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©2010 Engines and Energy Conversion Laboratory
Operation of Internal
Combustion Engines on Digas
for Electricity Production
Livestock & Poultry Environmental Learning Center
National Conference: From Waste to Worth:
“Spreading” Science & Solutions
Grand Hyatt Hotel, Denver, Colorado
April 1-5, 2013
Daniel B. Olsen
Associate Professor
Mechanical Engineering Dept.
22 May 2013
• Stationary Gas Engines
• Digas Characteristics
• Engine Design Modifications for Digas
• Gas Scrubbers
• Digas Installation
Outline
Digas Engine Design Options
1. Compression Ignition (Diesel) Engine
– Blend biogas with intake air
– Requires two fuels on site
2. Spark Ignition Stoichiometric Gas Engine
– 3-way catalyst for emissions control
– Lower efficiency
3. Spark Ignition Lean-burn Gas Engine
– Low emissions
– High efficiency
– High power density (bmep)
3
Stationary
Gas Engines
Power generation, Combined
heat and power, Gas
compression Pumping
Wärtsilä 34SG
Waukesha VGF
KUBOTA DG972-E2
Jenbacher Type 2
Cummins Genset
Caterpillar 3516C
4
Guascor V16
MAN CHP
Efficiency Trends
5 Heywood, J. B., “Internal Combustion Engine Fundamentals”, McGraw-Hill, Inc., 1988.
34%
35%
36%
37%
38%
39%
40%
41%
42%
100 150 200 250 300 350 400
bmep (psi)
Increasing boost & power at constant A/F
• Higher power density
(bmep) results in higher
efficiency
• Higher compression ratio
yields higher efficiency
Waukesha VGF (F18GLD)
• Knock (detonation)
limits compression
ratio of engine
• Fuel quality
determines
knock limit
Fuel A Knock Limit
Fuel B Knock Limit
Efficiency
62 May 2013
• Stationary Gas Engines
• Digas Characteristics
• Engine Design Modifications for Digas
• Gas Scrubbers
• Digas Installation
Outline
Biogas Composition
• Two general types of biogas
– Wood gas from a gasifier
– Digas from sewage
processing, landfill, etc.
• Very different properties
from each other and from
natural gas
• Our focus is on digas from
agricultural systems
7
Wood Gas % Composition
Nitrogen, 55.4%
CO, 20.6%
Hydrogen, 18.4%
Methane, 2.2%
Oxygen, 1.8%
CO2, 1.3%
Test Results
62.4
30.0
61.5
70.2 66.3
23.9
139.1 139.6
0
20
40
60
80
100
120
140
160
1, Reformed
Natural Gas
2, Coal Gas 3, Wood Gas 4, Wood Gas 5, Digester
Gas
6, Landfill Gas 7, Reformed
Natural Gas
8, Coal Gas
MethaneNumber
Typical Natural Gas
# Test Gas %CH4 %H2 %N2 %CO %CO2
1
Reformed
Natural Gas
39.7 46.7 0.8 0.9 11.9
2 Coal Gas * 24.8 16.3 58 1
3 Wood Gas 10 40 3 24 23
4 Wood Gas 1 31 35 18 15
5 Digester Gas 60 * 2 * 38
6 Landfill Gas 60 * * * 40
7
Reformed
Natural Gas
1.2 30.8 49.0 15.6 3.4
8 Coal Gas 7 44 * 43 6
8
CriticalCompressionRatio
Malenshek M., Olsen D.B., “Methane number testing of alternative gaseous fuels”, Fuel, Volume 88, pp. 650-656, 2009.
Hydrogen Sulfide (H2S)
• Digas levels ~2000-5000 ppm H2S from hog and
cattle digesters
• Impact on engines
– Corrodes copper-based bearing materials
– Contaminates oil via blow-by
– Combustion of H2S produces SO2
9
/
102 May 2013
• Stationary Gas Engines
• Digas Characteristics
• Engine Design Modifications for Digas
• Gas Scrubbers
• Digas Installation
Outline
Case Study: Waukesha 16V150LTD
(152 mm Bore x 165 mm Stroke)
• 1.1 MW at 1800 rpm, 15.8 bar
bmep
• Regulator spring replaced with
stiffer spring to increase fuel
pressure
• Fuel piping from regulator to
mixer increased from 3” to 4”
• Mixer insert flow area for digas
increased by 2.3X relative to
natural gas
11
Reinbold, E. and von der Ehe, James, “Development of the Dresser Waukesha 16V150LTD Engine for Bio-Gas Fuels”, ASME
Internal Combustion Engine Division 2009 Spring Technical Conference, ICES2009-76079, May 3-6, 2009.
Case Study: Waukesha 16V150LTD
(152 mm Bore x 165 mm Stroke)
• For 1 g/bhp-hr NOx for
NG (900 Btu/SCF) to
digas (400 Btu/SCF),
respectively,
– Timing 21to 30bTDC
– Lambda 1.70 to 1.42
• Slightly lower digas boost
requirement due to richer
lambda
12
Reinbold, E. and von der Ehe, James, “Development of the Dresser Waukesha 16V150LTD Engine for Bio-Gas Fuels”, ASME
Internal Combustion Engine Division 2009 Spring Technical Conference, ICES2009-76079, May 3-6, 2009.
Biogas operating
envelope shift
LeanRich
132 May 2013
• Stationary Gas Engines
• Digas Characteristics
• Engine Design Modifications for Digas
• Gas Scrubbers
• Digas Installation
Outline
142 May 2013
Digas Specifications
Guascor Power, “Anaerobic Digestion Gas Fuel Specifications – Landfill and Digester Gas”, Product Information IC-G-D-30-003e, Sept 2011.
Manufacturer
Relative
Humidity (%)
Temperature
(C)
H2S (mg/MJfuel, ppm) NH3 (mg/MJfuel, ppm) PM (mg)
D-R Guascor < 80 > 15 above DP < 70, 990 < 1.5, 42 < 5
Jenbacher < 80 < 40 < 21, 290 < 1.4, 39 < 5
Caterpillar < 80 -10 to 60 < 57, 810 < 2.8, 79 < 1
Notes:
1 - Relative humidity specification is at the engine fuel gas inlet connection.
2 - Calulation of ppm values based on Guascor SFGLD240 Biogas engine flowrates,
operating on biogas 60% CO2, 38% CO2, and 2% N2.
3 - Caterpillar values given as an example; actual specification is dependent on
engine and application.
4 - Sulfur specifications are without a catalyst; limits are lower if a catalyst is required.
152 May 2013
• Iron Oxides
– Remove sulfur by forming insoluble
iron sulfides
– Iron-oxide-impregnated material (wood-chips,
ceramic, ..)
– Removal reaction
Fe2O3 + 3H2S  Fe2S3 + 3H2O, ΔH= -22 kJ/g-mol H2S
– Regeneration reaction
2Fe2S3 + O2  2Fe2O3 + 3S2, ΔH= -198 kJ/g-mol H2S
H2S Removal: Iron Oxide
Steven McKinsey Zicari, “Removal of Hydrogen Sulfide from Biogas Using Cow-Manure Compost”, MS Thesis, Cornell University, 2003.
162 May 2013
• Filter media provides
environment for establishment of
a bacteria biofilm.
• As the biogas comes in contact
with the biofilm, hydrogen sulfide
is solubilized and subsequently
oxidized by the microbes.
• Sulfur and sulfate compounds
are formed as by-products and
are collected at the bottom or
purged with re-circulated water.
H2S Removal: Biotrickling
172 May 2013
• Stationary Gas Engines
• Digas Characteristics
• Engine Design Modifications for Digas
• Gas Scrubbers
• Digas Installation
Outline
182 May 2013
• Raw digas contains 4000-5000 ppm H2S
• Biotrickler is used to reduce H2S to 200-300 ppm
• Typical gas composition supplied to engines: 57% CH4,
40% CO2, 2% O2, 250 ppm H2S, and 1% other trace
species.
• Two Guascor SFGLD560 V16 engines, rated at 788 kW at
1200 rpm
• Nominal Operating Parameters:
− 525 CFM total digas supply (both engines)
− Engines typically produce 730 kW each, supplying just over 100% of
dairy electricity in winter and 2/3 of electricity in summer
• Oil is changed every 500 hours; currently 8500 hours since
install without rebuild
Windy Ridge Dairy Farm, Fair Oaks,
Indiana (Martin Machinery Installation)
192 May 2013
Windy Ridge Dairy Farm, Fair Oaks,
Indiana (Martin Machinery Installation)
Digester maximum manure temperature 105F.
Digester residence time typically 25-30 days.
202 May 2013
Windy Ridge Dairy Farm, Fair Oaks,
Indiana
Manure Supply to Digester
Digester : 100 X
80 yards X 20 feet
deep
Clockwise from left: biotrickler, rough
water dropout, and iron sponge
Biotrickler control skid
Sulfur and sulfate
compound collection
Guascor
SFGLD560 V16
engine
212 May 2013
Contact:
Daniel B. Olsen
Associate Professor
Mechanical Engineering Department
(970) 491-3580
daniel.olsen@colostate.edu

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Operation of Internal Combustion Engines on Digas for Electricity Production

  • 1. ©2010 Engines and Energy Conversion Laboratory Operation of Internal Combustion Engines on Digas for Electricity Production Livestock & Poultry Environmental Learning Center National Conference: From Waste to Worth: “Spreading” Science & Solutions Grand Hyatt Hotel, Denver, Colorado April 1-5, 2013 Daniel B. Olsen Associate Professor Mechanical Engineering Dept.
  • 2. 22 May 2013 • Stationary Gas Engines • Digas Characteristics • Engine Design Modifications for Digas • Gas Scrubbers • Digas Installation Outline
  • 3. Digas Engine Design Options 1. Compression Ignition (Diesel) Engine – Blend biogas with intake air – Requires two fuels on site 2. Spark Ignition Stoichiometric Gas Engine – 3-way catalyst for emissions control – Lower efficiency 3. Spark Ignition Lean-burn Gas Engine – Low emissions – High efficiency – High power density (bmep) 3
  • 4. Stationary Gas Engines Power generation, Combined heat and power, Gas compression Pumping Wärtsilä 34SG Waukesha VGF KUBOTA DG972-E2 Jenbacher Type 2 Cummins Genset Caterpillar 3516C 4 Guascor V16 MAN CHP
  • 5. Efficiency Trends 5 Heywood, J. B., “Internal Combustion Engine Fundamentals”, McGraw-Hill, Inc., 1988. 34% 35% 36% 37% 38% 39% 40% 41% 42% 100 150 200 250 300 350 400 bmep (psi) Increasing boost & power at constant A/F • Higher power density (bmep) results in higher efficiency • Higher compression ratio yields higher efficiency Waukesha VGF (F18GLD) • Knock (detonation) limits compression ratio of engine • Fuel quality determines knock limit Fuel A Knock Limit Fuel B Knock Limit Efficiency
  • 6. 62 May 2013 • Stationary Gas Engines • Digas Characteristics • Engine Design Modifications for Digas • Gas Scrubbers • Digas Installation Outline
  • 7. Biogas Composition • Two general types of biogas – Wood gas from a gasifier – Digas from sewage processing, landfill, etc. • Very different properties from each other and from natural gas • Our focus is on digas from agricultural systems 7 Wood Gas % Composition Nitrogen, 55.4% CO, 20.6% Hydrogen, 18.4% Methane, 2.2% Oxygen, 1.8% CO2, 1.3%
  • 8. Test Results 62.4 30.0 61.5 70.2 66.3 23.9 139.1 139.6 0 20 40 60 80 100 120 140 160 1, Reformed Natural Gas 2, Coal Gas 3, Wood Gas 4, Wood Gas 5, Digester Gas 6, Landfill Gas 7, Reformed Natural Gas 8, Coal Gas MethaneNumber Typical Natural Gas # Test Gas %CH4 %H2 %N2 %CO %CO2 1 Reformed Natural Gas 39.7 46.7 0.8 0.9 11.9 2 Coal Gas * 24.8 16.3 58 1 3 Wood Gas 10 40 3 24 23 4 Wood Gas 1 31 35 18 15 5 Digester Gas 60 * 2 * 38 6 Landfill Gas 60 * * * 40 7 Reformed Natural Gas 1.2 30.8 49.0 15.6 3.4 8 Coal Gas 7 44 * 43 6 8 CriticalCompressionRatio Malenshek M., Olsen D.B., “Methane number testing of alternative gaseous fuels”, Fuel, Volume 88, pp. 650-656, 2009.
  • 9. Hydrogen Sulfide (H2S) • Digas levels ~2000-5000 ppm H2S from hog and cattle digesters • Impact on engines – Corrodes copper-based bearing materials – Contaminates oil via blow-by – Combustion of H2S produces SO2 9 /
  • 10. 102 May 2013 • Stationary Gas Engines • Digas Characteristics • Engine Design Modifications for Digas • Gas Scrubbers • Digas Installation Outline
  • 11. Case Study: Waukesha 16V150LTD (152 mm Bore x 165 mm Stroke) • 1.1 MW at 1800 rpm, 15.8 bar bmep • Regulator spring replaced with stiffer spring to increase fuel pressure • Fuel piping from regulator to mixer increased from 3” to 4” • Mixer insert flow area for digas increased by 2.3X relative to natural gas 11 Reinbold, E. and von der Ehe, James, “Development of the Dresser Waukesha 16V150LTD Engine for Bio-Gas Fuels”, ASME Internal Combustion Engine Division 2009 Spring Technical Conference, ICES2009-76079, May 3-6, 2009.
  • 12. Case Study: Waukesha 16V150LTD (152 mm Bore x 165 mm Stroke) • For 1 g/bhp-hr NOx for NG (900 Btu/SCF) to digas (400 Btu/SCF), respectively, – Timing 21to 30bTDC – Lambda 1.70 to 1.42 • Slightly lower digas boost requirement due to richer lambda 12 Reinbold, E. and von der Ehe, James, “Development of the Dresser Waukesha 16V150LTD Engine for Bio-Gas Fuels”, ASME Internal Combustion Engine Division 2009 Spring Technical Conference, ICES2009-76079, May 3-6, 2009. Biogas operating envelope shift LeanRich
  • 13. 132 May 2013 • Stationary Gas Engines • Digas Characteristics • Engine Design Modifications for Digas • Gas Scrubbers • Digas Installation Outline
  • 14. 142 May 2013 Digas Specifications Guascor Power, “Anaerobic Digestion Gas Fuel Specifications – Landfill and Digester Gas”, Product Information IC-G-D-30-003e, Sept 2011. Manufacturer Relative Humidity (%) Temperature (C) H2S (mg/MJfuel, ppm) NH3 (mg/MJfuel, ppm) PM (mg) D-R Guascor < 80 > 15 above DP < 70, 990 < 1.5, 42 < 5 Jenbacher < 80 < 40 < 21, 290 < 1.4, 39 < 5 Caterpillar < 80 -10 to 60 < 57, 810 < 2.8, 79 < 1 Notes: 1 - Relative humidity specification is at the engine fuel gas inlet connection. 2 - Calulation of ppm values based on Guascor SFGLD240 Biogas engine flowrates, operating on biogas 60% CO2, 38% CO2, and 2% N2. 3 - Caterpillar values given as an example; actual specification is dependent on engine and application. 4 - Sulfur specifications are without a catalyst; limits are lower if a catalyst is required.
  • 15. 152 May 2013 • Iron Oxides – Remove sulfur by forming insoluble iron sulfides – Iron-oxide-impregnated material (wood-chips, ceramic, ..) – Removal reaction Fe2O3 + 3H2S  Fe2S3 + 3H2O, ΔH= -22 kJ/g-mol H2S – Regeneration reaction 2Fe2S3 + O2  2Fe2O3 + 3S2, ΔH= -198 kJ/g-mol H2S H2S Removal: Iron Oxide Steven McKinsey Zicari, “Removal of Hydrogen Sulfide from Biogas Using Cow-Manure Compost”, MS Thesis, Cornell University, 2003.
  • 16. 162 May 2013 • Filter media provides environment for establishment of a bacteria biofilm. • As the biogas comes in contact with the biofilm, hydrogen sulfide is solubilized and subsequently oxidized by the microbes. • Sulfur and sulfate compounds are formed as by-products and are collected at the bottom or purged with re-circulated water. H2S Removal: Biotrickling
  • 17. 172 May 2013 • Stationary Gas Engines • Digas Characteristics • Engine Design Modifications for Digas • Gas Scrubbers • Digas Installation Outline
  • 18. 182 May 2013 • Raw digas contains 4000-5000 ppm H2S • Biotrickler is used to reduce H2S to 200-300 ppm • Typical gas composition supplied to engines: 57% CH4, 40% CO2, 2% O2, 250 ppm H2S, and 1% other trace species. • Two Guascor SFGLD560 V16 engines, rated at 788 kW at 1200 rpm • Nominal Operating Parameters: − 525 CFM total digas supply (both engines) − Engines typically produce 730 kW each, supplying just over 100% of dairy electricity in winter and 2/3 of electricity in summer • Oil is changed every 500 hours; currently 8500 hours since install without rebuild Windy Ridge Dairy Farm, Fair Oaks, Indiana (Martin Machinery Installation)
  • 19. 192 May 2013 Windy Ridge Dairy Farm, Fair Oaks, Indiana (Martin Machinery Installation) Digester maximum manure temperature 105F. Digester residence time typically 25-30 days.
  • 20. 202 May 2013 Windy Ridge Dairy Farm, Fair Oaks, Indiana Manure Supply to Digester Digester : 100 X 80 yards X 20 feet deep Clockwise from left: biotrickler, rough water dropout, and iron sponge Biotrickler control skid Sulfur and sulfate compound collection Guascor SFGLD560 V16 engine
  • 21. 212 May 2013 Contact: Daniel B. Olsen Associate Professor Mechanical Engineering Department (970) 491-3580 daniel.olsen@colostate.edu