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By: Eric Nauman
    Pat Johnson
      John Mauk
      Yimu Yang
 History   of the Otto engine

 Assumptions


 Energy    Balance and Calculations

 New   Technologies/Alternative Fuels
Nicolaus Otto was born in Germany in 1832

The Otto engine was first made in 1876

He obtained total of 25 patents

Contrary to belief Alphonse Eugène Beau de Rochas
         made the first “Otto” cycle
-Otto cycle
-Closed System
-Assumed as an ideal Otto Cycle
-Kinetic Energy and Potential Energy
effects negligible
-Reversible
Energy Balance
Q+W = mdot[ΔU + ΔKE + ΔPE]

ΔKE=ΔPE=0

Step 1: Intake Stroke

 Air/Fuel mixture is drawn into
the chamber to be ignited
Step 1-2: Adiabatic Compression
Q=0 (adiabatic) W = ΔU = U 2 - U1
Step 2-3: Isochoric Heating
W=0 (Const Vol)          Q = ΔU = U 3 – U2
Heat is added from combustion


 Calculating   Efficiency

η = Wnet/Q23
~35%-40% efficient
η = 1 – r (1/r)^γ - 1

P4/P1 = P3/P2 = r = compression ratio

γ = Cp/Cv

 “ECO-”   Portion9:

How does it work?
1. Uses EGR (Exhaust Gas Recirculation)
2. EG cooled after combustion
3. These inerts take up dead space in cylinder, allowing for
   less of an intake of “fresh” air (oxygen).
4. Less intake of “fresh” causes less fuel to be injected by
   ECU
5. Kept at stoichiometric ratio of 14.1-1 (A/F), with less fuel
   used.
6. Causes 19-20% less fuel to be burned.

Ethanol:   CH3CH2OH + 3 O2  2CO2 + 3 H2O
Butanol:    C4H9OH + 6 O2  4CO2 + 5 H2O

Ethanol ΔHc (LHV) = 19.6 MJ/L
Butanol ΔHc (LHV) = 29.2 MJ/L
Gasoline ΔHc (LHV) = 32 MJ/L

Butanol Energy Density = 29% higher than EtOH
                  and      8.8% lower than Gasoline
   References
   1 Chemical Economics Handbook Report Plasticizer Alcohols, SRI International, May
    2002, pages 8- 9 and 27.
   2 Thaddeus Chukwuemeka Ezeji, Nasib Qureshi and Hans Peter Blaschek, 2007.
    Bioproduction of Butanol from Biomass: From Genes to Bioreactors, Current Opinion on
    Biotechnology 18:220–
    227, http://ddr.nal.usda.gov/bitstream/10113/14428/1/IND44052939.pdf, retrieved 12 Apr.
    2012.
   3 1-Butanol as a Gasoline Blending Bio-Component, BP Mobile Sources Technical Review
    Subcommittee, March
    28, 2007, www.epa.gov/air/caaac/mstrs/March2007/Wolf.pdf, retrieved 12 Apr. 2012.
   4 The Biobutanol Advantage, Butamax Advanced Fuels LLC, http://www.butamax.com/the-
    biobutanol-advantage.ashx, retrieved 12 Apr. 2012.
   5Smith, J.M., Van Ness, H.C., Abbott, M.M., Introduction to Chemical Engineering
    Thermodynamics, New York: McGraw-Hill 2005.
   6 Wikipedia contributors. "Butanol fuel." Wikipedia, The Free Encyclopedia. Wikipedia, The
    Free Encyclopedia, 27 Mar. 2012. Web. Retrieved 12 Apr. 2012
   7Wikipedia contributors. "Otto cycle." Wikipedia, The Free Encyclopedia. Wikipedia, The
    Free Encyclopedia, 28 Mar. 2012. Web. 12 Apr. 2012.
    Good diversity of references.
   8 www.mazda.com/mazdaspirit/skyactiv/Cached
   9hpc4energy.org/hpc-road-map/success.../ford-ecoboost-technology/

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Thermodynamics Presentation

  • 1. By: Eric Nauman Pat Johnson John Mauk Yimu Yang
  • 2.  History of the Otto engine  Assumptions  Energy Balance and Calculations  New Technologies/Alternative Fuels
  • 3. Nicolaus Otto was born in Germany in 1832 The Otto engine was first made in 1876 He obtained total of 25 patents Contrary to belief Alphonse Eugène Beau de Rochas made the first “Otto” cycle
  • 4. -Otto cycle -Closed System -Assumed as an ideal Otto Cycle -Kinetic Energy and Potential Energy effects negligible -Reversible
  • 5. Energy Balance Q+W = mdot[ΔU + ΔKE + ΔPE] ΔKE=ΔPE=0 Step 1: Intake Stroke Air/Fuel mixture is drawn into the chamber to be ignited
  • 6. Step 1-2: Adiabatic Compression Q=0 (adiabatic) W = ΔU = U 2 - U1
  • 7. Step 2-3: Isochoric Heating W=0 (Const Vol) Q = ΔU = U 3 – U2 Heat is added from combustion
  • 8.
  • 9.
  • 10.  Calculating Efficiency η = Wnet/Q23 ~35%-40% efficient η = 1 – r (1/r)^γ - 1 P4/P1 = P3/P2 = r = compression ratio γ = Cp/Cv
  • 11.
  • 12.  “ECO-” Portion9: How does it work? 1. Uses EGR (Exhaust Gas Recirculation) 2. EG cooled after combustion 3. These inerts take up dead space in cylinder, allowing for less of an intake of “fresh” air (oxygen). 4. Less intake of “fresh” causes less fuel to be injected by ECU 5. Kept at stoichiometric ratio of 14.1-1 (A/F), with less fuel used. 6. Causes 19-20% less fuel to be burned.
  • 13.
  • 14. Ethanol: CH3CH2OH + 3 O2  2CO2 + 3 H2O Butanol: C4H9OH + 6 O2  4CO2 + 5 H2O Ethanol ΔHc (LHV) = 19.6 MJ/L Butanol ΔHc (LHV) = 29.2 MJ/L Gasoline ΔHc (LHV) = 32 MJ/L Butanol Energy Density = 29% higher than EtOH and 8.8% lower than Gasoline
  • 15. References  1 Chemical Economics Handbook Report Plasticizer Alcohols, SRI International, May 2002, pages 8- 9 and 27.  2 Thaddeus Chukwuemeka Ezeji, Nasib Qureshi and Hans Peter Blaschek, 2007. Bioproduction of Butanol from Biomass: From Genes to Bioreactors, Current Opinion on Biotechnology 18:220– 227, http://ddr.nal.usda.gov/bitstream/10113/14428/1/IND44052939.pdf, retrieved 12 Apr. 2012.  3 1-Butanol as a Gasoline Blending Bio-Component, BP Mobile Sources Technical Review Subcommittee, March 28, 2007, www.epa.gov/air/caaac/mstrs/March2007/Wolf.pdf, retrieved 12 Apr. 2012.  4 The Biobutanol Advantage, Butamax Advanced Fuels LLC, http://www.butamax.com/the- biobutanol-advantage.ashx, retrieved 12 Apr. 2012.  5Smith, J.M., Van Ness, H.C., Abbott, M.M., Introduction to Chemical Engineering Thermodynamics, New York: McGraw-Hill 2005.  6 Wikipedia contributors. "Butanol fuel." Wikipedia, The Free Encyclopedia. Wikipedia, The Free Encyclopedia, 27 Mar. 2012. Web. Retrieved 12 Apr. 2012  7Wikipedia contributors. "Otto cycle." Wikipedia, The Free Encyclopedia. Wikipedia, The Free Encyclopedia, 28 Mar. 2012. Web. 12 Apr. 2012.  Good diversity of references.  8 www.mazda.com/mazdaspirit/skyactiv/Cached  9hpc4energy.org/hpc-road-map/success.../ford-ecoboost-technology/