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Journal of Environment and Earth Science                                                               www.iiste.org
ISSN 2224-3216 (Paper) ISSN 2225-0948 (Online)
Vol 2, No.4, 2012


 Application of Resistivity Sounding In Environmental Studies: A
   Case Study of Kazai Crude-Oil Spillage Niger State, Nigeria
                               Abubakar Yusuf Ismail* and Umar Adamu Danbatta
                 Department of Geology, Ahmadu Bello University, Zaria. Kaduna State, Nigeria
               *E-mail of Correponding Author: ismi_asma@yahoo.com, ismazee2003@gmail.com.

Abstract
A pipeline conveying crude oil from Escravos via Izom ruptured in the year 2000 and polluted the Kazai area,
although the ruptured pipe was replaced and the site cleaned up, an examination of the point of spillage two
years later gave the impression that the pipeline might be still leaking. The present work presents the use of
Vertical Electrical Soundings (VES) techniques, and systematic trenching, to determine the source of this
environmental problem. A total number of eight soundings along two profiles were carried out around the point
of spillage, and data analysis revealed that the area is predominantly clayey in nature, and that the pipes are no
longer leaking. Due to the plasticity of the clay when wet, it expands when in contact with rainwater and, as it
does so, it entrapped any oil existing around it. However, when not in contact with water in the dry season, the
clay shrinks and cracks, thereby releasing the trapped oils. This mechanism continued seasonally, and the oil
released during the dry season, is the one responsible for the apparent leakage of the pipeline. Geoelectric
models in the form of Vertical Isoresistivity Sections (VIS) and Isoresistiviy Maps were plotted. These were used
to delineate the polluted zones, which were recommended for excavation and refilling.
Keywords: Vertical Electrical sounding, Geoelectric Models, Isopach map, Isoresistivity Map.

1. Introduction
In the Izom area of Niger State Nigeria, an underground high pressure pipeline that is conveying crude oil from
Escravos to the Kaduna Nigerian National Petroleum Cooperation ( N.N.P.C) refinery got ruptured at Kazai (km
198) in the year 2000. This caused severe environmental pollution and considerable ecological damage, in the
form of water pollution and loss of access to farmlands, which was immediately arrested. The Kazai area of Izom
lies within the Basement Complex region of northern Nigeria (Fig. 1), and is about 30 km south of Sarkin Pawa,
and about 20km East of Gwada. Danbatta et al. (2002) discussed the different basement rock types found in the
study area, which include migmatites, gneisses, metasediments (schists, quartzites), and Older Granites. The
dominant rock types are the migmatitic-gneisses, with subordinate amount of the Older Granites, one of which
outcropped near the point of spillage (Fig. 2).The crude oil pipeline is trending at 010° around the point of
spillage, and the spillage occurred along a tributary of River Dinya, which is sometimes called River Dapulo (Fig.
2). Although the ruptured pipe was replaced and the site cleaned up, oil kept appearing on the surface polluting
the water resources in the area particularly during the wet season. The present work illustrate the application
electrical resistivity survey to environmental studies, with the sole aim of investigating the source of the
persistent appearance of oil on the surface and to point out areas where urgent intervention is needed for the
rational use and protection of the water resources of the area
1.1 Materials and methods
A reconnaissance survey was first undertaken in order to study the location and nature of the oil spillage, and
used to delimit the study area. Literature review, fieldwork, and laboratory analysis were undertaken during the
investigations. Eight (8) surface Vertical Electrical Soundings (VES) geophysical data were acquired using an
ABEM Terrameter SAS 300, and a Schlumberger electrode array with a maximum electrode spacing of 100 m.
The 8 VES stations were established on two profiles, trending N-S and E-W (Fig. 3). Moreover two large pits
were dug to physically observe the soil profile in the study area.
    The data obtained were then reduced and were subjected to both qualitative and quantitatively interpretation
using different analytical methods.

1.1.1 Results and discussion
The data acquired from the eight soundings are presented in Table 1, and the field curves are predominantly
three-layer A and H-types. The thickness of the most conducting layers in the study area varied from 12 to 117m
with resistivities in the range of 4 to 115 ohm-m. Geoelectric models for the spillage site in the form of Vertical
Iso-ohms Section (VIS) and Iso-ohms Map (Resistivity contours) at different depths were plotted. These were
used to delineate the polluted zones around the west and central areas of the point of spillage.
    The acquired VES field curves were initially interpreted using the conventional partial curve matching



                                                       13
Journal of Environment and Earth Science                                                                  www.iiste.org
ISSN 2224-3216 (Paper) ISSN 2225-0948 (Online)
Vol 2, No.4, 2012


technique and the Petrowski's method (Telford et al., 1976). Initial estimates of the resistivities and thickness of
the various geoelectric layers were deduced from this preliminary interpretation. The deduced parameters were
later used as starting models in a "Zohdy" computer program. This computer assisted resistivity interpretation is
based on the calculation of theoretical VES curves, and gave the 'best fit' for the data obtained.
     The final computed computer parameters for VES1 are hi = 7.26m, rho (ρ1) = 100 Ωm, h2 -13.26 m, ρ
2=289 Ωm, ρ3=401 Ωm. Root mean square( R.m.s) error for the final model was 4.2, and the suggested depth of
the third layer (h3) is infinity. A similar procedure as discussed above was followed in the interpretation of all the
remaining 7 VES points collected for this work, and the result presented in Table 2. The resulting interpreted
models of the various profiles sounded were used to produce geoelectric sections, geologic sections, isopach
maps, and isoresistivity (iso-ohms) maps for the surface, overburden and basement.
     The composite geoelectric section was obtained for the four VES points established along the N-S profile.
It suggests that the subsurface along the profile is made up of 3 layers at VES point 1, while 2-layers underlay
VES points 2, 3 and 4. The resistivity of the first layer in all the VES points ranges from 100.7-1605 ohm-m, and
the thickness of the layer varies from 2.42 m to 30.54 m . The second layer has a resistivity in the range of
289-62479 Ωm, and the thickness of this second layer varies from 13.26 m –Infinity. The third layer is the
deepest and has resistivity values in the range of 400 Ωm.
     The geoelectric section derived from the interpreted VES data was converted to geologic section based on
available borehole data and dug pit in the area. The geologic section derived along the N-S profile suggests that
the first layer likely consists of two different types of soils. The high resistivity zone (5071 ohm-m) of the layer
occurring around VES point 2 is considered to be fresh crystalline rock. The second soil type occurred at zones
with relatively medium resistivity values (100-198 ohm-m), which occurred at VES points 1, 2 and 4, and is
considered to be dry clay.
     The data also suggests that the second layer likely consists of two types of soils. The first type occurred at
around VES point 1, with a resistivity value of 289 ohm-m, probably suggesting a sandy loam soil. The second
type occurred at VES points 2, 3 and 4, and is likely considered to be composed of fresh crystalline basement,
but at VES point 2 it is the oil pipeline which runs N-S across the VES profile. The third and final layer along the
N-S profile is composed of one soil type, which occurred at VES point 1, and is also considered a region of
fractured basement predominantly composed of gravelly sand.
     The interpreted resistivity data for the final models of each of the remaining four VES points along the E-W
profile in the study area were also interpreted in a similar way. Geologic section of some selected VES points are
shown in fig.4.
     In order to investigate other hydrogeophysical aspects of the study area, two isoresistivity maps and
isopach map were also prepared from the interpreted VES data, through contouring. These maps include the
isoresistivity map of the top layer (fig.5), the isoresistivity map at 5m depth (fig.6) and the isopach map of
aquifer (over burden and fractured basement) fig.7. The isoresistivity map of the top layer was primarily
produced to show the variation of resistivity of the topmost layer, which would be a function of the surface
geology of the study area. It could also suggest the possible existence of spilled oil saturated zones in the top
layer.
     Table 2 shows that the resistivity values of the upper layer range from 54-714,683 ohm-m at around VES 5
and 6, respectively. The figure further shows the zone with lowest resistivity values (>100 ohm-m), suggesting
that the soil formations within the zone consists of sand, silt and clay. The zone occurs largely in the western part
of the study area and some portions of its northern parts. The zone with medium resistivity values in the range of
711 ohm-m occurs around the central portion of the study area VES 7, and consists of fractured basement. The
low resistivity zone occurs at the eastern portion of the area, and is occupied by dry sand. These three zones have
incidentally coincided with what was obtained in the geologic section earlier derived at the corresponding VES
points. Moreover the interpreted categories of soils were physically mapped at the study are during the field data
acquisition after the dug pits were logged.
   Two high resistivity areas were identify in the topmost layer around VES 3 and 6,this areas might have been
polluted by spilled oil which accounts for the high resistivity values. The top layers in this areas were interpreted
to be sand,silt and clay. Due to the plastic nature of clay when wet, it usually expands when in contact with
rainwater, and as it does so it squeezes out the entrapped in it (Deer, et al., 1963; Bragg and Claringbull, 1965).
However, in the dry season when not in contact with water, the clay will shrink and crack, thereby releasing the
trapped oils. This mechanism continued in an alternating way following the dry and the wet seasons (Barrer,
1978), and the oil released during the wet season is the one responsible for the impression that the pipeline might
still be leaking.




                                                         14
Journal of Environment and Earth Science                                                                 www.iiste.org
ISSN 2224-3216 (Paper) ISSN 2225-0948 (Online)
Vol 2, No.4, 2012


1.1.1.1 Conclusion
The main conclusion reached from the study is that the pipes are no more leaking, and that the usual sources of
water in the study area are still contaminated with organic crude oil. For an effective and successful mitigation
operation, the cause of the spillage was accurately identified as due to the alternate trapping and releasing of part
of the oil that already leaked by plastic clay particles in the rainy and dry seasons. Simple excavation, evacuation
and disposal of the contaminated soils, and cleanliness of the polluted surroundings, are some of the methods of
improving and safeguarding further apparent leakage of the oil.

ACKNOWLEDGEMENT

The Department of Physics, A.B.U. Zaria, provided equipment and transport for the fieldwork component of this
work, and we are grateful. Our thanks go to P.M. Zaborski, M. A. Y. Hotoro and Mr. T. Najime for their valuable
suggestions in the course of preparation of this manuscript.


References
Ajayi, S. O. and Osibanjo, O., (1981). Pollution studies on Nigerian Rivers: Water quality of some Nigerian
rivers, Jour, of Env. Poll. 2:87-95
Barrer, R.M., (1978). Zeolites and Clay Minerals as Sorbents and Molecular Sieves. Academic Press, New York.
Bragg, L. and G.F. Claringbull, (1965). Crystal structures of minerals, Bell and Sons, p. 281.
Bowen, J. M.,(1979). Environmental Chemistry of the elements. Academic Press New York, p 74.
Concawe Report No. 10/83, (1983). A field guide to in / and spills and clean Strategy, TotalFinaElf Company
Ltd, p.22.
Coulon, C., Vidal, P., Dupuy, C., Popoff, M., Maluski, H., Hermite, D., (1996). The                 Mesozoic to
early Cenozoic magmatism of the Benue trough (Nigeria); geochemical evidence for the involvement of the St
Helena plume. Journal of Petrology37 (6), 1341–1358.
Danbatta, U. A. (2000): The role of physics in National development: Environmental issues. In: Proceedings of
the Annual Conference of Nigerian Institute of Physics (NIP), A.B.U., Zaria.
Danbatta U. A., M. B. Abubakar, W. B. Malgwi, M .L. Balarabe, and S. S. Adefila, (2002): Oil pipeline leakage
and geological formations, as part of a report on the post Impact Assessment of crude oil spillage at Izom area,
(in press).
Deer, W.A., Howie, R.A. and Zussmann, J., (1963). Rock forming Minerals, vol. VI, Longmans.
Eze, RAM., (2002). Oil pollution in the Riverine areas a study of Akwa-lbom State, Global Joum. Of Env.Scien.,
vo; (1), 1, pp. 21-26.
Federal Replublic of Nigeria, (1981-1985). Fourth National Development plan, L.agos, National Planning
office, pp.129.
Federal Environmental Protection Agency, (1991). Interim Guidelines and Standards for Environmental
Pollution Control in Nigeria, pp. 238.
Kakulu, S.E. and O. Osibanjo, (1988). Trace heavy metal polution studies in sediments of the Niger delta area of
Nigeria. J. Chem. Soc. Nigeria, 13:9-15.
Kakulu, S.E. and O. Osibanjo, (1992). Pollution studies of Nigerian rivers: Trace metals of surface waters in the
Niger Delta area. Int. J. Environ Stud. 41:287
Keller, G.V. and Frishnecht, F.D., (1966). Electrical methods in Geophysical Prospecting. Pergamon Press, New
York.
Kerry, P. and Brooks, M., (1984): An introduction to geophysical exploration. English Language Book Society
(ELBS). Blackwell Scientific Publications, 288 pp.
Telford, W.M., Geldart, L.P., Sheriff, R.E. and Keys, D.A,(1976): Appted Geophysics, Cambridge University
Press, London, 860pp.
USGS,( 1986). Study and interpretation of the chemical characteristics of natural water. USGS Water Supply
Paper, p 2254.
Ward, R.C. and Robinson, M.,( 1989). Principles of Hydrology. McGraw-Hill Publishers Ltd., London, pp.
79-103.
WHO, (1984). World Health Organization, Guidelines on Drinking Water Quality. Vol. I, II & III.
WHO, (1988). World Health Organization, Training course manuals for water and wastewater laboratory
techniques., Geneva, p 116.
World Bank, (1991). Environmental Assessment Sourcebook, Vol. III. The World Bank Washington D.C.




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Journal of Environment and Earth Science                                                     www.iiste.org
ISSN 2224-3216 (Paper) ISSN 2225-0948 (Online)
Vol 2, No.4, 2012



Table 1:    Electrode separation and field data of VES points

 AB/2         MN/2         VES1         VES1       VES3         VES4   VES5   VES6    VES7       VES8
  (m)          (m)         (Ωm)         (Ωm)       (Ωm)         (Ωm)   (Ωm)   (Ωm)    (Ωm)       (Ωm)
 1.00          0.5          168          166        204          401     51    528     377        166
 1.50          0.5          147          148       1340          315     41    278     646        142
 2.50          0.5          104          171       1524          225    108   1038     348        122
 3.75          0.5          80           220       1319          203    526    849     248        124
 5.00          0.5          66           274       1172          221    425    700     219        148
 7.500         0.5          385          700       1414          449    722    978    1511        536
 10.00         0.5          149          506        646          576    343    329     261        264
 15.00         1.5          284          626        515          420    423    441     357        491
 25.00         1.5         3751         1200        787          649    713    803    2706        918
 37.50         1.5         7610         1612       20.98         681   1709   2393    1229       1206
 50.0          1.5          548         1843       1717         1472   1240   1545     819       1189
 75.00         5.0          550         1842       3200         3117   1556   3166     570        978
 10.0          5.0          954         2178       4676         2755   1577   4738     369        338

Table 2:    Computer Interpretation of VES Data

                                                 DEPTH (m)                    RESISTIVITY (m)
             VES1                                 7.26040                           100.722
                                                  13.2622                           288.920
                                                 INFINITY                           400.693
             VES2                                   2.42                            146.947
                                                 INFINITY                          5071.881
             VES3                                  30.538                          1605.148
                                                 INFINITY                         62479.000
             VES4                                  1.784                            198.174
                                                 INFINITY                          4950.040
             VES5                                  0.598                             53.784
                                                   16.093                           427.222
                                                   31.026                          2214.760
                                                 INFINITY                         10029.134
             VES6                                  19.461                           714683
                                                   33.699                        270968.000
                                                   52.414                          8568.866
                                                 INFINITY                            53.272
             VES7                                   1.23                            711.713
                                                   15.05                           197.1292
                                                 INFINITY                           97.1292
             VES8                                  6.780                            113.674
                                                 INFINITY                          2414.414




                                                           16
Journal of Environment and Earth Science                                  www.iiste.org
ISSN 2224-3216 (Paper) ISSN 2225-0948 (Online)
Vol 2, No.4, 2012




Fig.1: Location map of the study area (adopted from Coulon et al.,1996)




                                                   17
Journal of Environment and Earth Science                                         www.iiste.org
ISSN 2224-3216 (Paper) ISSN 2225-0948 (Online)
Vol 2, No.4, 2012




                                        Fig.2: Geologic Map of the study area.




                                                         18
Journal of Environment and Earth Science                                                  www.iiste.org
ISSN 2224-3216 (Paper) ISSN 2225-0948 (Online)
Vol 2, No.4, 2012




                            Fig.3: Geologic map of the study area showing VES locations




                                      Fig.4: Geologic section of VES 2, 4, 6 and 8




                                                          19
Journal of Environment and Earth Science                                             www.iiste.org
ISSN 2224-3216 (Paper) ISSN 2225-0948 (Online)
Vol 2, No.4, 2012




                                        Fig.5: Isoresistivity Map of the top layer




                                        Fig.6: Isoresistivity map at a depth of 5M




                                                           20
Journal of Environment and Earth Science                                                 www.iiste.org
ISSN 2224-3216 (Paper) ISSN 2225-0948 (Online)
Vol 2, No.4, 2012




                                  Fig.7: Isopach map of the aquifer in the study area.




                                                          21
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Application of resistivity sounding in environmental studies

  • 1. Journal of Environment and Earth Science www.iiste.org ISSN 2224-3216 (Paper) ISSN 2225-0948 (Online) Vol 2, No.4, 2012 Application of Resistivity Sounding In Environmental Studies: A Case Study of Kazai Crude-Oil Spillage Niger State, Nigeria Abubakar Yusuf Ismail* and Umar Adamu Danbatta Department of Geology, Ahmadu Bello University, Zaria. Kaduna State, Nigeria *E-mail of Correponding Author: ismi_asma@yahoo.com, ismazee2003@gmail.com. Abstract A pipeline conveying crude oil from Escravos via Izom ruptured in the year 2000 and polluted the Kazai area, although the ruptured pipe was replaced and the site cleaned up, an examination of the point of spillage two years later gave the impression that the pipeline might be still leaking. The present work presents the use of Vertical Electrical Soundings (VES) techniques, and systematic trenching, to determine the source of this environmental problem. A total number of eight soundings along two profiles were carried out around the point of spillage, and data analysis revealed that the area is predominantly clayey in nature, and that the pipes are no longer leaking. Due to the plasticity of the clay when wet, it expands when in contact with rainwater and, as it does so, it entrapped any oil existing around it. However, when not in contact with water in the dry season, the clay shrinks and cracks, thereby releasing the trapped oils. This mechanism continued seasonally, and the oil released during the dry season, is the one responsible for the apparent leakage of the pipeline. Geoelectric models in the form of Vertical Isoresistivity Sections (VIS) and Isoresistiviy Maps were plotted. These were used to delineate the polluted zones, which were recommended for excavation and refilling. Keywords: Vertical Electrical sounding, Geoelectric Models, Isopach map, Isoresistivity Map. 1. Introduction In the Izom area of Niger State Nigeria, an underground high pressure pipeline that is conveying crude oil from Escravos to the Kaduna Nigerian National Petroleum Cooperation ( N.N.P.C) refinery got ruptured at Kazai (km 198) in the year 2000. This caused severe environmental pollution and considerable ecological damage, in the form of water pollution and loss of access to farmlands, which was immediately arrested. The Kazai area of Izom lies within the Basement Complex region of northern Nigeria (Fig. 1), and is about 30 km south of Sarkin Pawa, and about 20km East of Gwada. Danbatta et al. (2002) discussed the different basement rock types found in the study area, which include migmatites, gneisses, metasediments (schists, quartzites), and Older Granites. The dominant rock types are the migmatitic-gneisses, with subordinate amount of the Older Granites, one of which outcropped near the point of spillage (Fig. 2).The crude oil pipeline is trending at 010° around the point of spillage, and the spillage occurred along a tributary of River Dinya, which is sometimes called River Dapulo (Fig. 2). Although the ruptured pipe was replaced and the site cleaned up, oil kept appearing on the surface polluting the water resources in the area particularly during the wet season. The present work illustrate the application electrical resistivity survey to environmental studies, with the sole aim of investigating the source of the persistent appearance of oil on the surface and to point out areas where urgent intervention is needed for the rational use and protection of the water resources of the area 1.1 Materials and methods A reconnaissance survey was first undertaken in order to study the location and nature of the oil spillage, and used to delimit the study area. Literature review, fieldwork, and laboratory analysis were undertaken during the investigations. Eight (8) surface Vertical Electrical Soundings (VES) geophysical data were acquired using an ABEM Terrameter SAS 300, and a Schlumberger electrode array with a maximum electrode spacing of 100 m. The 8 VES stations were established on two profiles, trending N-S and E-W (Fig. 3). Moreover two large pits were dug to physically observe the soil profile in the study area. The data obtained were then reduced and were subjected to both qualitative and quantitatively interpretation using different analytical methods. 1.1.1 Results and discussion The data acquired from the eight soundings are presented in Table 1, and the field curves are predominantly three-layer A and H-types. The thickness of the most conducting layers in the study area varied from 12 to 117m with resistivities in the range of 4 to 115 ohm-m. Geoelectric models for the spillage site in the form of Vertical Iso-ohms Section (VIS) and Iso-ohms Map (Resistivity contours) at different depths were plotted. These were used to delineate the polluted zones around the west and central areas of the point of spillage. The acquired VES field curves were initially interpreted using the conventional partial curve matching 13
  • 2. Journal of Environment and Earth Science www.iiste.org ISSN 2224-3216 (Paper) ISSN 2225-0948 (Online) Vol 2, No.4, 2012 technique and the Petrowski's method (Telford et al., 1976). Initial estimates of the resistivities and thickness of the various geoelectric layers were deduced from this preliminary interpretation. The deduced parameters were later used as starting models in a "Zohdy" computer program. This computer assisted resistivity interpretation is based on the calculation of theoretical VES curves, and gave the 'best fit' for the data obtained. The final computed computer parameters for VES1 are hi = 7.26m, rho (ρ1) = 100 Ωm, h2 -13.26 m, ρ 2=289 Ωm, ρ3=401 Ωm. Root mean square( R.m.s) error for the final model was 4.2, and the suggested depth of the third layer (h3) is infinity. A similar procedure as discussed above was followed in the interpretation of all the remaining 7 VES points collected for this work, and the result presented in Table 2. The resulting interpreted models of the various profiles sounded were used to produce geoelectric sections, geologic sections, isopach maps, and isoresistivity (iso-ohms) maps for the surface, overburden and basement. The composite geoelectric section was obtained for the four VES points established along the N-S profile. It suggests that the subsurface along the profile is made up of 3 layers at VES point 1, while 2-layers underlay VES points 2, 3 and 4. The resistivity of the first layer in all the VES points ranges from 100.7-1605 ohm-m, and the thickness of the layer varies from 2.42 m to 30.54 m . The second layer has a resistivity in the range of 289-62479 Ωm, and the thickness of this second layer varies from 13.26 m –Infinity. The third layer is the deepest and has resistivity values in the range of 400 Ωm. The geoelectric section derived from the interpreted VES data was converted to geologic section based on available borehole data and dug pit in the area. The geologic section derived along the N-S profile suggests that the first layer likely consists of two different types of soils. The high resistivity zone (5071 ohm-m) of the layer occurring around VES point 2 is considered to be fresh crystalline rock. The second soil type occurred at zones with relatively medium resistivity values (100-198 ohm-m), which occurred at VES points 1, 2 and 4, and is considered to be dry clay. The data also suggests that the second layer likely consists of two types of soils. The first type occurred at around VES point 1, with a resistivity value of 289 ohm-m, probably suggesting a sandy loam soil. The second type occurred at VES points 2, 3 and 4, and is likely considered to be composed of fresh crystalline basement, but at VES point 2 it is the oil pipeline which runs N-S across the VES profile. The third and final layer along the N-S profile is composed of one soil type, which occurred at VES point 1, and is also considered a region of fractured basement predominantly composed of gravelly sand. The interpreted resistivity data for the final models of each of the remaining four VES points along the E-W profile in the study area were also interpreted in a similar way. Geologic section of some selected VES points are shown in fig.4. In order to investigate other hydrogeophysical aspects of the study area, two isoresistivity maps and isopach map were also prepared from the interpreted VES data, through contouring. These maps include the isoresistivity map of the top layer (fig.5), the isoresistivity map at 5m depth (fig.6) and the isopach map of aquifer (over burden and fractured basement) fig.7. The isoresistivity map of the top layer was primarily produced to show the variation of resistivity of the topmost layer, which would be a function of the surface geology of the study area. It could also suggest the possible existence of spilled oil saturated zones in the top layer. Table 2 shows that the resistivity values of the upper layer range from 54-714,683 ohm-m at around VES 5 and 6, respectively. The figure further shows the zone with lowest resistivity values (>100 ohm-m), suggesting that the soil formations within the zone consists of sand, silt and clay. The zone occurs largely in the western part of the study area and some portions of its northern parts. The zone with medium resistivity values in the range of 711 ohm-m occurs around the central portion of the study area VES 7, and consists of fractured basement. The low resistivity zone occurs at the eastern portion of the area, and is occupied by dry sand. These three zones have incidentally coincided with what was obtained in the geologic section earlier derived at the corresponding VES points. Moreover the interpreted categories of soils were physically mapped at the study are during the field data acquisition after the dug pits were logged. Two high resistivity areas were identify in the topmost layer around VES 3 and 6,this areas might have been polluted by spilled oil which accounts for the high resistivity values. The top layers in this areas were interpreted to be sand,silt and clay. Due to the plastic nature of clay when wet, it usually expands when in contact with rainwater, and as it does so it squeezes out the entrapped in it (Deer, et al., 1963; Bragg and Claringbull, 1965). However, in the dry season when not in contact with water, the clay will shrink and crack, thereby releasing the trapped oils. This mechanism continued in an alternating way following the dry and the wet seasons (Barrer, 1978), and the oil released during the wet season is the one responsible for the impression that the pipeline might still be leaking. 14
  • 3. Journal of Environment and Earth Science www.iiste.org ISSN 2224-3216 (Paper) ISSN 2225-0948 (Online) Vol 2, No.4, 2012 1.1.1.1 Conclusion The main conclusion reached from the study is that the pipes are no more leaking, and that the usual sources of water in the study area are still contaminated with organic crude oil. For an effective and successful mitigation operation, the cause of the spillage was accurately identified as due to the alternate trapping and releasing of part of the oil that already leaked by plastic clay particles in the rainy and dry seasons. Simple excavation, evacuation and disposal of the contaminated soils, and cleanliness of the polluted surroundings, are some of the methods of improving and safeguarding further apparent leakage of the oil. ACKNOWLEDGEMENT The Department of Physics, A.B.U. Zaria, provided equipment and transport for the fieldwork component of this work, and we are grateful. Our thanks go to P.M. Zaborski, M. A. Y. Hotoro and Mr. T. Najime for their valuable suggestions in the course of preparation of this manuscript. References Ajayi, S. O. and Osibanjo, O., (1981). Pollution studies on Nigerian Rivers: Water quality of some Nigerian rivers, Jour, of Env. Poll. 2:87-95 Barrer, R.M., (1978). Zeolites and Clay Minerals as Sorbents and Molecular Sieves. Academic Press, New York. Bragg, L. and G.F. Claringbull, (1965). Crystal structures of minerals, Bell and Sons, p. 281. Bowen, J. M.,(1979). Environmental Chemistry of the elements. Academic Press New York, p 74. Concawe Report No. 10/83, (1983). A field guide to in / and spills and clean Strategy, TotalFinaElf Company Ltd, p.22. Coulon, C., Vidal, P., Dupuy, C., Popoff, M., Maluski, H., Hermite, D., (1996). The Mesozoic to early Cenozoic magmatism of the Benue trough (Nigeria); geochemical evidence for the involvement of the St Helena plume. Journal of Petrology37 (6), 1341–1358. Danbatta, U. A. (2000): The role of physics in National development: Environmental issues. In: Proceedings of the Annual Conference of Nigerian Institute of Physics (NIP), A.B.U., Zaria. Danbatta U. A., M. B. Abubakar, W. B. Malgwi, M .L. Balarabe, and S. S. Adefila, (2002): Oil pipeline leakage and geological formations, as part of a report on the post Impact Assessment of crude oil spillage at Izom area, (in press). Deer, W.A., Howie, R.A. and Zussmann, J., (1963). Rock forming Minerals, vol. VI, Longmans. Eze, RAM., (2002). Oil pollution in the Riverine areas a study of Akwa-lbom State, Global Joum. Of Env.Scien., vo; (1), 1, pp. 21-26. Federal Replublic of Nigeria, (1981-1985). Fourth National Development plan, L.agos, National Planning office, pp.129. Federal Environmental Protection Agency, (1991). Interim Guidelines and Standards for Environmental Pollution Control in Nigeria, pp. 238. Kakulu, S.E. and O. Osibanjo, (1988). Trace heavy metal polution studies in sediments of the Niger delta area of Nigeria. J. Chem. Soc. Nigeria, 13:9-15. Kakulu, S.E. and O. Osibanjo, (1992). Pollution studies of Nigerian rivers: Trace metals of surface waters in the Niger Delta area. Int. J. Environ Stud. 41:287 Keller, G.V. and Frishnecht, F.D., (1966). Electrical methods in Geophysical Prospecting. Pergamon Press, New York. Kerry, P. and Brooks, M., (1984): An introduction to geophysical exploration. English Language Book Society (ELBS). Blackwell Scientific Publications, 288 pp. Telford, W.M., Geldart, L.P., Sheriff, R.E. and Keys, D.A,(1976): Appted Geophysics, Cambridge University Press, London, 860pp. USGS,( 1986). Study and interpretation of the chemical characteristics of natural water. USGS Water Supply Paper, p 2254. Ward, R.C. and Robinson, M.,( 1989). Principles of Hydrology. McGraw-Hill Publishers Ltd., London, pp. 79-103. WHO, (1984). World Health Organization, Guidelines on Drinking Water Quality. Vol. I, II & III. WHO, (1988). World Health Organization, Training course manuals for water and wastewater laboratory techniques., Geneva, p 116. World Bank, (1991). Environmental Assessment Sourcebook, Vol. III. The World Bank Washington D.C. 15
  • 4. Journal of Environment and Earth Science www.iiste.org ISSN 2224-3216 (Paper) ISSN 2225-0948 (Online) Vol 2, No.4, 2012 Table 1: Electrode separation and field data of VES points AB/2 MN/2 VES1 VES1 VES3 VES4 VES5 VES6 VES7 VES8 (m) (m) (Ωm) (Ωm) (Ωm) (Ωm) (Ωm) (Ωm) (Ωm) (Ωm) 1.00 0.5 168 166 204 401 51 528 377 166 1.50 0.5 147 148 1340 315 41 278 646 142 2.50 0.5 104 171 1524 225 108 1038 348 122 3.75 0.5 80 220 1319 203 526 849 248 124 5.00 0.5 66 274 1172 221 425 700 219 148 7.500 0.5 385 700 1414 449 722 978 1511 536 10.00 0.5 149 506 646 576 343 329 261 264 15.00 1.5 284 626 515 420 423 441 357 491 25.00 1.5 3751 1200 787 649 713 803 2706 918 37.50 1.5 7610 1612 20.98 681 1709 2393 1229 1206 50.0 1.5 548 1843 1717 1472 1240 1545 819 1189 75.00 5.0 550 1842 3200 3117 1556 3166 570 978 10.0 5.0 954 2178 4676 2755 1577 4738 369 338 Table 2: Computer Interpretation of VES Data DEPTH (m) RESISTIVITY (m) VES1 7.26040 100.722 13.2622 288.920 INFINITY 400.693 VES2 2.42 146.947 INFINITY 5071.881 VES3 30.538 1605.148 INFINITY 62479.000 VES4 1.784 198.174 INFINITY 4950.040 VES5 0.598 53.784 16.093 427.222 31.026 2214.760 INFINITY 10029.134 VES6 19.461 714683 33.699 270968.000 52.414 8568.866 INFINITY 53.272 VES7 1.23 711.713 15.05 197.1292 INFINITY 97.1292 VES8 6.780 113.674 INFINITY 2414.414 16
  • 5. Journal of Environment and Earth Science www.iiste.org ISSN 2224-3216 (Paper) ISSN 2225-0948 (Online) Vol 2, No.4, 2012 Fig.1: Location map of the study area (adopted from Coulon et al.,1996) 17
  • 6. Journal of Environment and Earth Science www.iiste.org ISSN 2224-3216 (Paper) ISSN 2225-0948 (Online) Vol 2, No.4, 2012 Fig.2: Geologic Map of the study area. 18
  • 7. Journal of Environment and Earth Science www.iiste.org ISSN 2224-3216 (Paper) ISSN 2225-0948 (Online) Vol 2, No.4, 2012 Fig.3: Geologic map of the study area showing VES locations Fig.4: Geologic section of VES 2, 4, 6 and 8 19
  • 8. Journal of Environment and Earth Science www.iiste.org ISSN 2224-3216 (Paper) ISSN 2225-0948 (Online) Vol 2, No.4, 2012 Fig.5: Isoresistivity Map of the top layer Fig.6: Isoresistivity map at a depth of 5M 20
  • 9. Journal of Environment and Earth Science www.iiste.org ISSN 2224-3216 (Paper) ISSN 2225-0948 (Online) Vol 2, No.4, 2012 Fig.7: Isopach map of the aquifer in the study area. 21
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