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Recommendation for Mixing
    Concentrated Acid in Large
  Diameter Pipelines -- Predilution
                                              Application Data - Bulletin 317


Abstract:                                       coming in contact with mixer
Mixing concentrated sulfuric acid (93%-         components that are not fully compatible
98%) to water or a wastewater pipeline          with the acid.
is a common and cost effective method
for managing the pH of the stream.
When injecting sulfuric acid in a large
diameter pipe, Komax has found that
prediluting and mixing this acid in two
stages provides many advantages over
directly mixing the concentrated acid in
the pipe.
Background:
Concentrated Sulfuric Acid has a                Solution: Pre-diluting concentrated
specific gravity of 1.8 so it tends to          Sulfuric Acid
migrate to the bottom of the mixer              By prediluting the concentrated acid
housing particularly at lower fluid             through the use of an inexpensive
velocities (i.e., less than 2 feet per          “premixer” down to a safer 10% or 5%
second) which compounds the problem.            concentration, the mixer can be
Sulfuric acid has a viscosity similar to        constructed of less costly material, and
honey, and requires vigorous mixing to          the life of the mixer will be extended for
fully dissolve the acid in water.               years.
Additionally, there is a strong heat            An additional advantage is the larger
producing exothermic reaction that              volume of diluted acid solution will
occurs during this dilution process. If         provide equal flow rates through each
water and concentrated acid are allowed         discharge orifice of the acid injector
to stagnate, high temperatures (over 350        resulting in improved acid distribution.
ºF) will occur, which can result in             When injecting one to two gallons per
damage to the piping and injection              hour of concentrated Sulfuric Acid the
system. Concentrated acid is not                resultant flow exiting the injector is only
particularly corrosive. However, as the         2 to 4 ounces per minute. At this flow
concentration decreases to 30%-50%,             rate all of the acid will exit the first
the acid becomes very reactive and will         injector orifice precluding uniform
damage mixers that are constructed of           dispersion of acid across the mixer
Ductile Iron, Carbon Steel, or 316              housing diameter. When the flow is
Stainless Steel Static Mixer. The key to a      measured in gallons per minute, even
long mixer life is to eliminate acid in the     distribution across the diameter of the
30-50% strength concentration from              mixer is easy to maintain.

                                       www.komax.com

                                                                                   04/29/06
www.komax.com

                04/29/06

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Recommendation for Mixing Concentrated Acid in Large Diameter Pipelines -- Predilution

  • 1. Recommendation for Mixing Concentrated Acid in Large Diameter Pipelines -- Predilution Application Data - Bulletin 317 Abstract: coming in contact with mixer Mixing concentrated sulfuric acid (93%- components that are not fully compatible 98%) to water or a wastewater pipeline with the acid. is a common and cost effective method for managing the pH of the stream. When injecting sulfuric acid in a large diameter pipe, Komax has found that prediluting and mixing this acid in two stages provides many advantages over directly mixing the concentrated acid in the pipe. Background: Concentrated Sulfuric Acid has a Solution: Pre-diluting concentrated specific gravity of 1.8 so it tends to Sulfuric Acid migrate to the bottom of the mixer By prediluting the concentrated acid housing particularly at lower fluid through the use of an inexpensive velocities (i.e., less than 2 feet per “premixer” down to a safer 10% or 5% second) which compounds the problem. concentration, the mixer can be Sulfuric acid has a viscosity similar to constructed of less costly material, and honey, and requires vigorous mixing to the life of the mixer will be extended for fully dissolve the acid in water. years. Additionally, there is a strong heat An additional advantage is the larger producing exothermic reaction that volume of diluted acid solution will occurs during this dilution process. If provide equal flow rates through each water and concentrated acid are allowed discharge orifice of the acid injector to stagnate, high temperatures (over 350 resulting in improved acid distribution. ºF) will occur, which can result in When injecting one to two gallons per damage to the piping and injection hour of concentrated Sulfuric Acid the system. Concentrated acid is not resultant flow exiting the injector is only particularly corrosive. However, as the 2 to 4 ounces per minute. At this flow concentration decreases to 30%-50%, rate all of the acid will exit the first the acid becomes very reactive and will injector orifice precluding uniform damage mixers that are constructed of dispersion of acid across the mixer Ductile Iron, Carbon Steel, or 316 housing diameter. When the flow is Stainless Steel Static Mixer. The key to a measured in gallons per minute, even long mixer life is to eliminate acid in the distribution across the diameter of the 30-50% strength concentration from mixer is easy to maintain. www.komax.com 04/29/06
  • 2. www.komax.com 04/29/06