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CHE 199 BIOFUELS FINAL PROJECT Gavin Chen
Production of Ethanol Page 1 of 15
Production of Ethanol with Corn
Using Dry Milling Method
Section Page Number
Block Flow Diagram pg 2
Process Flow Diagram pg 3
Biological Pathway & Chemical Reactions pg 5
Mass and Energy Balance pg 6
Sizing a CSTR Fermenter pg 8
Piping and Instrumentation Diagram pg 9
Characterization of Streams pg 10
Hazard and Operability Study pg 11
Capital Expenditure pg 12
Operation Expenditure pg 13
Reference pg 15
Dec. 20th
2016
By Gavin Chen
CHE 199 BIOFUELS FINAL PROJECT Gavin Chen
Production of Ethanol Page 2 of 15
Block Flow Diagram
The Dry Mill Process will happen in 4 basic steps
The first process is the preprocessing process. In this step, the dry corn feedstock would be
mashed into smaller particle sizes. Then the dry corn feedstock would be treated with fresh water
for hydrolysis process.
The second process is the liquefaction and the saccharification process. The hydrolyzed corn
feedstock would be treated with hot steam through jet cooker. In the liquefaction step, the
enzyme, Alpha Amylase, is added to perform saccharification for converting corn into glucose
slurry.
The third process is the fermentation process. The purpose of fermentation is to convert glucose
slurry to alcohol slurry. Gluco Amylase and yeast are required for this process. The residence
time of the glucose slurry should be between 50 to 60 hours, and it is determined to be 60 hours
for maximum conversion.
The forth process is the purification process. The alcohol slurry would be transferred to a
distillation column. The desired ethanol would be vaporized to the overhead of the column.
Then, the ethanol-water azeotrope would be further purify. The co-product, DDGS, would be
dried and put to a storage.
CHE 199 BIOFUELS FINAL PROJECT Gavin Chen
Production of Ethanol Page 3 of 15
Process Flow Diagram
This process begins by breaking the dry corn feedstock from the storage tank (TK-110) into
smaller particle sizes through the Hammer Mill (V-410). Then the dry corn would be mixed with
fresh water(TK-120) to perform hydrolysis in the cyclone (TK-130).
The second step involves liquefaction and saccharification. The corn slurry from cyclone (TK-
130) would be transferred and heated through a steam jet cooker (E-210). This process
approximately takes about 30 to 40 minutes and the slurry is heated to 70 degrees C. Then, the
corn slurry is transferred to the liquefaction reactor (R-510) in order to convert corn slurry to
glucose slurry. The required enzyme, Alpha Amylase, would be added from the tank (TK-140).
The liquefaction process performs at the temperature between 85 to 95 degrees C. After the
liquefaction process, the glucose slurry would be discharged into a knock-out drum (E-220) for
the mash cooling process. When the temperature of the glucose slurry drops to 32 degrees C, the
glucose slurry would be ready for the fermentation process.
In the fermentation process (R-520), the entire process takes 60 hours for converting glucose
slurry to alcohol slurry with the maximum yield.
After the fermentation process, the next stage is the purification process. The alcohol slurry
would be transferred to the distillation column (T-310). The desired ethanol-water azeotrope
would be separated out in the overhead of the column through vaporization. The desired pure
ethanol product would be stored in the tank (TK-160). The remaining slurry would be discharged
from the bottom of the column. The ethanol-water azeotrope would be purified again through
CHE 199 BIOFUELS FINAL PROJECT Gavin Chen
Production of Ethanol Page 4 of 15
molecular sieves (T-320&T-330) for extracting out the majority of the water component. The
remaining slurry would be transferred to the knock-out drum (V-430) through the centrifuge (V-
420). After the slurry gets dried, the DDGS would be stored in the cyclone (TK-170).
CHE 199 BIOFUELS FINAL PROJECT Gavin Chen
Production of Ethanol Page 5 of 15
Biological Pathway
This report discusses the Dry Milling Method to produce Ethanol.
The process begins by adding process water to the milled corn grains, adjusting the pH to about
6, and adding a thermostable Alpha Amylase. The following step is starch liquefaction. After the
dry corn feedstock gets converted into glucose slurry by using thermal and pressure energy, the
glucose slurry gets transferred into the reactor for fermentation. While fermenting, the yeast,
Saccharomyces Cerevisiae, is added for ethanol production. The main reaction in the
fermentation stage is given as
𝐶6 𝐻12 𝑂6 + 2𝑃𝑖 + 2𝐴𝐷𝑃 → 2𝐶2 𝐻5 𝑂𝐻 + 2𝐶𝑂2 + 2𝐴𝑇𝑃 + 2𝐻2 𝑂
𝐺𝑙𝑢𝑐𝑜𝑠𝑒 → 2 𝑒𝑡ℎ𝑎𝑛𝑜𝑙 + 2 𝑐𝑎𝑟𝑏𝑜𝑛 𝑑𝑖𝑜𝑥𝑖𝑑𝑒 + 𝑒𝑛𝑒𝑟𝑔𝑦
The theoretical yield is 0.511 𝑔 ethanol produced per gram glucose consumed. According to our
references and the adjustments due to the current market, the conversion factor of kg ethanol
produced per kg dry corn consumed is 0.3104. Our basis of corn feedstock is 1,000,000 metric
tons of corn feedstock which contains 85% dry corn and 15% moisture.
The following report discusses the process design of ethanol production starting with 1,000,000
metric tons of feedstock per hour as the initial mass flow rate to begin with.
CHE 199 BIOFUELS FINAL PROJECT Gavin Chen
Production of Ethanol Page 6 of 15
Mass and Energy Balance
The theoretical yield of ethanol from starch:
(𝐶6 𝐻10 𝑂5) 𝑛 + 𝐻2 𝑂 → 𝐶6 𝐻12 𝑂6 → 2𝐶2 𝐻5 𝑂𝐻 + 2𝐶𝑂2
Assumptions:
𝑆𝑡𝑎𝑟𝑐ℎ(𝑘𝑔) = 0.6 𝐷𝑟𝑦𝐶𝑜𝑟𝑛(𝑘𝑔)
90% ethanol yield
𝑌𝑒𝑎𝑠𝑡 = 0.0008(𝐺𝑙𝑢𝑐𝑜𝑠𝑒 𝑆𝑙𝑢𝑟𝑟𝑦)
𝐴𝑙𝑝ℎ𝑎 𝐴𝑚𝑦𝑙𝑎𝑠𝑒 = 0.0001(𝐷𝑟𝑦 𝑐𝑜𝑟𝑛)
𝑚 𝑦𝑒𝑎𝑠𝑡 = 172 𝑔/𝑚𝑜𝑙
Basis:
1,000,000
𝑚𝑒𝑡𝑟𝑖𝑐 𝑡𝑜𝑛
𝑦𝑒𝑎𝑟
𝐶𝑜𝑟𝑛 𝑓𝑒𝑒𝑑𝑠𝑡𝑜𝑐𝑘 𝑤𝑖𝑡ℎ 15% 𝑚𝑜𝑖𝑠𝑡𝑢𝑟𝑒
1,000,000
𝑚𝑒𝑡𝑟𝑖𝑐 𝑡𝑜𝑛
𝑦𝑒𝑎𝑟
1.10231 𝑡𝑜𝑛
𝑚𝑒𝑡𝑟𝑖𝑐 𝑡𝑜𝑛
2000 𝑙𝑏
𝑡𝑜𝑛
𝑦𝑒𝑎𝑟
330 𝑑𝑎𝑦
𝑑𝑎𝑦
24 ℎ𝑟
= 280,000
𝑙𝑏
ℎ𝑟
𝐶𝑜𝑟𝑛 𝐹𝑒𝑒𝑑𝑠𝑡𝑜𝑐𝑘
280,000
𝑙𝑏
ℎ𝑟
𝑐𝑜𝑟𝑛 ∗ (0.85) = 240,000
𝑙𝑏
ℎ𝑟
𝑑𝑟𝑦 𝑐𝑜𝑟𝑛
240,000
𝑙𝑏
ℎ𝑟
𝑑𝑟𝑦 𝑐𝑜𝑟𝑛 (0.617) = 150,000
𝑙𝑏
ℎ𝑟
𝑆𝑡𝑎𝑟𝑐ℎ = 68,000
𝑘𝑔
ℎ
𝑆𝑡𝑎𝑟𝑐ℎ
= 380
𝑘𝑚𝑜𝑙
ℎ
𝑆𝑡𝑎𝑟𝑐ℎ
Based on the stoichiometry:
380
𝑘𝑚𝑜𝑙
ℎ
𝑠𝑡𝑎𝑟𝑐ℎ + 380
𝑘𝑚𝑜𝑙
ℎ
𝑊𝑎𝑡𝑒𝑟 → 380 𝑀𝑀
𝑘𝑚𝑜𝑙
ℎ
𝑔𝑙𝑢𝑐𝑜𝑠𝑒
→ 2(380
𝑘𝑚𝑜𝑙
ℎ
𝑒𝑡ℎ𝑎𝑛𝑜𝑙) + 2(380
𝑘𝑚𝑜𝑙
ℎ
𝐶𝑂2)
CHE 199 BIOFUELS FINAL PROJECT Gavin Chen
Production of Ethanol Page 7 of 15
Amount of water used in fermentation:
380
𝑘𝑚𝑜𝑙
ℎ
𝑤𝑎𝑡𝑒𝑟 = 6,900
𝑘𝑔
ℎ
𝑤𝑎𝑡𝑒𝑟 = 15,000
𝑙𝑏
ℎ
𝑤𝑎𝑡𝑒𝑟 = 30 𝑔𝑝𝑚 𝑤𝑎𝑡𝑒𝑟
Theoretical yield of glucose:
380 𝑘𝑚𝑜𝑙
𝑔𝑙𝑢𝑐𝑜𝑠𝑒
ℎ𝑟
= 69,000
𝑘𝑔
ℎ𝑟
𝑔𝑙𝑢𝑐𝑜𝑠𝑒 = 150,000
𝑙𝑏
ℎ𝑟
𝑔𝑙𝑢𝑐𝑜𝑠𝑒
Theoretical yield of ethanol and CO2:
2 (380
𝑘𝑚𝑜𝑙
ℎ
𝑒𝑡ℎ𝑎𝑛𝑜𝑙) = 760
𝑘𝑚𝑜𝑙
ℎ𝑟
𝑒𝑡ℎ𝑎𝑛𝑜𝑙 = 35,000
𝑘𝑔
ℎ
𝑒𝑡ℎ𝑎𝑛𝑜𝑙 = 77,000
𝑙𝑏
ℎ𝑟
𝑒𝑡ℎ𝑎𝑛𝑜𝑙
= 195 𝑔𝑝𝑚 𝑒𝑡ℎ𝑎𝑛𝑜𝑙
2 (380
𝑘𝑚𝑜𝑙
ℎ𝑟
𝐶𝑂2) = 760
𝑘𝑚𝑜𝑙
ℎ𝑟
𝐶𝑂2 = 34,000
𝑘𝑔
ℎ𝑟
𝐶𝑂2 = 74,000
𝑙𝑏
ℎ𝑟
𝐶𝑂2
Alpha Amylase Calculation:
0.0001 (280,000
𝑙𝑏
ℎ𝑟
𝐷𝑟𝑦 𝐶𝑜𝑟𝑛) = 28
𝑙𝑏
ℎ𝑟
𝐴𝑙𝑝ℎ𝑎 𝐴𝑚𝑦𝑙𝑎𝑠𝑒
Yeast Calculation:
0.0008 (28
𝑙𝑏
ℎ𝑟
𝐴𝑙𝑝ℎ𝑎 𝑎𝑚𝑦𝑙𝑎𝑠𝑒 + 150,000
𝑙𝑏
ℎ𝑟
𝑔𝑙𝑢𝑐𝑜𝑠𝑒 + 15,000
𝑙𝑏
ℎ𝑟
𝑤𝑎𝑡𝑒𝑟) = 140
𝑙𝑏
ℎ𝑟
𝑦𝑒𝑎𝑠𝑡
Theoretical Yield of Ethanol:
0.90 (77,000
𝑙𝑏
ℎ𝑟
) = 69,000
𝑙𝑏
ℎ𝑟
𝑒𝑡ℎ𝑎𝑛𝑜𝑙 = 180 𝑔𝑝𝑚 𝑒𝑡ℎ𝑎𝑛𝑜𝑙
Amount of water outlet:
15,000
𝑙𝑏
ℎ𝑟
𝑤𝑎𝑡𝑒𝑟 − (0.90 ∗ 15,000
𝑙𝑏
ℎ𝑟
𝑤𝑎𝑡𝑒𝑟) = 1,500
𝑙𝑏
ℎ𝑟
𝑤𝑎𝑡𝑒𝑟 = 3 𝑔𝑝𝑚 𝑤𝑎𝑡𝑒𝑟
Amount of glucose outlet:
150,000
𝑙𝑏
ℎ𝑟
𝑔𝑙𝑢𝑐𝑜𝑠𝑒 − (0.90 ∗ 150,000
𝑙𝑏
ℎ𝑟
𝑔𝑙𝑢𝑐𝑜𝑠𝑒) = 15,000
𝑙𝑏
ℎ𝑟
𝑔𝑙𝑢𝑐𝑜𝑠𝑒
Total amount of beer slurry:
69,000
𝑙𝑏 𝑒𝑡ℎ𝑎𝑛𝑜𝑙
ℎ𝑟
+ 15,000
𝑙𝑏 𝑤𝑎𝑡𝑒𝑟
ℎ𝑟
+ 150,000
𝑙𝑏 𝑔𝑙𝑢𝑐𝑜𝑠𝑒
ℎ𝑟
+ 28
𝑙𝑏 𝑎𝑙𝑝ℎ𝑎 𝑎𝑚𝑦𝑙𝑎𝑠𝑒
ℎ𝑟
+ 140
𝑙𝑏 𝑦𝑒𝑎𝑠𝑡
ℎ𝑟
≈ 230,000
𝑙𝑏
ℎ𝑟
𝑏𝑒𝑒𝑟 𝑠𝑙𝑢𝑟𝑟𝑦
CHE 199 BIOFUELS FINAL PROJECT Gavin Chen
Production of Ethanol Page 8 of 15
Sizing a CSTR Fermenter
Calculations of Alcohol Slurry out of Fermenter
150,000
𝑙𝑏 𝑔𝑙𝑢𝑐𝑜𝑠𝑒
ℎ𝑟
𝑘𝑔
2.205
= 68,000
𝑘𝑔 𝑔𝑙𝑢𝑐𝑜𝑠𝑒
ℎ𝑟
𝑚3
1540 𝑘𝑔 𝑔𝑙𝑢𝑐𝑜𝑠𝑒
= 44
𝑚3
ℎ𝑟
𝑔𝑙𝑢𝑐𝑜𝑠𝑒
1,500
𝑙𝑏 𝑤𝑎𝑡𝑒𝑟
ℎ𝑟
𝑘𝑔
2.205
= 680
𝑘𝑔 𝑤𝑎𝑡𝑒𝑟
ℎ𝑟
𝑚3
1000 𝑘𝑔 𝑔𝑙𝑢𝑐𝑜𝑠𝑒
= 0.68
𝑚3
ℎ𝑟
𝑤𝑎𝑡𝑒𝑟
69,000
𝑙𝑏 𝑒𝑡ℎ𝑎𝑛𝑜𝑙
ℎ𝑟
𝑘𝑔
2.205
= 32,000
𝑘𝑔 𝑒𝑡ℎ𝑎𝑛𝑜𝑙
ℎ𝑟
𝑚3
789 𝑘𝑔 𝑒𝑡ℎ𝑎𝑛𝑜𝑙
= 40
𝑚3
ℎ𝑟
𝑒𝑡ℎ𝑎𝑛𝑜𝑙
Total Mass of Beer
68,000
𝑘𝑔 𝑔𝑙𝑢𝑐𝑜𝑠𝑒
ℎ𝑟
+ 680
𝑘𝑔 𝑤𝑎𝑡𝑒𝑟
ℎ𝑟
+ 32,000
𝑘𝑔 𝑒𝑡ℎ𝑎𝑛𝑜𝑙
ℎ𝑟
= 100,000
𝑘𝑔 𝑏𝑒𝑒𝑟 𝑠𝑙𝑢𝑟𝑟𝑦
ℎ𝑟
Total Volumetric Flow Rate
4
𝑚3
ℎ𝑟
𝑔𝑙𝑢𝑐𝑜𝑠𝑒 + 0.68
𝑚3
ℎ𝑟
𝑤𝑎𝑡𝑒𝑟 + 40
𝑚3
ℎ𝑟
𝑔𝑙𝑢𝑐𝑜𝑠𝑒 = 45
𝑚3
ℎ𝑟
𝑏𝑒𝑒𝑟 𝑠𝑙𝑢𝑟𝑟𝑦
Density of Beer Slurry
100,000
𝑘𝑔 𝑏𝑒𝑒𝑟 𝑠𝑙𝑢𝑟𝑟𝑦
ℎ𝑟
ℎ𝑟
45 𝑚3
= 2254
𝑘𝑔
𝑚3
𝑏𝑒𝑒𝑟 𝑠𝑙𝑢𝑟𝑟𝑦
GPM Flow Rate of Beer Slurry
100,000
𝑘𝑔 𝑏𝑒𝑒𝑟 𝑠𝑙𝑢𝑟𝑟𝑦
ℎ𝑟
𝑚3
2254 𝑘𝑔 𝑏𝑒𝑒𝑟 𝑠𝑙𝑢𝑟𝑟𝑦
264
𝑔𝑎𝑙
𝑚𝑖𝑛
ℎ𝑟
60 𝑚𝑖𝑛
= 197 gpm beer slurry
Total Capacity needed for 60 hours Residence Time
197
𝑔𝑎𝑙𝑙𝑜𝑛 𝑏𝑒𝑒𝑟𝑦 𝑠𝑙𝑢𝑟𝑟𝑦
𝑚𝑖𝑛
60
𝑚𝑖𝑛
ℎ𝑟
60 ℎ𝑟 𝑟𝑒𝑠𝑖𝑑𝑒𝑛𝑐𝑒 𝑡𝑖𝑚𝑒 = 707,843 gallons of beer
slurry_out
707,843 gallons
# 𝑜𝑓 𝐶𝑆𝑇𝑅 𝐹𝑒𝑟𝑚𝑒𝑛𝑡𝑒𝑟𝑠
15,000 𝑔𝑎𝑙𝑙𝑜𝑛𝑠
~ 47 𝐶𝑆𝑇𝑅 𝐹𝑒𝑟𝑚𝑒𝑛𝑡𝑒𝑟𝑠
CHE 199 BIOFUELS FINAL PROJECT Gavin Chen
Production of Ethanol Page 9 of 15
Piping and Instrumentation Diagram
This is the P&ID of R-520 Fermenter. Overall, there are 4 loops for monitoring this fermenter.
In Loop 1, we are detecting the flow rate of glucose slurry going in.
In Loop 2, we are detecting the temperature of steam stream going into the jacket in order to
control the flow of steam and to adjust the flow of condensate.
In Loop 3, we are detecting the pressure of the CO2 gas product coming out from the fermenter.
In Loop 4, we are detecting the leveling control in order to adjust the flow of the product stream
going out from the fermenter.
For the inlet and the outlet streams, 7” Schedule 40 Stainless Steel pipes are used for transferring
the glucose slurry and the alcohol slurry.
For the gas product stream, 4” Schedule 40 Stainless Steel pipe is used.
For the steam streams, 4” Schedule 40 Stainless Steel pipes are used for the incoming steam and
and the outgoing condensate.
CHE 199 BIOFUELS FINAL PROJECT Gavin Chen
Production of Ethanol Page 10 of 15
Characterization of Streams
These testing methods have been taken from ASTM method. ASTM standards are used world
wide to improve product quality, enhance safety.
D887 (11.02) is a practice used for sampling water-formed deposits.
E1758 (11.06) is test method for determination of carbohydrates in biomass by HPLC.
D3048 (15.04) is test method for enzymes assay
E346 (15.05) is test method for analysis of ethanol
CHE 199 BIOFUELS FINAL PROJECT Gavin Chen
Production of Ethanol Page 11 of 15
Hazard and Operability Study
If reactor temperature is too high, set parameters. Fouled or failed exchanger tubes. Fire
situation. Defective control valve. Internal Fires. Heating fluid/medium leaking. Faulty
instrumentation and control.
If higher pressure inside reactor happens, Surge problems for pump stop/starting or valve turning
on/off. Relief valve isolated. Thermal overpressure. Boiling. Worst case, explosion.
If reaching high level in reactor, reactor outlet blocked or isolated. Inflow greater than outflow.
Faulty level measurement. Pressure surges for sudden change in the velocity of the fluids; caused
by pump starting/stopping or valve opening/closing.
If power outage happens, lightning, high winds, ice storms. Accidents at power plants and
transmission lines.
CHE 199 BIOFUELS FINAL PROJECT Gavin Chen
Production of Ethanol Page 12 of 15
Capital Expenditure
CHE 199 BIOFUELS FINAL PROJECT Gavin Chen
Production of Ethanol Page 13 of 15
Operation Expenditure
In the Operation Expenditure, we are estimating the overall costs of the entire operation of our
Dry Milling Ethanol plant.
The basis of the feedstock is 280,000
𝑙𝑏 𝐷𝑟𝑦 𝐶𝑜𝑟𝑛
ℎ𝑟
. As the kg-ethanol-to-kg-corn conversion factor
given in the textbook, Biofuels Engineering Process Technology by C. Drapcho, N. Nhuan, and
T. Walker, being applied, the annual production of ethanol is estimated to be 90,000,000
𝑔𝑎𝑙𝑙𝑜𝑛𝑠 𝐸𝑡ℎ𝑎𝑛𝑜𝑙
𝑦𝑒𝑎𝑟
. According to the price of ethanol from Nasdaq.com, one gallon of ethanol is sold
for $1.80 USD. As result, the estimated annual revenue comes out to be around $162 million
USD.
The operating cost of steam is the major component in our budget. It takes 8 million dollars for
having 330,000 lb/hr steam in supporting each of the 47 fermenters we have and 1 reactor for
liquification over a year. The price of steam varies from
$2 𝑈𝑆𝐷
1000 𝑙𝑏 𝑆𝑡𝑒𝑎𝑚
to
$3 𝑈𝑆𝐷
1000 𝑙𝑏 𝑆𝑡𝑒𝑎𝑚
.
Unit cost of enzymes is respectively high comparing to others. The costs of enzymes include the
cost of Alpha Amylase in liquefaction, and the cost Glu Amylase in fermentation.
The cost of maintenance is 5% of the CapEx.
For the labor distribution, we plan to have 42 operators alternating 3 shifts a day. 14 engineers
doing safety check, 14 engineers doing maintenance, and 7 operating manager.
Due to the annual revenue, $162 millions USD, the operating cost, $155 millions USD, and the
capital cost, $17 millions, can be balanced off as a result of having positive $8 million USD.
The profit in 1st
is estimated to be $7 millions USD.
CHE 199 BIOFUELS FINAL PROJECT Gavin Chen
Production of Ethanol Page 14 of 15
Operation Expenditure-Calculation
BASIS 240,000
𝑙𝑏 𝐷𝑟𝑦 𝐶𝑜𝑟𝑛
ℎ𝑟
Annual Ethanol Production
240,000
𝑙𝑏 𝐷𝑟𝑦 𝐶𝑜𝑟𝑛
ℎ𝑟
𝑘𝑔
2.205 𝑙𝑏
0.3104 𝑘𝑔 𝐸𝑡ℎ𝑎𝑛𝑜𝑙
𝑘𝑔 𝐷𝑟𝑦 𝐶𝑜𝑟𝑛
𝑚3
789𝑘𝑔
264.1 𝑔𝑎𝑙
𝑚3
24 ℎ𝑟
𝑑𝑎𝑦
330 𝑑𝑎𝑦
𝑦𝑒𝑎𝑟
= 90,000,000
𝑔𝑎𝑙𝑙𝑜𝑛 𝐸𝑡ℎ𝑎𝑛𝑜𝑙
𝑦𝑒𝑎𝑟
Revenue from Ethanol
90,000,000
𝑔𝑎𝑙 𝐸𝑡ℎ𝑎𝑛𝑜𝑙
𝑦𝑒𝑎𝑟
$ 1.80 𝑈𝑆𝐷
𝑔𝑎𝑙𝑙𝑜𝑛 𝐸𝑡ℎ𝑎𝑛𝑜𝑙
= $162,000,000 𝑈𝑆𝐷
Annual Amount of Steam
90,000,000
𝑔𝑎𝑙 𝐸𝑡ℎ𝑎𝑛𝑜𝑙
𝑦𝑒𝑎𝑟
48,000 𝐵𝑡𝑢 𝑆𝑡𝑒𝑎𝑚
𝑔𝑎𝑙 𝐸𝑡ℎ𝑎𝑛𝑜𝑙
𝐵𝐻𝑃
33479 𝐵𝑡𝑢
34.5 𝑙𝑏
𝐵𝐻𝑃
= 4,500,000,000
𝑙𝑏 𝑆𝑡𝑒𝑎𝑚
𝑦𝑒𝑎𝑟
Annual Cost of Steam
4,500,000,000
𝑙𝑏 𝑆𝑡𝑒𝑎𝑚
𝑦𝑒𝑎𝑟
$3𝑈𝑆𝐷
1000 𝑙𝑏 𝑆𝑡𝑒𝑎𝑚
= $14,000,000 𝑈𝑆𝐷
Annual Amount of Corn Feedstock
280,000
𝑙𝑏 𝑐𝑜𝑟𝑛 𝑓𝑒𝑒𝑑𝑠𝑡𝑜𝑐𝑘
ℎ𝑟
24
𝑑𝑎𝑦
330 𝑑𝑎𝑦
𝑦𝑒𝑎𝑟
= 2,200,000,000
𝑙𝑏 𝑐𝑜𝑟𝑛 𝑓𝑒𝑒𝑑𝑠𝑡𝑜𝑐𝑘
𝑦𝑒𝑎𝑟
Annual Cost of Corn Feedstock
2,200,000,000
𝑙𝑏 𝑐𝑜𝑟𝑛 𝑓𝑒𝑒𝑑𝑠𝑡𝑜𝑐𝑘
𝑦𝑒𝑎𝑟
$0.057 𝑈𝑆𝐷
𝑙𝑏 𝑐𝑜𝑟𝑛 𝑓𝑒𝑒𝑑𝑠𝑡𝑜𝑐𝑘
= $126,000,000 𝑈𝑆𝐷
CHE 199 BIOFUELS FINAL PROJECT Gavin Chen
Production of Ethanol Page 15 of 15
Reference
Alexander, R.J. 1994. Corn Dry Milling: Processes, Products, and Applications. Pages 351 –
371 in: Corn Chemistry and Technology. Watson, S.A. and Ramstad, P.E. eds. American
Association of Cereal Chemist, St. Paul, MN
BBI International, 2003. “The Ethanol Plant Development Handbook,” Edition Four.
Jennifer Lyons and Charles W. White, III. "Process Equipment Cost Estimation Final Report.",
vol. U.S. Department of Energy National Energy Technology Laboratory, no. January 2002,
2002. Thys T. Dale and Wallace E. Tyner. "Economic and Technical Analysis of Ethanol Dry
Milling: Model user’s Manual." Agricultural Economics Department ,Purdue University, no.
Staff Paper # 06-05, 2006.
Jason R. Kwiatkowski ∗, Andrew J. McAloon, Frank Taylor, David B. Johnston. “Modeling the
process and costs of fuel ethanol production
by the corn dry-grind process.” , U.S. Department of Agriculture, Agricultural Research Service,
Eastern Regional Research Center,
600 East Mermaid Lane, Wyndmoor, PA 19038-8598, USA
Received 10 February 2005; accepted 25 August 2005
Musgrove, D., Dale, M.C. 2004. Feasibility Study for an Integrated Grain/Cellulose Ethanol
Plant in Arizona. Report to: USDA, Washington DC, (USDA 02-025-086019322).
Peters, M.S., Timmerhaus, K.D., and West, R.E. 2003. Plant Design and Economics for
Chemical Engineers. McGraw-Hill, New York, NY.
Robert Wooley, Mark Ruth, John Sheehan, and Kelly Ibsen, Henry Majdeski and Adrian Galvez.
"Lignocellulosic Biomass to Ethanol Process Design and Economics Utilizing Co-Current Dilute
Acid Prehydrolysis and Enzymatic Hydrolysis Current and Futuristic Scenario." Technical
Report, no. NREL/TP-580-26157, 1999.
Thys T. Dale and Wallace E. Tyner. "Economic and Technical Analysis of Ethanol Dry Milling:
Model user’s Manual." Agricultural Economics Department ,Purdue University, no. Staff Paper
# 06-05, 2006.

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Production of Ethanol by Gavin Chen

  • 1. CHE 199 BIOFUELS FINAL PROJECT Gavin Chen Production of Ethanol Page 1 of 15 Production of Ethanol with Corn Using Dry Milling Method Section Page Number Block Flow Diagram pg 2 Process Flow Diagram pg 3 Biological Pathway & Chemical Reactions pg 5 Mass and Energy Balance pg 6 Sizing a CSTR Fermenter pg 8 Piping and Instrumentation Diagram pg 9 Characterization of Streams pg 10 Hazard and Operability Study pg 11 Capital Expenditure pg 12 Operation Expenditure pg 13 Reference pg 15 Dec. 20th 2016 By Gavin Chen
  • 2. CHE 199 BIOFUELS FINAL PROJECT Gavin Chen Production of Ethanol Page 2 of 15 Block Flow Diagram The Dry Mill Process will happen in 4 basic steps The first process is the preprocessing process. In this step, the dry corn feedstock would be mashed into smaller particle sizes. Then the dry corn feedstock would be treated with fresh water for hydrolysis process. The second process is the liquefaction and the saccharification process. The hydrolyzed corn feedstock would be treated with hot steam through jet cooker. In the liquefaction step, the enzyme, Alpha Amylase, is added to perform saccharification for converting corn into glucose slurry. The third process is the fermentation process. The purpose of fermentation is to convert glucose slurry to alcohol slurry. Gluco Amylase and yeast are required for this process. The residence time of the glucose slurry should be between 50 to 60 hours, and it is determined to be 60 hours for maximum conversion. The forth process is the purification process. The alcohol slurry would be transferred to a distillation column. The desired ethanol would be vaporized to the overhead of the column. Then, the ethanol-water azeotrope would be further purify. The co-product, DDGS, would be dried and put to a storage.
  • 3. CHE 199 BIOFUELS FINAL PROJECT Gavin Chen Production of Ethanol Page 3 of 15 Process Flow Diagram This process begins by breaking the dry corn feedstock from the storage tank (TK-110) into smaller particle sizes through the Hammer Mill (V-410). Then the dry corn would be mixed with fresh water(TK-120) to perform hydrolysis in the cyclone (TK-130). The second step involves liquefaction and saccharification. The corn slurry from cyclone (TK- 130) would be transferred and heated through a steam jet cooker (E-210). This process approximately takes about 30 to 40 minutes and the slurry is heated to 70 degrees C. Then, the corn slurry is transferred to the liquefaction reactor (R-510) in order to convert corn slurry to glucose slurry. The required enzyme, Alpha Amylase, would be added from the tank (TK-140). The liquefaction process performs at the temperature between 85 to 95 degrees C. After the liquefaction process, the glucose slurry would be discharged into a knock-out drum (E-220) for the mash cooling process. When the temperature of the glucose slurry drops to 32 degrees C, the glucose slurry would be ready for the fermentation process. In the fermentation process (R-520), the entire process takes 60 hours for converting glucose slurry to alcohol slurry with the maximum yield. After the fermentation process, the next stage is the purification process. The alcohol slurry would be transferred to the distillation column (T-310). The desired ethanol-water azeotrope would be separated out in the overhead of the column through vaporization. The desired pure ethanol product would be stored in the tank (TK-160). The remaining slurry would be discharged from the bottom of the column. The ethanol-water azeotrope would be purified again through
  • 4. CHE 199 BIOFUELS FINAL PROJECT Gavin Chen Production of Ethanol Page 4 of 15 molecular sieves (T-320&T-330) for extracting out the majority of the water component. The remaining slurry would be transferred to the knock-out drum (V-430) through the centrifuge (V- 420). After the slurry gets dried, the DDGS would be stored in the cyclone (TK-170).
  • 5. CHE 199 BIOFUELS FINAL PROJECT Gavin Chen Production of Ethanol Page 5 of 15 Biological Pathway This report discusses the Dry Milling Method to produce Ethanol. The process begins by adding process water to the milled corn grains, adjusting the pH to about 6, and adding a thermostable Alpha Amylase. The following step is starch liquefaction. After the dry corn feedstock gets converted into glucose slurry by using thermal and pressure energy, the glucose slurry gets transferred into the reactor for fermentation. While fermenting, the yeast, Saccharomyces Cerevisiae, is added for ethanol production. The main reaction in the fermentation stage is given as 𝐶6 𝐻12 𝑂6 + 2𝑃𝑖 + 2𝐴𝐷𝑃 → 2𝐶2 𝐻5 𝑂𝐻 + 2𝐶𝑂2 + 2𝐴𝑇𝑃 + 2𝐻2 𝑂 𝐺𝑙𝑢𝑐𝑜𝑠𝑒 → 2 𝑒𝑡ℎ𝑎𝑛𝑜𝑙 + 2 𝑐𝑎𝑟𝑏𝑜𝑛 𝑑𝑖𝑜𝑥𝑖𝑑𝑒 + 𝑒𝑛𝑒𝑟𝑔𝑦 The theoretical yield is 0.511 𝑔 ethanol produced per gram glucose consumed. According to our references and the adjustments due to the current market, the conversion factor of kg ethanol produced per kg dry corn consumed is 0.3104. Our basis of corn feedstock is 1,000,000 metric tons of corn feedstock which contains 85% dry corn and 15% moisture. The following report discusses the process design of ethanol production starting with 1,000,000 metric tons of feedstock per hour as the initial mass flow rate to begin with.
  • 6. CHE 199 BIOFUELS FINAL PROJECT Gavin Chen Production of Ethanol Page 6 of 15 Mass and Energy Balance The theoretical yield of ethanol from starch: (𝐶6 𝐻10 𝑂5) 𝑛 + 𝐻2 𝑂 → 𝐶6 𝐻12 𝑂6 → 2𝐶2 𝐻5 𝑂𝐻 + 2𝐶𝑂2 Assumptions: 𝑆𝑡𝑎𝑟𝑐ℎ(𝑘𝑔) = 0.6 𝐷𝑟𝑦𝐶𝑜𝑟𝑛(𝑘𝑔) 90% ethanol yield 𝑌𝑒𝑎𝑠𝑡 = 0.0008(𝐺𝑙𝑢𝑐𝑜𝑠𝑒 𝑆𝑙𝑢𝑟𝑟𝑦) 𝐴𝑙𝑝ℎ𝑎 𝐴𝑚𝑦𝑙𝑎𝑠𝑒 = 0.0001(𝐷𝑟𝑦 𝑐𝑜𝑟𝑛) 𝑚 𝑦𝑒𝑎𝑠𝑡 = 172 𝑔/𝑚𝑜𝑙 Basis: 1,000,000 𝑚𝑒𝑡𝑟𝑖𝑐 𝑡𝑜𝑛 𝑦𝑒𝑎𝑟 𝐶𝑜𝑟𝑛 𝑓𝑒𝑒𝑑𝑠𝑡𝑜𝑐𝑘 𝑤𝑖𝑡ℎ 15% 𝑚𝑜𝑖𝑠𝑡𝑢𝑟𝑒 1,000,000 𝑚𝑒𝑡𝑟𝑖𝑐 𝑡𝑜𝑛 𝑦𝑒𝑎𝑟 1.10231 𝑡𝑜𝑛 𝑚𝑒𝑡𝑟𝑖𝑐 𝑡𝑜𝑛 2000 𝑙𝑏 𝑡𝑜𝑛 𝑦𝑒𝑎𝑟 330 𝑑𝑎𝑦 𝑑𝑎𝑦 24 ℎ𝑟 = 280,000 𝑙𝑏 ℎ𝑟 𝐶𝑜𝑟𝑛 𝐹𝑒𝑒𝑑𝑠𝑡𝑜𝑐𝑘 280,000 𝑙𝑏 ℎ𝑟 𝑐𝑜𝑟𝑛 ∗ (0.85) = 240,000 𝑙𝑏 ℎ𝑟 𝑑𝑟𝑦 𝑐𝑜𝑟𝑛 240,000 𝑙𝑏 ℎ𝑟 𝑑𝑟𝑦 𝑐𝑜𝑟𝑛 (0.617) = 150,000 𝑙𝑏 ℎ𝑟 𝑆𝑡𝑎𝑟𝑐ℎ = 68,000 𝑘𝑔 ℎ 𝑆𝑡𝑎𝑟𝑐ℎ = 380 𝑘𝑚𝑜𝑙 ℎ 𝑆𝑡𝑎𝑟𝑐ℎ Based on the stoichiometry: 380 𝑘𝑚𝑜𝑙 ℎ 𝑠𝑡𝑎𝑟𝑐ℎ + 380 𝑘𝑚𝑜𝑙 ℎ 𝑊𝑎𝑡𝑒𝑟 → 380 𝑀𝑀 𝑘𝑚𝑜𝑙 ℎ 𝑔𝑙𝑢𝑐𝑜𝑠𝑒 → 2(380 𝑘𝑚𝑜𝑙 ℎ 𝑒𝑡ℎ𝑎𝑛𝑜𝑙) + 2(380 𝑘𝑚𝑜𝑙 ℎ 𝐶𝑂2)
  • 7. CHE 199 BIOFUELS FINAL PROJECT Gavin Chen Production of Ethanol Page 7 of 15 Amount of water used in fermentation: 380 𝑘𝑚𝑜𝑙 ℎ 𝑤𝑎𝑡𝑒𝑟 = 6,900 𝑘𝑔 ℎ 𝑤𝑎𝑡𝑒𝑟 = 15,000 𝑙𝑏 ℎ 𝑤𝑎𝑡𝑒𝑟 = 30 𝑔𝑝𝑚 𝑤𝑎𝑡𝑒𝑟 Theoretical yield of glucose: 380 𝑘𝑚𝑜𝑙 𝑔𝑙𝑢𝑐𝑜𝑠𝑒 ℎ𝑟 = 69,000 𝑘𝑔 ℎ𝑟 𝑔𝑙𝑢𝑐𝑜𝑠𝑒 = 150,000 𝑙𝑏 ℎ𝑟 𝑔𝑙𝑢𝑐𝑜𝑠𝑒 Theoretical yield of ethanol and CO2: 2 (380 𝑘𝑚𝑜𝑙 ℎ 𝑒𝑡ℎ𝑎𝑛𝑜𝑙) = 760 𝑘𝑚𝑜𝑙 ℎ𝑟 𝑒𝑡ℎ𝑎𝑛𝑜𝑙 = 35,000 𝑘𝑔 ℎ 𝑒𝑡ℎ𝑎𝑛𝑜𝑙 = 77,000 𝑙𝑏 ℎ𝑟 𝑒𝑡ℎ𝑎𝑛𝑜𝑙 = 195 𝑔𝑝𝑚 𝑒𝑡ℎ𝑎𝑛𝑜𝑙 2 (380 𝑘𝑚𝑜𝑙 ℎ𝑟 𝐶𝑂2) = 760 𝑘𝑚𝑜𝑙 ℎ𝑟 𝐶𝑂2 = 34,000 𝑘𝑔 ℎ𝑟 𝐶𝑂2 = 74,000 𝑙𝑏 ℎ𝑟 𝐶𝑂2 Alpha Amylase Calculation: 0.0001 (280,000 𝑙𝑏 ℎ𝑟 𝐷𝑟𝑦 𝐶𝑜𝑟𝑛) = 28 𝑙𝑏 ℎ𝑟 𝐴𝑙𝑝ℎ𝑎 𝐴𝑚𝑦𝑙𝑎𝑠𝑒 Yeast Calculation: 0.0008 (28 𝑙𝑏 ℎ𝑟 𝐴𝑙𝑝ℎ𝑎 𝑎𝑚𝑦𝑙𝑎𝑠𝑒 + 150,000 𝑙𝑏 ℎ𝑟 𝑔𝑙𝑢𝑐𝑜𝑠𝑒 + 15,000 𝑙𝑏 ℎ𝑟 𝑤𝑎𝑡𝑒𝑟) = 140 𝑙𝑏 ℎ𝑟 𝑦𝑒𝑎𝑠𝑡 Theoretical Yield of Ethanol: 0.90 (77,000 𝑙𝑏 ℎ𝑟 ) = 69,000 𝑙𝑏 ℎ𝑟 𝑒𝑡ℎ𝑎𝑛𝑜𝑙 = 180 𝑔𝑝𝑚 𝑒𝑡ℎ𝑎𝑛𝑜𝑙 Amount of water outlet: 15,000 𝑙𝑏 ℎ𝑟 𝑤𝑎𝑡𝑒𝑟 − (0.90 ∗ 15,000 𝑙𝑏 ℎ𝑟 𝑤𝑎𝑡𝑒𝑟) = 1,500 𝑙𝑏 ℎ𝑟 𝑤𝑎𝑡𝑒𝑟 = 3 𝑔𝑝𝑚 𝑤𝑎𝑡𝑒𝑟 Amount of glucose outlet: 150,000 𝑙𝑏 ℎ𝑟 𝑔𝑙𝑢𝑐𝑜𝑠𝑒 − (0.90 ∗ 150,000 𝑙𝑏 ℎ𝑟 𝑔𝑙𝑢𝑐𝑜𝑠𝑒) = 15,000 𝑙𝑏 ℎ𝑟 𝑔𝑙𝑢𝑐𝑜𝑠𝑒 Total amount of beer slurry: 69,000 𝑙𝑏 𝑒𝑡ℎ𝑎𝑛𝑜𝑙 ℎ𝑟 + 15,000 𝑙𝑏 𝑤𝑎𝑡𝑒𝑟 ℎ𝑟 + 150,000 𝑙𝑏 𝑔𝑙𝑢𝑐𝑜𝑠𝑒 ℎ𝑟 + 28 𝑙𝑏 𝑎𝑙𝑝ℎ𝑎 𝑎𝑚𝑦𝑙𝑎𝑠𝑒 ℎ𝑟 + 140 𝑙𝑏 𝑦𝑒𝑎𝑠𝑡 ℎ𝑟 ≈ 230,000 𝑙𝑏 ℎ𝑟 𝑏𝑒𝑒𝑟 𝑠𝑙𝑢𝑟𝑟𝑦
  • 8. CHE 199 BIOFUELS FINAL PROJECT Gavin Chen Production of Ethanol Page 8 of 15 Sizing a CSTR Fermenter Calculations of Alcohol Slurry out of Fermenter 150,000 𝑙𝑏 𝑔𝑙𝑢𝑐𝑜𝑠𝑒 ℎ𝑟 𝑘𝑔 2.205 = 68,000 𝑘𝑔 𝑔𝑙𝑢𝑐𝑜𝑠𝑒 ℎ𝑟 𝑚3 1540 𝑘𝑔 𝑔𝑙𝑢𝑐𝑜𝑠𝑒 = 44 𝑚3 ℎ𝑟 𝑔𝑙𝑢𝑐𝑜𝑠𝑒 1,500 𝑙𝑏 𝑤𝑎𝑡𝑒𝑟 ℎ𝑟 𝑘𝑔 2.205 = 680 𝑘𝑔 𝑤𝑎𝑡𝑒𝑟 ℎ𝑟 𝑚3 1000 𝑘𝑔 𝑔𝑙𝑢𝑐𝑜𝑠𝑒 = 0.68 𝑚3 ℎ𝑟 𝑤𝑎𝑡𝑒𝑟 69,000 𝑙𝑏 𝑒𝑡ℎ𝑎𝑛𝑜𝑙 ℎ𝑟 𝑘𝑔 2.205 = 32,000 𝑘𝑔 𝑒𝑡ℎ𝑎𝑛𝑜𝑙 ℎ𝑟 𝑚3 789 𝑘𝑔 𝑒𝑡ℎ𝑎𝑛𝑜𝑙 = 40 𝑚3 ℎ𝑟 𝑒𝑡ℎ𝑎𝑛𝑜𝑙 Total Mass of Beer 68,000 𝑘𝑔 𝑔𝑙𝑢𝑐𝑜𝑠𝑒 ℎ𝑟 + 680 𝑘𝑔 𝑤𝑎𝑡𝑒𝑟 ℎ𝑟 + 32,000 𝑘𝑔 𝑒𝑡ℎ𝑎𝑛𝑜𝑙 ℎ𝑟 = 100,000 𝑘𝑔 𝑏𝑒𝑒𝑟 𝑠𝑙𝑢𝑟𝑟𝑦 ℎ𝑟 Total Volumetric Flow Rate 4 𝑚3 ℎ𝑟 𝑔𝑙𝑢𝑐𝑜𝑠𝑒 + 0.68 𝑚3 ℎ𝑟 𝑤𝑎𝑡𝑒𝑟 + 40 𝑚3 ℎ𝑟 𝑔𝑙𝑢𝑐𝑜𝑠𝑒 = 45 𝑚3 ℎ𝑟 𝑏𝑒𝑒𝑟 𝑠𝑙𝑢𝑟𝑟𝑦 Density of Beer Slurry 100,000 𝑘𝑔 𝑏𝑒𝑒𝑟 𝑠𝑙𝑢𝑟𝑟𝑦 ℎ𝑟 ℎ𝑟 45 𝑚3 = 2254 𝑘𝑔 𝑚3 𝑏𝑒𝑒𝑟 𝑠𝑙𝑢𝑟𝑟𝑦 GPM Flow Rate of Beer Slurry 100,000 𝑘𝑔 𝑏𝑒𝑒𝑟 𝑠𝑙𝑢𝑟𝑟𝑦 ℎ𝑟 𝑚3 2254 𝑘𝑔 𝑏𝑒𝑒𝑟 𝑠𝑙𝑢𝑟𝑟𝑦 264 𝑔𝑎𝑙 𝑚𝑖𝑛 ℎ𝑟 60 𝑚𝑖𝑛 = 197 gpm beer slurry Total Capacity needed for 60 hours Residence Time 197 𝑔𝑎𝑙𝑙𝑜𝑛 𝑏𝑒𝑒𝑟𝑦 𝑠𝑙𝑢𝑟𝑟𝑦 𝑚𝑖𝑛 60 𝑚𝑖𝑛 ℎ𝑟 60 ℎ𝑟 𝑟𝑒𝑠𝑖𝑑𝑒𝑛𝑐𝑒 𝑡𝑖𝑚𝑒 = 707,843 gallons of beer slurry_out 707,843 gallons # 𝑜𝑓 𝐶𝑆𝑇𝑅 𝐹𝑒𝑟𝑚𝑒𝑛𝑡𝑒𝑟𝑠 15,000 𝑔𝑎𝑙𝑙𝑜𝑛𝑠 ~ 47 𝐶𝑆𝑇𝑅 𝐹𝑒𝑟𝑚𝑒𝑛𝑡𝑒𝑟𝑠
  • 9. CHE 199 BIOFUELS FINAL PROJECT Gavin Chen Production of Ethanol Page 9 of 15 Piping and Instrumentation Diagram This is the P&ID of R-520 Fermenter. Overall, there are 4 loops for monitoring this fermenter. In Loop 1, we are detecting the flow rate of glucose slurry going in. In Loop 2, we are detecting the temperature of steam stream going into the jacket in order to control the flow of steam and to adjust the flow of condensate. In Loop 3, we are detecting the pressure of the CO2 gas product coming out from the fermenter. In Loop 4, we are detecting the leveling control in order to adjust the flow of the product stream going out from the fermenter. For the inlet and the outlet streams, 7” Schedule 40 Stainless Steel pipes are used for transferring the glucose slurry and the alcohol slurry. For the gas product stream, 4” Schedule 40 Stainless Steel pipe is used. For the steam streams, 4” Schedule 40 Stainless Steel pipes are used for the incoming steam and and the outgoing condensate.
  • 10. CHE 199 BIOFUELS FINAL PROJECT Gavin Chen Production of Ethanol Page 10 of 15 Characterization of Streams These testing methods have been taken from ASTM method. ASTM standards are used world wide to improve product quality, enhance safety. D887 (11.02) is a practice used for sampling water-formed deposits. E1758 (11.06) is test method for determination of carbohydrates in biomass by HPLC. D3048 (15.04) is test method for enzymes assay E346 (15.05) is test method for analysis of ethanol
  • 11. CHE 199 BIOFUELS FINAL PROJECT Gavin Chen Production of Ethanol Page 11 of 15 Hazard and Operability Study If reactor temperature is too high, set parameters. Fouled or failed exchanger tubes. Fire situation. Defective control valve. Internal Fires. Heating fluid/medium leaking. Faulty instrumentation and control. If higher pressure inside reactor happens, Surge problems for pump stop/starting or valve turning on/off. Relief valve isolated. Thermal overpressure. Boiling. Worst case, explosion. If reaching high level in reactor, reactor outlet blocked or isolated. Inflow greater than outflow. Faulty level measurement. Pressure surges for sudden change in the velocity of the fluids; caused by pump starting/stopping or valve opening/closing. If power outage happens, lightning, high winds, ice storms. Accidents at power plants and transmission lines.
  • 12. CHE 199 BIOFUELS FINAL PROJECT Gavin Chen Production of Ethanol Page 12 of 15 Capital Expenditure
  • 13. CHE 199 BIOFUELS FINAL PROJECT Gavin Chen Production of Ethanol Page 13 of 15 Operation Expenditure In the Operation Expenditure, we are estimating the overall costs of the entire operation of our Dry Milling Ethanol plant. The basis of the feedstock is 280,000 𝑙𝑏 𝐷𝑟𝑦 𝐶𝑜𝑟𝑛 ℎ𝑟 . As the kg-ethanol-to-kg-corn conversion factor given in the textbook, Biofuels Engineering Process Technology by C. Drapcho, N. Nhuan, and T. Walker, being applied, the annual production of ethanol is estimated to be 90,000,000 𝑔𝑎𝑙𝑙𝑜𝑛𝑠 𝐸𝑡ℎ𝑎𝑛𝑜𝑙 𝑦𝑒𝑎𝑟 . According to the price of ethanol from Nasdaq.com, one gallon of ethanol is sold for $1.80 USD. As result, the estimated annual revenue comes out to be around $162 million USD. The operating cost of steam is the major component in our budget. It takes 8 million dollars for having 330,000 lb/hr steam in supporting each of the 47 fermenters we have and 1 reactor for liquification over a year. The price of steam varies from $2 𝑈𝑆𝐷 1000 𝑙𝑏 𝑆𝑡𝑒𝑎𝑚 to $3 𝑈𝑆𝐷 1000 𝑙𝑏 𝑆𝑡𝑒𝑎𝑚 . Unit cost of enzymes is respectively high comparing to others. The costs of enzymes include the cost of Alpha Amylase in liquefaction, and the cost Glu Amylase in fermentation. The cost of maintenance is 5% of the CapEx. For the labor distribution, we plan to have 42 operators alternating 3 shifts a day. 14 engineers doing safety check, 14 engineers doing maintenance, and 7 operating manager. Due to the annual revenue, $162 millions USD, the operating cost, $155 millions USD, and the capital cost, $17 millions, can be balanced off as a result of having positive $8 million USD. The profit in 1st is estimated to be $7 millions USD.
  • 14. CHE 199 BIOFUELS FINAL PROJECT Gavin Chen Production of Ethanol Page 14 of 15 Operation Expenditure-Calculation BASIS 240,000 𝑙𝑏 𝐷𝑟𝑦 𝐶𝑜𝑟𝑛 ℎ𝑟 Annual Ethanol Production 240,000 𝑙𝑏 𝐷𝑟𝑦 𝐶𝑜𝑟𝑛 ℎ𝑟 𝑘𝑔 2.205 𝑙𝑏 0.3104 𝑘𝑔 𝐸𝑡ℎ𝑎𝑛𝑜𝑙 𝑘𝑔 𝐷𝑟𝑦 𝐶𝑜𝑟𝑛 𝑚3 789𝑘𝑔 264.1 𝑔𝑎𝑙 𝑚3 24 ℎ𝑟 𝑑𝑎𝑦 330 𝑑𝑎𝑦 𝑦𝑒𝑎𝑟 = 90,000,000 𝑔𝑎𝑙𝑙𝑜𝑛 𝐸𝑡ℎ𝑎𝑛𝑜𝑙 𝑦𝑒𝑎𝑟 Revenue from Ethanol 90,000,000 𝑔𝑎𝑙 𝐸𝑡ℎ𝑎𝑛𝑜𝑙 𝑦𝑒𝑎𝑟 $ 1.80 𝑈𝑆𝐷 𝑔𝑎𝑙𝑙𝑜𝑛 𝐸𝑡ℎ𝑎𝑛𝑜𝑙 = $162,000,000 𝑈𝑆𝐷 Annual Amount of Steam 90,000,000 𝑔𝑎𝑙 𝐸𝑡ℎ𝑎𝑛𝑜𝑙 𝑦𝑒𝑎𝑟 48,000 𝐵𝑡𝑢 𝑆𝑡𝑒𝑎𝑚 𝑔𝑎𝑙 𝐸𝑡ℎ𝑎𝑛𝑜𝑙 𝐵𝐻𝑃 33479 𝐵𝑡𝑢 34.5 𝑙𝑏 𝐵𝐻𝑃 = 4,500,000,000 𝑙𝑏 𝑆𝑡𝑒𝑎𝑚 𝑦𝑒𝑎𝑟 Annual Cost of Steam 4,500,000,000 𝑙𝑏 𝑆𝑡𝑒𝑎𝑚 𝑦𝑒𝑎𝑟 $3𝑈𝑆𝐷 1000 𝑙𝑏 𝑆𝑡𝑒𝑎𝑚 = $14,000,000 𝑈𝑆𝐷 Annual Amount of Corn Feedstock 280,000 𝑙𝑏 𝑐𝑜𝑟𝑛 𝑓𝑒𝑒𝑑𝑠𝑡𝑜𝑐𝑘 ℎ𝑟 24 𝑑𝑎𝑦 330 𝑑𝑎𝑦 𝑦𝑒𝑎𝑟 = 2,200,000,000 𝑙𝑏 𝑐𝑜𝑟𝑛 𝑓𝑒𝑒𝑑𝑠𝑡𝑜𝑐𝑘 𝑦𝑒𝑎𝑟 Annual Cost of Corn Feedstock 2,200,000,000 𝑙𝑏 𝑐𝑜𝑟𝑛 𝑓𝑒𝑒𝑑𝑠𝑡𝑜𝑐𝑘 𝑦𝑒𝑎𝑟 $0.057 𝑈𝑆𝐷 𝑙𝑏 𝑐𝑜𝑟𝑛 𝑓𝑒𝑒𝑑𝑠𝑡𝑜𝑐𝑘 = $126,000,000 𝑈𝑆𝐷
  • 15. CHE 199 BIOFUELS FINAL PROJECT Gavin Chen Production of Ethanol Page 15 of 15 Reference Alexander, R.J. 1994. Corn Dry Milling: Processes, Products, and Applications. Pages 351 – 371 in: Corn Chemistry and Technology. Watson, S.A. and Ramstad, P.E. eds. American Association of Cereal Chemist, St. Paul, MN BBI International, 2003. “The Ethanol Plant Development Handbook,” Edition Four. Jennifer Lyons and Charles W. White, III. "Process Equipment Cost Estimation Final Report.", vol. U.S. Department of Energy National Energy Technology Laboratory, no. January 2002, 2002. Thys T. Dale and Wallace E. Tyner. "Economic and Technical Analysis of Ethanol Dry Milling: Model user’s Manual." Agricultural Economics Department ,Purdue University, no. Staff Paper # 06-05, 2006. Jason R. Kwiatkowski ∗, Andrew J. McAloon, Frank Taylor, David B. Johnston. “Modeling the process and costs of fuel ethanol production by the corn dry-grind process.” , U.S. Department of Agriculture, Agricultural Research Service, Eastern Regional Research Center, 600 East Mermaid Lane, Wyndmoor, PA 19038-8598, USA Received 10 February 2005; accepted 25 August 2005 Musgrove, D., Dale, M.C. 2004. Feasibility Study for an Integrated Grain/Cellulose Ethanol Plant in Arizona. Report to: USDA, Washington DC, (USDA 02-025-086019322). Peters, M.S., Timmerhaus, K.D., and West, R.E. 2003. Plant Design and Economics for Chemical Engineers. McGraw-Hill, New York, NY. Robert Wooley, Mark Ruth, John Sheehan, and Kelly Ibsen, Henry Majdeski and Adrian Galvez. "Lignocellulosic Biomass to Ethanol Process Design and Economics Utilizing Co-Current Dilute Acid Prehydrolysis and Enzymatic Hydrolysis Current and Futuristic Scenario." Technical Report, no. NREL/TP-580-26157, 1999. Thys T. Dale and Wallace E. Tyner. "Economic and Technical Analysis of Ethanol Dry Milling: Model user’s Manual." Agricultural Economics Department ,Purdue University, no. Staff Paper # 06-05, 2006.