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Bob Falco, PhD
                       Pete Sheehey, PhD
              Institute for Energy Resourcefulness

Presented to the LAC Transportation Committee        12 July 2012
 The EPA has researched the use of high percentages of
     alcohol in engines
    Scientifically prescribed path to easy introduction of
     methanol
           MIT Engine Lab and Lotus Engineering
    The path utilizes the availability of current Flex Fueled
     Vehicles (FFV)
    There are over 11,000,000 FFV in the US
    All new vehicles purchased by Los Alamos County are
     Flex Fuel Capable

7/12/12                                Institute for Energy Resourcefulness   2
 High cost of vehicle conversion
 High cost of pumping stations
 High cost of maintenance
 Lower efficiency/power of vehicles
 No easy transition path
 Locked into a single technology and fuel
 at a time of rapidly developing fuels
 technology
40%G 10%E 50%M                   Lotus Engineering Research
                                                        7/12/12
    4            Institute for Energy Resourcefulness
G=$
3.11
         %
         methano
         l




 G=
 $3.73




                   Lotus Engineering
• Can be made from natural gas (100-120 yrs)
• No competition with food
• No water use issues
• Cheaper to make than gasoline
             Additional advantages
• Engines can be optimized to run with higher
  efficiency than diesels
• Lower CO2,
     • CO2 neutral if bio methanol
     • CO2 negative if solar energy is used
• Methanol can be made renewably
Institute for Energy Resourcefulness   6      7/12/12
 Reduce engine system costs (engine plus exhaust
  treatment) by $10,000 - $15,000.
   The engines cost less (diesels are more expensive)
   No need for either the Diesel Particulate Filter or the
    Urea Filter (NOx)
 Reduced maintenance
 Fuel costs less
 Better mileage – up to 5% better fuel economy




                    Institute for Energy Resourcefulness   7/12/12   9
EIA Nov 08                           100 -120 years supply
             Institute for Energy Resourcefulness
COWS------ > BIOGAS----- > GASIFIER -- > METHANOL---- > VEHICLES

                    Landfill




                                NET EFFICIENCY = .70*.85 = 59.5%

Institute for Energy Resourcefulness            11                 5/30/12
COWS---- > BIOGAS--- > SOLAR FURNACE -- > METHANOL--- > VEHICLES

                      Landfill




                     Maximum theoretical efficiency = 1.3*.85 = 1.10%


                                        12                     5/30/12
Institute for Energy Resourcefulness
A Way Forward for Economical
 Environmentally Responsible Transportation
        Policy in Los Alamos County
• Do a test on an older E-85 vehicle. Buy methanol on open market and establish
  the use of GEM mixtures.
• If successful run a small test fleet
    • Mix locally at airport pumping station?
• Expand fleet using GEM mixture
    • Contract for a long term methanol price (see supplemental slides)
                    The above can be done with existing vehicles
• Buy all new vehicles with capability of 100% methanol usage
    • Passage of the “Open Fuels Act” will mandate this
• Renewable methanol from LA landfill gas emissions
• Use classical gasifiers to make methanol from landfill gas
• In the future, add solar gasifiers to make additional methanol
    • Gain 30% in available energy
    • Utilize all of the CO2 emitted
• Apply for Federal Production Tax Credit
    Institute for Energy Resourcefulness    7/12/12                               13
   CNG $2.54*200,000/5 = $101,600
   LNG $1.70 * 200,000/5 = $68,000
   Diesel $3.91 *200000/5 = $156,400
   Methanol $2.64*200000/5 = $105,600
   $75,000 cost increment to convert a full sized bus to CNG
   ---------------------------------
   Over 200,000 miles --
     Converting to Methanol                 Saves:
         Diesel – Methanol = $156,400 - $105,600           = $50,800
     Converting to LNG Saves:
        Diesel – (LNG + $75,000) = $156,400 – ($68,000 + $75,000) = $156,400 – 143,000 =
           $13,400
 ----------------------------
     Additional cost of CNG fuel pumps $300,000-$500,000
     Additional cost of methanol dispenser/tank from $25,000 to $50,000

              Institute for Energy Resourcefulness    7/12/12                               14
   CNG $2.54*200,000/5 = $101,600
   LNG $1.70 * 200,000/5 = $68,000
   Diesel $3.91 *200000/5 = $156,400
   Methanol $2.64*200000/5 = $105,600
   $75,000 cost increment to convert a full sized bus to CNG
   ---------------------------------
   Over 200,000 miles --
     Converting to Methanol                 Saves:
         Diesel – Methanol = $156,400 - $105,600           = $50,800
     Converting to LNG Saves:
        Diesel – (LNG + $75,000) = $156,400 – ($68,000 + $75,000) = $156,400 – 143,000 =
           $13,400
 ----------------------------
     Additional cost of CNG fuel pumps $300,000-$500,000
     Additional cost of methanol dispenser/tank from $25,000 to $50,000

              Institute for Energy Resourcefulness    7/12/12                               15
 Transportation costs can be reduced using existing vehicles
    – hundreds of dollars vs. tens of thousands per vehicle.
   Future vehicles can be less expensive to purchase and
    operate if run on GEM mixtures.
   Methanol can be contracted from NM farms or purchased
    cheaply on long term contract.
   Maintenance is traditional, not the complication of CNG
   Flexibility in fueling
     Cellulosic ethanol production breakthrough can immediately be accommodated
     Butanol production breakthrough can be accommodated
     Flex Fueled hybrids are a natural extension for increased mileage




     Institute for Energy Resourcefulness    7/12/12                      16
Experience with Methanol

           In California




        Institute for Energy Resourcefulness   5/30/12   18
Methanol is much cheaper
          The contract pricing is
   substantially less than market prices
    as the California experience shows




                                       from




Institute for Energy Resourcefulness          5/30/12   19
Let’s look at the Carbon Dioxide Emissions
       from methanol fuel production




                                             Gasoline refining

                                                       renewables




             Institute for Energy Resourcefulness   5/30/12         20
Safety


                                                             GASOLINE


            METHANOL




• In the California test (15 years), with over 200 million miles of methanol
driving, there was not a single case of accidental methanol poisoning.

• For M100 a 90% reduction in fuel related automotive fires is projected.
                      P. A. Machiele, Summary Of The Fire Safety Impacts of Methanol
                     as a Transportation Fuel, SAE International paper 901113
Solar Methanol will use no water

        Institute for Energy Resourcefulness   5/30/12   22
Volumetric vs. gravimetric energy density




   Institute for Energy Resourcefulness   23   5/30/12
 Supports national policy/renewable fuel initiatives
  Vehicle demonstration program
   High efficiency hybrid (hydraulic)
   Heavy-duty Class 6 delivery truck
   Captive fleet
 High efficiency engine program (neat alcohol fuels and
  blends with gasoline)
       Ethanol or Methanol engines
        with high efficiency (>40% peak)
       Lends itself to exhaust thermal energy
        recovery in the form of chemical
        and mechanical energy
       Combined system yields fuel cell
        efficiency (>55% peak) at a
        significantly lower cost
                                                           24
Bromberg, L. and Cohn, D., "Alcohol Fueled Heavy Duty Vehicles
                           Using Clean, High Efficiency Engines,”

                           SAE Technical Paper 2010-01-2199, 2010, doi:10.4271/2010-01-2199.
                           Author(s): Leslie Bromberg - Massachusetts Institute of Technology
                           Daniel Cohn - Massachusetts Institute of Technology
Institute for Energy Resourcefulness         25            5/30/12
EPA Brake Thermal Efficiency Comparison

engine fueled on 100%                            same engine run in its
       methanol                               native diesel mode (1.9L VW
in spark ignition mode                                 TDI diesel)

                                                             39%
           42%




Typical 1.9L gasoline engine has 22-25% BTE
  Institute for Energy Resourcefulness   26        5/30/12
Ethanol/Methanol can give diesel engine efficiencies
without the need for high pressure injection systems and
either DPF or Urea NOx reducing exhaust treatment.




     Test in a VW TDI 1.9 L diesel engine which was converted to spark ignition
     for the ethanol tests. The compression ratio was 19.5 to 1.
“Combined with an optimized conventional drivetrain, the
efficiency gain shown in the previous slide for E30 should
yield an estimated 10% - 12% gain in fuel economy. Thus it
more than compensates for the approximately 8% loss in fuel
energy density of E30 vs. straight gasoline.”
                                                      EPA
Even Ethanol/Gasoline mixtures as low as
E30 can give engine efficiencies that
approach those of a diesel.




These SI engine efficiencies are 25% greater
than attainable in current gasoline only fueled engines
Contact

                         Bob Falco
          Institute for Energy Resourcefulness

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Methanol Fuel can free us from oIl - with appendices

  • 1. Bob Falco, PhD Pete Sheehey, PhD Institute for Energy Resourcefulness Presented to the LAC Transportation Committee 12 July 2012
  • 2.  The EPA has researched the use of high percentages of alcohol in engines  Scientifically prescribed path to easy introduction of methanol  MIT Engine Lab and Lotus Engineering  The path utilizes the availability of current Flex Fueled Vehicles (FFV)  There are over 11,000,000 FFV in the US  All new vehicles purchased by Los Alamos County are Flex Fuel Capable 7/12/12 Institute for Energy Resourcefulness 2
  • 3.  High cost of vehicle conversion  High cost of pumping stations  High cost of maintenance  Lower efficiency/power of vehicles  No easy transition path  Locked into a single technology and fuel at a time of rapidly developing fuels technology
  • 4. 40%G 10%E 50%M Lotus Engineering Research 7/12/12 4 Institute for Energy Resourcefulness
  • 5. G=$ 3.11 % methano l G= $3.73 Lotus Engineering
  • 6. • Can be made from natural gas (100-120 yrs) • No competition with food • No water use issues • Cheaper to make than gasoline Additional advantages • Engines can be optimized to run with higher efficiency than diesels • Lower CO2, • CO2 neutral if bio methanol • CO2 negative if solar energy is used • Methanol can be made renewably Institute for Energy Resourcefulness 6 7/12/12
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  • 9.  Reduce engine system costs (engine plus exhaust treatment) by $10,000 - $15,000.  The engines cost less (diesels are more expensive)  No need for either the Diesel Particulate Filter or the Urea Filter (NOx)  Reduced maintenance  Fuel costs less  Better mileage – up to 5% better fuel economy Institute for Energy Resourcefulness 7/12/12 9
  • 10. EIA Nov 08 100 -120 years supply Institute for Energy Resourcefulness
  • 11. COWS------ > BIOGAS----- > GASIFIER -- > METHANOL---- > VEHICLES Landfill NET EFFICIENCY = .70*.85 = 59.5% Institute for Energy Resourcefulness 11 5/30/12
  • 12. COWS---- > BIOGAS--- > SOLAR FURNACE -- > METHANOL--- > VEHICLES Landfill Maximum theoretical efficiency = 1.3*.85 = 1.10% 12 5/30/12 Institute for Energy Resourcefulness
  • 13. A Way Forward for Economical Environmentally Responsible Transportation Policy in Los Alamos County • Do a test on an older E-85 vehicle. Buy methanol on open market and establish the use of GEM mixtures. • If successful run a small test fleet • Mix locally at airport pumping station? • Expand fleet using GEM mixture • Contract for a long term methanol price (see supplemental slides) The above can be done with existing vehicles • Buy all new vehicles with capability of 100% methanol usage • Passage of the “Open Fuels Act” will mandate this • Renewable methanol from LA landfill gas emissions • Use classical gasifiers to make methanol from landfill gas • In the future, add solar gasifiers to make additional methanol • Gain 30% in available energy • Utilize all of the CO2 emitted • Apply for Federal Production Tax Credit Institute for Energy Resourcefulness 7/12/12 13
  • 14. CNG $2.54*200,000/5 = $101,600  LNG $1.70 * 200,000/5 = $68,000  Diesel $3.91 *200000/5 = $156,400  Methanol $2.64*200000/5 = $105,600  $75,000 cost increment to convert a full sized bus to CNG  ---------------------------------  Over 200,000 miles --  Converting to Methanol Saves:  Diesel – Methanol = $156,400 - $105,600 = $50,800  Converting to LNG Saves:  Diesel – (LNG + $75,000) = $156,400 – ($68,000 + $75,000) = $156,400 – 143,000 = $13,400  ----------------------------  Additional cost of CNG fuel pumps $300,000-$500,000  Additional cost of methanol dispenser/tank from $25,000 to $50,000 Institute for Energy Resourcefulness 7/12/12 14
  • 15. CNG $2.54*200,000/5 = $101,600  LNG $1.70 * 200,000/5 = $68,000  Diesel $3.91 *200000/5 = $156,400  Methanol $2.64*200000/5 = $105,600  $75,000 cost increment to convert a full sized bus to CNG  ---------------------------------  Over 200,000 miles --  Converting to Methanol Saves:  Diesel – Methanol = $156,400 - $105,600 = $50,800  Converting to LNG Saves:  Diesel – (LNG + $75,000) = $156,400 – ($68,000 + $75,000) = $156,400 – 143,000 = $13,400  ----------------------------  Additional cost of CNG fuel pumps $300,000-$500,000  Additional cost of methanol dispenser/tank from $25,000 to $50,000 Institute for Energy Resourcefulness 7/12/12 15
  • 16.  Transportation costs can be reduced using existing vehicles – hundreds of dollars vs. tens of thousands per vehicle.  Future vehicles can be less expensive to purchase and operate if run on GEM mixtures.  Methanol can be contracted from NM farms or purchased cheaply on long term contract.  Maintenance is traditional, not the complication of CNG  Flexibility in fueling  Cellulosic ethanol production breakthrough can immediately be accommodated  Butanol production breakthrough can be accommodated  Flex Fueled hybrids are a natural extension for increased mileage Institute for Energy Resourcefulness 7/12/12 16
  • 17.
  • 18. Experience with Methanol In California Institute for Energy Resourcefulness 5/30/12 18
  • 19. Methanol is much cheaper The contract pricing is substantially less than market prices as the California experience shows from Institute for Energy Resourcefulness 5/30/12 19
  • 20. Let’s look at the Carbon Dioxide Emissions from methanol fuel production Gasoline refining renewables Institute for Energy Resourcefulness 5/30/12 20
  • 21. Safety GASOLINE METHANOL • In the California test (15 years), with over 200 million miles of methanol driving, there was not a single case of accidental methanol poisoning. • For M100 a 90% reduction in fuel related automotive fires is projected. P. A. Machiele, Summary Of The Fire Safety Impacts of Methanol as a Transportation Fuel, SAE International paper 901113
  • 22. Solar Methanol will use no water Institute for Energy Resourcefulness 5/30/12 22
  • 23. Volumetric vs. gravimetric energy density Institute for Energy Resourcefulness 23 5/30/12
  • 24.  Supports national policy/renewable fuel initiatives  Vehicle demonstration program  High efficiency hybrid (hydraulic)  Heavy-duty Class 6 delivery truck  Captive fleet  High efficiency engine program (neat alcohol fuels and blends with gasoline)  Ethanol or Methanol engines with high efficiency (>40% peak)  Lends itself to exhaust thermal energy recovery in the form of chemical and mechanical energy  Combined system yields fuel cell efficiency (>55% peak) at a significantly lower cost 24
  • 25. Bromberg, L. and Cohn, D., "Alcohol Fueled Heavy Duty Vehicles Using Clean, High Efficiency Engines,” SAE Technical Paper 2010-01-2199, 2010, doi:10.4271/2010-01-2199. Author(s): Leslie Bromberg - Massachusetts Institute of Technology Daniel Cohn - Massachusetts Institute of Technology Institute for Energy Resourcefulness 25 5/30/12
  • 26. EPA Brake Thermal Efficiency Comparison engine fueled on 100% same engine run in its methanol native diesel mode (1.9L VW in spark ignition mode TDI diesel) 39% 42% Typical 1.9L gasoline engine has 22-25% BTE Institute for Energy Resourcefulness 26 5/30/12
  • 27. Ethanol/Methanol can give diesel engine efficiencies without the need for high pressure injection systems and either DPF or Urea NOx reducing exhaust treatment. Test in a VW TDI 1.9 L diesel engine which was converted to spark ignition for the ethanol tests. The compression ratio was 19.5 to 1.
  • 28. “Combined with an optimized conventional drivetrain, the efficiency gain shown in the previous slide for E30 should yield an estimated 10% - 12% gain in fuel economy. Thus it more than compensates for the approximately 8% loss in fuel energy density of E30 vs. straight gasoline.” EPA
  • 29. Even Ethanol/Gasoline mixtures as low as E30 can give engine efficiencies that approach those of a diesel. These SI engine efficiencies are 25% greater than attainable in current gasoline only fueled engines
  • 30.
  • 31. Contact Bob Falco Institute for Energy Resourcefulness