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GBH Enterprises, Ltd.

Process Engineering Guide:
GBHE-PEG-FLO-305

Introduction to Pressure Surge in
Liquid Systems

Information contained in this publication or as otherwise supplied to Users is
believed to be accurate and correct at time of going to press, and is given in
good faith, but it is for the User to satisfy itself of the suitability of the information
for its own particular purpose. GBHE gives no warranty as to the fitness of this
information for any particular purpose and any implied warranty or condition
(statutory or otherwise) is excluded except to the extent that exclusion is
prevented by law. GBHE accepts no liability resulting from reliance on this
information. Freedom under Patent, Copyright and Designs cannot be assumed.

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Process Engineering Guide:

Introduction to Pressure Surge
in Liquid Systems

CONTENTS

SECTION

0

INTRODUCTION/PURPOSE

3

1

SCOPE

3

2

FIELD OF APPLICATION

3

3

DEFINITIONS

3

4

CAUSES OF PRESSURE SURGE

3

4.1

Start-up

4

5

CONSEQUENCES OF PRESSURE SURGES

5

6

PRELIMINARY CALCULATIONS

5

6.1
6.2

Estimation of the Sonic Velocity
Pipeline Period

5
7

7

CALCULATION OF PEAK PRESSURES

8

7.1
7.2
7.3
7.4
7.5
7.6

Rigid Liquid Column Theory
Sudden Changes in Flowrate
Moderately Rapid Changes in Flowrate
Reflections and Attenuations
Vapor Cavity Formation
Complex Piping Systems

8
9
9
10
10
10

8

FORCES ON PIPE SUPPORTS

10

.
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9

METHODS OF REDUCING THE EFFECTS OF
PRESSURE SURGE

13

9.1
9.2
9.3
9.4
9.5
9.6
9.7

Flowrate
Pipe Diameter
Valve Selection and Operation
Pump Start-up/Shut-down
Surge Tanks and Accumulators
Vacuum Breakers
Changes to Equipment

13
13
13
16
16
17
18

10

DETAILED ANALYSIS

18

10.1
10.2

Data Requirements
Interpretation of Results

18
19

11

GUIDELINES FOR CALCULATIONS

21

12
12.1
12.2
12.3
12.4
12.5
12.6

EXAMPLES OF PRESSURE SURGE INCIDENTS
Caustic Soda Pipeline Movement
Ammonia Pipe Movement
Propylene Reactor Start-up
Cooling Water Failure
Dry Riser Fire Sprinkler Systems
Cast Iron Fire Main Pressurization

21
21
22
23
23
23
23

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13
14

REFERENCES

24

NOMENCLATURE

25

TABLES
1

2

3

BULK MODULUS OF ELASTICITY AND SONIC
VELOCITY FOR SOME LIQUIDS

26

YOUNG'S MODULUS AND POISSON'S RATIO OF
SOME PIPE MATERIALS

30

GUIDELINES FOR PRESSURE SURGE ANALYSIS
OF PIPING SYSTEMS

31

FIGURES
1

WAVESPEED IN PIPES FILLED WITH WATER

7

2

FORCES ON A PIPING SYSTEM IN STEADY
STATE FLOW

11

FORCES ON A PIPING SYSTEM IN
TRANSIENT FLOW

11

EFFECT OF VALVE CLOSURE TIME ON OUT-OF
-BALANCE FORCES

13

EFFECT OF VALVE TYPE ON FLOWRATE DURING
TRANSIENT FLOW

15

6

EFFECT OF VALVE TYPE ON SURGE PRESSURE

15

7

CAUSTIC SALES PIPELINE

22

3

4

5

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0

INTRODUCTION/PURPOSE

This document is one of a series on fluid flow produced by GBH Enterprises.
If a rapid change is made to the flowrate of a liquid in a piping system, for
example by the operation of a valve, a transient pressure change will be
propagated through the system. This transient pressure may be significantly
greater than either the initial pressure or the final steady state pressure which the
system reaches. This may cause damage to the piping system; either by
exceeding the design pressure of the piping system with consequent risk of
rupture, or by producing out of balance forces which are greater than can be
sustained by the pipe supports. The phenomenon known as 'water hammer' is a
special case of 'pressure surge'.

1

SCOPE

This Guide provides an introduction for process engineers to the problems
associated with pressure surge. It describes the causes of pressure surge and
indicates how to make preliminary estimations of the likely magnitude of its
effects. Methods of reducing the magnitude of the effects are discussed.
Guidelines are given to help in assessing which piping system should be
analyzed in detail and the data requirements to perform a detailed computer
analysis of the system are given. Some examples are given of problems
encountered by GBH Enterprises due to pressure surge. Tables 1, 2 and 3
contain some useful data to assist in surge calculations.
This Guide is not a comprehensive treatise on pressure transients. More detailed
information is available in standard texts on the subject, for example references
1, 2 and 3.
This Guide does not give advice on the mechanical design of piping systems
subjected to pressure surge, although it does indicate how to calculate the loads
arising from pressure surge.

2

FIELD OF APPLICATION

This Guide is of use to all process engineers and plant operating personnel in the
GBH Enterprises world-wide, who may be involved in the specification, design
or operation of equipment involving the flow of liquids in pipelines.

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3

DEFINITIONS

For the purposes of this Guide, the following definition applies:
Joukowski Pressure or
Joukowski Head

4

The initial change in pressure or liquid head
associated with an instantaneous change in
liquid velocity.

CAUSES OF PRESSURE SURGE

Any operation which can result in a rapid change in velocity is a potential cause
of serious pressure surge. Typical operations include:
(a)

Rapid change in position, either closing or opening, of a control or
isolation valve.

(b)

Opening of a safety valve or rupture of a bursting disc.

(c)

Starting or stopping of a pump.

(d)

Priming of an empty pipeline.

(e)

Unsteady flow generated by a reciprocating pump.

(f)

Rapid phase change, due to thermal effects, rapid chemical reaction or
the collapse of a vapor cavity.

Traditionally, process engineers have associated pressure surge problems
almost exclusively with UPSTREAM effects following the RAPID closure of
valves at the DOWNSTREAM end of LONG pipelines. It will be shown later that
the magnitude of the initial surge resulting from a rapid valve closure is
independent of the pipe length. The pipe length only influences what is
meant by 'rapid'. The pressure rise associated with a slow closure of a valve
does, however, depend on the pipe length.
The effects DOWNSTREAM of a rapidly closed valve are also very important.
The initial result is a reduction in pressure. This may be sufficient to reduce the
absolute pressure below the vapor pressure of the liquid, whereupon a vapor
cavity will form.

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The subsequent collapse of this cavity can give rise to severe problems, with
high transient pressures and out of balance forces. Vapor cavity collapse is one
of the most intractable problems in pressure surge analysis, and any system with
the potential for cavity formation should be viewed with caution.
4.1

Start-up

It is important to realize that during start-up and filling of piping systems the liquid
velocities may be considerably greater than the maximum which may occur
during normal operation, due to the reduced frictional resistances which may
occur during this period. The associated potential for
surge problems may be greater than during normal operation.
4.1.1 Vapor cavities
At start-up it is quite possible that vapor cavities will be present at the high points
of the system, which will collapse as the system is pressurized.
4.1.2 Gas pockets
Gas pockets may reduce fluid friction and allow much higher velocities than
occur in normal full liquid operation. The deceleration of the liquid by the gas
compression can lead under certain circumstances to very high gas pressures
and temperatures. Explosive ignition of flammable mixtures has been known.
4.1.3 Venting
The volumetric flow of a gas through an orifice is considerably greater than that
of a liquid for the same pressure drop. When venting gas from a system, high
flowrates can occur, which cannot be maintained when the gas has been
expelled; a sudden flow reduction occurs, resulting in pressure surge. Specific
examples include priming distributors in columns and batch blowing in systems
with valves at the downstream end of the line.
4.1.4 Fast Pressurization
Fast pressurization of a closed system can double the pressure rise at the far
end of the system as the pressure wave is reflected from the closed end. This
can arise either from the fast opening of a valve at the inlet end of the system or
pump start-up with the pump discharge valve open.

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5

CONSEQUENCES OF PRESSURE SURGES

Usually, the initial reason for investigating the possibility of pressure surge is a
concern that the design pressure of the piping system may be exceeded. Another
problem, not always appreciated, is that even if the surge pressure is within the
design pressure, a surge may result in the creation of large out-of-balance forces
within the piping system. These may damage the supports, or in the extreme,
cause the collapse of pipe bridges. The resulting displacement of the pipes may
be sufficient to cause failure through bending, or might result in a branch pipe
being torn off due to impact when the main pipe is displaced. This may extend to
other pipes on the same pipe bridge which are not themselves subject to
pressure surge. Experiences indicate that failure of pipework supports as a result
of pressure surge is more likely than pipeline rupture due to over-pressure.
Some examples of pressure surge incidents are given in Clause 12.

6

PRELIMINARY CALCULATIONS

Detailed pressure surge analysis of most piping systems is a complex and
lengthy operation, usually involving the use of a computer program, and is
beyond the scope of this Guide. However, some simple preliminary calculations
are possible in order to estimate the likely magnitude of any effects. These may
show that no significant problem exists, or may indicate the need for a more
detailed study. Guidelines for determining whether piping systems require
detailed analysis are given in Table 3.
6.1

Estimation of the Sonic Velocity

Pressure surges are propagated through a piping system at the local sonic
velocity. An estimation of this is basic to all calculations.
In a rigid pipe, pressure disturbances will propagate at the basic sonic velocity for
the fluid, which is given by:

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Dissolved gases have little effect on the sonic velocity, provided they remain in
solution. Even small traces of undissolved gas reduce the sonic velocity
dramatically, and will greatly reduce the magnitude of pressure surges. However,
it is very difficult to quantify such effects, and it is recommended that such
benefits be ignored when assessing a system for potential surge damage.
The bulk modulus of elasticity is not readily obtainable for many liquids. It is not
an item which is stored in the GBH Enterprises; “The VAULT” physical
properties data bank.
Some commercially available programs purport to calculate the speed of sound
in liquids, but the method used is of doubtful validity. It should not be used.
Table 1 gives typical values of bulk modulus of elasticity and sonic velocity for
some liquids. Note that different sources may give significantly different values
for these properties. The most extreme case known to the author is for liquid HF,
where the sonic velocity calculated from the bulk modulus obtained from one
source differs by a factor of 3 from another source's claimed direct measurement
of sonic velocity. In general, a higher assumed value for the sonic velocity
can be expected to lead to predictions of higher surge pressures.
The velocity of propagation of a pressure wave in a thin walled elastic pipe is
lower than the sonic velocity in a rigid pipe, and can be calculated from:

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The value of B depends on the method of pipe support and the Poisson ratio of
the pipe material. When the Young's Modulus, E, is large, as for metal pipes, the
numerical value of B may be taken as unity without significant error. In other
cases, B may be calculated from:

Values of Young's Modulus and Poisson's ratio for some common materials are
given in Table 2.
The reduction in velocity due to the elasticity of the pipe is normally relatively
small for metal pipes, but can be considerable with plastic pipes. Figure 1, which
is taken from reference 4, shows the effects of pipe material and wall thickness
on the velocity of propagation of a pressure wave in a water filled pipe.

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FIGURE 1

WAVESPEED IN PIPES FILLED WITH WATER

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6.2

Pipeline Period

The magnitude of the initial pressure transient associated with a change in
flowrate depends on whether the change can be regarded as 'fast' or 'slow'. In
this context, the terms 'fast' and 'slow' are relative rather than absolute, and are
related to a quantity known as the 'pipeline period', t*. This is the time that
elapses between initiation of the change and the return of the reflected surge
from the end of the pipeline to the point of initiation (see below). Thus:

where L is the length of the pipeline from the source of the disturbance to the end
of the pipe (m) and c is the velocity of propagation of the pressure wave (m/s).
There will be two pipeline periods associated with a single pipe having a valve
part way down it; one will be based on the upstream length and one on the
downstream length.
7

CALCULATION OF PEAK PRESSURES

7.1

Rigid Liquid Column Theory

If the velocity of a liquid in a pipeline is changed gradually and steadily, such that
the change takes place over more than about 10 pipeline periods, the simplifying
assumptions can be made that the rate of change of velocity is the same at all
points along the pipeline. Compressibility effects can be ignored and the liquid
treated as a rigid column. Pressure changes can then be calculated by
considering the momentum effects. For the upstream side of the disturbance:

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Similarly, for the downstream side of the disturbance:
Note:
The above approach assumes that the rate of change of velocity is reasonably
uniform. Most types of valve have non-linear characteristics, some very much so
such that most of the effect occurs over the last 10-20% of closure. The effective
closure times of these valves are thus considerably less than the nominal times.
This has to be remembered when determining if the closure can be considered
'slow'. Note also that the effects are very much dependent on valve size, with
much better performance being obtained when small valves are used in large
lines. See sub clauses 9.3.2.1, 9.3.2.2 and figures 5 and 6.

7.2

Sudden Changes in Flowrate.

Any change in flowrate which is completed in under one pipeline period can be
considered instantaneous as far as the initial pressure transient is concerned.
Note that for a long pipeline, this time could be quite significant. For example, if
the sonic velocity is 1000 m/s and the pipeline is 10 km long the pipeline period
will be 20 seconds. A valve which closes in 15 s will have the same effect as one
which closes in 1 s. Rigid column theory can only safely be applied to this system
if the closure time exceeds 200 s.

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When the velocity at any point in a pipe carrying liquid is suddenly changed, for
example by the closure of a valve, a pressure wave is propagated from that point
along the pipe. The magnitude of the initial pressure change is given by the
formulae:

This pressure change is usually known as the Joukowski Pressure, or, if
expressed in terms of a head of the liquid, the Joukowski Head. Note that the
equations do not include the length of the pipeline. The same value will be
obtained in a short pipe as in a long one, provided the closure is sufficiently rapid
to occur within one pipeline period.
If the disturbance is caused by the sudden closure of a valve, the upstream
pressure will initially increase by the Joukowski Pressure, whereas the
downstream pressure will decrease by this amount. Conversely, the sudden
opening of a valve will produce a fall in upstream pressure and a rise in
downstream pressure.
When a liquid is flowing down a pipeline there is a reduction in pressure along
the line due to frictional effects. When the liquid has been brought to rest
following the closure of a valve at the end of the line this frictional loss no longer
occurs. The pressure at the valve initially rises rapidly by the Joukowski
Pressure. Then, over the next pipeline period, it continues to rise
gradually by an amount equal to the original frictional loss.
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7.3

Moderately Rapid Changes in Flowrate

If a change in flowrate takes place over an interval between one and ten pipeline
periods, neither the rigid liquid column method nor the Joukowski Head
calculation is strictly applicable. For simple unbranched systems it is possible to
estimate the magnitude of the peak pressure by a stepwise manual method, as
explained in reference 6, but the procedure is quite involved. If the calculation of
the Joukowski Head indicates the possibility of problems, it is generally
preferable to perform a detailed computer analysis.

7.4

Reflections and Attenuations

When a pressure surge reaches the end of a pipeline, it is reflected back down
the line. If the end of the pipe is open, the magnitude of the reflection is the same
as the incident surge, but the sign is reversed. Thus a positive pressure surge is
reflected as a rarefaction, and vice versa. When a surge reaches a closed end,
the reflected surge has double the incoming magnitude.
Because of these reflections, alternate pressure and rarefaction surges pass up
and down the line, being reflected from each end. Due to friction effects, the
magnitude of the surges gradually dies away.

7.5

Vapor Cavity Formation

If the static pressure in the system falls below the vapor pressure at any point, a
vapor cavity will tend to form, which will continue to grow all the while the
pressure remains low. Subsequent positive pressures will cause the cavity to
collapse. This will lead to a large abrupt pressure surge as the cavity is
condensed. Experience shows that this is one of the most severe problems to
deal with. If preliminary calculations indicate that cavity formation is likely, a
more detailed analysis is recommended.

7.6

Complex Piping Systems

For a branched piping system, or one including several high points where vapor
cavity formation may occur, reflections will occur off the ends of each pipeline,
and vapor cavities will collapse in differing times. The result is a very complex
pressure/time history, which cannot sensibly be analyzed by hand calculations.
Computer analysis of the system is then essential if preliminary calculations give
any indication of potential problems.
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8

FORCES ON PIPE SUPPORTS

A flowing fluid has the potential to exert a force on account of its pressure and its
momentum. The potential force of a fluid in a pipe, acting in the direction of the
flow, is given by:

When a fluid is flowing in steady flow through a pipeline, as it approaches a
bend, it will exert a force on that bend, equal to the potential force in the direction
at which it approaches the bend. After flowing round the bend, it will exert a
backward force of the same magnitude in the new direction of flow. The resultant
force acts outwards on the bend in a direction bisecting the angle of the bend.
Thus for a 90° bend, the resulting force (F') is given by:
.

The force on the bend is restrained by the tension in the pipe.
As the fluid flows along the straight lengths between bends, its pressure falls due
to the effects of friction, thus reducing F, but the corresponding reduction in
tension in the pipe is balanced by the shear forces on the wall. There is thus no
net force on the pipework, except on the last bend before the discharge from the
pipe, where there is a backward force F along the direction of the pipe. See
Figure 2.
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FIGURE 2

FORCES ON A PIPING SYSTEM IN STEADY STATE FLOW

However, if a pressure transient is passing through the piping system, the forces
on the pipework are no longer in balance. Consider the section of pipe shown in
FIGURE 3

FORCES ON A PIPING SYSTEM IN TRANSIENT FLOW

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Assume that the valve is closed suddenly. A transient will pass back up the pipe
from the valve at the sonic velocity. On the valve side of the transient, the fluid
will have been brought to rest and the pressure will be greater than the initial
pressure by the Joukowski Pressure for the system, ρ.c.v. Upstream of the
transient, the fluid will still be travelling with the original velocity and pressure.
Consider the length of pipe between the two bends in Figure 3, when the
transient is somewhere between the bends, and ignore the effects of friction. The
force along the pipe from the upstream bend is then:

In the simple system considered here, where the pressure remains at the higher
value for a significant time after the transient has passed, this force will act for a
time Δt, the time taken for the pressure transient to pass along the length of pipe
between the two bends:

For more complex systems, involving multiple reflections and vapor cavity
collapses, for example, a very complex pressure/time response may occur, and
the duration of a high pressure may be shorter than that taken for the transient to
pass between the two bends. When analyzing the forces on the piping system it
is necessary to consider both the magnitude and duration of the forces.
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For a sudden pressure rise, the effect of these forces cannot be considered as
equivalent to steady state forces. It is generally necessary to apply a multiplying
factor, the Dynamic Load Factor or DLF, to the calculated shock loading when
performing a dynamic pipeline support analysis. The magnitude of this factor
depends on the nature of the pipe supports, and the duration of the force in
relation to the natural frequency of the piping system. The DLF can be
up to a value of 2 for rigidly anchored systems with a relatively long force
duration. Conversely, for short duration pressure pulses in flexible (low
frequency) pipes the dynamic load factor on supports can be much less than
unity. Consult a piping engineer for advice. For more information on the
mechanical aspects of designing pipework for pressure surge, Visit us at
www.gbhenterprises.com.
If the valve is closed gradually rather than suddenly, not only will the magnitude
of the surge pressure be reduced, but the pressure will rise gradually rather than
in a stepwise fashion. The effect of this is to reduce significantly the magnitude of
the out of balance forces. This is illustrated in Figure 4.
FIGURE 4

EFFECT OF VALVE CLOSURE TIME ON OUT-OF-BALANCE
FORCES

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9

METHODS OF REDUCING THE EFFECTS OF PRESSURE SURGE

Pressure surges occur because a rapid change in liquid flowrate is imposed on
the system. Surge reduction methods work by reducing the magnitude of this
change or increasing the time over which it occurs. They usually rely either on
reducing the rate at which the primary event causing the surge (e.g. valve
closure) occurs, or providing an alternative source or sink for the liquid in the
form of a surge tank or accumulator.
9.1

Flowrate

For most pipelines, the required flowrate is determined by the process. However,
for some operations, such as the batchwise transfer of liquid from one vessel to
another, it may be possible to increase the transfer time, thus reducing the flow
velocity. Closure of the system valves will then produce a smaller change in
velocity, and hence a reduced surge pressure.
9.2

Pipe Diameter

Increasing the diameter of a pipeline for a given flowrate will reduce the velocity,
and hence the peak surge pressure. However, this approach is likely to be
expensive compared with the alternatives. Moreover, although it will reduce the
magnitude of the peak pressure, the out-of balance forces will remain
substantially the same, as the reduction in pressure is balanced by an increase in
pipe cross sectional area. This method will not be considered further here.
9.3

Valve Selection and Operation
9.3.1 Isolation valves
The unthinking operation of an isolation valve when the liquid is flowing in
the pipeline can have serious consequences, especially as many types of
isolation valve can be closed very rapidly, for example with a quarter turn
of a handle. If the surge analysis indicates that this is unacceptable, some
action will be necessary to prevent this happening. An operating
procedure may be considered adequate for this purpose, but in general
some physical constraint is preferable. It may be necessary to remove the
operating handles from key valves, or provide them with locks. An
alternative is to fit them with gear drives with low ratios, such that very
many turns are required to operate the valves.

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For some designs of butterfly valve, the forces on the disk from the flowing
liquid tend to turn the valve into the closed position, particularly when the
valve is initially in the partially closed position. This may result in the
inadvertent rapid closure of the valve, and it may be necessary to provide
some physical constraint to prevent this happening.
9.3.2 Control valves
9.3.2.1

Stroke time

Where the process demands permit it, the speed of closure of a control
valve may be reduced by selection of a suitable actuator. Certain types of
valve, particularly butterfly and ball valves, have unfavorable
characteristics from the point of pressure surge, as most of their effect
occurs over the last few percent of the closure. For these valves, a split
range actuator may be useful. This will have a rapid rate of closure over
the part of the characteristic where flowrate does not vary much with valve
position, and a slower response during the last stages of closure.
9.3.2.2

Valve type

As has been stated before, some valve types have better characteristics
than others from the point of view of pressure surge. Where piping
specifications permit, a change in valve type may have significant effects
on the magnitude and rapidity of pressure changes in the system.
In order to illustrate this, a model of a simple piping system has been set
up using the “The Vault” (see Clause 10). The system modeled consists
of a feed tank, a pump, a length of pipeline with a pipeline period of 2
seconds, a control valve and a receiving tank. Five different valve
characteristics (loss coefficient as a function of valve position) have been
simulated, with a valve closure time of 10 seconds in each case. The
valve types used were:
•

A diaphragm valve (Saunders type K).

•

A reduced bore ball valve.

•

A butterfly valve.

•

A control valve with nominally linear characteristics.

•

A control valve with nominally equal percentage characteristics.

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Figure 5 shows the variation of flowrate with time for the five valve types. It
can be seen that over most of the closure, the equal percentage valve
gives the most gradual change in flowrate. However, towards the end of
the closure, there is a rapid change in flow. This is because the
characteristic used represents a real valve, (Taylor Instruments, ideal
rangeability 40:1, practical rangeability 20:1) which only exhibits equal
percentage characteristics over the major portion of its range. Indeed, an
ideal equal percentage valve would never shut off completely.
At the other extreme the 'K' type diaphragm valve has very little effect on
the flow for the first 90% of the closure, followed by a very rapid reduction
in flow, giving an effective closure time of only about 1 second in this case.
FIGURE 5

EFFECT OF VALVE TYPE ON FLOWRATE DURING TRANSIENT
FLOW

Figure 6 shows the corresponding pressures resulting from the different
valve closures. It can be seen that the diaphragm valve gives both the
highest peak pressures, and the most rapid rate of change. The equal
percentage valve gives the lowest pressure rise, but note the rapid rate of
rise occurring at the end of the closure, as the valve departs from ideal
behavior.

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FIGURE 6 EFFECT OF VALVE TYPE ON SURGE PRESSURE

It should be emphasized that these two Figures are illustrative only. The
actual magnitude of the differences between different valve types will
depend on the system. The effects of valve size should also be
considered; a large valve will have worse characteristics than a small one
of the same type, as the initial stages of closure of a large valve result in
little extra flow resistance and hence little change in flow rate. It cannot be
concluded that an equal percentage valve will always give the best results.
9.3.3 Emergency shut-down valves
Emergency shut-down valves may be required to operate very rapidly.
However, it is always worth considering the safety consequences of
increasing the closure time. Alternatively, a change in valve type, as
discussed above, may produce a reduced pressure surge with the same
overall closure time.

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9.4

Pump Start-up/Shut-down

It is in general bad practice to start up a pump with an open delivery valve into a
long piping system. The preferred arrangement is to have a recycle line from the
pump delivery to the feed tank sized to give the minimum acceptable flowrate for
the pump (a 'kick-back' line), and an isolation valve at the start of the main
system. When the pump is up to speed, this valve may be opened in a slow,
controlled fashion to divert the flow into the main piping system.
For critical applications, where there are likely to be vapor cavities present at
start-up, it is recommended that a small bore bypass be installed round the main
discharge valve to ensure that the line is started up under well defined low flow
conditions. The practice of 'cracking valves' open to restrict flowrate is unsafe.
Pump shut-downs should also be done in a controlled manner. Unfortunately,
this is not always possible, as power failures, for example, can result in a pump
trip.
It may be possible to increase the run-up time of a pump by choice of a suitable
motor. There are now control systems available which allow the start-up to take
place over an extended period, say 2 minutes. These have been used
successfully in many locations. Alternatively, addition of a flywheel to the pump
drive will increase both run-up and run-down times. The motor will obviously
have to be suitable to deal with the higher inertia. Unfortunately, this approach is
not possible with a canned pump.
Note:
The use of a non-return valve on a pump delivery may itself be a cause of
pressure surges.

9.5

Surge Tanks and Accumulators

If the methods described above are not suitable to prevent surge problems, the
use of a surge tank or accumulator may be required. These devices operate by
providing an alternative source or sink for the liquid, enabling, for example, a key
valve to be opened or closed rapidly while allowing the flow in the pipeline to be
increased or reduced in a more gradual and controlled manner. To be most
effective, these devices should be connected to the piping system close
to the source of the flow disturbance, e.g. the control valve which has been
identified as the cause of the surge. If there is more than one potential cause of
surge, several surge tanks or accumulators may be needed, one at the location
of each potential source.
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9.5.1 Surge tanks
A surge tank consists of a vertical cylindrical tank mounted at some
suitable point along the line. The tank is open to the atmosphere at the
top, and is placed so that its top is higher than the steady state head at
that point. It has to have sufficient capacity such that it will not be drained
or over-filled by the highest flow that might occur during a transient.
Because they are open to the atmosphere, surge tanks are not generally
used in the chemical industry, but they are
common in the water supply and hydro-electric industries.
9.5.2 Accumulators
An accumulator is a closed vessel, partly filled with gas, which is
connected to the pipeline at a suitable point. The gas acts as a cushion
which absorbs some of the pressure surges passing along the pipe by
allowing some of the flow to be diverted into or out of the accumulator.
Accumulators are common on reciprocating pumps, where they reduce
the pressure fluctuations. They may be located on the suction side,
delivery side or both, depending on the perceived problems. Like surge
tanks, accumulators have to be sized to allow for the magnitude of the
flows. This may make them large and prohibitively costly for high flow
lines.
The main disadvantage of accumulators apart from cost is the problem of
ensuring that they are in a suitable condition to operate when required. If
the gas is in direct contact with the liquid it may dissolve over a period of
time, and some means of checking for this is necessary. Some designs of
accumulator get round this by the use of a bladder or diaphragm.
However, there is always a danger that the diaphragm may rupture. It may
not be easy to determine if this has happened. It may also be difficult to
find a material for the diaphragm which is compatible with the chemicals
being handled.
An alternative to the diaphragm is to separate the liquid and gas by a
piston. Here there is a danger that corrosion of the piston or cylinder, or
dirt in the process fluid, may cause the piston to stick. The gas space
above the cylinder will normally be pre-pressured to a pressure above
the normal operating pressure of the system, resulting in the piston being
in its fully extended position. It is normal to mount a pressure gauge on the
gas side of the piston to ensure that it is properly charged. Regular
checking of this pressure and topping up when necessary is
essential to maintain the integrity of the system.
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Note:
A piston type accumulator may itself be a cause of vapor cavity formation.
The gas behind the piston has to be initially pressurized above the system
pressure or the position of the cylinder is indeterminate. However,
following a surge incident the liquid will be forced out of the cylinder
by the gas pressure. This liquid outflow may stop abruptly when the piston
reaches its lower limit, giving a negative pressure wave.
It is a regrettable fact that the maintenance of accumulators is often
neglected. For this reason, they are not recommended as the primary
safety device where the consequences of failure to operate are
unacceptable. If it does prove unavoidable to use them in such
circumstances, it is essential that suitable maintenance procedures are
implemented and can be demonstrated. Inspection of accumulators
should be included in safety inspection routines.

9.6

Vacuum Breakers

If a pipeline passes through a high point, during shut-down conditions the
pressure at that point may fall below the vapor pressure and a vapor cavity may
form. When flow is re-started in the line, this cavity will collapse and initiate a
pressure surge. Ideally, pipelines should be routed to avoid such high points, but
this is rarely possible in practice.
If a vacuum breaking valve is installed at the high point, the vapor cavity will be
replaced by an air pocket. When the flow is re-started in the line, this air pocket
will compress, gradually accelerating the liquid column ahead of it and reducing
the surge. The air pocket acts in effect like an accumulator.
This approach is obviously only applicable where ingress of air into the liquid line
is acceptable. It has been recommended to alleviate surge problems on aqueous
caustic soda lines. The approach could in principle be modified to let an inert gas
such as nitrogen into the liquid line, provided that the gas does not cause
problems when it is passed through the system. This obviously results in a more
complex system, and the observations on maintenance given in 9.5.2 also apply.
Note:
Air venting valves, which are sometimes installed at the high points of pipelines
to remove air during start-up, are themselves a potential cause of surge. See
4.1.3.
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9.7

Changes to Equipment

As an alternative to reducing the magnitude of a surge, it may be worth
considering whether the design rating of the piping system could be increased.
The design pressure of a piping system may be dictated not by the pipe wall
thickness or the flange rating, but by the pressure rating of a valve or instrument
in the pipeline. Changes here, particularly if made at the design stage, may
enable rapid valve closures to occur without exceeding the design pressure.
However, remember that not only the piping but also the supports have to be
designed to handle the effects of the surge.
Conversely, applying one of the surge alleviation techniques above may permit
the use of a lower design pressure for the pipeline. Analysis on a new boat
loading installation in 1987, involving a long 10" stainless steel line, showed that
the slowing of a valve closure would enable thinner piping to be used, with a
saving of $36,000.

10

DETAILED ANALYSIS

The preliminary hand calculations described in Clauses 6-8 can give an estimate
of the likely magnitude of a pressure surge, but if these indicate a possible
problem, (for example, predicted Joukowski Pressure close to the design
pressure, the potential to form vapor cavities, or large predicted out of balance
forces), expert advice should be sought.
The analysis of all but the simplest systems requires the use of a computer
program.
Experience is necessary to obtain the best results from these programs, and to
interpret the answers.
There are sources of specialist advice and assistance with modeling pressure
surge within GBH Enterprises.

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10.1 Data Requirements
In order to perform a complete pressure surge analysis, a significant quantity of
data is required. Much of this will be readily available for a normal project, but
certain items are less likely to be known. The following is a list of the ideal data
requirements. In practice, not all the data may be available, and reasonable
guesses may have to be made for the missing items, based on typical values for
similar items. Reference 7 is a good source of pressure drop data for many
pipeline components.
(a)

Density of the process liquid at operating conditions.

(b)

Vapor pressure of the liquid at normal operating temperature. This is
needed to determine the conditions under which vapor cavity formation is
likely.

(c)

Bulk modulus of elasticity of the liquid. This is the inverse of the
compressibility. Combined with information on the pipe wall thickness, it is
used to determine the speed of propagation of a pressure wave in the
piping system, using equation (2). This property is not easy to find. Values
for some liquids are given in Table 1, but for other liquids it will probably
be necessary to consult a physical properties specialist for assistance. In
the absence of any reliable data, an estimate of the wave speed will have
to be made by analogy with similar liquids.

(d)

An isometric drawing of the pipeline installation, including all valves and
other fittings, and giving pipe lengths and elevations. It is not necessary
for lengths to be highly accurate. When doing the analysis, the pipeline will
be divided up into sections corresponding to the distance travelled by a
pressure wave in one time-step, and some rounding of the data will
be necessary to ensure an integer number of these sections. Section
lengths in a typical analysis might be 10 to 50 meters. The relative
elevations should be given with reasonable accuracy, as they influence
the formation of vapor cavities.

(e)

The pipe diameter, wall thickness and Young's modulus of the pipe
material. These items are needed, along with the liquid compressibility, to
determine the speed of propagation of a pressure wave (equation (2)).

(f)

The liquid level and pressure above the liquid in all tanks connected to the
piping system.

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(g)

For each valve which is to be considered as a potential cause of pressure
surge, the valve resistance (K value), as a function of position. Ideally, the
data should be obtained from the manufacturer, especially for control
valves. Standard data are available for certain valve types, which can be
used in the absence of manufacturer's data.

(h)

For each valve, the position as a function of time. Often only a closure
time is known. In such cases, the position has to be assumed to vary
linearly with time. It is possible to provide a valve actuator with a nonlinear characteristic; this can be useful for valves such as butterfly and
ball, where most of the effect occurs in the last part of the closure.

(j)

For all other fittings, including isolation valves which are not operated
when fluid is flowing, a resistance expressed as a K value (which has to
include the diameter on which the K value is based). Note that the experts
running the analyses can usually provide these data for most common
fittings, provided the type is known.

(k)

Pump data. During the course of a pressure transient, the differential
pressure across a pump, and hence the flowrate through it, will change. If
the effects of pump start-up and shut-down are not to be modeled, only
the pump characteristic curves (flowrate against differential head) are
necessary. If start-up and shut-down are to be modeled, several other
items of data are required, which are less readily available. These are: the
moment of inertia of the pump and drive assembly; the friction torque; the
speed/torque characteristics of the motor. Machines Sections should be
approached for these data.

The boundaries for an analysis are normally vessels which either feed the piping
system or receive liquid from it, and which can be regarded as regions of
constant pressure. It is not possible to analyze a section of pipework in the
middle of an existing piping system without also considering the pipes to which it
is connected. Thus if a section of a pipe is to be re-routed, for example, the
complete system from supply vessel to outlet has to be analyzed.

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10.2

Interpretation of Results

A computer simulation of a surge problem generates a large quantity of data. A
typical relatively simple analysis might have 20 piping components and 15 nodes.
The analysis might run for 20 seconds with a time step of 0.005 seconds,
producing results at 4000 time steps. It is usual to produce most of the answers
in graphical form, giving values of the parameters of interest as a function of
time.
When considering the mechanical design of the piping system, the items of most
interest are the maximum (and for lined pipes, the minimum) pressures, and the
out-of-balance forces. Pressures are obtainable directly from “The VAULT”
results. The estimation of the magnitude and effect of the out-of-balance forces
cannot be obtained directly from the “The VAULT” output, but can be inferred
from the results.
Vapor cavity collapse generally results in a step change in pressure, whereas
other surge events may give a more gradual, but still rapid, change. Because of
the calculation methods used by “The VAULT”, any pressure change which
takes place over a single time step is considered as instantaneous.
For an instantaneous pressure change, the magnitude of the out-of-balance
forces at each pipe bend can be estimated as the product of the pressure change
and the pipe cross sectional area.

This force will act along the axis of the pipe. In considering the anchoring
requirements, this has to be regarded as a shock loading, and the appropriate
factor DLF on the steady state value used.

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For a more gradual pressure change, it is necessary to estimate the rate of
change of pressure. The out of balance force along a length of pipe between two
bends is then given by:

Note:
Although this force is proportional to the pipe length, it is subject to a maximum
value of the total pressure change × the cross sectional area.
In many cases, the frictional resistance between the pipe and the supports will be
significant compared with the above force. The frictional resistance between a
pipe and skid supports is proportional to the weight of the pipe plus contents.

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Equating equations 10 and 11, the maximum allowable rate of pressure rise to
avoid pipe movement is then given by:

A typical value for the coefficient of friction between the pipe and its supports is
0.2.
For a pipe supported on hangers rather than skids, there is no significant
frictional force, and any out of balance force will tend to result in some
movement. However, as the pipe swings on the hangers they will move away
from the vertical and thus exert a restraining force on the pipe. For a discussion
on the behavior of pipes supported on hangers when subjected to dynamic
forces is given contact GBH Enterprises..

11 GUIDELINES FOR CALCULATIONS
It is obviously impractical to perform a detailed surge analysis of every pipeline
on a plant. However, it is not always obvious which lines should be analyzed.
The guidelines in Table 3 were developed during discussions between the author
and other members of GBH Enterprises, and are proposed for use throughout
the company. In developing these guidelines, consideration was also given to the
practices within other major national/multinational organizations. Table 3 should
be read in conjunction with the more detailed explanations in the main body of
this Guide.
The ultimate responsibility for determining whether a surge analysis should be
carried out lies with the responsible engineer. If in doubt, a specialist should be
consulted for advice.

Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown
Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
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12

EXAMPLES OF PRESSURE SURGE INCIDENTS
12.1

Caustic Soda Pipeline Movement

An example which illustrates the generation of large out of balance forces
from vapor cavity collapse was experienced by a European Caustic
manufacturer in the 80’s. The incident occurred on the last section of a 6"
stainless steel line carrying aqueous caustic soda to a stock tank. The
pipeline is shown schematically in Figure 7.
There was an isolation valve approximately 75 m from the end of the pipe,
which then ran for 35!m horizontally on sliding supports, through a 90°
bend, along another 35 m of horizontal section supported on hangers and
finally up 5 m before discharging into the stock tank. The pipe was
anchored near to the isolation valve, and also to the tank near its
discharge, but only supported between these points, without lateral
restraint.
Although the exact cause of the incident is not certain, the most likely
explanation is that at some unknown time the isolation valve was closed
while the line was discharging to the tank. This would have resulted in the
formation of a vapor cavity downstream of the valve. The subsequent
collapse of this cavity sent a positive pressure surge back down the line to
the tank. The resulting out of balance force on the bend displaced the line
by about 0.15 m, severely distorting the supports and hangers.
Piping Section estimated that the force necessary to do the observed damage
was about 2 te, a figure that was in reasonable agreement with that calculated
from the results of a surge analysis. Points to note from this incident are:
(a)

The peak pressures calculated were well within the design pressure for
the piping system.

(b)

The pipe length was relatively short and discharged through an open end.

(c)

The problem occurred on the downstream side of a valve.

(d)

The pipe supports were not designed to cope with lateral forces.

(e)

Those involved before and after the incident had some knowledge of
pressure surge, as analyses had been done for other pipelines in the area,
but their state of knowledge before the incident would not have suggested
any need to model the particular pipe section.

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Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
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FIGURE 7

CAUSTIC SALES PIPELINE

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Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
12.2

Ammonia Pipe Movement
Liquid ammonia was held at low temperature in atmospheric pressure
storage tanks. It was pumped into the distribution network which was held
at 15 bar g pressure at ambient temperature. During hot weather ammonia
vaporized in the unlagged pipework, forming vapor pockets. Subsequent
pumping of cold liquid ammonia into the system caused the vapor to
condense, resulting in a pressure wave being transmitted along the pipe.
The pressure imbalance caused by the wave resulted in failure of the pipe
anchors and displacement of the pipe by 0.6 m.

12.3

Propylene Reactor Start-up
Liquid propylene was fed through restriction orifices into a reactor. In order
to assist start-up, propylene vapor rather than liquid was fed through a
side branch, the liquid line being closed. Inadvertent opening of the liquid
line caused the vapor pocket to collapse, allowing a very high liquid
velocity in the feed line. This flowrate could not be sustained through the
restriction orifice, and the resulting liquid hammer caused the non-return
valve to slam shut. The bolts on the valve cover stretched, allowing
propylene to jet from the broken joint.

12.4

Cooling Water Failure
The cooling water pump tripped on a large cooling water circuit on an
ammonia plant. During the short delay between the trip and the automatic
start-up of the stand-by pump a vapor pocket formed at an elevated heat
exchanger. The presence of the cavity allowed high flow from the stand-by
pump. Severe damage resulted from the water hammer which arose from
the cavity collapse.

12.5

Dry Riser Fire Sprinkler Systems
Many fire sprinkler systems are pressurized with gas to avoid freezing
during winter. In the event of a fire a sensor bulb bursts, allowing release
of the gas pressure. Loss of gas pressure triggers the fire pump, and
water is pumped into the system. High flows occur as the system fills with
water, but these cannot be sustained due to the restriction of the sprinkler
orifice. The resulting water hammer has led to the failure of a number of
fire systems.

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Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
12.6

Cast Iron Fire Main Pressurization
A cast iron fire main was kept under pressure by towns water. On fall of
pressure, the fire pump automatically started. The dead head pressure of
the pump was below the design pressure of the main. However, the runup time of the pump was much less than the pipeline period, so a pressure
rise of almost twice the dead head pressure of the pump arose. As a
result, the spigot and socket joints on the line were subject to frequent
failure.

Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown
Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
13

REFERENCES

1.

Thorley A R D, Enever K J. "Control and suppression of pressure surges
in pipelines and tunnels", Construction Industry Research and Information
Association. London 1979.

2.

Wylie E B, Streeter V L. "Fluid Transients" FEB Press, Ann Arbor,
Michigan, USA.

3.

Thorley A R D."Fluid Transients in Pipeline Systems." 1991. D & L George
Ltd. ISBN 0-9517830-0-9.

4.

“The VAULT” Technical Guide. GBH Enterprises.

5.

“The VAULT” User Manual. GBH Enterprises.

6.

HTFS Handbook Sheet FM13. "Pressure surges in a pipeline with liquid
flow due to valve closure." Smith R A, 1990.

7.

Miller D S. "Internal Flow Systems." 2nd edition (1990). BHRA. ISBN 0947711-77-5

Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown
Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown
Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
TABLE 1

BULK MODULUS OF ELASTICITY AND SONIC
VELOCITY FOR SOME LIQUIDS

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Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown
Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown
Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown
Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
Source References:
1.

M Rama Rao. 'Velocity of sound in some liquids and Chemical
composition.' Journal of Chemical Physics. Vol 9 September 1941, pp6825.

2.

A.R.D. Thorley & K.J. Enever. 'Control and suppression of pressure
surges in pipelines and tunnels.' CIRIA, 1979.

3.

J.J. Tuma. 'Handbook of physical correlations'. McGraw-Hill, 1983.

4.

Journal of Chemical Engineering Data. Volume 23 (3) 1978, page 194.

5.

A. Dibrov, V.P. Mashovets, R.P. Matveeva. 'The density and
compressibility of aqueous sodium hydroxide solutions at high
temperatures. Zh. Prikladnoi Khimii. Volume 37 (1) 1964. pp 29-36.

6.

R.T. Langman, C.H. Knowles. 'Velocity of compressional waves in liquid
hydrogen fluoride and some thermodynamic properties derived there
from.' Journal of the Chemical society. Volume 32 (2) 1960. p 561.

7.

The Handbook of Chemistry and Physics. The Rubber Company.

8.

G.W.C Kaye & T. H. Laby. 'Tables of Physical and Chemical Constants'.

9.

BHRA Report TN 411. Plinton.

10.

I.S. Pearsall. 'The velocity of water hammer waves.' Symposium on
surges in pipelines.

11.

F.W.Bridgeman. The physics of high pressure.

The author would be grateful for any additional data to supplement the
above list.

Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown
Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
TABLE 2

YOUNG'S MODULUS AND POISSON'S RATIO OF
SOME PIPE MATERIALS

Note:
GRP properties will vary according to the proportion of fibre, bonding material
and method of manufacture. Information from external consultants, suggests that
the very low values quoted in reference 3 may be most appropriate for certain
types of piping.
.
Source references:
1.

Thorley ARD, Enever KJ " Control & suppression of pressure surges in
pipelines and tunnels." CIRA report 84.

2.

Perry "Chemical Engineer's Handbook" (4th edition).

Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown
Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
TABLE 3

GUIDELINES FOR PRESSURE SURGE ANALYSIS OF
PIPING SYSTEMS

Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown
Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown
Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
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Introduction To Pressure Surge In Liquid Systems

  • 1. GBH Enterprises, Ltd. Process Engineering Guide: GBHE-PEG-FLO-305 Introduction to Pressure Surge in Liquid Systems Information contained in this publication or as otherwise supplied to Users is believed to be accurate and correct at time of going to press, and is given in good faith, but it is for the User to satisfy itself of the suitability of the information for its own particular purpose. GBHE gives no warranty as to the fitness of this information for any particular purpose and any implied warranty or condition (statutory or otherwise) is excluded except to the extent that exclusion is prevented by law. GBHE accepts no liability resulting from reliance on this information. Freedom under Patent, Copyright and Designs cannot be assumed. Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts / Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries Web Site: www.GBHEnterprises.com
  • 2. Process Engineering Guide: Introduction to Pressure Surge in Liquid Systems CONTENTS SECTION 0 INTRODUCTION/PURPOSE 3 1 SCOPE 3 2 FIELD OF APPLICATION 3 3 DEFINITIONS 3 4 CAUSES OF PRESSURE SURGE 3 4.1 Start-up 4 5 CONSEQUENCES OF PRESSURE SURGES 5 6 PRELIMINARY CALCULATIONS 5 6.1 6.2 Estimation of the Sonic Velocity Pipeline Period 5 7 7 CALCULATION OF PEAK PRESSURES 8 7.1 7.2 7.3 7.4 7.5 7.6 Rigid Liquid Column Theory Sudden Changes in Flowrate Moderately Rapid Changes in Flowrate Reflections and Attenuations Vapor Cavity Formation Complex Piping Systems 8 9 9 10 10 10 8 FORCES ON PIPE SUPPORTS 10 . Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts / Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries Web Site: www.GBHEnterprises.com
  • 3. 9 METHODS OF REDUCING THE EFFECTS OF PRESSURE SURGE 13 9.1 9.2 9.3 9.4 9.5 9.6 9.7 Flowrate Pipe Diameter Valve Selection and Operation Pump Start-up/Shut-down Surge Tanks and Accumulators Vacuum Breakers Changes to Equipment 13 13 13 16 16 17 18 10 DETAILED ANALYSIS 18 10.1 10.2 Data Requirements Interpretation of Results 18 19 11 GUIDELINES FOR CALCULATIONS 21 12 12.1 12.2 12.3 12.4 12.5 12.6 EXAMPLES OF PRESSURE SURGE INCIDENTS Caustic Soda Pipeline Movement Ammonia Pipe Movement Propylene Reactor Start-up Cooling Water Failure Dry Riser Fire Sprinkler Systems Cast Iron Fire Main Pressurization 21 21 22 23 23 23 23 Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts / Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries Web Site: www.GBHEnterprises.com
  • 4. 13 14 REFERENCES 24 NOMENCLATURE 25 TABLES 1 2 3 BULK MODULUS OF ELASTICITY AND SONIC VELOCITY FOR SOME LIQUIDS 26 YOUNG'S MODULUS AND POISSON'S RATIO OF SOME PIPE MATERIALS 30 GUIDELINES FOR PRESSURE SURGE ANALYSIS OF PIPING SYSTEMS 31 FIGURES 1 WAVESPEED IN PIPES FILLED WITH WATER 7 2 FORCES ON A PIPING SYSTEM IN STEADY STATE FLOW 11 FORCES ON A PIPING SYSTEM IN TRANSIENT FLOW 11 EFFECT OF VALVE CLOSURE TIME ON OUT-OF -BALANCE FORCES 13 EFFECT OF VALVE TYPE ON FLOWRATE DURING TRANSIENT FLOW 15 6 EFFECT OF VALVE TYPE ON SURGE PRESSURE 15 7 CAUSTIC SALES PIPELINE 22 3 4 5 Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts / Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries Web Site: www.GBHEnterprises.com
  • 5. 0 INTRODUCTION/PURPOSE This document is one of a series on fluid flow produced by GBH Enterprises. If a rapid change is made to the flowrate of a liquid in a piping system, for example by the operation of a valve, a transient pressure change will be propagated through the system. This transient pressure may be significantly greater than either the initial pressure or the final steady state pressure which the system reaches. This may cause damage to the piping system; either by exceeding the design pressure of the piping system with consequent risk of rupture, or by producing out of balance forces which are greater than can be sustained by the pipe supports. The phenomenon known as 'water hammer' is a special case of 'pressure surge'. 1 SCOPE This Guide provides an introduction for process engineers to the problems associated with pressure surge. It describes the causes of pressure surge and indicates how to make preliminary estimations of the likely magnitude of its effects. Methods of reducing the magnitude of the effects are discussed. Guidelines are given to help in assessing which piping system should be analyzed in detail and the data requirements to perform a detailed computer analysis of the system are given. Some examples are given of problems encountered by GBH Enterprises due to pressure surge. Tables 1, 2 and 3 contain some useful data to assist in surge calculations. This Guide is not a comprehensive treatise on pressure transients. More detailed information is available in standard texts on the subject, for example references 1, 2 and 3. This Guide does not give advice on the mechanical design of piping systems subjected to pressure surge, although it does indicate how to calculate the loads arising from pressure surge. 2 FIELD OF APPLICATION This Guide is of use to all process engineers and plant operating personnel in the GBH Enterprises world-wide, who may be involved in the specification, design or operation of equipment involving the flow of liquids in pipelines. Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts / Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries Web Site: www.GBHEnterprises.com
  • 6. 3 DEFINITIONS For the purposes of this Guide, the following definition applies: Joukowski Pressure or Joukowski Head 4 The initial change in pressure or liquid head associated with an instantaneous change in liquid velocity. CAUSES OF PRESSURE SURGE Any operation which can result in a rapid change in velocity is a potential cause of serious pressure surge. Typical operations include: (a) Rapid change in position, either closing or opening, of a control or isolation valve. (b) Opening of a safety valve or rupture of a bursting disc. (c) Starting or stopping of a pump. (d) Priming of an empty pipeline. (e) Unsteady flow generated by a reciprocating pump. (f) Rapid phase change, due to thermal effects, rapid chemical reaction or the collapse of a vapor cavity. Traditionally, process engineers have associated pressure surge problems almost exclusively with UPSTREAM effects following the RAPID closure of valves at the DOWNSTREAM end of LONG pipelines. It will be shown later that the magnitude of the initial surge resulting from a rapid valve closure is independent of the pipe length. The pipe length only influences what is meant by 'rapid'. The pressure rise associated with a slow closure of a valve does, however, depend on the pipe length. The effects DOWNSTREAM of a rapidly closed valve are also very important. The initial result is a reduction in pressure. This may be sufficient to reduce the absolute pressure below the vapor pressure of the liquid, whereupon a vapor cavity will form. Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts / Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries Web Site: www.GBHEnterprises.com
  • 7. The subsequent collapse of this cavity can give rise to severe problems, with high transient pressures and out of balance forces. Vapor cavity collapse is one of the most intractable problems in pressure surge analysis, and any system with the potential for cavity formation should be viewed with caution. 4.1 Start-up It is important to realize that during start-up and filling of piping systems the liquid velocities may be considerably greater than the maximum which may occur during normal operation, due to the reduced frictional resistances which may occur during this period. The associated potential for surge problems may be greater than during normal operation. 4.1.1 Vapor cavities At start-up it is quite possible that vapor cavities will be present at the high points of the system, which will collapse as the system is pressurized. 4.1.2 Gas pockets Gas pockets may reduce fluid friction and allow much higher velocities than occur in normal full liquid operation. The deceleration of the liquid by the gas compression can lead under certain circumstances to very high gas pressures and temperatures. Explosive ignition of flammable mixtures has been known. 4.1.3 Venting The volumetric flow of a gas through an orifice is considerably greater than that of a liquid for the same pressure drop. When venting gas from a system, high flowrates can occur, which cannot be maintained when the gas has been expelled; a sudden flow reduction occurs, resulting in pressure surge. Specific examples include priming distributors in columns and batch blowing in systems with valves at the downstream end of the line. 4.1.4 Fast Pressurization Fast pressurization of a closed system can double the pressure rise at the far end of the system as the pressure wave is reflected from the closed end. This can arise either from the fast opening of a valve at the inlet end of the system or pump start-up with the pump discharge valve open. Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts / Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries Web Site: www.GBHEnterprises.com
  • 8. 5 CONSEQUENCES OF PRESSURE SURGES Usually, the initial reason for investigating the possibility of pressure surge is a concern that the design pressure of the piping system may be exceeded. Another problem, not always appreciated, is that even if the surge pressure is within the design pressure, a surge may result in the creation of large out-of-balance forces within the piping system. These may damage the supports, or in the extreme, cause the collapse of pipe bridges. The resulting displacement of the pipes may be sufficient to cause failure through bending, or might result in a branch pipe being torn off due to impact when the main pipe is displaced. This may extend to other pipes on the same pipe bridge which are not themselves subject to pressure surge. Experiences indicate that failure of pipework supports as a result of pressure surge is more likely than pipeline rupture due to over-pressure. Some examples of pressure surge incidents are given in Clause 12. 6 PRELIMINARY CALCULATIONS Detailed pressure surge analysis of most piping systems is a complex and lengthy operation, usually involving the use of a computer program, and is beyond the scope of this Guide. However, some simple preliminary calculations are possible in order to estimate the likely magnitude of any effects. These may show that no significant problem exists, or may indicate the need for a more detailed study. Guidelines for determining whether piping systems require detailed analysis are given in Table 3. 6.1 Estimation of the Sonic Velocity Pressure surges are propagated through a piping system at the local sonic velocity. An estimation of this is basic to all calculations. In a rigid pipe, pressure disturbances will propagate at the basic sonic velocity for the fluid, which is given by: Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts / Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries Web Site: www.GBHEnterprises.com
  • 9. Dissolved gases have little effect on the sonic velocity, provided they remain in solution. Even small traces of undissolved gas reduce the sonic velocity dramatically, and will greatly reduce the magnitude of pressure surges. However, it is very difficult to quantify such effects, and it is recommended that such benefits be ignored when assessing a system for potential surge damage. The bulk modulus of elasticity is not readily obtainable for many liquids. It is not an item which is stored in the GBH Enterprises; “The VAULT” physical properties data bank. Some commercially available programs purport to calculate the speed of sound in liquids, but the method used is of doubtful validity. It should not be used. Table 1 gives typical values of bulk modulus of elasticity and sonic velocity for some liquids. Note that different sources may give significantly different values for these properties. The most extreme case known to the author is for liquid HF, where the sonic velocity calculated from the bulk modulus obtained from one source differs by a factor of 3 from another source's claimed direct measurement of sonic velocity. In general, a higher assumed value for the sonic velocity can be expected to lead to predictions of higher surge pressures. The velocity of propagation of a pressure wave in a thin walled elastic pipe is lower than the sonic velocity in a rigid pipe, and can be calculated from: Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts / Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries Web Site: www.GBHEnterprises.com
  • 10. The value of B depends on the method of pipe support and the Poisson ratio of the pipe material. When the Young's Modulus, E, is large, as for metal pipes, the numerical value of B may be taken as unity without significant error. In other cases, B may be calculated from: Values of Young's Modulus and Poisson's ratio for some common materials are given in Table 2. The reduction in velocity due to the elasticity of the pipe is normally relatively small for metal pipes, but can be considerable with plastic pipes. Figure 1, which is taken from reference 4, shows the effects of pipe material and wall thickness on the velocity of propagation of a pressure wave in a water filled pipe. Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts / Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries Web Site: www.GBHEnterprises.com
  • 11. FIGURE 1 WAVESPEED IN PIPES FILLED WITH WATER Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts / Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries Web Site: www.GBHEnterprises.com
  • 12. 6.2 Pipeline Period The magnitude of the initial pressure transient associated with a change in flowrate depends on whether the change can be regarded as 'fast' or 'slow'. In this context, the terms 'fast' and 'slow' are relative rather than absolute, and are related to a quantity known as the 'pipeline period', t*. This is the time that elapses between initiation of the change and the return of the reflected surge from the end of the pipeline to the point of initiation (see below). Thus: where L is the length of the pipeline from the source of the disturbance to the end of the pipe (m) and c is the velocity of propagation of the pressure wave (m/s). There will be two pipeline periods associated with a single pipe having a valve part way down it; one will be based on the upstream length and one on the downstream length. 7 CALCULATION OF PEAK PRESSURES 7.1 Rigid Liquid Column Theory If the velocity of a liquid in a pipeline is changed gradually and steadily, such that the change takes place over more than about 10 pipeline periods, the simplifying assumptions can be made that the rate of change of velocity is the same at all points along the pipeline. Compressibility effects can be ignored and the liquid treated as a rigid column. Pressure changes can then be calculated by considering the momentum effects. For the upstream side of the disturbance: Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts / Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries Web Site: www.GBHEnterprises.com
  • 13. Similarly, for the downstream side of the disturbance: Note: The above approach assumes that the rate of change of velocity is reasonably uniform. Most types of valve have non-linear characteristics, some very much so such that most of the effect occurs over the last 10-20% of closure. The effective closure times of these valves are thus considerably less than the nominal times. This has to be remembered when determining if the closure can be considered 'slow'. Note also that the effects are very much dependent on valve size, with much better performance being obtained when small valves are used in large lines. See sub clauses 9.3.2.1, 9.3.2.2 and figures 5 and 6. 7.2 Sudden Changes in Flowrate. Any change in flowrate which is completed in under one pipeline period can be considered instantaneous as far as the initial pressure transient is concerned. Note that for a long pipeline, this time could be quite significant. For example, if the sonic velocity is 1000 m/s and the pipeline is 10 km long the pipeline period will be 20 seconds. A valve which closes in 15 s will have the same effect as one which closes in 1 s. Rigid column theory can only safely be applied to this system if the closure time exceeds 200 s. Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts / Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries Web Site: www.GBHEnterprises.com
  • 14. When the velocity at any point in a pipe carrying liquid is suddenly changed, for example by the closure of a valve, a pressure wave is propagated from that point along the pipe. The magnitude of the initial pressure change is given by the formulae: This pressure change is usually known as the Joukowski Pressure, or, if expressed in terms of a head of the liquid, the Joukowski Head. Note that the equations do not include the length of the pipeline. The same value will be obtained in a short pipe as in a long one, provided the closure is sufficiently rapid to occur within one pipeline period. If the disturbance is caused by the sudden closure of a valve, the upstream pressure will initially increase by the Joukowski Pressure, whereas the downstream pressure will decrease by this amount. Conversely, the sudden opening of a valve will produce a fall in upstream pressure and a rise in downstream pressure. When a liquid is flowing down a pipeline there is a reduction in pressure along the line due to frictional effects. When the liquid has been brought to rest following the closure of a valve at the end of the line this frictional loss no longer occurs. The pressure at the valve initially rises rapidly by the Joukowski Pressure. Then, over the next pipeline period, it continues to rise gradually by an amount equal to the original frictional loss. Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts / Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries Web Site: www.GBHEnterprises.com
  • 15. 7.3 Moderately Rapid Changes in Flowrate If a change in flowrate takes place over an interval between one and ten pipeline periods, neither the rigid liquid column method nor the Joukowski Head calculation is strictly applicable. For simple unbranched systems it is possible to estimate the magnitude of the peak pressure by a stepwise manual method, as explained in reference 6, but the procedure is quite involved. If the calculation of the Joukowski Head indicates the possibility of problems, it is generally preferable to perform a detailed computer analysis. 7.4 Reflections and Attenuations When a pressure surge reaches the end of a pipeline, it is reflected back down the line. If the end of the pipe is open, the magnitude of the reflection is the same as the incident surge, but the sign is reversed. Thus a positive pressure surge is reflected as a rarefaction, and vice versa. When a surge reaches a closed end, the reflected surge has double the incoming magnitude. Because of these reflections, alternate pressure and rarefaction surges pass up and down the line, being reflected from each end. Due to friction effects, the magnitude of the surges gradually dies away. 7.5 Vapor Cavity Formation If the static pressure in the system falls below the vapor pressure at any point, a vapor cavity will tend to form, which will continue to grow all the while the pressure remains low. Subsequent positive pressures will cause the cavity to collapse. This will lead to a large abrupt pressure surge as the cavity is condensed. Experience shows that this is one of the most severe problems to deal with. If preliminary calculations indicate that cavity formation is likely, a more detailed analysis is recommended. 7.6 Complex Piping Systems For a branched piping system, or one including several high points where vapor cavity formation may occur, reflections will occur off the ends of each pipeline, and vapor cavities will collapse in differing times. The result is a very complex pressure/time history, which cannot sensibly be analyzed by hand calculations. Computer analysis of the system is then essential if preliminary calculations give any indication of potential problems. Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts / Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries Web Site: www.GBHEnterprises.com
  • 16. 8 FORCES ON PIPE SUPPORTS A flowing fluid has the potential to exert a force on account of its pressure and its momentum. The potential force of a fluid in a pipe, acting in the direction of the flow, is given by: When a fluid is flowing in steady flow through a pipeline, as it approaches a bend, it will exert a force on that bend, equal to the potential force in the direction at which it approaches the bend. After flowing round the bend, it will exert a backward force of the same magnitude in the new direction of flow. The resultant force acts outwards on the bend in a direction bisecting the angle of the bend. Thus for a 90° bend, the resulting force (F') is given by: . The force on the bend is restrained by the tension in the pipe. As the fluid flows along the straight lengths between bends, its pressure falls due to the effects of friction, thus reducing F, but the corresponding reduction in tension in the pipe is balanced by the shear forces on the wall. There is thus no net force on the pipework, except on the last bend before the discharge from the pipe, where there is a backward force F along the direction of the pipe. See Figure 2. Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts / Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries Web Site: www.GBHEnterprises.com
  • 17. FIGURE 2 FORCES ON A PIPING SYSTEM IN STEADY STATE FLOW However, if a pressure transient is passing through the piping system, the forces on the pipework are no longer in balance. Consider the section of pipe shown in FIGURE 3 FORCES ON A PIPING SYSTEM IN TRANSIENT FLOW Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts / Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries Web Site: www.GBHEnterprises.com
  • 18. Assume that the valve is closed suddenly. A transient will pass back up the pipe from the valve at the sonic velocity. On the valve side of the transient, the fluid will have been brought to rest and the pressure will be greater than the initial pressure by the Joukowski Pressure for the system, ρ.c.v. Upstream of the transient, the fluid will still be travelling with the original velocity and pressure. Consider the length of pipe between the two bends in Figure 3, when the transient is somewhere between the bends, and ignore the effects of friction. The force along the pipe from the upstream bend is then: In the simple system considered here, where the pressure remains at the higher value for a significant time after the transient has passed, this force will act for a time Δt, the time taken for the pressure transient to pass along the length of pipe between the two bends: For more complex systems, involving multiple reflections and vapor cavity collapses, for example, a very complex pressure/time response may occur, and the duration of a high pressure may be shorter than that taken for the transient to pass between the two bends. When analyzing the forces on the piping system it is necessary to consider both the magnitude and duration of the forces. Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts / Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries Web Site: www.GBHEnterprises.com
  • 19. For a sudden pressure rise, the effect of these forces cannot be considered as equivalent to steady state forces. It is generally necessary to apply a multiplying factor, the Dynamic Load Factor or DLF, to the calculated shock loading when performing a dynamic pipeline support analysis. The magnitude of this factor depends on the nature of the pipe supports, and the duration of the force in relation to the natural frequency of the piping system. The DLF can be up to a value of 2 for rigidly anchored systems with a relatively long force duration. Conversely, for short duration pressure pulses in flexible (low frequency) pipes the dynamic load factor on supports can be much less than unity. Consult a piping engineer for advice. For more information on the mechanical aspects of designing pipework for pressure surge, Visit us at www.gbhenterprises.com. If the valve is closed gradually rather than suddenly, not only will the magnitude of the surge pressure be reduced, but the pressure will rise gradually rather than in a stepwise fashion. The effect of this is to reduce significantly the magnitude of the out of balance forces. This is illustrated in Figure 4. FIGURE 4 EFFECT OF VALVE CLOSURE TIME ON OUT-OF-BALANCE FORCES Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts / Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries Web Site: www.GBHEnterprises.com
  • 20. 9 METHODS OF REDUCING THE EFFECTS OF PRESSURE SURGE Pressure surges occur because a rapid change in liquid flowrate is imposed on the system. Surge reduction methods work by reducing the magnitude of this change or increasing the time over which it occurs. They usually rely either on reducing the rate at which the primary event causing the surge (e.g. valve closure) occurs, or providing an alternative source or sink for the liquid in the form of a surge tank or accumulator. 9.1 Flowrate For most pipelines, the required flowrate is determined by the process. However, for some operations, such as the batchwise transfer of liquid from one vessel to another, it may be possible to increase the transfer time, thus reducing the flow velocity. Closure of the system valves will then produce a smaller change in velocity, and hence a reduced surge pressure. 9.2 Pipe Diameter Increasing the diameter of a pipeline for a given flowrate will reduce the velocity, and hence the peak surge pressure. However, this approach is likely to be expensive compared with the alternatives. Moreover, although it will reduce the magnitude of the peak pressure, the out-of balance forces will remain substantially the same, as the reduction in pressure is balanced by an increase in pipe cross sectional area. This method will not be considered further here. 9.3 Valve Selection and Operation 9.3.1 Isolation valves The unthinking operation of an isolation valve when the liquid is flowing in the pipeline can have serious consequences, especially as many types of isolation valve can be closed very rapidly, for example with a quarter turn of a handle. If the surge analysis indicates that this is unacceptable, some action will be necessary to prevent this happening. An operating procedure may be considered adequate for this purpose, but in general some physical constraint is preferable. It may be necessary to remove the operating handles from key valves, or provide them with locks. An alternative is to fit them with gear drives with low ratios, such that very many turns are required to operate the valves. Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts / Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries Web Site: www.GBHEnterprises.com
  • 21. For some designs of butterfly valve, the forces on the disk from the flowing liquid tend to turn the valve into the closed position, particularly when the valve is initially in the partially closed position. This may result in the inadvertent rapid closure of the valve, and it may be necessary to provide some physical constraint to prevent this happening. 9.3.2 Control valves 9.3.2.1 Stroke time Where the process demands permit it, the speed of closure of a control valve may be reduced by selection of a suitable actuator. Certain types of valve, particularly butterfly and ball valves, have unfavorable characteristics from the point of pressure surge, as most of their effect occurs over the last few percent of the closure. For these valves, a split range actuator may be useful. This will have a rapid rate of closure over the part of the characteristic where flowrate does not vary much with valve position, and a slower response during the last stages of closure. 9.3.2.2 Valve type As has been stated before, some valve types have better characteristics than others from the point of view of pressure surge. Where piping specifications permit, a change in valve type may have significant effects on the magnitude and rapidity of pressure changes in the system. In order to illustrate this, a model of a simple piping system has been set up using the “The Vault” (see Clause 10). The system modeled consists of a feed tank, a pump, a length of pipeline with a pipeline period of 2 seconds, a control valve and a receiving tank. Five different valve characteristics (loss coefficient as a function of valve position) have been simulated, with a valve closure time of 10 seconds in each case. The valve types used were: • A diaphragm valve (Saunders type K). • A reduced bore ball valve. • A butterfly valve. • A control valve with nominally linear characteristics. • A control valve with nominally equal percentage characteristics. Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts / Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries Web Site: www.GBHEnterprises.com
  • 22. Figure 5 shows the variation of flowrate with time for the five valve types. It can be seen that over most of the closure, the equal percentage valve gives the most gradual change in flowrate. However, towards the end of the closure, there is a rapid change in flow. This is because the characteristic used represents a real valve, (Taylor Instruments, ideal rangeability 40:1, practical rangeability 20:1) which only exhibits equal percentage characteristics over the major portion of its range. Indeed, an ideal equal percentage valve would never shut off completely. At the other extreme the 'K' type diaphragm valve has very little effect on the flow for the first 90% of the closure, followed by a very rapid reduction in flow, giving an effective closure time of only about 1 second in this case. FIGURE 5 EFFECT OF VALVE TYPE ON FLOWRATE DURING TRANSIENT FLOW Figure 6 shows the corresponding pressures resulting from the different valve closures. It can be seen that the diaphragm valve gives both the highest peak pressures, and the most rapid rate of change. The equal percentage valve gives the lowest pressure rise, but note the rapid rate of rise occurring at the end of the closure, as the valve departs from ideal behavior. Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts / Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries Web Site: www.GBHEnterprises.com
  • 23. FIGURE 6 EFFECT OF VALVE TYPE ON SURGE PRESSURE It should be emphasized that these two Figures are illustrative only. The actual magnitude of the differences between different valve types will depend on the system. The effects of valve size should also be considered; a large valve will have worse characteristics than a small one of the same type, as the initial stages of closure of a large valve result in little extra flow resistance and hence little change in flow rate. It cannot be concluded that an equal percentage valve will always give the best results. 9.3.3 Emergency shut-down valves Emergency shut-down valves may be required to operate very rapidly. However, it is always worth considering the safety consequences of increasing the closure time. Alternatively, a change in valve type, as discussed above, may produce a reduced pressure surge with the same overall closure time. Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts / Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries Web Site: www.GBHEnterprises.com
  • 24. 9.4 Pump Start-up/Shut-down It is in general bad practice to start up a pump with an open delivery valve into a long piping system. The preferred arrangement is to have a recycle line from the pump delivery to the feed tank sized to give the minimum acceptable flowrate for the pump (a 'kick-back' line), and an isolation valve at the start of the main system. When the pump is up to speed, this valve may be opened in a slow, controlled fashion to divert the flow into the main piping system. For critical applications, where there are likely to be vapor cavities present at start-up, it is recommended that a small bore bypass be installed round the main discharge valve to ensure that the line is started up under well defined low flow conditions. The practice of 'cracking valves' open to restrict flowrate is unsafe. Pump shut-downs should also be done in a controlled manner. Unfortunately, this is not always possible, as power failures, for example, can result in a pump trip. It may be possible to increase the run-up time of a pump by choice of a suitable motor. There are now control systems available which allow the start-up to take place over an extended period, say 2 minutes. These have been used successfully in many locations. Alternatively, addition of a flywheel to the pump drive will increase both run-up and run-down times. The motor will obviously have to be suitable to deal with the higher inertia. Unfortunately, this approach is not possible with a canned pump. Note: The use of a non-return valve on a pump delivery may itself be a cause of pressure surges. 9.5 Surge Tanks and Accumulators If the methods described above are not suitable to prevent surge problems, the use of a surge tank or accumulator may be required. These devices operate by providing an alternative source or sink for the liquid, enabling, for example, a key valve to be opened or closed rapidly while allowing the flow in the pipeline to be increased or reduced in a more gradual and controlled manner. To be most effective, these devices should be connected to the piping system close to the source of the flow disturbance, e.g. the control valve which has been identified as the cause of the surge. If there is more than one potential cause of surge, several surge tanks or accumulators may be needed, one at the location of each potential source. Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts / Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries Web Site: www.GBHEnterprises.com
  • 25. 9.5.1 Surge tanks A surge tank consists of a vertical cylindrical tank mounted at some suitable point along the line. The tank is open to the atmosphere at the top, and is placed so that its top is higher than the steady state head at that point. It has to have sufficient capacity such that it will not be drained or over-filled by the highest flow that might occur during a transient. Because they are open to the atmosphere, surge tanks are not generally used in the chemical industry, but they are common in the water supply and hydro-electric industries. 9.5.2 Accumulators An accumulator is a closed vessel, partly filled with gas, which is connected to the pipeline at a suitable point. The gas acts as a cushion which absorbs some of the pressure surges passing along the pipe by allowing some of the flow to be diverted into or out of the accumulator. Accumulators are common on reciprocating pumps, where they reduce the pressure fluctuations. They may be located on the suction side, delivery side or both, depending on the perceived problems. Like surge tanks, accumulators have to be sized to allow for the magnitude of the flows. This may make them large and prohibitively costly for high flow lines. The main disadvantage of accumulators apart from cost is the problem of ensuring that they are in a suitable condition to operate when required. If the gas is in direct contact with the liquid it may dissolve over a period of time, and some means of checking for this is necessary. Some designs of accumulator get round this by the use of a bladder or diaphragm. However, there is always a danger that the diaphragm may rupture. It may not be easy to determine if this has happened. It may also be difficult to find a material for the diaphragm which is compatible with the chemicals being handled. An alternative to the diaphragm is to separate the liquid and gas by a piston. Here there is a danger that corrosion of the piston or cylinder, or dirt in the process fluid, may cause the piston to stick. The gas space above the cylinder will normally be pre-pressured to a pressure above the normal operating pressure of the system, resulting in the piston being in its fully extended position. It is normal to mount a pressure gauge on the gas side of the piston to ensure that it is properly charged. Regular checking of this pressure and topping up when necessary is essential to maintain the integrity of the system. Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts / Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries Web Site: www.GBHEnterprises.com
  • 26. Note: A piston type accumulator may itself be a cause of vapor cavity formation. The gas behind the piston has to be initially pressurized above the system pressure or the position of the cylinder is indeterminate. However, following a surge incident the liquid will be forced out of the cylinder by the gas pressure. This liquid outflow may stop abruptly when the piston reaches its lower limit, giving a negative pressure wave. It is a regrettable fact that the maintenance of accumulators is often neglected. For this reason, they are not recommended as the primary safety device where the consequences of failure to operate are unacceptable. If it does prove unavoidable to use them in such circumstances, it is essential that suitable maintenance procedures are implemented and can be demonstrated. Inspection of accumulators should be included in safety inspection routines. 9.6 Vacuum Breakers If a pipeline passes through a high point, during shut-down conditions the pressure at that point may fall below the vapor pressure and a vapor cavity may form. When flow is re-started in the line, this cavity will collapse and initiate a pressure surge. Ideally, pipelines should be routed to avoid such high points, but this is rarely possible in practice. If a vacuum breaking valve is installed at the high point, the vapor cavity will be replaced by an air pocket. When the flow is re-started in the line, this air pocket will compress, gradually accelerating the liquid column ahead of it and reducing the surge. The air pocket acts in effect like an accumulator. This approach is obviously only applicable where ingress of air into the liquid line is acceptable. It has been recommended to alleviate surge problems on aqueous caustic soda lines. The approach could in principle be modified to let an inert gas such as nitrogen into the liquid line, provided that the gas does not cause problems when it is passed through the system. This obviously results in a more complex system, and the observations on maintenance given in 9.5.2 also apply. Note: Air venting valves, which are sometimes installed at the high points of pipelines to remove air during start-up, are themselves a potential cause of surge. See 4.1.3. Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts / Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries Web Site: www.GBHEnterprises.com
  • 27. 9.7 Changes to Equipment As an alternative to reducing the magnitude of a surge, it may be worth considering whether the design rating of the piping system could be increased. The design pressure of a piping system may be dictated not by the pipe wall thickness or the flange rating, but by the pressure rating of a valve or instrument in the pipeline. Changes here, particularly if made at the design stage, may enable rapid valve closures to occur without exceeding the design pressure. However, remember that not only the piping but also the supports have to be designed to handle the effects of the surge. Conversely, applying one of the surge alleviation techniques above may permit the use of a lower design pressure for the pipeline. Analysis on a new boat loading installation in 1987, involving a long 10" stainless steel line, showed that the slowing of a valve closure would enable thinner piping to be used, with a saving of $36,000. 10 DETAILED ANALYSIS The preliminary hand calculations described in Clauses 6-8 can give an estimate of the likely magnitude of a pressure surge, but if these indicate a possible problem, (for example, predicted Joukowski Pressure close to the design pressure, the potential to form vapor cavities, or large predicted out of balance forces), expert advice should be sought. The analysis of all but the simplest systems requires the use of a computer program. Experience is necessary to obtain the best results from these programs, and to interpret the answers. There are sources of specialist advice and assistance with modeling pressure surge within GBH Enterprises. Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts / Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries Web Site: www.GBHEnterprises.com
  • 28. 10.1 Data Requirements In order to perform a complete pressure surge analysis, a significant quantity of data is required. Much of this will be readily available for a normal project, but certain items are less likely to be known. The following is a list of the ideal data requirements. In practice, not all the data may be available, and reasonable guesses may have to be made for the missing items, based on typical values for similar items. Reference 7 is a good source of pressure drop data for many pipeline components. (a) Density of the process liquid at operating conditions. (b) Vapor pressure of the liquid at normal operating temperature. This is needed to determine the conditions under which vapor cavity formation is likely. (c) Bulk modulus of elasticity of the liquid. This is the inverse of the compressibility. Combined with information on the pipe wall thickness, it is used to determine the speed of propagation of a pressure wave in the piping system, using equation (2). This property is not easy to find. Values for some liquids are given in Table 1, but for other liquids it will probably be necessary to consult a physical properties specialist for assistance. In the absence of any reliable data, an estimate of the wave speed will have to be made by analogy with similar liquids. (d) An isometric drawing of the pipeline installation, including all valves and other fittings, and giving pipe lengths and elevations. It is not necessary for lengths to be highly accurate. When doing the analysis, the pipeline will be divided up into sections corresponding to the distance travelled by a pressure wave in one time-step, and some rounding of the data will be necessary to ensure an integer number of these sections. Section lengths in a typical analysis might be 10 to 50 meters. The relative elevations should be given with reasonable accuracy, as they influence the formation of vapor cavities. (e) The pipe diameter, wall thickness and Young's modulus of the pipe material. These items are needed, along with the liquid compressibility, to determine the speed of propagation of a pressure wave (equation (2)). (f) The liquid level and pressure above the liquid in all tanks connected to the piping system. Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts / Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries Web Site: www.GBHEnterprises.com
  • 29. (g) For each valve which is to be considered as a potential cause of pressure surge, the valve resistance (K value), as a function of position. Ideally, the data should be obtained from the manufacturer, especially for control valves. Standard data are available for certain valve types, which can be used in the absence of manufacturer's data. (h) For each valve, the position as a function of time. Often only a closure time is known. In such cases, the position has to be assumed to vary linearly with time. It is possible to provide a valve actuator with a nonlinear characteristic; this can be useful for valves such as butterfly and ball, where most of the effect occurs in the last part of the closure. (j) For all other fittings, including isolation valves which are not operated when fluid is flowing, a resistance expressed as a K value (which has to include the diameter on which the K value is based). Note that the experts running the analyses can usually provide these data for most common fittings, provided the type is known. (k) Pump data. During the course of a pressure transient, the differential pressure across a pump, and hence the flowrate through it, will change. If the effects of pump start-up and shut-down are not to be modeled, only the pump characteristic curves (flowrate against differential head) are necessary. If start-up and shut-down are to be modeled, several other items of data are required, which are less readily available. These are: the moment of inertia of the pump and drive assembly; the friction torque; the speed/torque characteristics of the motor. Machines Sections should be approached for these data. The boundaries for an analysis are normally vessels which either feed the piping system or receive liquid from it, and which can be regarded as regions of constant pressure. It is not possible to analyze a section of pipework in the middle of an existing piping system without also considering the pipes to which it is connected. Thus if a section of a pipe is to be re-routed, for example, the complete system from supply vessel to outlet has to be analyzed. Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts / Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries Web Site: www.GBHEnterprises.com
  • 30. 10.2 Interpretation of Results A computer simulation of a surge problem generates a large quantity of data. A typical relatively simple analysis might have 20 piping components and 15 nodes. The analysis might run for 20 seconds with a time step of 0.005 seconds, producing results at 4000 time steps. It is usual to produce most of the answers in graphical form, giving values of the parameters of interest as a function of time. When considering the mechanical design of the piping system, the items of most interest are the maximum (and for lined pipes, the minimum) pressures, and the out-of-balance forces. Pressures are obtainable directly from “The VAULT” results. The estimation of the magnitude and effect of the out-of-balance forces cannot be obtained directly from the “The VAULT” output, but can be inferred from the results. Vapor cavity collapse generally results in a step change in pressure, whereas other surge events may give a more gradual, but still rapid, change. Because of the calculation methods used by “The VAULT”, any pressure change which takes place over a single time step is considered as instantaneous. For an instantaneous pressure change, the magnitude of the out-of-balance forces at each pipe bend can be estimated as the product of the pressure change and the pipe cross sectional area. This force will act along the axis of the pipe. In considering the anchoring requirements, this has to be regarded as a shock loading, and the appropriate factor DLF on the steady state value used. Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts / Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries Web Site: www.GBHEnterprises.com
  • 31. For a more gradual pressure change, it is necessary to estimate the rate of change of pressure. The out of balance force along a length of pipe between two bends is then given by: Note: Although this force is proportional to the pipe length, it is subject to a maximum value of the total pressure change × the cross sectional area. In many cases, the frictional resistance between the pipe and the supports will be significant compared with the above force. The frictional resistance between a pipe and skid supports is proportional to the weight of the pipe plus contents. Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts / Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries Web Site: www.GBHEnterprises.com
  • 32. Equating equations 10 and 11, the maximum allowable rate of pressure rise to avoid pipe movement is then given by: A typical value for the coefficient of friction between the pipe and its supports is 0.2. For a pipe supported on hangers rather than skids, there is no significant frictional force, and any out of balance force will tend to result in some movement. However, as the pipe swings on the hangers they will move away from the vertical and thus exert a restraining force on the pipe. For a discussion on the behavior of pipes supported on hangers when subjected to dynamic forces is given contact GBH Enterprises.. 11 GUIDELINES FOR CALCULATIONS It is obviously impractical to perform a detailed surge analysis of every pipeline on a plant. However, it is not always obvious which lines should be analyzed. The guidelines in Table 3 were developed during discussions between the author and other members of GBH Enterprises, and are proposed for use throughout the company. In developing these guidelines, consideration was also given to the practices within other major national/multinational organizations. Table 3 should be read in conjunction with the more detailed explanations in the main body of this Guide. The ultimate responsibility for determining whether a surge analysis should be carried out lies with the responsible engineer. If in doubt, a specialist should be consulted for advice. Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts / Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries Web Site: www.GBHEnterprises.com
  • 33. 12 EXAMPLES OF PRESSURE SURGE INCIDENTS 12.1 Caustic Soda Pipeline Movement An example which illustrates the generation of large out of balance forces from vapor cavity collapse was experienced by a European Caustic manufacturer in the 80’s. The incident occurred on the last section of a 6" stainless steel line carrying aqueous caustic soda to a stock tank. The pipeline is shown schematically in Figure 7. There was an isolation valve approximately 75 m from the end of the pipe, which then ran for 35!m horizontally on sliding supports, through a 90° bend, along another 35 m of horizontal section supported on hangers and finally up 5 m before discharging into the stock tank. The pipe was anchored near to the isolation valve, and also to the tank near its discharge, but only supported between these points, without lateral restraint. Although the exact cause of the incident is not certain, the most likely explanation is that at some unknown time the isolation valve was closed while the line was discharging to the tank. This would have resulted in the formation of a vapor cavity downstream of the valve. The subsequent collapse of this cavity sent a positive pressure surge back down the line to the tank. The resulting out of balance force on the bend displaced the line by about 0.15 m, severely distorting the supports and hangers. Piping Section estimated that the force necessary to do the observed damage was about 2 te, a figure that was in reasonable agreement with that calculated from the results of a surge analysis. Points to note from this incident are: (a) The peak pressures calculated were well within the design pressure for the piping system. (b) The pipe length was relatively short and discharged through an open end. (c) The problem occurred on the downstream side of a valve. (d) The pipe supports were not designed to cope with lateral forces. (e) Those involved before and after the incident had some knowledge of pressure surge, as analyses had been done for other pipelines in the area, but their state of knowledge before the incident would not have suggested any need to model the particular pipe section. Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts / Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries Web Site: www.GBHEnterprises.com
  • 34. FIGURE 7 CAUSTIC SALES PIPELINE Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts / Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries Web Site: www.GBHEnterprises.com
  • 35. 12.2 Ammonia Pipe Movement Liquid ammonia was held at low temperature in atmospheric pressure storage tanks. It was pumped into the distribution network which was held at 15 bar g pressure at ambient temperature. During hot weather ammonia vaporized in the unlagged pipework, forming vapor pockets. Subsequent pumping of cold liquid ammonia into the system caused the vapor to condense, resulting in a pressure wave being transmitted along the pipe. The pressure imbalance caused by the wave resulted in failure of the pipe anchors and displacement of the pipe by 0.6 m. 12.3 Propylene Reactor Start-up Liquid propylene was fed through restriction orifices into a reactor. In order to assist start-up, propylene vapor rather than liquid was fed through a side branch, the liquid line being closed. Inadvertent opening of the liquid line caused the vapor pocket to collapse, allowing a very high liquid velocity in the feed line. This flowrate could not be sustained through the restriction orifice, and the resulting liquid hammer caused the non-return valve to slam shut. The bolts on the valve cover stretched, allowing propylene to jet from the broken joint. 12.4 Cooling Water Failure The cooling water pump tripped on a large cooling water circuit on an ammonia plant. During the short delay between the trip and the automatic start-up of the stand-by pump a vapor pocket formed at an elevated heat exchanger. The presence of the cavity allowed high flow from the stand-by pump. Severe damage resulted from the water hammer which arose from the cavity collapse. 12.5 Dry Riser Fire Sprinkler Systems Many fire sprinkler systems are pressurized with gas to avoid freezing during winter. In the event of a fire a sensor bulb bursts, allowing release of the gas pressure. Loss of gas pressure triggers the fire pump, and water is pumped into the system. High flows occur as the system fills with water, but these cannot be sustained due to the restriction of the sprinkler orifice. The resulting water hammer has led to the failure of a number of fire systems. Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts / Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries Web Site: www.GBHEnterprises.com
  • 36. 12.6 Cast Iron Fire Main Pressurization A cast iron fire main was kept under pressure by towns water. On fall of pressure, the fire pump automatically started. The dead head pressure of the pump was below the design pressure of the main. However, the runup time of the pump was much less than the pipeline period, so a pressure rise of almost twice the dead head pressure of the pump arose. As a result, the spigot and socket joints on the line were subject to frequent failure. Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts / Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries Web Site: www.GBHEnterprises.com
  • 37. 13 REFERENCES 1. Thorley A R D, Enever K J. "Control and suppression of pressure surges in pipelines and tunnels", Construction Industry Research and Information Association. London 1979. 2. Wylie E B, Streeter V L. "Fluid Transients" FEB Press, Ann Arbor, Michigan, USA. 3. Thorley A R D."Fluid Transients in Pipeline Systems." 1991. D & L George Ltd. ISBN 0-9517830-0-9. 4. “The VAULT” Technical Guide. GBH Enterprises. 5. “The VAULT” User Manual. GBH Enterprises. 6. HTFS Handbook Sheet FM13. "Pressure surges in a pipeline with liquid flow due to valve closure." Smith R A, 1990. 7. Miller D S. "Internal Flow Systems." 2nd edition (1990). BHRA. ISBN 0947711-77-5 Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts / Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries Web Site: www.GBHEnterprises.com
  • 38. Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts / Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries Web Site: www.GBHEnterprises.com
  • 39. TABLE 1 BULK MODULUS OF ELASTICITY AND SONIC VELOCITY FOR SOME LIQUIDS Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts / Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries Web Site: www.GBHEnterprises.com
  • 40. Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts / Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries Web Site: www.GBHEnterprises.com
  • 41. Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts / Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries Web Site: www.GBHEnterprises.com
  • 42. Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts / Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries Web Site: www.GBHEnterprises.com
  • 43. Source References: 1. M Rama Rao. 'Velocity of sound in some liquids and Chemical composition.' Journal of Chemical Physics. Vol 9 September 1941, pp6825. 2. A.R.D. Thorley & K.J. Enever. 'Control and suppression of pressure surges in pipelines and tunnels.' CIRIA, 1979. 3. J.J. Tuma. 'Handbook of physical correlations'. McGraw-Hill, 1983. 4. Journal of Chemical Engineering Data. Volume 23 (3) 1978, page 194. 5. A. Dibrov, V.P. Mashovets, R.P. Matveeva. 'The density and compressibility of aqueous sodium hydroxide solutions at high temperatures. Zh. Prikladnoi Khimii. Volume 37 (1) 1964. pp 29-36. 6. R.T. Langman, C.H. Knowles. 'Velocity of compressional waves in liquid hydrogen fluoride and some thermodynamic properties derived there from.' Journal of the Chemical society. Volume 32 (2) 1960. p 561. 7. The Handbook of Chemistry and Physics. The Rubber Company. 8. G.W.C Kaye & T. H. Laby. 'Tables of Physical and Chemical Constants'. 9. BHRA Report TN 411. Plinton. 10. I.S. Pearsall. 'The velocity of water hammer waves.' Symposium on surges in pipelines. 11. F.W.Bridgeman. The physics of high pressure. The author would be grateful for any additional data to supplement the above list. Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts / Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries Web Site: www.GBHEnterprises.com
  • 44. TABLE 2 YOUNG'S MODULUS AND POISSON'S RATIO OF SOME PIPE MATERIALS Note: GRP properties will vary according to the proportion of fibre, bonding material and method of manufacture. Information from external consultants, suggests that the very low values quoted in reference 3 may be most appropriate for certain types of piping. . Source references: 1. Thorley ARD, Enever KJ " Control & suppression of pressure surges in pipelines and tunnels." CIRA report 84. 2. Perry "Chemical Engineer's Handbook" (4th edition). Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts / Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries Web Site: www.GBHEnterprises.com
  • 45. TABLE 3 GUIDELINES FOR PRESSURE SURGE ANALYSIS OF PIPING SYSTEMS Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts / Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries Web Site: www.GBHEnterprises.com
  • 46. Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts / Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries Web Site: www.GBHEnterprises.com