the problem at the source... • Product modifications can lead to a highly improved ecological situation in terms of production, utilization and disposal of the product. They may lead to the substitution of the product by another, to increased longevity by using different materials or changing the product design. In this context, the term of ”ecological design“ has gained in importance in recent years. However, many companies are very reluctant to modify their products. • Process modifications can help to greatly reduce waste and emissions. By process, one understands the entire production process within the company which comprises a whole set of measures: Good housekeeping of raw and process materials, including changes on the organisational level: in most cases these are economically the most interesting measures and can be very easily put into practice. They may include personnel training and motivation, changes regarding the operation of equipment, handling instructions for materials and containers etc. Substitution of raw and process materials: raw and process materials which are toxic or otherwise difficult to recycle can often be substituted by less harmful ones thus helping to reduce waste and emission volumes. Technological modifications: these may range from simple reconstruction activities to comprehensive changes of the production process. Also included are many energy saving measures. ...only then should you consider... Internal recycling ... Waste products that cannot be avoided with the help of the above described measures should be re-integrated into the production process of your company (internal recycling, level 2). This may mean • recycling back into the original production process, • recycling of products to be used as inputs into another production process, • further exploitation for a different, minor purpose (downcycling) or • recovery and partial use of a residual substance. 12 Main Menu Teachers notesTeachers' notes
  • 13. Textbook 1 - CP Basics Only then should you opt for measures to recycle waste and emissions outside the company (level 3). This may happen in the form of external recycling or of a re-integration into the biogenic cycle (e.g. compost). The recovery of valuable materials and their re-integration into the economic cycle - such as paper, scrap, glass, compost materials - is a less widely recognised method of integrated environmental protection through waste minimization. This is essentially due to the fact that this approach does not help to further reduce the amount of materials used in the company. ...or external recycling As a rule, one can say that the closer to the root of the problem and the smaller the cycles, the more efficient the measures will be. 13 Main Menu Teachers notesTeachers' notes
  • 14. Textbook 1 - CP Basics 1.6 Data collection: the basis for cleaner production In order to be able to detect the appropriate measures for a cleaner production, it is in most cases essential to use an up-to-date database. For this purpose you should establish an overview of the major material flows within your firm. Data represent the basis of your planning Before collecting data you should be able to answer the following questions: • Which data do I need? • Where do I get them from? • Which information sources exist in my company? First of all, you might want to determine for which areas of your company data should be collected. On this basis you can define the data you will need. Ideally, you should consider the company as a whole, however, it might be useful to leave out certain areas. Examples of typical areas: ENERGY CARRIER EMISSIONS material EMISSIONS energetic PRODUCTSMATERIALS ENERGY Administration Process A Process Z Energy plant Mainten. / Service OUTPUTINPUT How to determine the limits of your energy balance By defining the areas to be worked upon you determine the limits of your energy balance. The principle of conservation of mass and energy states that any material entering an observed scope of balance also has to leave it: it is either stored there or transformed into another material. Mass and energy are constant This means that everything you may wish to dispose of as waste once could be found in your shopping basket. 14 Main Menu Teachers notesTeachers' notes
  • 15. Textbook 1 - CP Basics Within an industrial production orientated company, all materials and energy resources can be monitored at three points: • at the point of entry into the scope of balance - i.e. at the moment they are bought • at the point of leaving the scope of balance - i.e. the product in the form of emissions, waste, waste heat • at the point of use - on the machine, at the production unit On the basis of the above principles of conservation, the same quantities should be detected at all three points. However, that is all mere theory. In reality, you will see that these principles can be verified only in very rare cases. And here arises another question: Do the collected data correspond to reality? In most cases, one tends to underestimate the importance of this question. There have actually been severe problems due to unverified data. As an example, the data stored in accounting (purchasing department) do not always have to correspond to the quantities that were consumed in reality. Different working documents available from various information sources can be of equally different quality: How to collect and verify data For materials entering the scope of balance: documents for accounting and costing, delivery notes, documents from suppliers on product formulas, internal book keeping of packaging, ... For materials leaving the scope of balance: product lists and product formulas, internal documents on waste and emissions, delivery notes, invoices of disposal firms, documents from the waste water association, ... 15 Main Menu Teachers notesTeachers' notes
  • 16. Textbook 1 - CP Basics In-site use: allocation to cost centres measurements carried out on machines and installations information of personnel on working time and shift changing intervals lists of parts product formulas machine specifications model identifications ... As it appears, information can never be complete at any of those points. For example, take the materials entering the balance space: data on containers are only very rarely available. Very often, the designation of a product (e.g. detergent) does not suggest in any way its chemical composition. For goods leaving the balance space, information on volatile matters is missing in most cases (evaporated solvents, waste heat) as well as information on product formulas. After collecting all data, you should be able to answer the following questions: What should you know after having collected the data? • How much raw and process material, how much energy do we use? • How much waste and emissions are produced? • From which part/s of the process do they come from? • Which waste products are hazardous/have to be controlled and why? • Which portion of the raw or process material becomes waste? • Which portion of the raw or process material is lost in the form of volatile emissions? • What are the costs incurred due to waste disposal and the loss of raw materials? However: It's a long way to Tipperary and may be you are only at the beginning. 16 Main Menu Teachers notesTeachers' notes
  • 17. Textbook 1 - CP Basics 1.7 How to classify waste after its origin? Waste and emissions can originate from different raw materials for different reasons. By establishing a list of possible origins, waste and emissions can be classified accordingly. The table on the following page contains 11 categories. For each category, various strategies can be applied to avoid or minimize waste or emissions. The avoiding strategies described below may serve as an example of which type of measure could be taken for a certain type of waste. Main categories of waste and typical solutions C* CATEGORY OF WASTE EXAMPLES TYPICAL SOLUTIONS A Raw materials, not used plate scraps, paper blanks, varnish residues, dyeing agents in waste water from textile producers changes in technology, automation, thoughtful use, personnel training, use of different raw materials, improved stock-keeping, ... B Impurities / secondary substances from raw materials ash from combustibles, oil and grease on metal plates, skins and seeds in fruit processing use of different raw materials, search for further exploitation possibilities C Undesired by-products gypsum from flue gas precipitation, mud from waste water treatment re-utilisation as a new product, technological improvement, process changes D Used auxiliary materials oils, solvents, paintbrushes, catalysts internal recycling, cleaning and maintenance, checking of dosage E Substances produced at start-up or shut-down non-commercial products, only partly filled containers improved operations scheduling, personnel training, improved technology, larger production batches, internal recycling F Misproduced batches, refuse non-commercial products improved technology, personnel training, automation, quality assurance G Residues and materials from maintenance filter cloths, lubricant oils, cleaning rags improved serviceable life, different raw materials, outsourcing, maintenance H Materials from handling, storage, sampling, analysis, residues from the lab or from container cleaning, spoiled or check logistics, outsourcing 17 Main Menu Teachers notesTeachers' notes
  • 18. Textbook 1 - CP Basics C* CATEGORY OF WASTE EXAMPLES TYPICAL SOLUTIONS transport damaged goods I Losses due to evaporation loss of solvents due to open containers, evaporation during varnishing/cleaning etc. personnel training, thoughtful use, different raw materials J Materials from disturbances and leakages oil fixing agents, impurities in raw materials or products due to inexpert handling, loss of heat (leakage) quality assurance, improved maintenance, automation, training K Packaging material cardboard, foil, pallets, ... purchasing directives, returnable packs, recycling 1.8 How to proceed systematically to minimize waste and emissions In order to work systematically on the minimization and avoidance of waste and emissions, you should know about the most important mass flows in your company. In this case the term „important“ may have several meanings: Which mass flows within the company are particularly important? • important in terms of legal regulations • important in terms of large quantities • important in terms of high costs • important in terms of toxicity, ecological effects As a working period you might want to choose a calendar year. For the worksheets, please refer to the annex. Worksheet 1: The most important products/services Here you should enter the main products / services you produce. Even if the unit does not correspond to the quantity produced, it may be useful to try to calculate the quantity in kg - as far as possible - (e.g. through conversion). What do you produce? Worksheet 2: The most important wastes and emissions This worksheet refers to the main wastes and emissions occurring in your company. Here you should not forget about waste water and waste air. The categories refer to the above mentioned identification initials. In addition to the quantities produced, there are also questions on specific purchasing and disposal costs - please indicate in money unit per quantitiy Waste water and waste air must also be taken into account 18 Main Menu Teachers notesTeachers' notes
  • 19. Textbook 1 - CP Basics unit. The total expense in money units is then calculated from the specific cost multiplied with the quantity. Worksheet 3 and 4: The most important raw and process materials Here you should indicate the main raw and process materials used in your company. Besides the quantity, specific and total costs as well as their purpose of use are of great interest. Please also try to determine the portion of any raw material used for production. Depending on the material, this may vary from 0 to 100%. If there are no exact documents or measuring data available try to give a reliable estimation. Please do not forget water and air, two elements that are often overlooked in this context. Which portion of the raw and process material is used for production? As soon as you have collected the main data, you may start to define measures to minimize or even totally avoid waste and emissions as well as solutions for other problem zones. The systematic overview of the main approaches (partly illustrated by simple examples) may help you to do so. Use the worksheet and tick the measures in the table that you consider useful for your own purpose. Which materials used in your company are particularly dangerous? Tip: Use worksheets 4 as a brainstorming aid and tick everything you consider useful for your work. Try to get away from the beaten track of ideas and strategies you may have developed within your company. In the heading line of the worksheets, please indicate the waste and emissions from worksheet 2 as well as other problem zones you might think of (e.g. because of raw materials used). How to define measures to minimize them Example: It is possible to avoid waste by using other detergents. Those do not appear on worksheet 2 or are subsumed under the term of „waste water“. In this case the raw material „detergent“ should appear on the worksheets as a „problem zone“. In many cases measures to avoid or minimize waste and emissions cannot be clearly assigned to one or more columns. However, this is not a great problem for your further work. In the following you will find possible measures for minimizing waste and emissions. Some of them have already been put into practice and are mentioned as an example to illustrate this. Here it is also possible to allocate one example to several categories. As an example, technological modifications can be accompanied by a change of raw materials and personnel training. Possibilities of avoiding waste 19 Main Menu Teachers notesTeachers' notes
  • 20. Textbook 1 - CP Basics Product modification Product modification can be an important approach, albeit sometimes hard to realize. The most widely accepted argument against changing a product are customer preferences. Product modification may include: • Substitution of a product Examples: instead of offering a certain quantity of energy, an energy supplier offers the insulation of buildings; solar cells instead of batteries for pocket calculators; energy saving light bulbs. • Increased longevity Examples: accumulators instead of batteries; increased product longevity through improved corrosion protection. • Changing materials Example: aerosol substitutes in refrigerating agents. • Modification of the product design Examples: special furniture design to minimize cuttings; module design allows easier access for repair purposes. • Use of recycled materials Examples: leather fibre scraps as filling material in leather production; granulated recycled plastic for the production of bumpers. • Avoiding critical components Example: asbestos as heat insulator in irons. • Improved possibilities of returning products Examples: the electronic part of the energy saving bulb is kept, only the tube is changed; module systems ensure easier disassembly and return of products. 20 Main Menu Teachers notesTeachers' notes
  • 21. Textbook 1 - CP Basics Substitution/change of raw and process materials There is a whole range of possibilities available of substituting or changing raw or process materials which are dealt with in a special worksheet. It includes the following measures: • Substituting organic solvents by aqueous agents • Examples: hydrosoluble varnishes, waterbased alkaline cleansing agents for metal degreasing. • Substituting halogenated solvents Examples: substitution of aerosols in cleansing units, in the production of insulating materials and cooling units; halogen free hydrocarbon solvents in dry cleaning instead of perchloroethylene (per). • Substituting petrochemical with biochemical products Examples: cleansing agents on a soya or rape basis; natural dyeing substances instead of dyeing agents on a petrochemical basis; lubricants on biological bases. • Choose materials with less impurities Examples: fuels containing less sulphur (natural gas instead of coal); minerals containing less hazardous substances; use of clearly separated corrugated board in the packaging industry; use of de- ionized water to prepare process solutions. • Use of residues as raw materials Example: use of fibre mucilage from chemical pulp production for the brick industry, products from recycled materials (glass, paper, ...). • Use of biodegradable materials Examples: biodegradable washing active substances. • Reducing the number of components Examples: less plastic in car manufacture; use of standardized screws for assembly of do-it-yourself furniture. 21 Main Menu Teachers notesTeachers' notes
  • 22. Textbook 1 - CP Basics • Use of alternative energy carrier Example: natural gas or renewable sources of energy (solar energy, water power, biomass) instead of coal or oil. • Use of heavy metal-free substances Example: heavy metal-free substances in paints and varnishes (especially lead and cadmium). • In general: use of less toxic materials Examples: cyanide-free galvanizing; chromating on the basis of chrome (III) rather than of chrome (VI). Technological modifications A wide selection of measures can be applied at the technology end of the process. They can range from relatively simple reconstructions to time and energy consuming changes of the production process. Quite often these measures have to be combined with improved housekeeping and the use of modified raw materials. The multitude of possibilities available has led us to prepare a special worksheet for this area. It comprises the following items: • Substituting thermo-chemical processes through mechanical alternatives Examples: cleaning of surfaces with brushes or supersonic methods rather than with acid or alkaline solutions; engraving instead of chemical etching. • Use of countercurrent rather than single-cascade techniques Examples: countercurrent cascades in washing processes; countercurrent method in drying units; heat integration in processes with different temperatures; stripping of product carriers in two steps. • Separate management of waste and waste water streams Examples: the separate management of waste water streams permits the electrolytic recovery of metals; separate waste collection facilitates both internal and external recycling. 22 Main Menu Teachers notesTeachers' notes
  • 23. Textbook 1 - CP Basics • Improved process conditions Examples: varying pressure and temperature helps to increase the production yield; use of appropriate catalyzers. • Increasing energy efficiency, use of waste heat To increase the energy efficiency, several measures can be pointed out. Example: insulation of the heat source and/or of the point of consumption Reducing loss through distribution Example: insulation of pipes Heat recovery Example: preheating of the air with hot oven flue gas; use of flash vapours Capacity management Example: stopping certain units at peak times, such as air extraction fans, etc. Co-generation of heat and electricity Example: combined heat and power plants for the co-generation of heat, electrical power and possibly refrigerating. Turning off lighting and heating outside working hours Example: ... e.g. with movement detectors Energy-efficient machinery with speed control Example: for feed pumps, ventilation, flue gas fans etc. 23 Main Menu Teachers notesTeachers' notes
  • 24. Textbook 1 - CP Basics • Closing of equipment (air) Example: metal protection of CHC cleaning installations (required by the CHC regulations). • Recovery and re-use of materials (water) Example: by changing the water tubing the rinsing water of an acid pickling bath can be re-used to rinse the preceding alkaline degreasing bath; directing the rinsing water circuit through an ion exchanger. • Improved life time of chemicals / materials Examples: treatment of cooling lubricant emulsions with ultrafine filtration, pH and bacteria regulation; use of high performance fine oil filters in car maintenance. • Reducing the drag in of impurities Examples: covering of process baths; careful cleaning of storage areas. Good housekeeping and operation As mentioned above, this group of measures allows one of the most efficient approaches featuring low investment cost in most cases while at the same time showing a great saving potential. Besides the thoughtful use of raw and process materials, it also includes all types of organisational measures. • Good housekeeping and operation: the following measures can be taken in this field. Changing the dosage / concentration Examples: reducing the temperature of a degreasing bath; changing the pH values of solutions; checking if the concentration of chemicals recommended by the producer can be reduced (reduction of the often very high security buffers); introduction of a rinsing water regulation. 24 Main Menu Teachers notesTeachers' notes
  • 25. Textbook 1 - CP Basics Increasing the use of process capacities Examples: filling the drying unit to the full; creating buffer capacities to be able to operate continuously working machinery at full capacity (by avoiding unnecessary losses of partial capacities); turning off momentarily unnecessary equipment and machinery. Reorganisation of cleaning and maintenance intervals Examples: less cleaning stages in batch yoghurt production; monitoring of oil-changes with regard to time intervals, working hours and quality assurance. Avoiding loss due to evaporation and leakage Examples: emptying barrels with handpumps when securely sealed. Improved purchasing, storage and delivery Examples: refusing leaking barrels; refusing unnecessary varnish samples; internal transport in closed circuits (tubes). Retracing the material flow Example: a waterbalance shows that main consumption and leakage is within the company, which allows one to detect possibilities of saving water. • Improved waste logistics • Improving waste logistics/waste separation may present the following advantages: Facilitates closed circuits Facilitates recovery and re-utilisation Minimizes quantities of hazardous substances Minimizes disposal costs 25 Main Menu Teachers notesTeachers' notes
  • 26. Textbook 1 - CP Basics Minimizes cleaning expenses Examples: newly designed waste collection areas („waste islands“) in assorted colours; separate waste collection in the workplace. • Improved information Developing awareness Training Operating instructions aiming to minimize waste Transparent costs Adding consumption, loss and emission features to the existing documentation Defining responsibilities Coupling with controlling Examples: personnel education; information through a „green corner“; nominating people to be in charge of matters concerning environment and waste in each department; collecting ideas; setting up teams in charge of environmental matters; computerizing the use of materials. • Standardization/automation • Examples: taking racks out of a galvanic bath, usually done by hand, can be automized in order to avoid loss through dripping; predefining cleaning intervals; predefining colours and tools. • Improved purchasing Examples: reducing the huge number of different detergents to three brands. 26 Main Menu Teachers notesTeachers' notes
  • 27. Textbook 1 - CP Basics Closing internal loops Closing internal circuits requires another set of measures among which are: • Re-utilisation: renewed utilization of a material or product for the same purpose as before Examples: recovery of solvents used for the same purpose, returnable packs; washing cleaning rags; electrolytic or chemical recycling of caustic chemical solutions. • Further utilization: utilization of a material or product for a different purpose Examples: use of the solvent acetone for cleaning purposes only; use of varnish residues for paintspraying invisible parts (e.g. for undersealing). • Downcycling: further exploitation of a material for another purpose, generally of minor quality Example: plastic or paper residues as fillings for packaging. • Recovery: partial use of a residual substance Example: recovery of silver from photochemicals. 27 Main Menu Teachers notesTeachers' notes
  • 28. Textbook 1 - CP Basics External recycling The above general classification of internal recycling is equally valid for external recycling. For the reasons we explained above it is generally preferable to create closed circuits within your own company. In this context it is also important to know whether you are dealing with real recycling or with downcycling, which in principle does not solve the disposal problem, as it is only postponed to a later date. Examples: aluminium; glass; recovery of metal from waste water; but also the use of plastic in noise protection walls and for park benches. Furthermore we can distinguish between: • the renewed use of whole structures Examples: containers as containers, pallets as pallets • the use of different materials Examples: waste paper, scrap as a raw material for production • the use of the energy contained Example: pallets as firing material In addition to recycling in the proper sense of the word, external recycling may also include the re-integration of waste into biogenic circuits. Example: composting of labels from the cleaning process of milk and beer bottles Modification of the work flow/omission of a process sequence In some areas the - often justified - question arises whether it is possible to change the work flow by omitting a certain sequence of the production process and thus avoiding the generation of waste right from the beginning. Examples: no intermediate greasing of metal plates; no chromating of metal parts which are going to be treated with an anticorrosive coating anyway, no priming ; no unnecessary drying procedures. 28 Main Menu Teachers notesTeachers' notes
  • 29. Textbook 1 - CP Basics Returnable packs In packaging there is a wide range of approaches to minimize waste which comprise the above discussed groups of measures. Examples: use of 1000 l returnable skeleton containers rather than 70 l throw-away packs; use of compostable packaging and/or filling materials (on the basis of pulp/paper or vegetable amylum); cloths for furniture transport; packing units in the right size (neither too big nor too small); complete emptying of packs. After having received some ideas on how to minimize and avoid waste and having identified a few approaches and concepts for your own firm, it is now time to formulate them for yourself and carry out a first simple evaluation using the enclosed worksheet. The evaluation (a simple three- scale rating) should give an insight into the value and the projected potential for improvement of each single measure taken in your company. A more exact evaluation of the quantities and costs reduced as well as of the feasibility of these measures will only be possible after a more detailed input-output study and/or after a precise analysis of the material flow have been carried out. For details please refer to volume 4 of this series of brochures. In the annex you will find an overview of a number of copy originals on waste minimization which might be of great help for you for further argumentation. 29 Main Menu Teachers notesTeachers' notes