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Chemistry of Paper Making 
ARTICLE WRITTEN AND PUBLISHED 
BY 
WWW.WORLDOFCHEMICALS.COM
HISTORY OF PAPER MAKING 
Paper was first invented in ancient China by Cai Lun. 
Chinese made the first paper from fibers of plants 
such as hemp. The plant fibres were soaked and 
beaten into sludge. 
The sludge was strained through a cloth sieve 
attached to a frame that also served as a drying 
platform for the resulting paper. 
Papermaking was introduced to Korea and Vietnam 
during the 3rd century and to the West around the 
8th century. The first paper mill in Europe was built 
in 1009
ROLE OF CHEMICALS IN PAPER MAKING 
There are about 3000 or so different types of chemicals which can be used in 
papermaking, in practice only about 200 individual chemicals are typically 
used, each satisfying a specific need. Some of the important chemicals used 
are – 
1) Caustic soda, sodium sulfide for the Kraft process, the process of 
conversion of wood into wood pulp consisting of almost pure cellulose fibre. 
2) Sulfurous acid for the Sulfite process 
3) Caustic soda, Anthraquinone for the Soda pulping 
4) Caustic soda is added to increase the pH in the pulping process of fibers. 
The higher pH of the paper fiber solution causes the fibers to smoothen and 
swell, which is important for the grinding process of the fibers. 
5) Sodium dithionite, chlorine dioxide, hydrogen peroxide, ozone for 
bleaching of wood pulp 
6) Bleaching additives: sodium silicate 
7) sequestering agents: EDTA, DTPA
APPLICATIONS OF PAPER 
1. One of the major use of paper is for books, charts, cards, 
report card etc. 
2. Paper is used in making writing pads, envelopes, 
newspapers, magazines, greeting cards, calendars, diaries, 
telephone directories, labels, business and passports. 
3. Paper is used in making domestic products such as tissues, 
paper plates, paper cups, toilet paper, kitchen towels, table 
napkins, wallpaper and lampshades. 
4. Paper finds use in special insulating boards, electrolytic 
condenser paper, wrapping and identification for electrical 
cables, printed circuits, and battery separators. 
5. It is also used for making menu cards, paper hats, crackers, 
wrapping paper, playing cards, board games, kites, model 
aircraft, and race cards.
APPLICATIONS OF PAPER Cont .. 
6. Paper is used in making filters for water, air, tea bags, 
medicine, beer, oil, and mechanical uses. 
7. Impregnated Papers are used polishing, waxing, and 
cleaning. 
8. It finds use in medical field for wrapping to keep 
instruments and equipment sterile, bandages, first aid 
bands, clothing for nurses, face masks, surgeons’ caps, 
disposable bed pans, sheets, and pillowcases. 
9. Another important use of papers are for bank notes, 
insurance forms, cheque books, stamps, cash bags and 
security papers that contain special markings which are 
only visible when subjected to ultra-violet light.
TOP PAPER MANUFACTURUING COMPANIES 
1) International Paper, Memphis, TN, US 
2) Stora Enso , Helsinki, Finland 
3) Oji Paper, Tokyo, Japan 
4) Nippon Paper, Tokyo, Japan 
5) Cellulosa Aktiebolaget (SCA), Stockholm, Sweden 
6) UPM , Helsinki, Finland 
7) Kimberly Clark, Dallas, Texas, US 
8) Smurfit Kappa Group, Dublin, Ireland 
9) Mondi, Addlestone, UK; Johannesburg, South 
Africa
INTERESTING FACTS ABOUT PAPER 
Paper was invented by the Chinese around 105 A.D. and was kept a 
secret for many years. 
Every tonne of paper that is recovered saves 3.3 cubic yards of 
landfill space. 
It takes 7 days for a recycled newspaper to come back as a 
newspaper again. 
We use kraft paper every day when we ask supermarkets to pack our 
groceries in brown paper bags. 
All of the newspaper made in the UK is now made from 100 per cent 
recycled paper. 
Much of our toilet paper is made from recycled paper. 
Corrugated cardboard packaging consists nearly of 100 per cent 
recycled material. 
Paper bags were first measured by how many pounds of sugar they 
held.
References 
Buy paper and pulp chemicals, paper making 
chemicals here 
http://www.worldofchemicals.com/Chemicals/Pulp 
_and_Paper/id-15.html?lst=trt 
Read complete article online 
http://www.worldofchemicals.com/458/chemistry-articles/ 
about-3000-chemicals-used-in-papermaking. 
html

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Chemistry of papermaking - Around 3000 chemicals used in paper making process

  • 1. Chemistry of Paper Making ARTICLE WRITTEN AND PUBLISHED BY WWW.WORLDOFCHEMICALS.COM
  • 2. HISTORY OF PAPER MAKING Paper was first invented in ancient China by Cai Lun. Chinese made the first paper from fibers of plants such as hemp. The plant fibres were soaked and beaten into sludge. The sludge was strained through a cloth sieve attached to a frame that also served as a drying platform for the resulting paper. Papermaking was introduced to Korea and Vietnam during the 3rd century and to the West around the 8th century. The first paper mill in Europe was built in 1009
  • 3. ROLE OF CHEMICALS IN PAPER MAKING There are about 3000 or so different types of chemicals which can be used in papermaking, in practice only about 200 individual chemicals are typically used, each satisfying a specific need. Some of the important chemicals used are – 1) Caustic soda, sodium sulfide for the Kraft process, the process of conversion of wood into wood pulp consisting of almost pure cellulose fibre. 2) Sulfurous acid for the Sulfite process 3) Caustic soda, Anthraquinone for the Soda pulping 4) Caustic soda is added to increase the pH in the pulping process of fibers. The higher pH of the paper fiber solution causes the fibers to smoothen and swell, which is important for the grinding process of the fibers. 5) Sodium dithionite, chlorine dioxide, hydrogen peroxide, ozone for bleaching of wood pulp 6) Bleaching additives: sodium silicate 7) sequestering agents: EDTA, DTPA
  • 4. APPLICATIONS OF PAPER 1. One of the major use of paper is for books, charts, cards, report card etc. 2. Paper is used in making writing pads, envelopes, newspapers, magazines, greeting cards, calendars, diaries, telephone directories, labels, business and passports. 3. Paper is used in making domestic products such as tissues, paper plates, paper cups, toilet paper, kitchen towels, table napkins, wallpaper and lampshades. 4. Paper finds use in special insulating boards, electrolytic condenser paper, wrapping and identification for electrical cables, printed circuits, and battery separators. 5. It is also used for making menu cards, paper hats, crackers, wrapping paper, playing cards, board games, kites, model aircraft, and race cards.
  • 5. APPLICATIONS OF PAPER Cont .. 6. Paper is used in making filters for water, air, tea bags, medicine, beer, oil, and mechanical uses. 7. Impregnated Papers are used polishing, waxing, and cleaning. 8. It finds use in medical field for wrapping to keep instruments and equipment sterile, bandages, first aid bands, clothing for nurses, face masks, surgeons’ caps, disposable bed pans, sheets, and pillowcases. 9. Another important use of papers are for bank notes, insurance forms, cheque books, stamps, cash bags and security papers that contain special markings which are only visible when subjected to ultra-violet light.
  • 6. TOP PAPER MANUFACTURUING COMPANIES 1) International Paper, Memphis, TN, US 2) Stora Enso , Helsinki, Finland 3) Oji Paper, Tokyo, Japan 4) Nippon Paper, Tokyo, Japan 5) Cellulosa Aktiebolaget (SCA), Stockholm, Sweden 6) UPM , Helsinki, Finland 7) Kimberly Clark, Dallas, Texas, US 8) Smurfit Kappa Group, Dublin, Ireland 9) Mondi, Addlestone, UK; Johannesburg, South Africa
  • 7. INTERESTING FACTS ABOUT PAPER Paper was invented by the Chinese around 105 A.D. and was kept a secret for many years. Every tonne of paper that is recovered saves 3.3 cubic yards of landfill space. It takes 7 days for a recycled newspaper to come back as a newspaper again. We use kraft paper every day when we ask supermarkets to pack our groceries in brown paper bags. All of the newspaper made in the UK is now made from 100 per cent recycled paper. Much of our toilet paper is made from recycled paper. Corrugated cardboard packaging consists nearly of 100 per cent recycled material. Paper bags were first measured by how many pounds of sugar they held.
  • 8. References Buy paper and pulp chemicals, paper making chemicals here http://www.worldofchemicals.com/Chemicals/Pulp _and_Paper/id-15.html?lst=trt Read complete article online http://www.worldofchemicals.com/458/chemistry-articles/ about-3000-chemicals-used-in-papermaking. html