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Electrochemistry Electrode Potentials
Electrochemistry 1. What are electrode potentials?
Electrochemistry ,[object Object],[object Object],[object Object],1. What are electrode potentials?   Zn 2+  (aq) + 2e –   ⇌ Zn  (s) Fe 3+  (aq) + e –   ⇌ Fe 2+  (aq) 2H +  (aq) + e –   ⇌ H 2   (g) Cu 2+  (aq) + 2e –   ⇌ Cu (s)
Electrochemistry 2. What can we know from electrode potentials?
Electrochemistry 2. What can we know from electrode potentials?   ,[object Object],[object Object],[object Object],[object Object],[object Object]
Electrochemistry 3. How can we measure standard electrode potentials?
Electrochemistry ,[object Object],[object Object],[object Object],[object Object],3. How can we measure standard electrode potentials?
Electrochemistry 4. How can we use standard electrode potentials?
Electrochemistry ,[object Object],[object Object],4. How can we use standard electrode potentials?   I 2   + Cr 2+     feasible? V 3+  + Cu 2+     feasible?
Electrochemistry 4. How can we use standard electrode potentials?   ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Electrochemistry Galvanic Cells
Electrochemistry 5. How to distinguish anode and cathode?   Galvanic Cell
Electrochemistry 5. How to distinguish anode and cathode?   Positive     remove electrons    Reduction     Cathode Negative     produce electrons    Oxidation     Anode Electrons flow from A  C Galvanic Cell
Electrochemistry 6. How to draw cell diagram?
Electrochemistry 6. How to draw cell diagram?   Example
Electrochemistry 6. How to draw cell diagram?   ,[object Object],[object Object],[object Object],[object Object],[object Object],Pt (s) | Anode || Cathode | Pt (s) Pt (s) | Fe 2+  Fe 3+  || H +  H 2  | Pt (s) Pt(s) | Fe 2+ , Fe 3+ (aq) || H + (aq) | H 2 (g) | Pt(s)
Electrochemistry Electrolytic Cells
Electrochemistry 7. How to distinguish anode and cathode?   Electrolytic Cell
Electrochemistry 7. How to distinguish anode and cathode?   Positive     attract anions    oxidized     Anode Negative     attract cations    reduced     Cathode Electrons flow from A  C Electrolytic Cell
Electrochemistry 8. How to predict what species is discharged?   ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Electrochemistry Calculations (Strategy) Question will  surely  involve 1 or more of the formulas: Q = I  t = n F I: current (A) n: moles of  electrons! t: time ( s ) F: Faradays constant (96500 C/mol) F = Le L: Avogadro’s constant e: 1.6 x 10 –19  C

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Electrochemistry